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The title compound, [Rh(C8H12)(C20H16N2)](CF3SO3)·2C4H10O, was readily synthesized from the reaction between [RhCl(1,5-cyclo-octa­diene)]2 and (R)-(+)-1,1-bi­naphthyl-2,2'-di­amine in tetra­hydro­furan. The compound crystallizes in the non-centrosymmetric space group P212121 and contains one crystallograph­ically unique Rh+ metal centre in a pseudo-square-planar geometry.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536802022158/cf6228sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536802022158/cf6228Isup2.hkl
Contains datablock I

CCDC reference: 202967

Key indicators

  • Single-crystal X-ray study
  • T = 180 K
  • Mean [sigma](C-C) = 0.006 Å
  • R factor = 0.038
  • wR factor = 0.083
  • Data-to-parameter ratio = 14.8

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


Amber Alert Alert Level B:
PLAT_360 Alert B Short C(sp3)-C(sp3) Bond C(35) - C(36) = 1.32 Ang.
Author response: Please, see our comments on the _exptl_special_details section.
General Notes

REFLT_03 From the CIF: _diffrn_reflns_theta_max 25.03 From the CIF: _reflns_number_total 6615 Count of symmetry unique reflns 3720 Completeness (_total/calc) 177.82% TEST3: Check Friedels for noncentro structure Estimate of Friedel pairs measured 2895 Fraction of Friedel pairs measured 0.778 Are heavy atom types Z>Si present yes Please check that the estimate of the number of Friedel pairs is correct. If it is not, please give the correct count in the _publ_section_exptl_refinement section of the submitted CIF.
0 Alert Level A = Potentially serious problem
1 Alert Level B = Potential problem
0 Alert Level C = Please check

Computing details top

Data collection: COLLECT (Nonius, 1998); cell refinement: HKL SCALEPACK (Otwinowski & Minor, 1997); data reduction: HKL DENZO (Otwinowski & Minor, 1997) and SCALEPACK; program(s) used to solve structure: SIR92 (Altomare et al., 1994); program(s) used to refine structure: SHELXTL (Bruker, 2001); molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

[Rh(R)-(+)-1,1-binaphthyl-2,2'-diamine](1,5-cyclo-octadiene)rhodium(I) trifluoromethanesulfonate diethyl ether disolvate top
Crystal data top
[Rh(C8H12)(C20H16N2)](CF3SO3)·2C4H10ODx = 1.402 Mg m3
Mr = 792.74Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, P212121Cell parameters from 14723 reflections
a = 10.7729 (2) Åθ = 1.0–25.0°
b = 18.0442 (4) ŵ = 0.57 mm1
c = 19.3180 (5) ÅT = 180 K
V = 3755.19 (15) Å3Block, yellow
Z = 40.18 × 0.12 × 0.07 mm
F(000) = 1648
Data collection top
Nonius KappaCCD
diffractometer
5644 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tubeRint = 0.049
Thin–slice ω and φ scansθmax = 25.0°, θmin = 3.6°
Absorption correction: multi-scan
(SORTAV; Blessing, 1995)
h = 1212
Tmin = 0.915, Tmax = 0.955k = 2021
21982 measured reflectionsl = 2222
6615 independent reflections
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.038H-atom parameters constrained
wR(F2) = 0.083 w = 1/[σ2(Fo2) + (0.0321P)2 + 2.0203P]
where P = (Fo2 + 2Fc2)/3
S = 1.02(Δ/σ)max = 0.029
6615 reflectionsΔρmax = 0.37 e Å3
447 parametersΔρmin = 0.57 e Å3
4 restraintsAbsolute structure: Flack (1983); 2872 Friedel pairs
Primary atom site location: structure-invariant direct methodsAbsolute structure parameter: 0.03 (3)
Special details top

Experimental. The diethyl ether solvent molecules are not well resolved. The C—C distances in these moieties were restrained with the SHELXL DFIX instruction: final ls distance: 1.44 (2) Angstrom.

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Rh10.74028 (2)0.157887 (15)0.201350 (15)0.02779 (9)
N10.5980 (3)0.22107 (19)0.25164 (18)0.0263 (8)
H1A0.61200.27090.24490.032*
H1B0.52190.20940.23300.032*
N20.8730 (3)0.20692 (18)0.27095 (18)0.0267 (8)
H2A0.87650.17790.31000.032*
H2B0.94980.20460.25020.032*
C10.5983 (3)0.2048 (2)0.3242 (2)0.0256 (9)
C20.5157 (3)0.1497 (2)0.3504 (2)0.0301 (9)
H20.45960.12570.31980.036*
C30.5163 (3)0.1314 (2)0.4183 (2)0.0314 (10)
H30.45770.09640.43500.038*
C40.6025 (3)0.1636 (2)0.4652 (2)0.0296 (9)
C50.6054 (4)0.1440 (2)0.5362 (2)0.0393 (11)
H50.54630.10990.55410.047*
C60.6922 (4)0.1739 (2)0.5790 (2)0.0462 (12)
H60.69360.16030.62650.055*
C70.7797 (4)0.2246 (2)0.5536 (2)0.0444 (12)
H70.84090.24420.58400.053*
C80.7781 (4)0.2464 (2)0.4855 (2)0.0356 (10)
H80.83740.28140.46930.043*
C90.6878 (3)0.2168 (2)0.4389 (2)0.0282 (9)
C100.6818 (3)0.2391 (2)0.3685 (2)0.0268 (9)
C110.7623 (4)0.29890 (18)0.33977 (18)0.0251 (8)
C120.7394 (4)0.37516 (18)0.35806 (18)0.0269 (8)
C130.6449 (4)0.3966 (2)0.4039 (2)0.0346 (10)
H130.59390.35980.42460.042*
C140.6249 (4)0.4696 (2)0.4195 (2)0.0400 (11)
H140.56000.48290.45040.048*
C150.6999 (4)0.5248 (2)0.3899 (3)0.0448 (12)
H150.68650.57520.40180.054*
C160.7908 (4)0.5070 (2)0.3447 (3)0.0415 (12)
H160.83960.54510.32440.050*
C170.8140 (4)0.4309 (2)0.3272 (2)0.0332 (10)
C180.9078 (3)0.4110 (2)0.2797 (2)0.0365 (11)
H180.95770.44850.25930.044*
C190.9274 (3)0.3389 (2)0.2629 (2)0.0339 (9)
H190.99120.32620.23110.041*
C200.8530 (3)0.2824 (2)0.2927 (2)0.0283 (9)
C210.8824 (4)0.1217 (3)0.1316 (3)0.0470 (14)
H210.92500.16650.14180.056*
C220.8687 (4)0.0710 (3)0.1842 (3)0.0409 (12)
H220.90490.08270.22770.049*
C230.8001 (4)0.0026 (2)0.1781 (3)0.0504 (14)
H23A0.85150.03750.15080.060*
H23B0.78940.02390.22500.060*
C240.6740 (4)0.0044 (3)0.1441 (3)0.0621 (16)
H24A0.61900.03530.16180.075*
H24B0.68320.00260.09360.075*
C250.6131 (4)0.0799 (3)0.1578 (3)0.0422 (13)
H250.56480.08620.19850.051*
C260.6259 (4)0.1378 (3)0.1138 (3)0.0470 (13)
H260.58310.18220.12540.056*
C270.7022 (5)0.1388 (4)0.0475 (3)0.0694 (18)
H27A0.70470.19000.02920.083*
H27B0.66110.10710.01250.083*
C280.8344 (4)0.1114 (3)0.0585 (3)0.0596 (16)
H28A0.83810.05810.04660.072*
H28B0.89000.13810.02620.072*
C290.2291 (5)0.2652 (3)0.1255 (3)0.0519 (12)
S10.24695 (9)0.22864 (5)0.21199 (5)0.0361 (2)
O10.2687 (4)0.29281 (18)0.25334 (18)0.0686 (10)
O20.1303 (2)0.19173 (19)0.22331 (18)0.0495 (10)
O30.3507 (2)0.17899 (17)0.20498 (19)0.0456 (8)
F10.3307 (3)0.2979 (2)0.1032 (2)0.0922 (12)
F20.1367 (3)0.31403 (19)0.1219 (2)0.0886 (12)
F30.2025 (3)0.21188 (18)0.08006 (15)0.0808 (10)
O50.6558 (4)0.3612 (2)0.1582 (3)0.0918 (14)
C350.8273 (8)0.3573 (7)0.0773 (5)0.161 (4)
H35A0.85310.32660.03810.241*
H35B0.87940.34610.11750.241*
H35C0.83620.40980.06520.241*
C360.7099 (8)0.3432 (8)0.0924 (6)0.198 (6)
H36A0.69780.28930.08550.237*
H36B0.65910.36850.05680.237*
C370.5753 (7)0.4193 (4)0.1509 (4)0.094 (2)
H37A0.51410.40740.11430.113*
H37B0.62210.46380.13590.113*
C380.5095 (6)0.4358 (4)0.2152 (4)0.088 (2)
H38A0.44930.47560.20700.132*
H38B0.56920.45170.25050.132*
H38C0.46590.39140.23120.132*
O40.9436 (3)0.09958 (17)0.37244 (17)0.0471 (8)
C311.1670 (5)0.0861 (4)0.3852 (4)0.0793 (19)
H31A1.24130.11290.40030.119*
H31B1.17400.07440.33580.119*
H31C1.15920.04010.41180.119*
C321.0553 (4)0.1331 (3)0.3970 (3)0.0596 (15)
H32A1.04690.14310.44720.072*
H32B1.06700.18130.37330.072*
C330.8885 (4)0.0489 (3)0.4188 (3)0.0542 (14)
H33A0.85670.07550.45990.065*
H33B0.95110.01240.43450.065*
C340.7849 (4)0.0100 (3)0.3833 (3)0.0572 (14)
H34A0.73880.01990.41700.086*
H34B0.81840.02240.34710.086*
H34C0.72910.04660.36240.086*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Rh10.02232 (13)0.03253 (15)0.02852 (16)0.00234 (15)0.00116 (14)0.00350 (14)
N10.0235 (16)0.0314 (19)0.024 (2)0.0001 (14)0.0066 (14)0.0015 (16)
N20.0213 (15)0.0301 (19)0.029 (2)0.0026 (14)0.0018 (13)0.0009 (15)
C10.0215 (18)0.028 (2)0.027 (2)0.0052 (16)0.0029 (16)0.0004 (17)
C20.0236 (18)0.026 (2)0.041 (3)0.0036 (17)0.0024 (16)0.000 (2)
C30.026 (2)0.032 (2)0.037 (3)0.0015 (17)0.0037 (18)0.005 (2)
C40.0321 (19)0.026 (2)0.030 (2)0.0004 (19)0.0013 (16)0.0025 (19)
C50.052 (3)0.032 (2)0.034 (3)0.002 (2)0.002 (2)0.006 (2)
C60.071 (3)0.035 (3)0.032 (3)0.005 (2)0.011 (2)0.006 (2)
C70.060 (3)0.036 (2)0.037 (3)0.005 (2)0.016 (2)0.001 (2)
C80.037 (2)0.029 (2)0.041 (3)0.0025 (18)0.0072 (19)0.0005 (18)
C90.030 (2)0.024 (2)0.030 (3)0.0026 (16)0.0005 (18)0.0023 (18)
C100.0232 (18)0.026 (2)0.031 (3)0.0022 (15)0.0006 (17)0.0029 (18)
C110.0198 (18)0.0281 (18)0.028 (2)0.0050 (18)0.0004 (19)0.0006 (15)
C120.0260 (19)0.0262 (17)0.028 (2)0.0027 (18)0.007 (2)0.0002 (15)
C130.036 (2)0.032 (2)0.036 (3)0.0000 (18)0.0017 (19)0.0006 (19)
C140.046 (3)0.037 (3)0.037 (3)0.008 (2)0.003 (2)0.004 (2)
C150.054 (3)0.026 (2)0.054 (3)0.004 (2)0.001 (2)0.007 (2)
C160.046 (3)0.022 (2)0.056 (3)0.0029 (19)0.003 (2)0.004 (2)
C170.030 (2)0.033 (2)0.037 (3)0.0048 (18)0.0060 (18)0.0010 (19)
C180.029 (2)0.034 (2)0.046 (3)0.0077 (18)0.0001 (19)0.004 (2)
C190.0249 (18)0.038 (2)0.039 (3)0.003 (2)0.0050 (16)0.001 (2)
C200.0237 (17)0.028 (2)0.033 (2)0.0024 (15)0.0013 (19)0.0015 (19)
C210.035 (2)0.062 (3)0.044 (3)0.004 (2)0.005 (2)0.022 (3)
C220.034 (2)0.046 (3)0.043 (3)0.005 (2)0.006 (2)0.013 (2)
C230.046 (3)0.039 (3)0.066 (4)0.008 (2)0.006 (2)0.019 (2)
C240.045 (3)0.054 (3)0.087 (5)0.002 (2)0.015 (3)0.016 (3)
C250.031 (2)0.048 (3)0.048 (3)0.000 (2)0.004 (2)0.017 (3)
C260.034 (2)0.067 (4)0.040 (3)0.007 (2)0.004 (2)0.012 (3)
C270.064 (3)0.111 (5)0.034 (3)0.008 (3)0.003 (2)0.012 (3)
C280.046 (3)0.092 (4)0.041 (3)0.001 (3)0.007 (2)0.014 (3)
C290.056 (3)0.054 (3)0.046 (3)0.005 (3)0.006 (3)0.006 (2)
S10.0278 (5)0.0446 (5)0.0358 (6)0.0001 (5)0.0030 (6)0.0050 (4)
O10.081 (3)0.070 (2)0.055 (2)0.009 (2)0.011 (2)0.0320 (18)
O20.0211 (13)0.062 (2)0.066 (3)0.0000 (13)0.0083 (14)0.0127 (17)
O30.0221 (12)0.065 (2)0.050 (2)0.0091 (12)0.0064 (15)0.0099 (18)
F10.086 (2)0.113 (3)0.078 (3)0.026 (2)0.032 (2)0.028 (2)
F20.111 (3)0.083 (2)0.071 (3)0.050 (2)0.017 (2)0.030 (2)
F30.118 (3)0.083 (2)0.0415 (18)0.0130 (19)0.0223 (18)0.0080 (17)
O50.088 (3)0.086 (3)0.101 (4)0.016 (3)0.016 (3)0.025 (3)
C350.124 (7)0.263 (13)0.094 (7)0.045 (9)0.010 (6)0.026 (8)
C360.120 (7)0.299 (14)0.174 (10)0.067 (9)0.068 (7)0.173 (11)
C370.095 (5)0.065 (4)0.121 (7)0.003 (4)0.005 (5)0.017 (4)
C380.090 (4)0.084 (4)0.090 (6)0.020 (4)0.014 (4)0.003 (4)
O40.0373 (16)0.055 (2)0.049 (2)0.0047 (15)0.0121 (15)0.0189 (17)
C310.044 (3)0.102 (5)0.092 (5)0.004 (3)0.008 (3)0.011 (4)
C320.048 (3)0.071 (4)0.060 (4)0.007 (3)0.020 (3)0.007 (3)
C330.045 (3)0.062 (3)0.055 (4)0.004 (2)0.004 (2)0.022 (3)
C340.050 (3)0.055 (3)0.067 (4)0.005 (2)0.002 (3)0.016 (3)
Geometric parameters (Å, º) top
Rh1—C222.117 (4)C22—H220.950
Rh1—C262.124 (5)C23—C241.514 (6)
Rh1—C252.136 (4)C23—H23A0.990
Rh1—C212.141 (4)C23—H23B0.990
Rh1—N12.143 (3)C24—C251.534 (6)
Rh1—N22.153 (3)C24—H24A0.990
N1—C11.432 (5)C24—H24B0.990
N1—H1A0.920C25—C261.355 (7)
N1—H1B0.920C25—H250.950
N2—C201.441 (5)C26—C271.521 (7)
N2—H2A0.920C26—H260.950
N2—H2B0.920C27—C281.522 (7)
C1—C101.387 (5)C27—H27A0.990
C1—C21.427 (5)C27—H27B0.990
C2—C31.352 (5)C28—H28A0.990
C2—H20.950C28—H28B0.990
C3—C41.421 (5)C29—F11.317 (6)
C3—H30.950C29—F21.331 (5)
C4—C51.418 (6)C29—F31.334 (5)
C4—C91.423 (5)C29—S11.806 (5)
C5—C61.359 (6)S1—O11.426 (3)
C5—H50.950S1—O31.439 (3)
C6—C71.402 (6)S1—O21.439 (3)
C6—H60.950O5—C371.369 (7)
C7—C81.374 (6)O5—C361.435 (9)
C7—H70.950C35—C361.322 (9)
C8—C91.429 (5)C35—H35A0.980
C8—H80.950C35—H35B0.980
C9—C101.421 (6)C35—H35C0.980
C10—C111.491 (5)C36—H36A0.990
C11—C201.368 (5)C36—H36B0.990
C11—C121.442 (5)C37—C381.462 (8)
C12—C131.405 (6)C37—H37A0.990
C12—C171.419 (5)C37—H37B0.990
C13—C141.367 (6)C38—H38A0.980
C13—H130.950C38—H38B0.980
C14—C151.404 (6)C38—H38C0.980
C14—H140.950O4—C331.412 (5)
C15—C161.350 (6)O4—C321.428 (5)
C15—H150.950C31—C321.490 (7)
C16—C171.436 (6)C31—H31A0.980
C16—H160.950C31—H31B0.980
C17—C181.410 (6)C31—H31C0.980
C18—C191.358 (6)C32—H32A0.990
C18—H180.950C32—H32B0.990
C19—C201.418 (5)C33—C341.487 (6)
C19—H190.950C33—H33A0.990
C21—C221.376 (7)C33—H33B0.990
C21—C281.515 (7)C34—H34A0.980
C21—H210.950C34—H34B0.980
C22—C231.524 (6)C34—H34C0.980
C22—Rh1—C2697.38 (18)C24—C23—C22113.3 (4)
C22—Rh1—C2582.52 (15)C24—C23—H23A108.9
C26—Rh1—C2537.08 (18)C22—C23—H23A108.9
C22—Rh1—C2137.70 (18)C24—C23—H23B108.9
C26—Rh1—C2182.04 (17)C22—C23—H23B108.9
C25—Rh1—C2190.57 (19)H23A—C23—H23B107.7
C22—Rh1—N1158.79 (17)C23—C24—C25112.5 (4)
C26—Rh1—N192.12 (15)C23—C24—H24A109.1
C25—Rh1—N194.03 (15)C25—C24—H24A109.1
C21—Rh1—N1163.46 (18)C23—C24—H24B109.1
C22—Rh1—N288.16 (15)C25—C24—H24B109.1
C26—Rh1—N2162.31 (18)H24A—C24—H24B107.8
C25—Rh1—N2160.47 (17)C26—C25—C24122.2 (5)
C21—Rh1—N292.48 (16)C26—C25—Rh171.0 (3)
N1—Rh1—N288.47 (11)C24—C25—Rh1112.2 (3)
C1—N1—Rh1109.4 (2)C26—C25—H25118.9
C1—N1—H1A109.8C24—C25—H25118.9
Rh1—N1—H1A109.8Rh1—C25—H2586.9
C1—N1—H1B109.8C25—C26—C27126.3 (5)
Rh1—N1—H1B109.8C25—C26—Rh172.0 (3)
H1A—N1—H1B108.2C27—C26—Rh1110.8 (3)
C20—N2—Rh1118.1 (2)C25—C26—H26116.8
C20—N2—H2A107.8C27—C26—H26116.8
Rh1—N2—H2A107.8Rh1—C26—H2687.1
C20—N2—H2B107.8C26—C27—C28112.6 (5)
Rh1—N2—H2B107.8C26—C27—H27A109.1
H2A—N2—H2B107.1C28—C27—H27A109.1
C10—C1—C2119.8 (4)C26—C27—H27B109.1
C10—C1—N1120.9 (4)C28—C27—H27B109.1
C2—C1—N1119.2 (3)H27A—C27—H27B107.8
C3—C2—C1120.7 (4)C21—C28—C27114.2 (5)
C3—C2—H2119.6C21—C28—H28A108.7
C1—C2—H2119.6C27—C28—H28A108.7
C2—C3—C4121.4 (4)C21—C28—H28B108.7
C2—C3—H3119.3C27—C28—H28B108.7
C4—C3—H3119.3H28A—C28—H28B107.6
C5—C4—C3122.0 (4)F1—C29—F2107.9 (4)
C5—C4—C9119.9 (4)F1—C29—F3106.6 (4)
C3—C4—C9118.1 (4)F2—C29—F3106.4 (4)
C6—C5—C4120.3 (4)F1—C29—S1112.2 (4)
C6—C5—H5119.9F2—C29—S1111.7 (4)
C4—C5—H5119.9F3—C29—S1111.6 (3)
C5—C6—C7120.6 (4)O1—S1—O3115.5 (2)
C5—C6—H6119.7O1—S1—O2115.7 (2)
C7—C6—H6119.7O3—S1—O2113.87 (17)
C8—C7—C6120.9 (4)O1—S1—C29103.8 (2)
C8—C7—H7119.6O3—S1—C29102.9 (2)
C6—C7—H7119.6O2—S1—C29102.5 (2)
C7—C8—C9120.3 (4)C37—O5—C36109.8 (8)
C7—C8—H8119.9C36—C35—H35A109.5
C9—C8—H8119.9C36—C35—H35B109.5
C10—C9—C4120.2 (4)H35A—C35—H35B109.5
C10—C9—C8121.9 (4)C36—C35—H35C109.5
C4—C9—C8117.9 (4)H35A—C35—H35C109.5
C1—C10—C9119.6 (3)H35B—C35—H35C109.5
C1—C10—C11118.1 (4)C35—C36—O5122.7 (9)
C9—C10—C11122.3 (3)C35—C36—H36A106.7
C20—C11—C12119.6 (3)O5—C36—H36A106.7
C20—C11—C10120.3 (3)C35—C36—H36B106.7
C12—C11—C10120.0 (3)O5—C36—H36B106.7
C13—C12—C17118.7 (3)H36A—C36—H36B106.6
C13—C12—C11122.8 (3)O5—C37—C38112.1 (6)
C17—C12—C11118.5 (4)O5—C37—H37A109.2
C14—C13—C12121.2 (4)C38—C37—H37A109.2
C14—C13—H13119.4O5—C37—H37B109.2
C12—C13—H13119.4C38—C37—H37B109.2
C13—C14—C15120.2 (4)H37A—C37—H37B107.9
C13—C14—H14119.9C37—C38—H38A109.5
C15—C14—H14119.9C37—C38—H38B109.5
C16—C15—C14120.8 (4)H38A—C38—H38B109.5
C16—C15—H15119.6C37—C38—H38C109.5
C14—C15—H15119.6H38A—C38—H38C109.5
C15—C16—C17120.4 (4)H38B—C38—H38C109.5
C15—C16—H16119.8C33—O4—C32114.7 (4)
C17—C16—H16119.8C32—C31—H31A109.5
C18—C17—C12119.9 (4)C32—C31—H31B109.5
C18—C17—C16121.5 (4)H31A—C31—H31B109.5
C12—C17—C16118.7 (4)C32—C31—H31C109.5
C19—C18—C17120.7 (4)H31A—C31—H31C109.5
C19—C18—H18119.6H31B—C31—H31C109.5
C17—C18—H18119.6O4—C32—C31112.8 (4)
C18—C19—C20120.3 (4)O4—C32—H32A109.0
C18—C19—H19119.8C31—C32—H32A109.0
C20—C19—H19119.8O4—C32—H32B109.0
C11—C20—C19121.1 (3)C31—C32—H32B109.0
C11—C20—N2120.5 (3)H32A—C32—H32B107.8
C19—C20—N2118.5 (3)O4—C33—C34109.2 (4)
C22—C21—C28124.8 (5)O4—C33—H33A109.8
C22—C21—Rh170.2 (3)C34—C33—H33A109.8
C28—C21—Rh1112.3 (3)O4—C33—H33B109.8
C22—C21—H21117.6C34—C33—H33B109.8
C28—C21—H21117.6H33A—C33—H33B108.3
Rh1—C21—H2187.5C33—C34—H34A109.5
C21—C22—C23125.1 (5)C33—C34—H34B109.5
C21—C22—Rh172.1 (3)H34A—C34—H34B109.5
C23—C22—Rh1109.9 (3)C33—C34—H34C109.5
C21—C22—H22117.5H34A—C34—H34C109.5
C23—C22—H22117.5H34B—C34—H34C109.5
Rh1—C22—H2288.0
 

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