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The molecular structure of the title compound, [Zn(C7H9O5)2(H2O)2], shows the Zn atom coordinated by two monoanionic bidentate enolate ligands and two O atoms of water resulting in a pseudo-octahedral arrangement. The H atoms of the water molecules are oriented in such a way that one H atom forms an intramolecular hydrogen bond [H6B...O2(−x, −y, −z)], while the other H atom forms an intermolecular hydrogen bond [H6A...O3(1 − x, −y, −z)]. The intermolecular contacts link the molecules into stacks.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks 9509, ks9509

fcf

Structure factor file (CIF format)
Contains datablock zerorign

CCDC reference: 129153

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