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Molecules of 4-hydroxy­isophthalic acid, C8H6O5, are disordered over two equally occupied orientations across a mirror plane. Each mol­ecule contains an O-H...O intramolecular hydrogen bond, and both carboxyl­ic acid groups are involved in R22(8) intermolecular hydrogen bonding. The crystal structure is further supported by [pi]-[pi]-stacking interactions.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803014740/cf6269sup1.cif
Contains datablocks global, 1

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536803014740/cf62691sup2.hkl
Contains datablock 1

CCDC reference: 221675

Key indicators

  • Single-crystal X-ray study
  • T = 120 K
  • Mean [sigma](C-C) = 0.004 Å
  • R factor = 0.084
  • wR factor = 0.214
  • Data-to-parameter ratio = 12.3

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry








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