Buy article online - an online subscription or single-article purchase is required to access this article.
Download citation
Download citation
link to html
The MoVI atom in the title complex, [MoCl(C9H10BN6)(C12H10N2)2] or TpMo(NNPh2)2Cl, where Tp = HB(C3H3N2)3 and Ph = C6H5, has a distorted octahedral environment afforded by the facially coordinated Tp ligand, two terminal NNPh2 ligands and the chloro ligand. The bond distances Mo—N of 1.773 (3) and 1.780 (3) Å, N-N of 1.319 (4) and 1.312 (4) Å, and bond angles Mo—N-N of 167.1 (2) and 170.9 (3)°, in the Mo(NNPh2)2 moiety, together with the absence of pyramidalization on the N atoms remote from the Mo atom, are indicative of an extensive delocalization of the π-electron density throughout the Mo—N—N system.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks hbn, global

fcf

Structure factor file (CIF format)
Contains datablock hbn

CCDC reference: 129173

-1

Subscribe to Acta Crystallographica Section C: Structural Chemistry

The full text of this article is available to subscribers to the journal.

If you have already registered and are using a computer listed in your registration details, please email support@iucr.org for assistance.

Buy online

You may purchase this article in PDF and/or HTML formats. For purchasers in the European Community who do not have a VAT number, VAT will be added at the local rate. Payments to the IUCr are handled by WorldPay, who will accept payment by credit card in several currencies. To purchase the article, please complete the form below (fields marked * are required), and then click on `Continue'.
E-mail address* 
Repeat e-mail address* 
(for error checking) 

Format*   PDF (US $40)
In order for VAT to be shown for your country javascript needs to be enabled.

VAT number 
(non-UK EC countries only) 
Country* 
 

Terms and conditions of use
Contact us

Follow Acta Cryst. C
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds