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In the title compound, [Ni(C7H3NO4)(C6H16N2)(H2O)]·2.5H2O, the discrete neutral [Ni(dpc)(dien)(H2O)] (dien is diethyl­ethylenediamine and dpc is dipicolinate) complex lies on a mirror plane. The NiII ion is coordinated by the dpc ligand through the pyridine N atom and one O atom of each carboxyl­ate group, an aqua ligand and two N atoms of the bidentate dien ligand, forming a distorted octa­hedral geometry. One of the C atoms of the ethyl­enediamine group is disordered across the mirror plane. The symmetry-independent ethyl group is disordered over two orientations with equal occupancy. The complex mol­ecules are connected via O—H...O and N—H...O inter­molecular hydrogen-bonding inter­actions.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807038196/ci2403sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536807038196/ci2403Isup2.hkl
Contains datablock I

CCDC reference: 660096

Key indicators

  • Single-crystal X-ray study
  • T = 297 K
  • Mean [sigma](C-C) = 0.003 Å
  • H-atom completeness 85%
  • Disorder in main residue
  • R factor = 0.046
  • wR factor = 0.123
  • Data-to-parameter ratio = 13.5

checkCIF/PLATON results

No syntax errors found



Alert level A PLAT306_ALERT_2_A Isolated Oxygen Atom (H-atoms Missing ?) ....... O4
Author Response: H atoms on O4 could not be reliably located from the difference map.

Alert level B PLAT245_ALERT_2_B U(iso) H5 Smaller than U(eq) O5 by ... 0.06 AngSq PLAT430_ALERT_2_B Short Inter D...A Contact O3 .. O4 .. 2.80 Ang. PLAT430_ALERT_2_B Short Inter D...A Contact O4 .. O4 .. 2.60 Ang.
Alert level C CHEMW03_ALERT_2_C The ratio of given/expected molecular weight as calculated from the _atom_site* data lies outside the range 0.99 <> 1.01 From the CIF: _cell_formula_units_Z 8 From the CIF: _chemical_formula_weight 403.08 TEST: Calculate formula weight from _atom_site_* atom mass num sum C 12.01 13.00 156.14 H 1.01 22.00 22.18 N 14.01 3.00 42.02 O 16.00 7.50 119.99 Ni 58.69 1.00 58.69 Calculated formula weight 399.02 DENSD01_ALERT_1_C The ratio of the submitted crystal density and that calculated from the formula is outside the range 0.99 <> 1.01 Crystal density given = 1.457 Calculated crystal density = 1.472 PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings Differ .... ? PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT043_ALERT_1_C Check Reported Molecular Weight ................ 403.08 PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............ 0.50 Ratio PLAT046_ALERT_1_C Reported Z, MW and D(calc) are Inconsistent .... 1.47 PLAT128_ALERT_4_C Non-standard setting of Space group Ibam .... Imcb PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.42 Ratio PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for C23B PLAT245_ALERT_2_C U(iso) H22A Smaller than U(eq) C23B by ... 0.02 AngSq PLAT301_ALERT_3_C Main Residue Disorder ......................... 19.00 Perc. PLAT369_ALERT_2_C Long C(sp2)-C(sp2) Bond C1 - C2 ... 1.53 Ang.
Alert level G FORMU01_ALERT_2_G There is a discrepancy between the atom counts in the _chemical_formula_sum and the formula from the _atom_site* data. Atom count from _chemical_formula_sum:C13 H26 N3 Ni1 O7.5 Atom count from the _atom_site data: C13 H22 N3 Ni1 O7.5 CELLZ01_ALERT_1_G Difference between formula and atom_site contents detected. CELLZ01_ALERT_1_G WARNING: H atoms missing from atom site list. Is this intentional? From the CIF: _cell_formula_units_Z 8 From the CIF: _chemical_formula_sum C13 H26 N3 Ni O7.50 TEST: Compare cell contents of formula and atom_site data atom Z*formula cif sites diff C 104.00 104.00 0.00 H 208.00 176.00 32.00 N 24.00 24.00 0.00 Ni 8.00 8.00 0.00 O 60.00 60.00 0.00 PLAT860_ALERT_3_G Note: Number of Least-Squares Restraints ....... 38
1 ALERT level A = In general: serious problem 3 ALERT level B = Potentially serious problem 13 ALERT level C = Check and explain 4 ALERT level G = General alerts; check 8 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 9 ALERT type 2 Indicator that the structure model may be wrong or deficient 3 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Comment top

Pyridine-2,6-dicarboxylic acid, known as dipicolinic acid (H2dpc), is a versatile ligand and it can function as a neutral, mono basic or dibasic tridentate chelating ligand (Nathan & Mai, 2000; Perry et al., 2004). Having potential donor oxygen and nitrogen atoms, dipicolinic acid has attracted the scientist from the coordination chemistry and number of studies have been carried out with dipicolinate (dpc) ligand by both inorganic and bioinorganic chemists during the past few years (Krillova et al., 2007). Dipicolinates commonly coordinate to transition metals by either carboxylate bridges between metal centres, to form polymeric (Ma et al., 2003) or dimeric complexes (Ramezaniopour et al., 2005), or tridentate (O, N, O') chelation to one metal ion (Okabe & Oya, 2000). The dipicolinate ligand with NiII ions commonly has one or two coordination modes. In one coordination mode, a single planar dpc ligand binds in the equatorial plane of a NiII cation and other ligands such as H2O or pyridine based heterocycles occupy the remaining sites, thereby forming square pyramidal or octahedral coordination geometry (Liu et al., 2006; Zhang et al., 2003), or two planar dpc molecules coordinate perpendicularly generating a distorted octahedral coordination geometry (Park et al., 2007). In our ongoing research on determination of further coordination modes of chelates of dipicolinic acid with biologically important transition metal ions, we have recently synthesized mixed-ligand metal(II) complexes of dipicolinic acid and their structures have been reported (Uçar et al., 2005; Uçar et al., 2007). As a continuation of these studies, we have now prepared and characterized a new NiII complex containing dipicolinate anion together with diethylethylenediamine (dien)ligand, namely [Ni(dien)(dpc)(H2O)].2.5H2O.

The asymmetric unit of the title compound consists of one-half of a discrete neutral [Ni(dien)(dpc)(H2O)] unit and 1.25 lattice water molecules. The [Ni(dien)(dpc)(H2O)] unit lies across a mirror plane with atoms Ni1, N1, N2, N3, C4 and C5 on the mirror plane. Atom C6 is disordered over two positions across the mirror plane (Fig. 1). The H2dpc is deprotoned during the reaction and acts as a tridentate ligand. The NiII ion is six-coordinated in a distorted octahedral geometry, with one N (N3) two O atoms of the tridentate dpc dianion and one N atom from the dien (N1) ligand composing the basal plane, and the aqua O atom and the other N atom (N2) of the dien ligand occuping the axial sites.

The fact that the Ni1—Ndpc [1.986 (3) Å] length is significantly shorter than Ni1—Ndien [2.070 (3) and 2.122 (3)] bond lengths indicates that atom N3 is the strongest site, because the two carboxylate groups in ortho positions enhance the basicity of this atom. The Ni1—Ndpc, Ni1—Odpc [2.145 (2) Å] and Ni1—Oaqua [2.070 (2) Å] bond lengths in the title complex are slightly different from those observed in previously reported mixed-ligand nickel(II) dipicolinate complexes (Ramadevi et al., 2005; Liu et al., 2006; Park et al., 2007). The dpc chelate angle is 77.79 (10)°, which is comparable to that found in other dipicolinate-metal complexes (Chaigneau et al., 2004; Altin et al., 2004).

The crystal packing is stabilized by intermolecular O—H···O and N—H···O hydrogen bonds, involving the oxygen atoms of coordinated and free water molecules (see Table 2 and Fig. 2).

Related literature top

For related literature, see: Altin et al. (2004); Chaigneau et al. (2004); Krillova et al. (2007); Liu et al. (2006); Ma et al. (2003); Nathan & Mai (2000); Okabe & Oya (2000); Park et al. (2007); Perry et al. (2004); Ramadevi et al. (2005); Ramezaniopour et al. (2005); Uçar et al. (2005, 2007); Zhang et al. (2003).

Experimental top

To an ethanol/water (30 ml, 1:1) containing NiCl24H2O (1 mmol) and disodium dipicolinate (1 mmol), dien (1 mmol) was added slowly with continuous stirring. The resulting solution was refluxed for 1 h and then filtered. The green filtrate was allowed to stand for about two weeks at room temperature, after which time light-green crystals of the title compound suitable for X-ray diffraction analysis were collected.

Refinement top

Atoms Ni1, N1, N2, N3, C4 and C5 lie on the crystallographic mirror plane. Atom C6 is disordered across the mirror plane and as a result the occupancy factor for the disordered components were fixed at 0.50 each. The independent ethyl group is disordered over two orientations with equal occupancy. The corresponding N—C and C—C distances involving the disorder components were restrained to be equal. In the ethyl group, the components of the displacement parameters in the direction of the bond were restrained to be equal. The displacement parameters of atoms C22A, C23A, C22B, C23B and O4 were restrained to approximate isotropic behaviour. The N1—C6 distance was restrained to 1.45 (1) Å. H atoms of the coordinated water molecule were located in a difference map and refined with O—H and H···H distances restrained to 0.84 (1) and 1.37 (2) Å, respectively. H atoms on O5 and N2 were located in a difference map and refined freely. H atoms on O5 are disordered over two positions. H atoms on one of the free water molecules (O4) could not be located from the difference map. H atoms attached to C atoms were placed at calculated positions (C—H = 0.93–0.97 Å) and were allowed to ride on the parent atom [Uiso(H) = 1.2–1.5Ueq(C)].

Structure description top

Pyridine-2,6-dicarboxylic acid, known as dipicolinic acid (H2dpc), is a versatile ligand and it can function as a neutral, mono basic or dibasic tridentate chelating ligand (Nathan & Mai, 2000; Perry et al., 2004). Having potential donor oxygen and nitrogen atoms, dipicolinic acid has attracted the scientist from the coordination chemistry and number of studies have been carried out with dipicolinate (dpc) ligand by both inorganic and bioinorganic chemists during the past few years (Krillova et al., 2007). Dipicolinates commonly coordinate to transition metals by either carboxylate bridges between metal centres, to form polymeric (Ma et al., 2003) or dimeric complexes (Ramezaniopour et al., 2005), or tridentate (O, N, O') chelation to one metal ion (Okabe & Oya, 2000). The dipicolinate ligand with NiII ions commonly has one or two coordination modes. In one coordination mode, a single planar dpc ligand binds in the equatorial plane of a NiII cation and other ligands such as H2O or pyridine based heterocycles occupy the remaining sites, thereby forming square pyramidal or octahedral coordination geometry (Liu et al., 2006; Zhang et al., 2003), or two planar dpc molecules coordinate perpendicularly generating a distorted octahedral coordination geometry (Park et al., 2007). In our ongoing research on determination of further coordination modes of chelates of dipicolinic acid with biologically important transition metal ions, we have recently synthesized mixed-ligand metal(II) complexes of dipicolinic acid and their structures have been reported (Uçar et al., 2005; Uçar et al., 2007). As a continuation of these studies, we have now prepared and characterized a new NiII complex containing dipicolinate anion together with diethylethylenediamine (dien)ligand, namely [Ni(dien)(dpc)(H2O)].2.5H2O.

The asymmetric unit of the title compound consists of one-half of a discrete neutral [Ni(dien)(dpc)(H2O)] unit and 1.25 lattice water molecules. The [Ni(dien)(dpc)(H2O)] unit lies across a mirror plane with atoms Ni1, N1, N2, N3, C4 and C5 on the mirror plane. Atom C6 is disordered over two positions across the mirror plane (Fig. 1). The H2dpc is deprotoned during the reaction and acts as a tridentate ligand. The NiII ion is six-coordinated in a distorted octahedral geometry, with one N (N3) two O atoms of the tridentate dpc dianion and one N atom from the dien (N1) ligand composing the basal plane, and the aqua O atom and the other N atom (N2) of the dien ligand occuping the axial sites.

The fact that the Ni1—Ndpc [1.986 (3) Å] length is significantly shorter than Ni1—Ndien [2.070 (3) and 2.122 (3)] bond lengths indicates that atom N3 is the strongest site, because the two carboxylate groups in ortho positions enhance the basicity of this atom. The Ni1—Ndpc, Ni1—Odpc [2.145 (2) Å] and Ni1—Oaqua [2.070 (2) Å] bond lengths in the title complex are slightly different from those observed in previously reported mixed-ligand nickel(II) dipicolinate complexes (Ramadevi et al., 2005; Liu et al., 2006; Park et al., 2007). The dpc chelate angle is 77.79 (10)°, which is comparable to that found in other dipicolinate-metal complexes (Chaigneau et al., 2004; Altin et al., 2004).

The crystal packing is stabilized by intermolecular O—H···O and N—H···O hydrogen bonds, involving the oxygen atoms of coordinated and free water molecules (see Table 2 and Fig. 2).

For related literature, see: Altin et al. (2004); Chaigneau et al. (2004); Krillova et al. (2007); Liu et al. (2006); Ma et al. (2003); Nathan & Mai (2000); Okabe & Oya (2000); Park et al. (2007); Perry et al. (2004); Ramadevi et al. (2005); Ramezaniopour et al. (2005); Uçar et al. (2005, 2007); Zhang et al. (2003).

Computing details top

Data collection: X-AREA (Stoe & Cie, 2002); cell refinement: X-AREA; data reduction: X-RED32 (Stoe & Cie, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEP-3 (Farrugia, 1997); software used to prepare material for publication: WinGX (Farrugia, 1999).

Figures top
[Figure 1] Fig. 1. The structure of [Ni(C7H3NO4)(C6H16N2)(H2O)] complex in the title compound. Displacement ellipsoids are drawn at the 30% probability level. Atoms Ni1, N1, N2, N3, C4 and C5 lie on a crystallographic mirror plane. Only one component of the disordered ethyl group is shown. Hydrogen atoms have been omitted for clarity. Symmetry code: (i) -x, y, z.
[Figure 2] Fig. 2. The crystal packing of the title compound, viewed down the a axis. Hydrogen bonds are shown as dashed lines.
Aqua(N,N-diethylethylenediamine-κ2N,N')(pyridine-2,6-\ dicarboxylato-κ3N,O,O')nickel(II) 2.5-hydrate top
Crystal data top
[Ni(C7H3NO4)(C6H16N2)(H2O)]·2.5H2OF(000) = 1672.0
Mr = 403.08Dx = 1.457 Mg m3
Orthorhombic, ImcbMo Kα radiation, λ = 0.71069 Å
Hall symbol: -I 2a 2Cell parameters from 1657 reflections
a = 11.268 (4) Åθ = 1.7–27.2°
b = 14.141 (5) ŵ = 1.11 mm1
c = 22.831 (12) ÅT = 297 K
V = 3638 (3) Å3Prism, light green
Z = 80.42 × 0.30 × 0.25 mm
Data collection top
Stoe IPDS2
diffractometer
2120 independent reflections
Radiation source: fine-focus sealed tube1926 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.047
Detector resolution: 6.67 pixels mm-1θmax = 27.2°, θmin = 1.7°
ω scansh = 1414
Absorption correction: integration
(X-RED32; Stoe & Cie, 2002)
k = 1818
Tmin = 0.925, Tmax = 0.974l = 2929
28305 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.046Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.123H atoms treated by a mixture of independent and constrained refinement
S = 1.18 w = 1/[σ2(Fo2) + (0.0761P)2 + 2.2047P]
where P = (Fo2 + 2Fc2)/3
2120 reflections(Δ/σ)max = 0.001
157 parametersΔρmax = 0.41 e Å3
38 restraintsΔρmin = 1.12 e Å3
Crystal data top
[Ni(C7H3NO4)(C6H16N2)(H2O)]·2.5H2OV = 3638 (3) Å3
Mr = 403.08Z = 8
Orthorhombic, ImcbMo Kα radiation
a = 11.268 (4) ŵ = 1.11 mm1
b = 14.141 (5) ÅT = 297 K
c = 22.831 (12) Å0.42 × 0.30 × 0.25 mm
Data collection top
Stoe IPDS2
diffractometer
2120 independent reflections
Absorption correction: integration
(X-RED32; Stoe & Cie, 2002)
1926 reflections with I > 2σ(I)
Tmin = 0.925, Tmax = 0.974Rint = 0.047
28305 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.04638 restraints
wR(F2) = 0.123H atoms treated by a mixture of independent and constrained refinement
S = 1.18Δρmax = 0.41 e Å3
2120 reflectionsΔρmin = 1.12 e Å3
157 parameters
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
C10.2093 (2)0.13012 (16)0.29423 (11)0.0402 (5)
C20.10328 (19)0.14295 (16)0.33506 (10)0.0392 (5)
C30.1064 (2)0.1627 (2)0.39387 (11)0.0523 (6)
H30.17830.16940.41340.063*
C40.00000.1726 (3)0.42341 (17)0.0602 (10)
H40.00000.18590.46330.072*
C50.00000.0869 (3)0.17882 (19)0.0589 (10)
H5A0.03860.14710.18300.071*0.50
H5B0.08000.09760.16590.071*0.50
C60.0666 (6)0.0233 (4)0.1345 (2)0.0596 (14)0.50
H6A0.06630.05380.09690.072*0.50
H6B0.14760.01530.14660.072*0.50
C22A0.1050 (6)0.0632 (5)0.1032 (3)0.0673 (16)0.50
H22A0.07300.06700.06380.081*0.50
H22B0.15220.00590.10450.081*0.50
C23A0.1689 (8)0.1566 (5)0.0959 (3)0.0741 (18)0.50
H23A0.19470.17900.13350.111*0.50
H23B0.23660.14810.07090.111*0.50
H23C0.11600.20200.07870.111*0.50
C22B0.0951 (7)0.1371 (5)0.1028 (3)0.0656 (16)0.50
H22C0.16700.13190.12590.079*0.50
H22D0.06770.20190.10600.079*0.50
C23B0.1277 (10)0.1164 (6)0.0386 (3)0.098 (3)0.50
H23D0.06380.13620.01350.147*0.50
H23E0.19850.15050.02840.147*0.50
H23F0.14100.04990.03370.147*0.50
N10.00000.0711 (2)0.13202 (13)0.0537 (8)
N20.00000.0374 (2)0.23465 (14)0.0428 (6)
H20.061 (2)0.051 (2)0.2546 (12)0.043 (7)*
N30.00000.13362 (19)0.30763 (12)0.0354 (5)
O10.00000.25168 (16)0.20606 (13)0.0472 (6)
H1A0.0615 (9)0.2816 (15)0.1993 (13)0.058 (8)*
O20.18606 (15)0.11705 (12)0.24116 (8)0.0433 (4)
O30.31037 (14)0.13235 (15)0.31665 (8)0.0520 (5)
O40.3847 (3)0.1075 (3)0.43248 (15)0.1158 (13)
O50.25000.00000.50000.1026 (19)
H50.294 (4)0.030 (4)0.4753 (19)0.042 (14)*0.50
Ni10.00000.10766 (2)0.222149 (16)0.03365 (18)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
C10.0317 (11)0.0375 (10)0.0516 (12)0.0017 (9)0.0012 (9)0.0059 (10)
C20.0324 (11)0.0397 (11)0.0455 (11)0.0001 (8)0.0018 (9)0.0030 (9)
C30.0415 (14)0.0685 (17)0.0470 (12)0.0032 (12)0.0069 (10)0.0014 (11)
C40.053 (2)0.086 (3)0.0423 (18)0.0000.0000.0039 (18)
C50.081 (3)0.0297 (15)0.066 (2)0.0000.0000.0072 (15)
C60.081 (4)0.046 (3)0.052 (3)0.015 (3)0.009 (3)0.010 (2)
C22A0.081 (4)0.058 (3)0.063 (3)0.002 (3)0.023 (3)0.014 (3)
C23A0.087 (5)0.065 (4)0.070 (4)0.013 (4)0.020 (4)0.003 (3)
C22B0.085 (5)0.060 (4)0.051 (3)0.010 (3)0.016 (3)0.001 (3)
C23B0.132 (7)0.097 (5)0.066 (4)0.003 (5)0.035 (5)0.005 (4)
N10.081 (2)0.0355 (15)0.0451 (15)0.0000.0000.0027 (12)
N20.0412 (15)0.0309 (13)0.0562 (17)0.0000.0000.0047 (12)
N30.0299 (12)0.0356 (12)0.0408 (13)0.0000.0000.0010 (10)
O10.0350 (12)0.0284 (10)0.0783 (16)0.0000.0000.0055 (11)
O20.0358 (9)0.0462 (9)0.0480 (9)0.0015 (7)0.0037 (7)0.0003 (7)
O30.0303 (8)0.0657 (11)0.0601 (11)0.0043 (8)0.0018 (7)0.0083 (9)
O40.086 (2)0.175 (4)0.0863 (19)0.006 (2)0.0049 (17)0.0427 (19)
O50.129 (6)0.111 (5)0.068 (4)0.0000.0000.000
Ni10.0328 (3)0.0287 (3)0.0394 (3)0.0000.0000.00016 (13)
Geometric parameters (Å, º) top
C1—O31.249 (3)C23A—H23A0.96
C1—O21.253 (3)C23A—H23B0.96
C1—C21.526 (3)C23A—H23C0.96
C2—N31.328 (3)C22B—C23B1.540 (8)
C2—C31.372 (3)C22B—N11.570 (7)
C3—C41.382 (3)C22B—H22C0.97
C3—H30.93C22B—H22D0.97
C4—C3i1.382 (3)C23B—H23D0.96
C4—H40.93C23B—H23E0.96
C5—N21.455 (5)C23B—H23F0.96
C5—C6i1.548 (7)N1—C22Ai1.358 (6)
C5—C61.548 (7)N1—C6i1.533 (5)
C5—H5A0.96N1—C22Bi1.570 (7)
C5—H5B0.96N1—Ni12.122 (3)
C6—C22Ai1.481 (9)N2—Ni12.070 (3)
C6—C6i1.501 (13)N2—H20.85 (3)
C6—N11.533 (5)N3—C2i1.328 (3)
C6—H6A0.96N3—Ni11.986 (3)
C6—H6B0.96O1—Ni12.070 (2)
C22A—N11.358 (6)O1—H1A0.827 (10)
C22A—C6i1.481 (9)O2—Ni12.145 (2)
C22A—C23A1.514 (9)O5—H50.862 (11)
C22A—H22A0.97Ni1—O2i2.145 (2)
C22A—H22B0.97
O3—C1—O2126.2 (2)N1—C22B—H22D108.2
O3—C1—C2117.4 (2)H22A—C22B—H22D133.1
O2—C1—C2116.4 (2)H22C—C22B—H22D107.3
N3—C2—C3120.2 (2)C22B—C23B—H23D109.5
N3—C2—C1112.7 (2)C22B—C23B—H23E109.5
C3—C2—C1127.0 (2)H23D—C23B—H23E109.5
C2—C3—C4118.4 (2)C22B—C23B—H23F109.5
C2—C3—H3120.8H23D—C23B—H23F109.5
C4—C3—H3120.8H23E—C23B—H23F109.5
C3i—C4—C3120.2 (3)C22A—N1—C6111.9 (4)
C3i—C4—H4119.9C22A—N1—C22Bi116.0 (5)
C3—C4—H4119.9C6—N1—C22Bi101.5 (4)
N2—C5—C6i107.0 (3)C22Ai—N1—C22B116.0 (5)
N2—C5—C6107.0 (3)C6i—N1—C22B101.5 (4)
N2—C5—H5A109.9C22A—N1—Ni1119.3 (3)
C6—C5—H5A111.1C22Ai—N1—Ni1119.3 (3)
N2—C5—H5B110.1C6—N1—Ni1100.2 (2)
C6—C5—H5B110.2C6i—N1—Ni1100.2 (2)
H5A—C5—H5B108.4C22Bi—N1—Ni1105.5 (3)
N1—C6—C5107.0 (4)C22B—N1—Ni1105.5 (3)
N1—C6—H6A110.9C5—N2—Ni1110.9 (2)
C5—C6—H6A108.8C5—N2—H2111.0 (19)
N1—C6—H6B111.9Ni1—N2—H2108 (2)
C5—C6—H6B109.9C2—N3—C2i122.4 (3)
H6A—C6—H6B108.3C2—N3—Ni1118.79 (14)
N1—C22A—C23A113.3 (6)C2i—N3—Ni1118.79 (14)
N1—C22A—H22A96.9Ni1—O1—H1A122.5 (15)
C23A—C22A—H22A91.5C1—O2—Ni1114.12 (15)
N1—C22A—H22B122.2N3—Ni1—O189.57 (11)
C23A—C22A—H22B118.1N3—Ni1—N292.73 (12)
H22A—C22A—H22B106.1O1—Ni1—N2177.70 (12)
C22A—C23A—H23A109.5N3—Ni1—N1176.55 (11)
C22A—C23A—H23B109.5O1—Ni1—N193.88 (12)
H23A—C23A—H23B109.5N2—Ni1—N183.83 (12)
C23A—C23A—H23C109.5N3—Ni1—O2i77.86 (5)
H23B—C23A—H23C109.5O1—Ni1—O2i88.57 (5)
H23B—C23A—H22C119.6N2—Ni1—O2i91.92 (5)
H23C—C23A—H22C130.6N1—Ni1—O2i102.20 (5)
C23B—C22B—N1117.1 (6)N3—Ni1—O277.86 (5)
C23B—C22B—H22C107.7O1—Ni1—O288.57 (5)
N1—C22B—H22C107.0N2—Ni1—O291.92 (5)
H22A—C22B—H22C117.0N1—Ni1—O2102.20 (5)
C23B—C22B—H22D109.2O2i—Ni1—O2155.57 (10)
O3—C1—C2—N3176.1 (2)C3—C2—N3—C2i0.1 (5)
O2—C1—C2—N33.0 (3)C1—C2—N3—C2i179.40 (19)
O3—C1—C2—C34.4 (4)C3—C2—N3—Ni1178.7 (2)
O2—C1—C2—C3176.5 (2)C1—C2—N3—Ni10.8 (3)
N3—C2—C3—C40.0 (5)O3—C1—O2—Ni1175.5 (2)
C1—C2—C3—C4179.4 (3)C2—C1—O2—Ni13.5 (2)
C2—C3—C4—C3i0.1 (6)C2—N3—Ni1—O189.3 (2)
N2—C5—C6—C22Ai41.7 (17)C2i—N3—Ni1—O189.3 (2)
C6i—C5—C6—C22Ai58.1 (17)C2—N3—Ni1—N290.7 (2)
N2—C5—C6—C6i99.78 (19)C2i—N3—Ni1—N290.7 (2)
N2—C5—C6—N158.8 (4)C2—N3—Ni1—O2i177.9 (2)
C6i—C5—C6—N141.0 (4)C2i—N3—Ni1—O2i0.7 (2)
C6i—C22A—N1—C22Ai99.5 (7)C2—N3—Ni1—O20.7 (2)
C23A—C22A—N1—C22Ai106.9 (6)C2i—N3—Ni1—O2177.9 (2)
C6i—C22A—N1—C630.7 (4)C5—N2—Ni1—N3180.0
C23A—C22A—N1—C6175.6 (5)C5—N2—Ni1—N10.0
C23A—C22A—N1—C6i153.6 (7)C5—N2—Ni1—O2i102.07 (5)
C6i—C22A—N1—C22Bi146.5 (5)C5—N2—Ni1—O2102.07 (5)
C23A—C22A—N1—C22Bi59.9 (7)C22A—N1—Ni1—O187.5 (4)
C6i—C22A—N1—C22B165.6 (7)C22Ai—N1—Ni1—O187.5 (4)
C23A—C22A—N1—C22B11.9 (6)C6—N1—Ni1—O1150.2 (3)
C6i—C22A—N1—Ni185.6 (4)C6i—N1—Ni1—O1150.2 (3)
C23A—C22A—N1—Ni168.0 (7)C22Bi—N1—Ni1—O145.1 (3)
C22Ai—C6—N1—C22A114.6 (7)C22B—N1—Ni1—O145.1 (3)
C6i—C6—N1—C22A31.7 (4)C22A—N1—Ni1—N292.5 (4)
C5—C6—N1—C22A72.8 (5)C22Ai—N1—Ni1—N292.5 (4)
C6i—C6—N1—C22Ai146.3 (4)C6—N1—Ni1—N229.8 (3)
C5—C6—N1—C22Ai172.6 (5)C6i—N1—Ni1—N229.8 (3)
C22Ai—C6—N1—C6i146.3 (4)C22Bi—N1—Ni1—N2134.9 (3)
C5—C6—N1—C6i41.1 (4)C22B—N1—Ni1—N2134.9 (3)
C22Ai—C6—N1—C22Bi9.7 (4)C22A—N1—Ni1—O2i1.9 (4)
C6i—C6—N1—C22Bi155.9 (4)C22Ai—N1—Ni1—O2i176.9 (4)
C5—C6—N1—C22Bi163.0 (4)C6—N1—Ni1—O2i120.5 (3)
C22Ai—C6—N1—C22B92.7 (9)C6i—N1—Ni1—O2i60.8 (3)
C6i—C6—N1—C22B53.5 (7)C22Bi—N1—Ni1—O2i134.5 (3)
C5—C6—N1—C22B94.6 (8)C22B—N1—Ni1—O2i44.3 (3)
C22Ai—C6—N1—Ni1118.0 (3)C22A—N1—Ni1—O2176.9 (4)
C6i—C6—N1—Ni195.78 (15)C22Ai—N1—Ni1—O21.9 (4)
C5—C6—N1—Ni154.7 (4)C6—N1—Ni1—O260.8 (3)
C23B—C22B—N1—C22A54.3 (7)C6i—N1—Ni1—O2120.5 (3)
C23B—C22B—N1—C22Ai54.2 (8)C22Bi—N1—Ni1—O244.3 (3)
C23B—C22B—N1—C622.8 (12)C22B—N1—Ni1—O2134.5 (3)
C23B—C22B—N1—C6i67.2 (7)C1—O2—Ni1—N32.43 (16)
C23B—C22B—N1—C22Bi83.7 (7)C1—O2—Ni1—O192.30 (17)
C23B—C22B—N1—Ni1171.3 (6)C1—O2—Ni1—N289.94 (17)
C6i—C5—N2—Ni130.5 (3)C1—O2—Ni1—N1174.04 (17)
C6—C5—N2—Ni130.5 (3)C1—O2—Ni1—O2i8.9 (3)
Symmetry code: (i) x, y, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O5—H5···O40.86 (1)1.79 (1)2.644 (3)171 (6)
N2—H2···O3ii0.85 (3)2.33 (3)3.142 (3)161 (3)
O1—H1A···O3iii0.83 (1)1.92 (1)2.743 (2)171 (2)
Symmetry codes: (ii) x+1/2, y, z; (iii) x+1/2, y+1/2, z+1/2.

Experimental details

Crystal data
Chemical formula[Ni(C7H3NO4)(C6H16N2)(H2O)]·2.5H2O
Mr403.08
Crystal system, space groupOrthorhombic, Imcb
Temperature (K)297
a, b, c (Å)11.268 (4), 14.141 (5), 22.831 (12)
V3)3638 (3)
Z8
Radiation typeMo Kα
µ (mm1)1.11
Crystal size (mm)0.42 × 0.30 × 0.25
Data collection
DiffractometerStoe IPDS2
Absorption correctionIntegration
(X-RED32; Stoe & Cie, 2002)
Tmin, Tmax0.925, 0.974
No. of measured, independent and
observed [I > 2σ(I)] reflections
28305, 2120, 1926
Rint0.047
(sin θ/λ)max1)0.642
Refinement
R[F2 > 2σ(F2)], wR(F2), S 0.046, 0.123, 1.18
No. of reflections2120
No. of parameters157
No. of restraints38
H-atom treatmentH atoms treated by a mixture of independent and constrained refinement
Δρmax, Δρmin (e Å3)0.41, 1.12

Computer programs: X-AREA (Stoe & Cie, 2002), X-AREA, X-RED32 (Stoe & Cie, 2002), SHELXS97 (Sheldrick, 1997), SHELXL97 (Sheldrick, 1997), ORTEP-3 (Farrugia, 1997), WinGX (Farrugia, 1999).

Selected geometric parameters (Å, º) top
N1—Ni12.122 (3)O1—Ni12.070 (2)
N2—Ni12.070 (3)O2—Ni12.145 (2)
N3—Ni11.986 (3)Ni1—O2i2.145 (2)
N3—Ni1—O189.57 (11)N3—Ni1—O277.86 (5)
N3—Ni1—N292.73 (12)O1—Ni1—O288.57 (5)
O1—Ni1—N2177.70 (12)N2—Ni1—O291.92 (5)
N3—Ni1—N1176.55 (11)N1—Ni1—O2102.20 (5)
O1—Ni1—N193.88 (12)O2i—Ni1—O2155.57 (10)
N2—Ni1—N183.83 (12)
Symmetry code: (i) x, y, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O5—H5···O40.862 (11)1.789 (14)2.644 (3)171 (6)
N2—H2···O3ii0.85 (3)2.33 (3)3.142 (3)161 (3)
O1—H1A···O3iii0.827 (10)1.922 (12)2.743 (2)171 (2)
Symmetry codes: (ii) x+1/2, y, z; (iii) x+1/2, y+1/2, z+1/2.
 

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