Bis(tetra-n-butylammonium) Bis[(4-cyanophenyl)dithiocarbimato(2–)-S,S']nickel(II)

Schougaard, S.B.; Pittelkow, T.; Krebs, F.; Larsen, S.; Sørensen, H.O.; Greve, D.R.; Bjørnholm, T.

doi:10.1107/S0108270197016971

Bis(tetra-n-butylammonium) Bis[(4-cyanophenyl)dithiocarbimato(2-)-S,S']nickel(II)

S. B. Schougaard, T. Pittelkow, F. Krebs, S. Larsen, H. O. Sørensen, D. R. Greve and T. Bjørnholm

The title compound, [N(C₄H₉)₄⁺]₂.[Ni(C₈H₄N₂S₂)₂]^2-, crystallizes with the Ni atom on a crystallographic inversion center. The phenyl rings of the ligands make an angle of 50.50 (5)° with the plane spanned by the central nickel-sulfur fragment. The bond lengths do not indicate that the formal negative charge on the dithiocarbimato moiety is delocalized into the phenyl ring.

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Bis(tetra-n-butylammonium) Bis[(4-cyanophenyl)dithiocarbimato(2-)-S,S']nickel(II)

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	Crystallographic Information File (CIF) Contains datablocks global, I
	Structure factor file (CIF format) Contains datablock fh421