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Crystal data of three compounds in the system SeO2–CuO have been determined from X-ray single-crystal and powder studies. CuSe2O5 is monoclinic, space group Cc or C2/c, with a = 12.254 (5), b = 4.858 (3), c = 7.960 (3) Å, β = 110.7 (1)°, Z = 4. CuSeO3 is monoclinic, space group P21/c, with a = 7.718 (2), b = 8.266 (3), c = 10.529 (3), β = 127.2 (2)°, Z = 8. Cu2SeO4 is cubic, space group P213 or P4232, with a = 8.928 (3) Å, Z = 8. Powder diffraction data are given for all three compounds.

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