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The configuration about the Sn centre in the title compound, [Sn(CH3)3(C10H13N2O2)], is intermediate between tetrahedral and trigonal bipyramidal. A weak intramolecular Sn...O(carbonyl) interaction of 3.070 (3) Å gives rise to an intramolecular six-membered chelate ring, formed through the carbonyl O atom; this a unique feature of tetraorganotin compounds. The title compound was prepared by consecutive reaction of 3-(tert-butoxycarbonylamino)pyridine with n-butyllithium and trimethyltin chloride.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks global, rau35

fcf

Structure factor file (CIF format)
Contains datablock rau35

CCDC reference: 130064

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