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The title compound, μ-[1,4-phenylenebis(diphenylphosphino)]-P:P'-bis­[μ3-phenylmethylidyne­octacarbonyl-1κ2C,2κ3C,3κ3C-triangulo-tricobalt(3 CoCo)], [{Co3(CO)8(C7H5)}2(C30H24P2)], lies about an inversion centre and consists of two approximately tetrahedral Co3C units capped with phenyl groups, and linked by a 1,4-bis(diphenylphosphino)phenylene ligand which replaces an equatorial carbonyl group on each cluster unit. The apical phenyl substituents and a phenyl ring from each P atom are arranged such that steric repulsion within the molecule is minimized.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock pdum

sft

Structure factor file (SHELXL table format)
Supplementary material

CCDC reference: 128587

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