Buy article online - an online subscription or single-article purchase is required to access this article.
Download citation
Download citation
link to html
The centrosymmetric formula unit of the title one-dimensional coordination polymer, [Mn(C7H3N2O6)2(C10H8N2)]n, which is twice the asymmetric unit, contains two MnII ions, four 3,5-dinitro­benzoate anions and two 2,2′-bipyridine ligands. The 3,5-dinitro­benzoate anions connect the MnII atoms through their O atoms, resulting in the formation of a one-dimensional chain structure.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807008823/ci2284sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536807008823/ci2284Isup2.hkl
Contains datablock I

CCDC reference: 640298

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.004 Å
  • R factor = 0.042
  • wR factor = 0.124
  • Data-to-parameter ratio = 15.1

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT066_ALERT_1_C Predicted and Reported Transmissions Identical . ? PLAT154_ALERT_1_C The su's on the Cell Angles are Equal (x 10000) 300 Deg. PLAT220_ALERT_2_C Large Non-Solvent N Ueq(max)/Ueq(min) ... 2.67 Ratio PLAT220_ALERT_2_C Large Non-Solvent O Ueq(max)/Ueq(min) ... 3.43 Ratio PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for N3 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for N4 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for N5 PLAT242_ALERT_2_C Check Low Ueq as Compared to Neighbors for N6
Alert level G PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature 293 K PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature . 293 K
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 8 ALERT level C = Check and explain 2 ALERT level G = General alerts; check 4 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 6 ALERT type 2 Indicator that the structure model may be wrong or deficient 0 ALERT type 3 Indicator that the structure quality may be low 0 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Siemens, 1996); cell refinement: SAINT (Siemens, 1994); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Bruker, 1997); software used to prepare material for publication: SHELXL97.

catena-Poly[[(2,2'-bipyridyl-κ2N,N')manganese(II)]-di-µ-3,5- dinitrobenzoato-κ4O:O'] top
Crystal data top
[Mn(C7H3N2O6)2(C10H8N2)]Z = 2
Mr = 633.20F(000) = 642
Triclinic, P1Dx = 1.623 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 7.8100 (5) ÅCell parameters from 5853 reflections
b = 11.9700 (4) Åθ = 3.0–27.5°
c = 14.7695 (3) ŵ = 0.59 mm1
α = 103.834 (3)°T = 293 K
β = 104.393 (3)°Block, yellow
γ = 90.169 (3)°0.26 × 0.16 × 0.11 mm
V = 1295.75 (10) Å3
Data collection top
Siemens SMART CCD area-detector
diffractometer
5856 independent reflections
Radiation source: fine-focus sealed tube4729 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.027
φ and ω scansθmax = 27.5°, θmin = 3.0°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 109
Tmin = 0.893, Tmax = 0.937k = 1515
12799 measured reflectionsl = 1919
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.042Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.124H-atom parameters constrained
S = 1.00 w = 1/[σ2(Fo2) + (0.0818P)2 + 0.0886P]
where P = (Fo2 + 2Fc2)/3
5853 reflections(Δ/σ)max = 0.001
388 parametersΔρmax = 0.48 e Å3
18 restraintsΔρmin = 0.48 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Mn10.27297 (4)0.04131 (3)0.58413 (2)0.02962 (12)
O10.4926 (2)0.14433 (16)0.56730 (12)0.0442 (4)
O20.7470 (3)0.06908 (19)0.55183 (13)0.0590 (6)
O30.6478 (6)0.5202 (3)0.8170 (3)0.1218 (13)
O40.7802 (5)0.5083 (3)0.95874 (19)0.1132 (12)
O51.0905 (4)0.0325 (3)0.8799 (3)0.1058 (10)
O61.0929 (6)0.1715 (4)1.0015 (2)0.1369 (15)
O70.1068 (2)0.16237 (14)0.46826 (12)0.0423 (4)
O80.0830 (2)0.07221 (15)0.60781 (12)0.0450 (4)
O90.0975 (6)0.4286 (4)0.8537 (3)0.1349 (15)
O100.2323 (5)0.2680 (4)0.8667 (2)0.1324 (15)
O110.3519 (6)0.5428 (3)0.4340 (3)0.1342 (14)
O120.2728 (7)0.6312 (3)0.5459 (3)0.1453 (15)
N10.4654 (3)0.05014 (18)0.68421 (13)0.0375 (4)
N20.3243 (3)0.14950 (17)0.73943 (13)0.0360 (4)
N30.7301 (5)0.4692 (3)0.8727 (2)0.0754 (9)
N41.0439 (4)0.1239 (4)0.9159 (2)0.0804 (9)
N50.2685 (6)0.5478 (3)0.5140 (3)0.0967 (12)
N60.1307 (6)0.3488 (4)0.8210 (3)0.0920 (11)
C10.5137 (4)0.1568 (2)0.65319 (18)0.0483 (6)
H10.49930.18610.58730.058*
C20.5833 (4)0.2247 (3)0.7139 (2)0.0585 (8)
H20.61330.29900.68960.070*
C30.6081 (5)0.1816 (3)0.8109 (2)0.0671 (9)
H30.65590.22610.85360.080*
C40.5617 (4)0.0721 (3)0.84453 (18)0.0597 (8)
H40.57880.04120.91040.072*
C50.2694 (4)0.2554 (2)0.76242 (19)0.0460 (6)
H50.19520.28360.71430.055*
C60.3189 (4)0.3250 (3)0.8554 (2)0.0590 (8)
H60.27770.39840.86950.071*
C70.4284 (4)0.2848 (3)0.9258 (2)0.0614 (8)
H70.46310.33040.98870.074*
C80.4872 (4)0.1762 (3)0.90345 (17)0.0510 (6)
H80.56310.14750.95060.061*
C90.4892 (3)0.0078 (2)0.77955 (15)0.0375 (5)
C100.4316 (3)0.1099 (2)0.80903 (15)0.0374 (5)
C110.7405 (3)0.1884 (2)0.70068 (15)0.0379 (5)
C120.6962 (3)0.2983 (2)0.73835 (17)0.0436 (6)
H120.61510.33590.70030.052*
C130.7750 (4)0.3510 (3)0.83374 (18)0.0532 (7)
C140.8860 (4)0.2973 (3)0.89399 (18)0.0598 (8)
H140.93260.33300.95890.072*
C150.9260 (4)0.1880 (3)0.85439 (19)0.0542 (7)
C160.8593 (3)0.1328 (3)0.75767 (18)0.0453 (6)
H160.89380.06030.73200.054*
C170.6523 (3)0.1282 (2)0.59720 (15)0.0379 (5)
C180.1566 (5)0.4458 (2)0.5745 (2)0.0649 (9)
C190.1453 (4)0.3521 (2)0.5370 (2)0.0493 (6)
H190.21080.35270.47500.059*
C200.0353 (3)0.2573 (2)0.59295 (17)0.0389 (5)
C210.0565 (4)0.2563 (3)0.6862 (2)0.0500 (6)
H210.13050.19260.72470.060*
C220.0368 (5)0.3514 (3)0.7215 (2)0.0614 (8)
C230.0685 (5)0.4480 (3)0.6664 (3)0.0712 (10)
H230.07930.51190.69050.085*
C240.0180 (3)0.1546 (2)0.55254 (16)0.0355 (5)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Mn10.03053 (19)0.02918 (19)0.02440 (17)0.00030 (13)0.00124 (13)0.00366 (12)
O10.0393 (9)0.0550 (11)0.0352 (8)0.0084 (8)0.0051 (7)0.0101 (7)
O20.0468 (10)0.0725 (13)0.0392 (9)0.0048 (10)0.0099 (9)0.0201 (9)
O30.196 (4)0.0604 (17)0.098 (2)0.028 (2)0.038 (2)0.0012 (16)
O40.153 (3)0.095 (2)0.0660 (16)0.004 (2)0.0388 (19)0.0389 (15)
O50.096 (2)0.122 (3)0.101 (2)0.031 (2)0.0058 (18)0.052 (2)
O60.139 (3)0.186 (4)0.0575 (16)0.004 (3)0.0332 (18)0.037 (2)
O70.0440 (9)0.0370 (8)0.0404 (8)0.0037 (7)0.0025 (7)0.0131 (7)
O80.0496 (10)0.0395 (9)0.0418 (9)0.0127 (8)0.0026 (8)0.0118 (7)
O90.185 (4)0.135 (3)0.116 (3)0.027 (3)0.031 (3)0.096 (3)
O100.128 (3)0.181 (4)0.080 (2)0.033 (3)0.029 (2)0.076 (2)
O110.186 (3)0.089 (2)0.103 (2)0.074 (2)0.011 (2)0.0053 (18)
O120.258 (4)0.0625 (17)0.126 (2)0.060 (2)0.075 (3)0.0179 (16)
N10.0384 (10)0.0409 (10)0.0273 (8)0.0032 (8)0.0009 (8)0.0051 (8)
N20.0386 (10)0.0367 (10)0.0304 (9)0.0016 (8)0.0096 (8)0.0029 (8)
N30.104 (2)0.0537 (16)0.0596 (16)0.0104 (16)0.0344 (17)0.0166 (13)
N40.0609 (17)0.118 (3)0.0574 (17)0.0075 (19)0.0051 (14)0.0347 (18)
N50.150 (3)0.0545 (17)0.088 (2)0.0367 (19)0.049 (2)0.0044 (16)
N60.105 (3)0.110 (3)0.076 (2)0.018 (2)0.011 (2)0.064 (2)
C10.0555 (15)0.0459 (14)0.0360 (12)0.0148 (12)0.0040 (11)0.0037 (10)
C20.0646 (18)0.0476 (15)0.0535 (15)0.0183 (14)0.0001 (14)0.0096 (12)
C30.082 (2)0.0616 (19)0.0534 (16)0.0170 (17)0.0032 (16)0.0274 (15)
C40.078 (2)0.0630 (18)0.0306 (12)0.0100 (16)0.0007 (13)0.0133 (12)
C50.0510 (14)0.0403 (13)0.0463 (13)0.0041 (11)0.0184 (12)0.0043 (11)
C60.0699 (19)0.0443 (15)0.0585 (17)0.0035 (14)0.0291 (16)0.0086 (13)
C70.076 (2)0.0598 (18)0.0368 (13)0.0063 (16)0.0163 (14)0.0117 (12)
C80.0588 (16)0.0577 (16)0.0291 (11)0.0048 (13)0.0084 (11)0.0002 (11)
C90.0374 (11)0.0416 (12)0.0288 (10)0.0019 (10)0.0017 (9)0.0067 (9)
C100.0388 (12)0.0416 (12)0.0292 (10)0.0039 (10)0.0097 (9)0.0029 (9)
C110.0348 (11)0.0444 (13)0.0290 (10)0.0091 (10)0.0091 (9)0.0024 (9)
C120.0500 (14)0.0451 (14)0.0323 (11)0.0077 (11)0.0137 (11)0.0001 (10)
C130.0612 (17)0.0528 (16)0.0381 (13)0.0144 (13)0.0194 (13)0.0096 (11)
C140.0620 (17)0.078 (2)0.0282 (11)0.0223 (16)0.0083 (12)0.0051 (12)
C150.0426 (14)0.077 (2)0.0371 (12)0.0113 (14)0.0021 (11)0.0129 (13)
C160.0370 (12)0.0533 (15)0.0408 (12)0.0052 (11)0.0082 (11)0.0042 (11)
C170.0380 (12)0.0398 (12)0.0307 (10)0.0121 (10)0.0077 (10)0.0005 (9)
C180.094 (2)0.0348 (14)0.073 (2)0.0106 (14)0.0431 (19)0.0057 (13)
C190.0582 (16)0.0396 (13)0.0495 (14)0.0089 (11)0.0152 (13)0.0088 (11)
C200.0383 (12)0.0358 (12)0.0446 (12)0.0017 (10)0.0090 (10)0.0154 (10)
C210.0470 (14)0.0525 (15)0.0528 (14)0.0012 (12)0.0053 (12)0.0249 (12)
C220.0700 (19)0.0637 (19)0.0623 (17)0.0149 (16)0.0175 (15)0.0374 (15)
C230.111 (3)0.0457 (17)0.079 (2)0.0155 (18)0.047 (2)0.0338 (16)
C240.0326 (11)0.0338 (11)0.0401 (11)0.0016 (9)0.0063 (9)0.0124 (9)
Geometric parameters (Å, º) top
Mn1—O2i2.0921 (17)C3—H30.93
Mn1—O7ii2.1049 (16)C4—C91.385 (4)
Mn1—O82.1548 (17)C4—H40.93
Mn1—O12.2072 (17)C5—C61.384 (4)
Mn1—N22.2843 (18)C5—H50.93
Mn1—N12.3068 (19)C6—C71.359 (5)
O1—C171.247 (3)C6—H60.93
O2—C171.232 (3)C7—C81.372 (4)
O2—Mn1i2.0921 (17)C7—H70.93
O3—N31.200 (5)C8—C101.390 (3)
O4—N31.206 (4)C8—H80.93
O5—N41.197 (5)C9—C101.479 (3)
O6—N41.218 (4)C11—C161.377 (4)
O7—C241.247 (3)C11—C121.381 (4)
O7—Mn1ii2.1049 (16)C11—C171.509 (3)
O8—C241.246 (3)C12—C131.380 (3)
O9—N61.221 (5)C12—H120.93
O10—N61.199 (5)C13—C141.360 (5)
O11—N51.214 (5)C14—C151.371 (5)
O12—N51.206 (4)C14—H140.93
N1—C11.338 (3)C15—C161.387 (4)
N1—C91.343 (3)C16—H160.93
N2—C51.333 (3)C18—C231.366 (5)
N2—C101.338 (3)C18—C191.377 (4)
N3—C131.473 (4)C19—C201.379 (4)
N4—C151.477 (4)C19—H190.93
N5—C181.462 (5)C20—C211.383 (4)
N6—C221.464 (4)C20—C241.509 (3)
C1—C21.367 (4)C21—C221.383 (4)
C1—H10.93C21—H210.93
C2—C31.364 (4)C22—C231.374 (5)
C2—H20.93C23—H230.93
C3—C41.371 (4)
O2i—Mn1—O7ii95.08 (8)C6—C7—C8119.4 (2)
O2i—Mn1—O889.38 (8)C6—C7—H7120.3
O7ii—Mn1—O8100.91 (7)C8—C7—H7120.3
O2i—Mn1—O190.37 (7)C7—C8—C10118.8 (3)
O7ii—Mn1—O186.11 (7)C7—C8—H8120.6
O8—Mn1—O1172.96 (7)C10—C8—H8120.6
O2i—Mn1—N2172.86 (8)N1—C9—C4121.3 (2)
O7ii—Mn1—N291.82 (7)N1—C9—C10115.5 (2)
O8—Mn1—N291.12 (7)C4—C9—C10123.2 (2)
O1—Mn1—N288.26 (7)N2—C10—C8121.9 (2)
O2i—Mn1—N1101.98 (8)N2—C10—C9116.23 (18)
O7ii—Mn1—N1162.86 (7)C8—C10—C9121.9 (2)
O8—Mn1—N181.18 (7)C16—C11—C12120.5 (2)
O1—Mn1—N191.99 (7)C16—C11—C17120.2 (2)
N2—Mn1—N171.08 (7)C12—C11—C17119.3 (2)
C17—O1—Mn1123.87 (16)C13—C12—C11118.5 (3)
C17—O2—Mn1i139.47 (17)C13—C12—H12120.8
C24—O7—Mn1ii127.85 (15)C11—C12—H12120.8
C24—O8—Mn1132.18 (15)C14—C13—C12123.1 (3)
C1—N1—C9118.1 (2)C14—C13—N3118.8 (3)
C1—N1—Mn1122.49 (15)C12—C13—N3118.1 (3)
C9—N1—Mn1116.87 (15)C13—C14—C15116.8 (2)
C5—N2—C10118.4 (2)C13—C14—H14121.6
C5—N2—Mn1123.03 (17)C15—C14—H14121.6
C10—N2—Mn1118.08 (14)C14—C15—C16122.8 (3)
O3—N3—O4124.6 (3)C14—C15—N4119.7 (3)
O3—N3—C13118.1 (3)C16—C15—N4117.5 (3)
O4—N3—C13117.3 (4)C11—C16—C15118.2 (3)
O5—N4—O6124.0 (4)C11—C16—H16120.9
O5—N4—C15119.7 (3)C15—C16—H16120.9
O6—N4—C15116.2 (4)O2—C17—O1127.5 (2)
O12—N5—O11124.0 (4)O2—C17—C11116.1 (2)
O12—N5—C18118.5 (4)O1—C17—C11116.4 (2)
O11—N5—C18117.5 (3)C23—C18—C19123.0 (3)
O10—N6—O9123.6 (4)C23—C18—N5118.2 (3)
O10—N6—C22118.7 (3)C19—C18—N5118.8 (3)
O9—N6—C22117.7 (4)C18—C19—C20118.9 (3)
N1—C1—C2123.0 (2)C18—C19—H19120.6
N1—C1—H1118.5C20—C19—H19120.6
C2—C1—H1118.5C19—C20—C21119.8 (2)
C3—C2—C1118.9 (3)C19—C20—C24119.8 (2)
C3—C2—H2120.6C21—C20—C24120.4 (2)
C1—C2—H2120.6C22—C21—C20119.0 (3)
C2—C3—C4119.2 (3)C22—C21—H21120.5
C2—C3—H3120.4C20—C21—H21120.5
C4—C3—H3120.4C23—C22—C21122.3 (3)
C3—C4—C9119.4 (2)C23—C22—N6118.9 (3)
C3—C4—H4120.3C21—C22—N6118.9 (3)
C9—C4—H4120.3C18—C23—C22117.0 (3)
N2—C5—C6122.3 (3)C18—C23—H23121.5
N2—C5—H5118.8C22—C23—H23121.5
C6—C5—H5118.8O8—C24—O7128.0 (2)
C7—C6—C5119.1 (3)O8—C24—C20115.8 (2)
C7—C6—H6120.4O7—C24—C20116.1 (2)
C5—C6—H6120.4
O2i—Mn1—O1—C1793.31 (18)C11—C12—C13—C144.1 (4)
O7ii—Mn1—O1—C17171.63 (18)C11—C12—C13—N3178.6 (2)
N2—Mn1—O1—C1779.68 (18)O3—N3—C13—C14172.1 (4)
N1—Mn1—O1—C178.69 (18)O4—N3—C13—C147.4 (5)
O2i—Mn1—O8—C2412.4 (2)O3—N3—C13—C1210.5 (5)
O7ii—Mn1—O8—C2482.6 (2)O4—N3—C13—C12170.1 (3)
N2—Mn1—O8—C24174.7 (2)C12—C13—C14—C153.5 (4)
N1—Mn1—O8—C24114.6 (2)N3—C13—C14—C15179.2 (3)
O2i—Mn1—N1—C110.2 (2)C13—C14—C15—C160.4 (4)
O7ii—Mn1—N1—C1175.7 (2)C13—C14—C15—N4179.2 (3)
O8—Mn1—N1—C177.3 (2)O5—N4—C15—C14173.9 (3)
O1—Mn1—N1—C1101.0 (2)O6—N4—C15—C143.6 (5)
N2—Mn1—N1—C1171.5 (2)O5—N4—C15—C166.5 (5)
O2i—Mn1—N1—C9171.87 (17)O6—N4—C15—C16176.0 (3)
O7ii—Mn1—N1—C914.1 (4)C12—C11—C16—C153.0 (4)
O8—Mn1—N1—C984.40 (18)C17—C11—C16—C15174.8 (2)
O1—Mn1—N1—C997.33 (18)C14—C15—C16—C113.6 (4)
N2—Mn1—N1—C99.86 (17)N4—C15—C16—C11176.0 (2)
O7ii—Mn1—N2—C57.62 (19)Mn1i—O2—C17—O13.9 (5)
O8—Mn1—N2—C5108.58 (19)Mn1i—O2—C17—C11176.5 (2)
O1—Mn1—N2—C578.43 (19)Mn1—O1—C17—O294.1 (3)
N1—Mn1—N2—C5171.1 (2)Mn1—O1—C17—C1186.3 (2)
O7ii—Mn1—N2—C10179.63 (17)C16—C11—C17—O240.1 (3)
O8—Mn1—N2—C1079.41 (17)C12—C11—C17—O2142.1 (3)
O1—Mn1—N2—C1093.58 (17)C16—C11—C17—O1140.3 (2)
N1—Mn1—N2—C100.87 (16)C12—C11—C17—O137.6 (3)
C9—N1—C1—C21.0 (4)O12—N5—C18—C233.1 (6)
Mn1—N1—C1—C2160.4 (2)O11—N5—C18—C23176.9 (4)
N1—C1—C2—C31.2 (5)O12—N5—C18—C19177.2 (4)
C1—C2—C3—C40.4 (6)O11—N5—C18—C192.7 (6)
C2—C3—C4—C90.6 (6)C23—C18—C19—C202.4 (5)
C10—N2—C5—C60.3 (4)N5—C18—C19—C20177.9 (3)
Mn1—N2—C5—C6172.3 (2)C18—C19—C20—C212.2 (4)
N2—C5—C6—C70.6 (4)C18—C19—C20—C24178.8 (2)
C5—C6—C7—C80.1 (5)C19—C20—C21—C220.4 (4)
C6—C7—C8—C100.6 (5)C24—C20—C21—C22179.5 (2)
C1—N1—C9—C40.0 (4)C20—C21—C22—C231.2 (5)
Mn1—N1—C9—C4162.5 (2)C20—C21—C22—N6178.5 (3)
C1—N1—C9—C10179.4 (2)O10—N6—C22—C23174.7 (4)
Mn1—N1—C9—C1016.9 (3)O9—N6—C22—C237.0 (6)
C3—C4—C9—N10.8 (5)O10—N6—C22—C215.6 (6)
C3—C4—C9—C10178.6 (3)O9—N6—C22—C21172.8 (4)
C5—N2—C10—C80.4 (3)C19—C18—C23—C220.8 (5)
Mn1—N2—C10—C8172.00 (19)N5—C18—C23—C22179.5 (3)
C5—N2—C10—C9179.7 (2)C21—C22—C23—C181.0 (5)
Mn1—N2—C10—C97.3 (3)N6—C22—C23—C18178.7 (3)
C7—C8—C10—N20.8 (4)Mn1—O8—C24—O740.7 (4)
C7—C8—C10—C9179.9 (2)Mn1—O8—C24—C20139.60 (18)
N1—C9—C10—N216.1 (3)Mn1ii—O7—C24—O848.5 (3)
C4—C9—C10—N2163.3 (3)Mn1ii—O7—C24—C20131.17 (18)
N1—C9—C10—C8163.2 (2)C19—C20—C24—O8179.5 (2)
C4—C9—C10—C817.3 (4)C21—C20—C24—O80.5 (3)
C16—C11—C12—C130.6 (4)C19—C20—C24—O70.2 (3)
C17—C11—C12—C13178.5 (2)C21—C20—C24—O7179.3 (2)
Symmetry codes: (i) x+1, y, z+1; (ii) x, y, z+1.
 

Subscribe to Acta Crystallographica Section E: Crystallographic Communications

The full text of this article is available to subscribers to the journal.

If you have already registered and are using a computer listed in your registration details, please email support@iucr.org for assistance.

Buy online

You may purchase this article in PDF and/or HTML formats. For purchasers in the European Community who do not have a VAT number, VAT will be added at the local rate. Payments to the IUCr are handled by WorldPay, who will accept payment by credit card in several currencies. To purchase the article, please complete the form below (fields marked * are required), and then click on `Continue'.
E-mail address* 
Repeat e-mail address* 
(for error checking) 

Format*   PDF (US $40)
   HTML (US $40)
   PDF+HTML (US $50)
In order for VAT to be shown for your country javascript needs to be enabled.

VAT number 
(non-UK EC countries only) 
Country* 
 

Terms and conditions of use
Contact us

Follow Acta Cryst. E
Sign up for e-alerts
Follow Acta Cryst. on Twitter
Follow us on facebook
Sign up for RSS feeds