Tricarbonyl(η5-2,4-dimethylpentadienyl)iron Tetrafluoroborate

Rheingold, A.L.; Haggerty, B.S.; Ma, H.; Ernst, R.D.

doi:10.1107/S010827019501465X

Tricarbonyl(η⁵-2,4-dimethylpentadienyl)iron Tetrafluoroborate

A. L. Rheingold, B. S. Haggerty, H. Ma and R. D. Ernst

The title compound, [Fe(C₇H₁₁)(CO)₃]BF₄, has been found to exist in the expected piano-stool geometry, except that the unique carbonyl ligand is tilted towards the dienyl ligand by about 25° relative to the other carbonyl ligands. As in the case of the [Co(C₅H₅)(C₇H₁₁)]⁺ cation, a large difference appears to exist between the internal C—C—C bond angles [129.1 (7) versus 122.1 (6)°] of the open dienyl ligand.

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Tricarbonyl(η⁵-2,4-dimethylpentadienyl)iron Tetrafluoroborate

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