Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807038214/ci2430sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536807038214/ci2430Isup2.hkl |
CCDC reference: 608875
3,5-Dibromosalicylaldehyde was prepared according to the literature method (Elzbieta et al., 1964). To a solution of 1,2-phenylenediamine (1 g) in pyridine (30 ml), one mole equivalent of 3,5-dibromosalicylaldehyde in pyridine (30 ml) was added slowly under continuous stirring and refluxed for 1 h. Then Ni(Ac)2 (10 mmol) in DMF (10 ml) was added and the solution were refluxed for 1 h. The hot solution was filtered and allowed to stand at room temperature undisturbed for about three weeks, resulting in yellow crystals.
The N-bound H atom was located in a difference map and refined with a N—H distance restraint of 0.86 (2) Å. C-bound H atoms were placed at calculated positions and refined using a riding model, with C—H = 0.93 Å and Uiso(H) = 1.2Ueq(C).
Crystal structure and properties of 1,2-N,N-disallicydene-phenylamineato nickel(II) has been reported (Wang et al., 2003). We report here the synthesis and crystal structure of bis[2-(3,5-dibromo-2-hydroxyphenyl) benzimidazole]nickel(II).
The asymmetric unit of the title compound consists of a half-molecule, with the NiII atom lying on a crystallographic twofold axis; the other half of the molecule is generated by the twofold axis (Fig. 1). The NiII atom exists in a distorted tetrahedral geometry (Table 1) and is coordinated by the O and one N atom each from two 3,5-dibromo-2-hydroxyphenyl benzimidazole ligands.
The crystal structure is stabilized by N—H···Br and N—H···O type hydrogen bonds which link the molecules into a chain along the b axis.
For ligand synthesis, see: Elzbieta et al. (1964). For a related structure, see: Wang et al. (2003).
Data collection: SMART (Bruker, 2000); cell refinement: SAINT (Bruker, 2000); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1997); software used to prepare material for publication: SHELXL97.
[Ni(C13H7Br2N2O)2] | Dx = 2.045 Mg m−3 |
Mr = 792.76 | Mo Kα radiation, λ = 0.71073 Å |
Tetragonal, I41/a | Cell parameters from 1302 reflections |
Hall symbol: -I 4ad | θ = 2.4–16.7° |
a = 12.4177 (14) Å | µ = 7.00 mm−1 |
c = 33.389 (6) Å | T = 292 K |
V = 5148.6 (12) Å3 | Block, yellow |
Z = 8 | 0.30 × 0.20 × 0.20 mm |
F(000) = 3056 |
Bruker SMART CCD area-detector diffractometer | 2510 independent reflections |
Radiation source: fine-focus sealed tube | 1324 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.127 |
φ and ω scans | θmax = 26.0°, θmin = 2.5° |
Absorption correction: multi-scan (SADABS; Bruker, 2000) | h = −15→9 |
Tmin = 0.228, Tmax = 0.335 | k = −15→14 |
13205 measured reflections | l = −41→41 |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.065 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.180 | H atoms treated by a mixture of independent and constrained refinement |
S = 0.95 | w = 1/[σ2(Fo2) + (0.0739P)2] where P = (Fo2 + 2Fc2)/3 |
2510 reflections | (Δ/σ)max = 0.001 |
172 parameters | Δρmax = 0.90 e Å−3 |
1 restraint | Δρmin = −0.48 e Å−3 |
[Ni(C13H7Br2N2O)2] | Z = 8 |
Mr = 792.76 | Mo Kα radiation |
Tetragonal, I41/a | µ = 7.00 mm−1 |
a = 12.4177 (14) Å | T = 292 K |
c = 33.389 (6) Å | 0.30 × 0.20 × 0.20 mm |
V = 5148.6 (12) Å3 |
Bruker SMART CCD area-detector diffractometer | 2510 independent reflections |
Absorption correction: multi-scan (SADABS; Bruker, 2000) | 1324 reflections with I > 2σ(I) |
Tmin = 0.228, Tmax = 0.335 | Rint = 0.127 |
13205 measured reflections |
R[F2 > 2σ(F2)] = 0.065 | 1 restraint |
wR(F2) = 0.180 | H atoms treated by a mixture of independent and constrained refinement |
S = 0.95 | Δρmax = 0.90 e Å−3 |
2510 reflections | Δρmin = −0.48 e Å−3 |
172 parameters |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Ni1 | 1.0000 | 0.2500 | 0.00587 (4) | 0.0486 (4) | |
Br1 | 0.69106 (11) | 0.20197 (9) | −0.08406 (3) | 0.0957 (5) | |
Br2 | 0.54458 (11) | 0.61501 (10) | −0.04228 (4) | 0.1101 (6) | |
N1 | 0.9689 (5) | 0.3813 (5) | 0.03615 (18) | 0.0519 (17) | |
C1 | 0.7060 (8) | 0.3281 (7) | −0.0523 (2) | 0.068 (3) | |
C2 | 0.6348 (8) | 0.4068 (8) | −0.0575 (3) | 0.069 (3) | |
H2 | 0.5784 | 0.3992 | −0.0756 | 0.083* | |
C3 | 0.6467 (8) | 0.5014 (8) | −0.0351 (3) | 0.073 (3) | |
C4 | 0.7292 (8) | 0.5120 (7) | −0.0096 (3) | 0.066 (2) | |
H4 | 0.7366 | 0.5759 | 0.0046 | 0.080* | |
C5 | 0.8040 (7) | 0.4306 (6) | −0.0038 (2) | 0.054 (2) | |
C6 | 0.7982 (7) | 0.3334 (7) | −0.0261 (2) | 0.054 (2) | |
C7 | 0.8901 (6) | 0.4497 (6) | 0.0259 (2) | 0.0455 (18) | |
C8 | 1.0267 (6) | 0.4270 (6) | 0.0663 (2) | 0.0498 (19) | |
C9 | 1.1152 (8) | 0.3939 (7) | 0.0879 (3) | 0.073 (3) | |
H9 | 1.1459 | 0.3267 | 0.0833 | 0.087* | |
C10 | 1.1577 (9) | 0.4622 (9) | 0.1164 (3) | 0.085 (3) | |
H10 | 1.2195 | 0.4418 | 0.1302 | 0.102* | |
C11 | 1.1105 (10) | 0.5600 (9) | 0.1249 (3) | 0.094 (3) | |
H11 | 1.1388 | 0.6018 | 0.1454 | 0.112* | |
C12 | 1.0223 (9) | 0.5978 (8) | 0.1038 (3) | 0.082 (3) | |
H12 | 0.9906 | 0.6641 | 0.1092 | 0.098* | |
C13 | 0.9851 (7) | 0.5306 (7) | 0.0744 (2) | 0.057 (2) | |
O1 | 0.8626 (5) | 0.2535 (4) | −0.02442 (16) | 0.0602 (15) | |
N2 | 0.8956 (6) | 0.5388 (6) | 0.0481 (2) | 0.0577 (18) | |
H2A | 0.867 (8) | 0.601 (5) | 0.052 (3) | 0.11 (4)* |
U11 | U22 | U33 | U12 | U13 | U23 | |
Ni1 | 0.0612 (10) | 0.0366 (8) | 0.0480 (7) | 0.0184 (7) | 0.000 | 0.000 |
Br1 | 0.1218 (10) | 0.0805 (8) | 0.0850 (7) | 0.0258 (7) | −0.0409 (7) | −0.0212 (6) |
Br2 | 0.1109 (10) | 0.0997 (9) | 0.1197 (10) | 0.0604 (8) | −0.0217 (7) | 0.0026 (7) |
N1 | 0.066 (4) | 0.033 (3) | 0.056 (4) | 0.014 (3) | 0.003 (3) | −0.001 (3) |
C1 | 0.085 (7) | 0.064 (6) | 0.056 (5) | 0.021 (5) | −0.005 (5) | −0.003 (4) |
C2 | 0.073 (6) | 0.073 (7) | 0.061 (5) | 0.020 (5) | −0.021 (4) | −0.004 (5) |
C3 | 0.082 (7) | 0.064 (6) | 0.072 (6) | 0.041 (5) | −0.003 (5) | 0.012 (5) |
C4 | 0.081 (7) | 0.058 (6) | 0.060 (5) | 0.027 (5) | 0.001 (5) | 0.005 (4) |
C5 | 0.067 (6) | 0.051 (5) | 0.042 (4) | 0.013 (4) | 0.000 (4) | −0.001 (4) |
C6 | 0.066 (6) | 0.051 (5) | 0.046 (4) | 0.013 (4) | 0.001 (4) | 0.009 (4) |
C7 | 0.059 (5) | 0.031 (4) | 0.047 (4) | 0.001 (4) | 0.017 (4) | 0.009 (3) |
C8 | 0.045 (5) | 0.055 (5) | 0.049 (4) | 0.006 (4) | 0.003 (4) | 0.010 (4) |
C9 | 0.091 (7) | 0.047 (5) | 0.080 (6) | −0.004 (5) | −0.007 (5) | 0.007 (5) |
C10 | 0.098 (8) | 0.098 (9) | 0.060 (6) | −0.018 (7) | −0.020 (5) | 0.004 (5) |
C11 | 0.118 (10) | 0.073 (8) | 0.090 (7) | 0.002 (7) | −0.015 (7) | −0.016 (6) |
C12 | 0.099 (8) | 0.057 (6) | 0.090 (7) | 0.001 (6) | −0.004 (6) | −0.021 (5) |
C13 | 0.070 (6) | 0.044 (5) | 0.057 (5) | 0.003 (4) | 0.010 (4) | −0.001 (4) |
O1 | 0.080 (4) | 0.038 (3) | 0.062 (3) | 0.016 (3) | −0.009 (3) | −0.005 (3) |
N2 | 0.067 (5) | 0.041 (4) | 0.065 (4) | 0.015 (4) | 0.006 (4) | −0.004 (3) |
Ni1—N1 | 1.957 (6) | C5—C7 | 1.480 (11) |
Ni1—N1i | 1.957 (6) | C6—O1 | 1.276 (9) |
Ni1—O1 | 1.984 (6) | C7—N2 | 1.333 (10) |
Ni1—O1i | 1.984 (6) | C8—C9 | 1.378 (11) |
Br1—C1 | 1.902 (9) | C8—C13 | 1.413 (11) |
Br2—C3 | 1.913 (8) | C9—C10 | 1.379 (12) |
N1—C7 | 1.340 (9) | C9—H9 | 0.93 |
N1—C8 | 1.359 (10) | C10—C11 | 1.378 (14) |
C1—C2 | 1.329 (11) | C10—H10 | 0.93 |
C1—C6 | 1.442 (12) | C11—C12 | 1.385 (15) |
C2—C3 | 1.400 (12) | C11—H11 | 0.93 |
C2—H2 | 0.93 | C12—C13 | 1.367 (12) |
C3—C4 | 1.338 (13) | C12—H12 | 0.93 |
C4—C5 | 1.385 (11) | C13—N2 | 1.421 (11) |
C4—H4 | 0.93 | N2—H2A | 0.86 (3) |
C5—C6 | 1.419 (11) | ||
N1—Ni1—N1i | 117.8 (4) | C5—C6—C1 | 113.3 (7) |
N1—Ni1—O1 | 94.4 (2) | N2—C7—N1 | 110.3 (7) |
N1i—Ni1—O1 | 116.8 (2) | N2—C7—C5 | 122.9 (7) |
N1—Ni1—O1i | 116.8 (2) | N1—C7—C5 | 126.7 (7) |
N1i—Ni1—O1i | 94.4 (2) | N1—C8—C9 | 133.1 (8) |
O1—Ni1—O1i | 118.7 (3) | N1—C8—C13 | 109.3 (7) |
C7—N1—C8 | 108.0 (6) | C9—C8—C13 | 117.5 (8) |
C7—N1—Ni1 | 122.7 (5) | C8—C9—C10 | 118.9 (9) |
C8—N1—Ni1 | 128.8 (5) | C8—C9—H9 | 120.6 |
C2—C1—C6 | 125.0 (8) | C10—C9—H9 | 120.6 |
C2—C1—Br1 | 117.9 (7) | C11—C10—C9 | 121.4 (10) |
C6—C1—Br1 | 117.0 (6) | C11—C10—H10 | 119.3 |
C1—C2—C3 | 118.5 (8) | C9—C10—H10 | 119.3 |
C1—C2—H2 | 120.8 | C10—C11—C12 | 122.1 (10) |
C3—C2—H2 | 120.8 | C10—C11—H11 | 119.0 |
C4—C3—C2 | 120.2 (8) | C12—C11—H11 | 119.0 |
C4—C3—Br2 | 121.0 (7) | C13—C12—C11 | 115.1 (9) |
C2—C3—Br2 | 118.8 (7) | C13—C12—H12 | 122.5 |
C3—C4—C5 | 122.0 (8) | C11—C12—H12 | 122.5 |
C3—C4—H4 | 119.0 | C12—C13—C8 | 124.9 (9) |
C5—C4—H4 | 119.0 | C12—C13—N2 | 131.6 (9) |
C4—C5—C6 | 120.9 (8) | C8—C13—N2 | 103.4 (7) |
C4—C5—C7 | 117.5 (7) | C6—O1—Ni1 | 125.3 (5) |
C6—C5—C7 | 121.6 (7) | C7—N2—C13 | 108.9 (7) |
O1—C6—C5 | 127.4 (8) | C7—N2—H2A | 145 (8) |
O1—C6—C1 | 119.3 (7) | C13—N2—H2A | 106 (8) |
N1i—Ni1—N1—C7 | −137.8 (6) | C6—C5—C7—N2 | −177.9 (7) |
O1—Ni1—N1—C7 | −14.4 (6) | C4—C5—C7—N1 | 179.3 (7) |
O1i—Ni1—N1—C7 | 110.9 (6) | C6—C5—C7—N1 | −1.4 (11) |
N1i—Ni1—N1—C8 | 51.4 (6) | C7—N1—C8—C9 | −179.7 (9) |
O1—Ni1—N1—C8 | 174.9 (6) | Ni1—N1—C8—C9 | −7.9 (13) |
O1i—Ni1—N1—C8 | −59.8 (7) | C7—N1—C8—C13 | −2.3 (8) |
C6—C1—C2—C3 | −2.4 (15) | Ni1—N1—C8—C13 | 169.5 (5) |
Br1—C1—C2—C3 | −178.2 (7) | N1—C8—C9—C10 | 178.0 (9) |
C1—C2—C3—C4 | 1.1 (14) | C13—C8—C9—C10 | 0.8 (12) |
C1—C2—C3—Br2 | −179.9 (7) | C8—C9—C10—C11 | 3.0 (15) |
C2—C3—C4—C5 | −1.2 (14) | C9—C10—C11—C12 | −3.9 (17) |
Br2—C3—C4—C5 | 179.8 (6) | C10—C11—C12—C13 | 0.8 (16) |
C3—C4—C5—C6 | 2.5 (13) | C11—C12—C13—C8 | 3.3 (15) |
C3—C4—C5—C7 | −178.2 (8) | C11—C12—C13—N2 | 177.0 (9) |
C4—C5—C6—O1 | 178.4 (8) | N1—C8—C13—C12 | 178.1 (8) |
C7—C5—C6—O1 | −0.9 (13) | C9—C8—C13—C12 | −4.1 (13) |
C4—C5—C6—C1 | −3.3 (11) | N1—C8—C13—N2 | 2.9 (8) |
C7—C5—C6—C1 | 177.4 (7) | C9—C8—C13—N2 | −179.3 (7) |
C2—C1—C6—O1 | −178.1 (9) | C5—C6—O1—Ni1 | −7.4 (11) |
Br1—C1—C6—O1 | −2.3 (10) | C1—C6—O1—Ni1 | 174.4 (6) |
C2—C1—C6—C5 | 3.4 (13) | N1—Ni1—O1—C6 | 12.9 (6) |
Br1—C1—C6—C5 | 179.2 (6) | N1i—Ni1—O1—C6 | 137.1 (6) |
C8—N1—C7—N2 | 0.7 (8) | O1i—Ni1—O1—C6 | −111.0 (6) |
Ni1—N1—C7—N2 | −171.7 (5) | N1—C7—N2—C13 | 1.1 (8) |
C8—N1—C7—C5 | −176.1 (7) | C5—C7—N2—C13 | 178.1 (7) |
Ni1—N1—C7—C5 | 11.5 (10) | C12—C13—N2—C7 | −177.1 (9) |
C4—C5—C7—N2 | 2.8 (11) | C8—C13—N2—C7 | −2.4 (8) |
Symmetry code: (i) −x+2, −y+1/2, z. |
D—H···A | D—H | H···A | D···A | D—H···A |
N2—H2A···Br1ii | 0.86 (3) | 2.74 (7) | 3.464 (7) | 143 (9) |
N2—H2A···O1ii | 0.86 (3) | 2.11 (8) | 2.811 (9) | 138 (9) |
Symmetry code: (ii) x, y+1/2, −z. |
Experimental details
Crystal data | |
Chemical formula | [Ni(C13H7Br2N2O)2] |
Mr | 792.76 |
Crystal system, space group | Tetragonal, I41/a |
Temperature (K) | 292 |
a, c (Å) | 12.4177 (14), 33.389 (6) |
V (Å3) | 5148.6 (12) |
Z | 8 |
Radiation type | Mo Kα |
µ (mm−1) | 7.00 |
Crystal size (mm) | 0.30 × 0.20 × 0.20 |
Data collection | |
Diffractometer | Bruker SMART CCD area-detector |
Absorption correction | Multi-scan (SADABS; Bruker, 2000) |
Tmin, Tmax | 0.228, 0.335 |
No. of measured, independent and observed [I > 2σ(I)] reflections | 13205, 2510, 1324 |
Rint | 0.127 |
(sin θ/λ)max (Å−1) | 0.617 |
Refinement | |
R[F2 > 2σ(F2)], wR(F2), S | 0.065, 0.180, 0.95 |
No. of reflections | 2510 |
No. of parameters | 172 |
No. of restraints | 1 |
H-atom treatment | H atoms treated by a mixture of independent and constrained refinement |
Δρmax, Δρmin (e Å−3) | 0.90, −0.48 |
Computer programs: SMART (Bruker, 2000), SAINT (Bruker, 2000), SAINT, SHELXS97 (Sheldrick, 1997), SHELXL97 (Sheldrick, 1997), SHELXTL (Bruker, 1997), SHELXL97.
Ni1—N1 | 1.957 (6) | Ni1—O1 | 1.984 (6) |
N1—Ni1—N1i | 117.8 (4) | N1—Ni1—O1i | 116.8 (2) |
N1—Ni1—O1 | 94.4 (2) | O1—Ni1—O1i | 118.7 (3) |
Symmetry code: (i) −x+2, −y+1/2, z. |
D—H···A | D—H | H···A | D···A | D—H···A |
N2—H2A···Br1ii | 0.86 (3) | 2.74 (7) | 3.464 (7) | 143 (9) |
N2—H2A···O1ii | 0.86 (3) | 2.11 (8) | 2.811 (9) | 138 (9) |
Symmetry code: (ii) x, y+1/2, −z. |
Crystal structure and properties of 1,2-N,N-disallicydene-phenylamineato nickel(II) has been reported (Wang et al., 2003). We report here the synthesis and crystal structure of bis[2-(3,5-dibromo-2-hydroxyphenyl) benzimidazole]nickel(II).
The asymmetric unit of the title compound consists of a half-molecule, with the NiII atom lying on a crystallographic twofold axis; the other half of the molecule is generated by the twofold axis (Fig. 1). The NiII atom exists in a distorted tetrahedral geometry (Table 1) and is coordinated by the O and one N atom each from two 3,5-dibromo-2-hydroxyphenyl benzimidazole ligands.
The crystal structure is stabilized by N—H···Br and N—H···O type hydrogen bonds which link the molecules into a chain along the b axis.