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The cyclic germanium (IV) imide thiolate, cyclo-tri-μ-imido-tris[bis(tert-butylthiolato-S)germanium], [Ge3{(CH3)3CS}6(NH)3], was synthesized and its absolute structure determined. The six-membered ring formed by the trimer has a greater non-planarity than the only other reported GeIV imide trimer. The Ge—N ring distances range from 1.755 (13) to 1.829 (12) Å and average 1.807 Å, and the Ge—S distances range from 2.171 (4) to 2.272 (5) Å and average 2.218 Å

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks pur42, global

fcf

Structure factor file (CIF format)
Contains datablock pur42

CCDC reference: 128020

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