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The crystal structure of the title compound, [ZnCl2(C7H10N2S)2], shows a discrete molecular structure with tetrahedral geometry around the zinc ion. The mean Zn-Cl and Zn-S distances are 2.259 (4) and 2.372 (4) Å, respectively. Bond angles around the zinc ion range from 102.8 (1) to 113.7 (1)°. Ring distances and angles in the ligand compare favorably with literature values of analogous compounds, and the mean C-S bond distance of 1.71 (1) Å is close to the average distance of 1.72 Å observed for several dialkylimidazolethione complexes of main group and transition metal halides.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock BD0437

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 128565

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