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In the title compound, [Ni(C3H7NO)6](BF4)2, there are two independent [Ni(dmf)6]2+ cations, each with a crystallographically imposed centre of symmetry. Hydrogen-bonding interactions between the cations and BF4- anions allow the formation of polymeric chains.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks nitrs3, global

fcf

Structure factor file (CIF format)
Contains datablock nitrs3

CCDC reference: 129675

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