metal-organic compounds
In [N,N'-bis(2-pyridylmethyl)-1,3-propandiamine-N,N',N′′,N′′′]dichloroiron(III) perchlorate, [FeCl2(C15H20N4)][ClO4, the linear tetradentate ligand adopts the cis-β configuration which provides a favourable geometry for the six-membered chelate ring. The Fe—N distances show lengthening from the trans-influence of the chloride ligands with Fe—Npy values of 2.152 (3) and 2.179 (3) Å and Fe—Namine distances of 2.141 (4) and 2.178 (4) Å.
Supporting information
Crystallographic Information File (CIF) | |
Structure factor file (CIF format) |
CCDC reference: 129163