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crystal data
Indexed powder patterns are reported for triphenyl telluronium azide, cyanate, thiocyanate and selenocyanate. Crystal data are as follows: (C6H5)3TeN3, triclinic (reduced), a = 13.954 (8), b = 14.099 (11), c = 19.924 (15) Å, α = 72.84 (6), β = 81.70 (5), γ = 62.04 (5)°; (C6H5)3Te(NCO). ½CHCl3, triclinic (reduced), space group -P, a = 12.038 (6), b = 12.900 (12), c = 13.878 (10) Å, α = 95.83 (6), β = 114.73 (5), γ = 98.87 (6)°; (C6H5)3Te(NCS), triclinic (reduced) space group -P, a = 13.339 (12), b = 13.885 (10), c = 14.796 (11) Å, α = 82.53 (6), β = 76.53 (7), γ = 78.20 (7)°; (C6H5)I3Te(NCSe), orthorhombic, space group -Pbca, a = 15.86 (1), b = 20.48 (3) and c = 21.87 (2) Å. These data are the first reported for an organo-telluronium salt, R3TeX, where X is a simple, non-tellurium-containing anion.