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This structure determination shows that in the two molybdenum complexes of the title, (I), [Mo(C2F3O2)(C3H5)(C12H8N2)(CO)2] and (II), [Mo(C2F3O2)(C4H7)(C12H8N2)(CO)2], the phenanthroline ligand is perpendicular to the molybdenum-dicarbonyl plane. This is in contrast to similar molybdenum complexes, where the ligand is in the plane.
Supporting information
| Crystallographic Information File (CIF) Contains datablocks I, II, global |
| Structure factor file (CIF format) Contains datablock I |
| Structure factor file (CIF format) Contains datablock mo2_15a |
CCDC references: 126205; 126206
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