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In [N,N'-bis(2-pyridylmethyl)-1,3-propandiamine-N,N',N′′,N′′′]dichloroiron(III) perchlorate, [FeCl2(C15H20N4)][ClO4, the linear tetradentate ligand adopts the cis-β configuration which provides a favourable geometry for the six-membered chelate ring. The Fe—N distances show lengthening from the trans-influence of the chloride ligands with Fe—Npy values of 2.152 (3) and 2.179 (3) Å and Fe—Namine distances of 2.141 (4) and 2.178 (4) Å.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks elnfeyb, global

fcf

Structure factor file (CIF format)
Contains datablock elnfey

CCDC reference: 129163

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