metal-organic compounds
The title structure, bis[μ1,3-bis(dimethylamino)-2-propanolato]-1κN:2κN′, 1:2κ2O; 1κN:3κN′, 1:3κ2O-bis[1,3-bis(dimethylamino)-2-propanolato]-2κN, 2κO; 3κN, 3κO-dichloro-2κCl, 3κCl-methanol-1κO-tricopper(II), [Cu3Cl2(C7H17N2O)4(CH4O)], contains discrete molecules with C2 crystallographic symmetry and a non-linear Cu3 arrangement. Each Cu atom is five coordinate. The central Cu atom is coordinated by a methanol molecule and is bridged by one bdmap ligand [bdmap = 1,3-bis(dimethylamino)-2-propanolato] to each of the outer Cu atoms, which are additionally coordinated by a Cl atom and a chelating bdmap ligand.
Supporting information
Crystallographic Information File (CIF) |
CCDC reference: 126197