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The cation of the title compound, 3,5-bis(2-methylphenyl)-1,2,4-dithiazolylium hexafluoroarsenate(V), (C16H14NS2)+.[AsF6], has a central planar five-membered NCSSC ring with two o-tolyl substituents lying 29.11 (9)° out of this plane because of the steric hindrance of the methyl groups; the cation has a twofold rotation axis through the nitrogen atom and the mid-point of the S—S bond. Interionic interactions include short S...F and N...F contacts, but the cations are well separated with no S...S or N...S interactions.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks 1, global

fcf

Structure factor file (CIF format)
Contains datablock ajb44

CCDC reference: 127170

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