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In [CpMo(SPh)(CO)(CNtBu)2], Cp = η5-C5H5, the Mo atom adopts a conventional four-legged piano-stool coordination; a pair of cis CNtBu ligands, together with carbonyl and benzenethiolato groups, make up the base. The Mo—CNtBu bond lengths [2.053 (4) Å trans to S, 2.086 (4) Å trans to CO] show a small but significant difference.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablock new

fcf

Structure factor file (CIF format)
Contains datablock new

CCDC reference: 126192

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