journal menuBuy article online - an online subscription or single-article purchase is required to access this article.
metal-organic compounds
Triphenylstibine dihydroxide [alternative name: dihydroxytriphenylantimony(V)], [Sb(OH)2(C6H5)3], was synthesized by the oxidative hydrolysis of Et4N+[PhSbCl2Br]- in methanol. The dihydroxide was characterized by IR spectroscopy, mass spectrometry and X-ray diffraction. The molecule is monomeric with very slightly distorted trigonal bipyramidal geometry around Sb with two OH groups in axial positions [Sb-O 1.963 (6) and 2.079 (7), Sb-C 2.090 (13)-2.109 (19) Å, O-Sb-O 178.5 (5)°]
Subscribe to Acta Crystallographica Section C: Structural Chemistry
