A 3:1 Disordered Solid Solution of Di-μ-methoxo-O:O-bis[trimethoxooxomolybdenum(VI)] and Di-μ-methoxo-O:O-bis[chlorodimethoxooxomolybdenum(VI)]

Clegg, W.; Elsegood, M.R.J.; Errington, R.J.; Bakri, R.

doi:10.1107/S0108270196006257

A 3:1 Disordered Solid Solution of Di-μ-methoxo-O:O-bis[trimethoxooxomolybdenum(VI)] and Di-μ-methoxo-O:O-bis[chlorodimethoxooxomolybdenum(VI)]

W. Clegg, M. R. J. Elsegood, R. J. Errington and R. Bakri

The title structure, [Mo₂(CH₃O)₂]_0.75.[Mo₂Cl₂(CH₃O)₆(O)₂]_0.25, contains two crystallographically independent centrosymmetric molecules, each of which has a major disorder component of [MoO(OMe)₄]₂ and a minor component of [MoOCl(OMe)₃]₂ with a cis arrangement of chloro and oxo ligands. The oxo ligands lie in the `equatorial' plane of the metal atoms and bridging ligands. The methoxo bridges are markedly asymmetric as a consequence of the strong trans influence of the terminal oxo ligands compared with terminal methoxy ligands. Coordination of the Mo atom is distorted octahedral.

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A 3:1 Disordered Solid Solution of Di-μ-methoxo-O:O-bis[trimethoxooxomolybdenum(VI)] and Di-μ-methoxo-O:O-bis[chlorodimethoxooxomolybdenum(VI)]

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	Crystallographic Information File (CIF) Contains datablocks 1, global
	Structure factor file (CIF format) Contains datablock rje52