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The anhydrous form of a known tetramanganese cluster, which was previously isolated in its trihydrate form, has been prepared from a different starting material. The new complex, bis­(μ3-oxo)-1:2:4-κ3O;2:3:4κ3O-heptakis(μ-acetato)-1:2κ4O:O';1:4κ2O:O';2:3κ2O:O';2:4κ2O:O';3:4κ4O:O'- bis(2,2'-bipyridine)-1κ2N,N';3κ2N,N'-tetramanganese perchlorate, [Mn4(O)2(C2H3O2)7(C10H8N2)2]ClO4, crystallizes in the monoclinic space group C2/c, in a higher symmetry compared to the previous form. A crystallographic twofold axis passes through the centre of the molecule. The fundamental structure of the complex clearly resembles that of the form already reported.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, Mn4Cluster

hkl

Structure factor file (CIF format)
Supplementary material

CCDC reference: 126491

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