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Hydrothermally prepared bis(methylammonium) heptamolybdate(VI) crystallizes in the monoclinic system (space group C2/c). Its structure was solved from conventional X-ray powder diffraction using the initial model of the molybdenum oxide layer from the known Tl2Mo7O22. Molybdenum coordination polyhedra are significantly distorted octahedra which form layers parallel to the bc plane. The methylammonium cations are incorporated between the layers.

Supporting information

rtv

Rietveld powder data file (CIF format)
Contains datablock structure(1)

cif

Crystallographic Information File (CIF)
Contains datablocks global, dma2MO7O22

hkl

Structure factor file (CIF format)
Contains datablock structure(1)

CCDC reference: 129154

-1

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