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In the title compound, [Sn(C4H9)2(C7H3N2O6)2]·C7H8, the SnIV atom is in a distorted tetra­hedral environment. The nitro groups are twisted slightly away from the planes of the attached benzene rings. The mol­ecules are linked by inter­molecular C—H...O inter­actions and short O...N contacts, forming sheet-like structures paralled to the ab plane, and are cross-linked by π–π inter­actions.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807008100/ci2300sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536807008100/ci2300Isup2.hkl
Contains datablock I

CCDC reference: 640303

Key indicators

  • Single-crystal X-ray study
  • T = 100 K
  • Mean [sigma](C-C) = 0.003 Å
  • R factor = 0.032
  • wR factor = 0.072
  • Data-to-parameter ratio = 27.3

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT430_ALERT_2_B Short Inter D...A Contact O1 .. N2 .. 2.85 Ang.
Alert level C PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density .... 2.02 PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.08 Ratio PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 4.00 Ratio PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Sn1 - O1 .. 8.53 su PLAT232_ALERT_2_C Hirshfeld Test Diff (M-X) Sn1 - O8 .. 8.77 su PLAT380_ALERT_4_C Check Incorrectly? Oriented X(sp2)-Methyl Moiety C29
0 ALERT level A = In general: serious problem 1 ALERT level B = Potentially serious problem 6 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 0 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 5 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: APEX2 (Bruker, 2005); cell refinement: APEX2; data reduction: SAINT (Bruker, 2005); program(s) used to solve structure: SHELXTL (Sheldrick, 1998); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and PLATON (Spek, 2003).

Dibutylbis(3,5-dinitrobenzoato-κO)tin(IV) toluene solvate top
Crystal data top
[Sn(C4H9)2(C7H3N2O6)2]·C7H8F(000) = 1520
Mr = 747.28Dx = 1.563 Mg m3
Monoclinic, P21/cMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ybcCell parameters from 6685 reflections
a = 20.4571 (10) Åθ = 1.3–33.3°
b = 7.0328 (3) ŵ = 0.87 mm1
c = 29.4029 (13) ÅT = 100 K
β = 131.364 (3)°Block, yellow
V = 3174.9 (3) Å30.28 × 0.21 × 0.10 mm
Z = 4
Data collection top
Bruker SMART APEX2 CCD area-detector
diffractometer
12186 independent reflections
Radiation source: fine-focus sealed tube9858 reflections with I > 2σ(I)'
Graphite monochromatorRint = 0.065
Detector resolution: 8.33 pixels mm-1θmax = 33.3°, θmin = 1.3°
ω scansh = 3131
Absorption correction: multi-scan
(SADABS; Bruker, 2005)
k = 1010
Tmin = 0.814, Tmax = 0.915l = 4544
98264 measured reflections
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.032Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.072Only H-atom displacement parameters refined
S = 1.05 w = 1/[σ2(Fo2) + (0.0238P)2 + 2.1069P]
where P = (Fo2 + 2Fc2)/3
12186 reflections(Δ/σ)max = 0.001
447 parametersΔρmax = 0.88 e Å3
0 restraintsΔρmin = 0.44 e Å3
Special details top

Experimental. The data was collected with the Oxford Cyrosystem Cobra low-temperature attachment.

Analysis found for C29H32N4O12Sn: C 45.90, H 4.42, N 7.48, Sn 15.73%; calculated: C 46.61 H 4.32, N 7.50, Sn 15.88%. FT–IR (KBr, cm-1): ν(COO)as 1629, ν(COO)s 1345, ν(O—Sn—O) 644, ν(Sn—C) 544, ν(Sn—O) 467. 1H NMR: δ benzene protons 9.26–9.27 (2H, t, J = 1.9 Hz), 9.28 - 9.29 (4H, d, J = 2.4 Hz), toluene CH3 2.36 (3H, s), CH2 7.13–7.17 (3H, m), 7.23–7.27 (2H, m), butyl CH3 0.95–0.98 (6H, t, J = 7.5 Hz), CH2 1.45–1.54 (4H, hx, 7.3 Hz), CH2 1.78–1.86 (4H, qn, 7.4 Hz), CH2 7.23–7.27 (2H, m). 13C NMR: δ benzene carbons 122.92, 130.55, 134.78, 149.09; butyl 13.91, 26.17, 26.83, 27.10; COO 171.47. 119Sn NMR: δ -121.78.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Sn10.712743 (7)0.178790 (15)0.217209 (5)0.01640 (3)
O10.84805 (8)0.17963 (17)0.22720 (6)0.0207 (2)
O20.74068 (8)0.38823 (17)0.18035 (6)0.0205 (2)
O30.76417 (9)0.96996 (19)0.09787 (6)0.0295 (3)
O40.87987 (10)1.01696 (18)0.11050 (7)0.0302 (3)
O51.06042 (8)0.47573 (18)0.15679 (6)0.0254 (3)
O61.07677 (9)0.2591 (2)0.21607 (6)0.0291 (3)
O70.59726 (8)0.33789 (16)0.17297 (5)0.0191 (2)
O80.59367 (8)0.10322 (17)0.22132 (6)0.0204 (2)
O90.35495 (9)0.0898 (2)0.22366 (7)0.0330 (3)
O100.25371 (9)0.30336 (19)0.17495 (8)0.0334 (3)
O110.30084 (9)0.87194 (18)0.11020 (7)0.0304 (3)
O120.40058 (9)0.87896 (18)0.10397 (7)0.0289 (3)
N10.83429 (10)0.9190 (2)0.11444 (7)0.0216 (3)
N21.04013 (9)0.3986 (2)0.18331 (7)0.0203 (3)
N30.32245 (10)0.2349 (2)0.19340 (7)0.0217 (3)
N40.36059 (10)0.79952 (19)0.11617 (7)0.0211 (3)
C10.82338 (11)0.6231 (2)0.15430 (7)0.0178 (3)
H1A0.77450.67180.14640.027 (6)*
C20.86590 (11)0.7270 (2)0.14035 (8)0.0182 (3)
C30.93685 (11)0.6581 (2)0.14918 (7)0.0182 (3)
H3A0.96360.72850.13860.027 (6)*
C40.96610 (10)0.4787 (2)0.17459 (7)0.0168 (3)
C50.92861 (10)0.3717 (2)0.19154 (7)0.0168 (3)
H5A0.95150.25380.21000.019 (5)*
C60.85582 (10)0.4443 (2)0.18045 (7)0.0164 (3)
C70.81362 (11)0.3282 (2)0.19747 (7)0.0175 (3)
C80.44045 (10)0.2469 (2)0.19104 (7)0.0164 (3)
H8A0.45880.12730.20900.021 (5)*
C90.36942 (10)0.3338 (2)0.17835 (7)0.0166 (3)
C100.34083 (10)0.5132 (2)0.15300 (7)0.0177 (3)
H10A0.29280.56920.14470.022 (5)*
C110.38710 (10)0.6046 (2)0.14061 (7)0.0168 (3)
C120.45768 (10)0.5230 (2)0.15095 (7)0.0169 (3)
H12A0.48660.58750.14110.025 (5)*
C130.48405 (10)0.3423 (2)0.17637 (7)0.0159 (3)
C140.56232 (10)0.2519 (2)0.19118 (7)0.0173 (3)
C150.67434 (12)0.0655 (2)0.16267 (9)0.0250 (4)
H15A0.69350.17750.18790.038 (7)*
H15B0.70400.06500.14710.049 (7)*
C160.57681 (13)0.0812 (3)0.10951 (9)0.0301 (4)
H16A0.54740.10060.12480.042 (7)*
H16B0.55580.03730.08700.039 (7)*
C170.55362 (14)0.2442 (3)0.06669 (10)0.0328 (4)
H17A0.57310.36340.08880.027 (6)*
H17B0.58390.22660.05190.036 (6)*
C180.45590 (17)0.2547 (4)0.01298 (12)0.0485 (6)
H18A0.44380.35810.01300.060 (9)*
H18B0.42590.27510.02740.067 (9)*
H18C0.43650.13770.00930.076 (11)*
C190.78915 (11)0.2526 (2)0.30973 (8)0.0194 (3)
H19A0.81720.13830.33390.020 (5)*
H19B0.75040.29770.31570.030 (6)*
C200.85916 (11)0.4032 (2)0.33403 (8)0.0199 (3)
H20A0.83200.52100.31190.026 (5)*
H20B0.89810.36140.32790.026 (6)*
C210.91106 (12)0.4375 (3)0.40118 (8)0.0253 (4)
H21A0.93440.31730.42260.025 (5)*
H21B0.87220.48580.40660.033 (6)*
C220.98554 (14)0.5772 (3)0.42894 (9)0.0323 (4)
H22A1.01600.59310.47120.027 (6)*
H22B1.02500.52900.42450.060 (8)*
H22C0.96280.69760.40870.043 (7)*
C230.21418 (14)0.2743 (3)0.02105 (9)0.0327 (4)
H23A0.20320.16790.03380.042 (7)*
C240.27805 (14)0.2663 (3)0.01756 (9)0.0335 (5)
H24A0.31000.15510.02830.034 (6)*
C250.29501 (13)0.4234 (3)0.00181 (9)0.0315 (4)
H25A0.33850.41800.00380.028 (6)*
C260.24681 (13)0.5890 (3)0.01811 (8)0.0284 (4)
H26A0.25740.69420.03160.030 (6)*
C270.18297 (12)0.5967 (3)0.01439 (8)0.0275 (4)
H27A0.15100.70790.02530.038 (7)*
C280.16559 (13)0.4402 (3)0.00560 (9)0.0294 (4)
C290.09763 (16)0.4512 (4)0.01097 (11)0.0419 (5)
H29A0.09450.33170.02520.082 (11)*
H29B0.04210.47920.02800.064 (9)*
H29C0.11280.54980.03910.074 (10)*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sn10.01582 (5)0.01666 (5)0.02158 (6)0.00086 (4)0.01442 (5)0.00111 (4)
O10.0201 (6)0.0222 (5)0.0237 (6)0.0012 (4)0.0162 (5)0.0043 (5)
O20.0183 (6)0.0229 (5)0.0262 (6)0.0009 (4)0.0172 (5)0.0024 (5)
O30.0348 (8)0.0258 (6)0.0382 (8)0.0103 (5)0.0285 (7)0.0070 (5)
O40.0387 (8)0.0203 (6)0.0422 (8)0.0019 (5)0.0313 (7)0.0036 (5)
O50.0282 (7)0.0274 (6)0.0341 (7)0.0049 (5)0.0264 (6)0.0040 (5)
O60.0269 (7)0.0307 (7)0.0361 (8)0.0101 (5)0.0236 (7)0.0092 (6)
O70.0176 (5)0.0218 (5)0.0233 (6)0.0026 (4)0.0159 (5)0.0023 (4)
O80.0184 (6)0.0213 (5)0.0247 (6)0.0041 (4)0.0156 (5)0.0033 (5)
O90.0268 (7)0.0349 (7)0.0421 (8)0.0078 (6)0.0247 (7)0.0194 (6)
O100.0263 (7)0.0301 (7)0.0585 (10)0.0056 (5)0.0342 (8)0.0093 (6)
O110.0334 (8)0.0217 (6)0.0458 (9)0.0112 (5)0.0302 (7)0.0075 (6)
O120.0311 (7)0.0208 (6)0.0423 (8)0.0022 (5)0.0274 (7)0.0077 (5)
N10.0294 (8)0.0181 (6)0.0243 (7)0.0011 (5)0.0206 (7)0.0009 (5)
N20.0178 (7)0.0230 (7)0.0234 (7)0.0019 (5)0.0150 (6)0.0035 (5)
N30.0198 (7)0.0228 (7)0.0274 (8)0.0012 (5)0.0177 (7)0.0035 (6)
N40.0227 (7)0.0158 (6)0.0252 (7)0.0014 (5)0.0159 (6)0.0008 (5)
C10.0174 (7)0.0194 (7)0.0190 (8)0.0002 (5)0.0131 (7)0.0002 (5)
C20.0199 (8)0.0158 (7)0.0203 (8)0.0000 (5)0.0139 (7)0.0001 (5)
C30.0188 (7)0.0191 (7)0.0198 (8)0.0035 (5)0.0140 (7)0.0022 (6)
C40.0155 (7)0.0192 (7)0.0174 (7)0.0015 (5)0.0116 (6)0.0022 (5)
C50.0163 (7)0.0177 (7)0.0172 (7)0.0007 (5)0.0114 (7)0.0001 (5)
C60.0163 (7)0.0191 (7)0.0165 (7)0.0018 (5)0.0119 (6)0.0008 (5)
C70.0181 (7)0.0187 (7)0.0189 (7)0.0022 (6)0.0135 (6)0.0017 (6)
C80.0143 (7)0.0153 (6)0.0177 (7)0.0013 (5)0.0098 (6)0.0012 (5)
C90.0158 (7)0.0182 (7)0.0180 (7)0.0005 (5)0.0120 (6)0.0002 (5)
C100.0155 (7)0.0188 (7)0.0192 (8)0.0017 (5)0.0117 (7)0.0012 (5)
C110.0167 (7)0.0143 (6)0.0186 (7)0.0017 (5)0.0114 (7)0.0015 (5)
C120.0159 (7)0.0181 (7)0.0182 (7)0.0012 (5)0.0119 (6)0.0007 (5)
C130.0141 (7)0.0173 (7)0.0168 (7)0.0001 (5)0.0105 (6)0.0009 (5)
C140.0157 (7)0.0193 (7)0.0190 (8)0.0007 (5)0.0123 (7)0.0010 (6)
C150.0265 (9)0.0208 (8)0.0340 (10)0.0003 (6)0.0226 (9)0.0032 (7)
C160.0293 (10)0.0305 (9)0.0368 (11)0.0058 (7)0.0246 (9)0.0110 (8)
C170.0389 (11)0.0287 (9)0.0379 (11)0.0092 (8)0.0285 (10)0.0114 (8)
C180.0434 (14)0.0557 (15)0.0455 (14)0.0198 (12)0.0289 (13)0.0237 (12)
C190.0185 (8)0.0220 (7)0.0221 (8)0.0005 (6)0.0153 (7)0.0004 (6)
C200.0210 (8)0.0193 (7)0.0245 (8)0.0008 (6)0.0172 (7)0.0000 (6)
C210.0274 (9)0.0257 (8)0.0243 (9)0.0037 (7)0.0177 (8)0.0007 (7)
C220.0368 (11)0.0349 (10)0.0265 (10)0.0135 (8)0.0215 (9)0.0084 (8)
C230.0383 (11)0.0225 (8)0.0223 (9)0.0016 (7)0.0136 (9)0.0018 (7)
C240.0370 (11)0.0231 (8)0.0214 (9)0.0078 (8)0.0111 (9)0.0006 (7)
C250.0280 (10)0.0342 (10)0.0222 (9)0.0023 (8)0.0122 (8)0.0022 (7)
C260.0274 (9)0.0237 (8)0.0211 (9)0.0014 (7)0.0105 (8)0.0002 (7)
C270.0261 (9)0.0205 (8)0.0226 (9)0.0019 (7)0.0104 (8)0.0025 (6)
C280.0277 (10)0.0273 (9)0.0210 (9)0.0010 (7)0.0108 (8)0.0003 (7)
C290.0371 (12)0.0445 (13)0.0394 (13)0.0004 (10)0.0233 (11)0.0062 (10)
Geometric parameters (Å, º) top
Sn1—O72.1127 (11)C15—C161.521 (3)
Sn1—C152.1155 (17)C15—H15A0.97
Sn1—O22.1188 (12)C15—H15B0.97
Sn1—C192.1197 (17)C16—C171.528 (3)
O1—C71.2404 (19)C16—H16A0.97
O2—C71.2904 (19)C16—H16B0.97
O3—N11.2245 (19)C17—C181.524 (3)
O4—N11.2249 (19)C17—H17A0.97
O5—N21.2255 (18)C17—H17B0.97
O6—N21.224 (2)C18—H18A0.96
O7—C141.2920 (19)C18—H18B0.96
O8—C141.240 (2)C18—H18C0.96
O9—N31.2221 (19)C19—C201.527 (2)
O10—N31.2229 (19)C19—H19A0.97
O11—N41.2251 (19)C19—H19B0.97
O12—N41.2237 (19)C20—C211.521 (2)
N1—C21.474 (2)C20—H20A0.97
N2—C41.471 (2)C20—H20B0.97
N3—C91.471 (2)C21—C221.520 (3)
N4—C111.474 (2)C21—H21A0.97
C1—C21.389 (2)C21—H21B0.97
C1—C61.392 (2)C22—H22A0.96
C1—H1A0.93C22—H22B0.96
C2—C31.382 (2)C22—H22C0.96
C3—C41.384 (2)C23—C241.378 (3)
C3—H3A0.93C23—C281.400 (3)
C4—C51.381 (2)C23—H23A0.93
C5—C61.394 (2)C24—C251.388 (3)
C5—H5A0.93C24—H24A0.93
C6—C71.495 (2)C25—C261.391 (3)
C8—C91.381 (2)C25—H25A0.93
C8—C131.393 (2)C26—C271.382 (3)
C8—H8A0.93C26—H26A0.93
C9—C101.383 (2)C27—C281.400 (3)
C10—C111.378 (2)C27—H27A0.93
C10—H10A0.93C28—C291.501 (3)
C11—C121.388 (2)C29—H29A0.96
C12—C131.390 (2)C29—H29B0.96
C12—H12A0.93C29—H29C0.96
C13—C141.495 (2)
O7—Sn1—C15105.03 (6)H15A—C15—H15B107.6
O7—Sn1—O283.49 (4)C15—C16—C17112.54 (16)
C15—Sn1—O2105.51 (6)C15—C16—H16A109.1
O7—Sn1—C19103.69 (6)C17—C16—H16A109.1
C15—Sn1—C19139.57 (7)C15—C16—H16B109.1
O2—Sn1—C19105.48 (6)C17—C16—H16B109.1
C7—O2—Sn1101.90 (10)H16A—C16—H16B107.8
C14—O7—Sn1101.34 (10)C18—C17—C16111.75 (19)
O3—N1—O4124.24 (15)C18—C17—H17A109.3
O3—N1—C2118.19 (14)C16—C17—H17A109.3
O4—N1—C2117.57 (14)C18—C17—H17B109.3
O6—N2—O5124.53 (15)C16—C17—H17B109.3
O6—N2—C4117.94 (14)H17A—C17—H17B107.9
O5—N2—C4117.53 (14)C17—C18—H18A109.4
O9—N3—O10124.38 (15)C17—C18—H18B109.5
O9—N3—C9117.69 (14)H18A—C18—H18B109.5
O10—N3—C9117.92 (14)C17—C18—H18C109.5
O12—N4—O11124.41 (14)H18A—C18—H18C109.5
O12—N4—C11117.74 (14)H18B—C18—H18C109.5
O11—N4—C11117.85 (14)C20—C19—Sn1116.01 (11)
C2—C1—C6118.36 (15)C20—C19—H19A108.3
C2—C1—H1A120.8Sn1—C19—H19A108.3
C6—C1—H1A120.8C20—C19—H19B108.3
C3—C2—C1123.01 (15)Sn1—C19—H19B108.3
C3—C2—N1117.78 (14)H19A—C19—H19B107.4
C1—C2—N1119.21 (14)C21—C20—C19110.60 (14)
C2—C3—C4116.53 (15)C21—C20—H20A109.5
C2—C3—H3A121.7C19—C20—H20A109.5
C4—C3—H3A121.7C21—C20—H20B109.5
C5—C4—C3123.10 (15)C19—C20—H20B109.5
C5—C4—N2118.78 (14)H20A—C20—H20B108.1
C3—C4—N2118.11 (14)C22—C21—C20113.08 (15)
C4—C5—C6118.55 (15)C22—C21—H21A109.0
C4—C5—H5A120.7C20—C21—H21A109.0
C6—C5—H5A120.7C22—C21—H21B108.9
C1—C6—C5120.38 (14)C20—C21—H21B109.0
C1—C6—C7120.55 (14)H21A—C21—H21B107.7
C5—C6—C7119.06 (14)C21—C22—H22A109.5
O1—C7—O2121.49 (15)C21—C22—H22B109.5
O1—C7—C6120.76 (15)H22A—C22—H22B109.5
O2—C7—C6117.75 (14)C21—C22—H22C109.5
C9—C8—C13118.54 (14)H22A—C22—H22C109.5
C9—C8—H8A120.8H22B—C22—H22C109.5
C13—C8—H8A120.7C24—C23—C28121.01 (19)
C8—C9—C10122.96 (15)C24—C23—H23A119.5
C8—C9—N3119.27 (14)C28—C23—H23A119.5
C10—C9—N3117.76 (14)C23—C24—C25120.29 (18)
C11—C10—C9116.66 (14)C23—C24—H24A119.8
C11—C10—H10A121.7C25—C24—H24A119.9
C9—C10—H10A121.7C24—C25—C26119.7 (2)
C10—C11—C12123.08 (14)C24—C25—H25A120.2
C10—C11—N4117.85 (14)C26—C25—H25A120.1
C12—C11—N4119.06 (14)C27—C26—C25119.84 (18)
C11—C12—C13118.29 (14)C27—C26—H26A120.1
C11—C12—H12A120.9C25—C26—H26A120.1
C13—C12—H12A120.8C26—C27—C28121.20 (18)
C12—C13—C8120.44 (14)C26—C27—H27A119.4
C12—C13—C14120.37 (14)C28—C27—H27A119.4
C8—C13—C14119.12 (14)C23—C28—C27118.0 (2)
O8—C14—O7121.62 (14)C23—C28—C29121.14 (19)
O8—C14—C13120.99 (14)C27—C28—C29120.90 (19)
O7—C14—C13117.36 (14)C28—C29—H29A109.5
C16—C15—Sn1114.56 (12)C28—C29—H29B109.4
C16—C15—H15A108.6H29A—C29—H29B109.5
Sn1—C15—H15A108.6C28—C29—H29C109.5
C16—C15—H15B108.6H29A—C29—H29C109.5
Sn1—C15—H15B108.6H29B—C29—H29C109.5
O7—Sn1—O2—C7177.17 (10)C8—C9—C10—C110.1 (2)
C15—Sn1—O2—C773.32 (11)N3—C9—C10—C11178.55 (15)
C19—Sn1—O2—C780.38 (11)C9—C10—C11—C121.7 (2)
C15—Sn1—O7—C1481.07 (11)C9—C10—C11—N4177.25 (14)
O2—Sn1—O7—C14174.57 (10)O12—N4—C11—C10178.46 (16)
C19—Sn1—O7—C1470.18 (11)O11—N4—C11—C102.5 (2)
C6—C1—C2—C32.5 (3)O12—N4—C11—C122.5 (2)
C6—C1—C2—N1178.08 (14)O11—N4—C11—C12176.52 (16)
O3—N1—C2—C3169.04 (16)C10—C11—C12—C131.6 (2)
O4—N1—C2—C310.4 (2)N4—C11—C12—C13177.34 (14)
O3—N1—C2—C110.4 (2)C11—C12—C13—C80.1 (2)
O4—N1—C2—C1170.07 (16)C11—C12—C13—C14177.05 (15)
C1—C2—C3—C41.7 (2)C9—C8—C13—C121.6 (2)
N1—C2—C3—C4178.88 (14)C9—C8—C13—C14178.58 (14)
C2—C3—C4—C50.9 (2)Sn1—O7—C14—O86.70 (18)
C2—C3—C4—N2178.53 (14)Sn1—O7—C14—C13171.19 (12)
O6—N2—C4—C514.6 (2)C12—C13—C14—O8169.94 (15)
O5—N2—C4—C5164.86 (15)C8—C13—C14—O87.0 (2)
O6—N2—C4—C3165.93 (16)C12—C13—C14—O78.0 (2)
O5—N2—C4—C314.6 (2)C8—C13—C14—O7175.07 (14)
C3—C4—C5—C62.5 (2)O7—Sn1—C15—C164.51 (15)
N2—C4—C5—C6176.90 (14)O2—Sn1—C15—C1691.81 (14)
C2—C1—C6—C50.7 (2)C19—Sn1—C15—C16129.36 (14)
C2—C1—C6—C7178.79 (15)Sn1—C15—C16—C17172.11 (14)
C4—C5—C6—C11.7 (2)C15—C16—C17—C18178.66 (19)
C4—C5—C6—C7178.82 (14)O7—Sn1—C19—C2099.13 (12)
Sn1—O2—C7—O10.90 (18)C15—Sn1—C19—C20126.64 (13)
Sn1—O2—C7—C6178.92 (11)O2—Sn1—C19—C2012.20 (13)
C1—C6—C7—O1171.35 (15)Sn1—C19—C20—C21177.99 (11)
C5—C6—C7—O18.2 (2)C19—C20—C21—C22176.39 (16)
C1—C6—C7—O28.5 (2)C28—C23—C24—C250.4 (3)
C5—C6—C7—O2172.01 (15)C23—C24—C25—C260.4 (3)
C13—C8—C9—C101.5 (2)C24—C25—C26—C270.6 (3)
C13—C8—C9—N3179.85 (14)C25—C26—C27—C280.0 (3)
O9—N3—C9—C89.2 (2)C24—C23—C28—C271.0 (3)
O10—N3—C9—C8170.98 (16)C24—C23—C28—C29178.3 (2)
O9—N3—C9—C10169.54 (16)C26—C27—C28—C230.8 (3)
O10—N3—C9—C1010.3 (2)C26—C27—C28—C29178.50 (19)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C15—H15B···O3i0.972.453.420 (4)172
C19—H19A···O5ii0.972.603.198 (3)120
C22—H22C···O5iii0.962.563.458 (3)156
C24—H24A···O12i0.932.593.427 (3)150
Symmetry codes: (i) x, y1, z; (ii) x+2, y1/2, z+1/2; (iii) x+2, y+1/2, z+1/2.
 

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