A Silver(I) Complex of a Tube-Shaped Hydrocarbon

Kammermeier, S.; Jones, P.G.; Dix, I.; Herges, R.

doi:10.1107/S0108270198002406

A Silver(I) Complex of a Tube-Shaped Hydrocarbon

S. Kammermeier, P. G. Jones, I. Dix and R. Herges

The bis[silver(I) trifluoromethanesulfonate] complex of the fully conjugated tubelike hydrocarbon 5,24:6,11:12,17:18,23-tetra[1,2]benzenotetrabenzo[a,e,i,m]cyclohexadecene crystallizes with two molecules of water and two of toluene, and thus has the formula [Ag₂(C₅₆H₃₂)(C₇H₈)₂(H₂O)₂](CF₃SO₃)₂. The formula unit of the latter displays inversion symmetry, the ligand itself approximate D_4h symmetry. Each Ag⁺ ion is coordinated by one carbon atom of each of two adjacent rings of the ligand, one water oxygen and one toluene C-C bond.

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A Silver(I) Complex of a Tube-Shaped Hydrocarbon

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	Crystallographic Information File (CIF) Contains datablocks hati, global
	Structure factor file (CIF format) Contains datablock fg1410