4,9-Diazonia-1,12-dodecanediammonium Dilithium cyclo-Hexaphosphate Tetrahydrate

Gharbi, A.; Jouini, A.

doi:10.1107/S0108270196000558

4,9-Diazonia-1,12-dodecanediammonium Dilithium cyclo-Hexaphosphate Tetrahydrate

In (C₁₀H₃₀N₄)[Li₂(P₆O₁₈)].4H₂O, the [P₆O₁₈]^6- anion is located around the twofold axis. Two Li cations, in regular tetrahedral environments, are connected to the phosphoric anion by a short Li-P bonds of 3.074 (4) Å. An isolated eight-membered complex ring anion [Li₂(P₆O₁₈)(H₂O)₄]^4- of symmetry 2 is then formed. Hydrogen bonds from the water molecules link these anions in successive layers parallel to the bc plane. The cohesion between these layers is a result of hydrogen bonds from the long chain tetracation, [NH₃(CH₂)₃NH₂(CH₂)₄NH₂(CH₂)₃NH₃]⁴⁺.

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4,9-Diazonia-1,12-dodecanediammonium Dilithium cyclo-Hexaphosphate Tetrahydrate

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	Crystallographic Information File (CIF) Contains datablocks spermine, global
	Structure factor file (CIF format) Contains datablock spermine