(Pyrrolidine-N)[1-(2-thiophenyliminomethyl)-2-naphtholato(2-)-N,O,S]nickel(II)

In the title compound, [Ni(C₁₇H₁₁NOS)(C₄H₉N)], the coordination around the Ni atom is slightly distorted from square planar. Bond angles within the coordination square have values between 85.0 (1) and 94.8 (1)°. The Ni-S, Ni-O and average Ni-N distances are 2.139 (1), 1.841 (3) and 1.908 (4) Å, respectively. The best plane through the pyrrolidine ring is approximately perpendicular to the planes of the other rings present in the molecule.

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