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The P-S bond in C13H10BrF2PS is somewhat shorter [1.9348 (11) Å] and the P-CF2Br bond longer [1.884 (3) Å] than standard values, which may reasonably be attributed to the halogen substituents. The conformation about the P-CF2Br bond is gauche.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks prolo, global

fcf

Structure factor file (CIF format)
Contains datablock prolo

CCDC reference: 126939

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