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The structure of [Ni(medien)(NCS)(μ-SCN)]n [medien is N-(2-aminoethyl)-N-methylethane-1,2-diamine, C5H15N3] is a polymeric chain with each pair of neighbouring nickel(II) ions linked by one SCN bridging ligand. The coordination polyhedron about the NiII atom is a distorted octahedron consisting of three N atoms of the medien ligand coordinating facially, one N atom of the non-bridging thio­cyanate ligand, and one N and one S atom of two bridging thiocyanate ligands. The five-membered chelate rings display envelope geometry.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks medien, thiocyanate

sft

Structure factor file (SHELXL table format)
Supplementary material

CCDC reference: 129522

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