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The cationic uranium complex, [UBr(H2O)8]3+, presents a tricapped trigonal prismatic structure in the solid state, with U-O distances (at T = 150 K) in the range 2.379 (8)-2.455 (8) Å and a U-Br bond length of 2.885 (2) Å, in addition to an extended network of intermolecular hydrogen-bonding interactions. The title compound is the first octaaqua complex to be structurally characterized for an actinide element.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, br1209

sft

Structure factor file (SHELXL table format)
Supplementary material

-1

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