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The solid-state structure of the title compound, [Rh(C
26H
24P
2)(B
9H
10S)].0.5CH
2Cl
2, has a
nido cluster geometry but apparently, only a
closo electron count. This anomaly is rationalized in terms of long range
ortho-phenyl agostic C—H
Rh interactions.
Supporting information
| Crystallographic Information File (CIF) Contains datablocks andy4new, global |
| Structure factor file (CIF format) Contains datablock an4n |
CCDC reference: 128233
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