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The anion of the title compound (NH4)[Au(C5H10NO2S)2].3.667H2O, has roughly linear coordination of the Au atom to the S atoms of the ligands [Au—S 2.2900 (13) Å, S—Au—S 178.47 (7)°]. The C—S...S—C torsion angle is 29.3 (2)°. The packing arrangement is determined by short Au...Au contacts [3.221 (1) Å] as well as hydrogen-bonding interactions between ligand carboxylate and amine functional groups, the ammonium countercation and water molecules of hydration. Bond lengths and angles are normal.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock global

fcf

Structure factor file (CIF format)
Contains datablock fr1038

CCDC reference: 129438

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