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metal-organic compounds
The title complex, [Mo2(OH)2(NO)2(C7H7)2(C10H15)2], was obtained in 19% isolated yield from the treatment of [Mo(NO)(CH2Ph)(OCMe3)(C10H15)] in tetrahydrofuran with H2 (276 kPa). A single-crystal X-ray crystallographic analysis confirmed its bimetallic nature, the near planarity of the central Mo2O2 core and the monohapticity of the CH2Ph ligands. The complex is diamagnetic (χM = −517 × 10−6 cm3 mol−1) at room temperature and its 1H NMR spectrum in C6D6 indicates that it exists as a mixture of isomers in this solution.
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