(1,3-Dimesityldi­hydro­imidazol-2-yl­idene)(2-peroxidopropan-2-olato-κ²O,O′)(tri­phenyl­phosphine-κP)­platinum(II) benzene-d₆ disolvate

The title compound, [Pt(C₃H₆O₃)(C₂₁H₂₆N₂)(C₁₈H₁₅P)]·2C₆D₆, displays a rare platinacycle formed by a peroxoacetonate (2-peroxidopropan-2-olate) ligand and the Pt ion. The platinacycle adopts a half-chair conformation, with the local twofold rotation axis running through the Pt atom. The di­hydro­imidazol-2-yl­idene deviates significantly from planarity.

Key indicators

• Single-crystal X-ray study
• T = 150 K
• Mean [sigma](C-C) = 0.003 Å
• R factor = 0.018
• wR factor = 0.041
• Data-to-parameter ratio = 19.0

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT220_ALERT_2_B Large Non-Solvent    C     Ueq(max)/Ueq(min) ...       3.93 Ratio

Alert level C
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT222_ALERT_3_C Large Non-Solvent    H     Ueq(max)/Ueq(min) ...       3.37 Ratio
PLAT331_ALERT_2_C Small Average Phenyl C-C Dist.   C49    -C54           1.37 Ang.

   0 ALERT level A = In general: serious problem
   1 ALERT level B = Potentially serious problem
   3 ALERT level C = Check and explain
   0 ALERT level G = General alerts; check

   1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   2 ALERT type 2 Indicator that the structure model may be wrong or deficient
   1 ALERT type 3 Indicator that the structure quality may be low
   0 ALERT type 4 Improvement, methodology, query or suggestion

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Computing details

Data collection: COLLECT (Nonius, 1998); cell refinement: DENZO (Otwinowski & Minor, 1997); data reduction: DENZO; program(s) used to solve structure: DIRDIF (Beurskens et al., 1999); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: PLATON (Spek, 2003); software used to prepare material for publication: PLATON.

(II)

Crystal data

[Pt(C3H6O3)(C21H26N2)(C18H15P)]·2C6D6	Z = 2
Mr = 1022.11	F(000) = 1028
Triclinic, P1	Quoted _cell_measurement_* data items refer to the initial cell determination. The cell parameters as reported in _cell_* are based on the complete data set.
Hall symbol: -P 1	Dx = 1.461 Mg m^−3
a = 11.5582 (10) Å	Mo Kα radiation, λ = 0.71073 Å
b = 12.6032 (10) Å	Cell parameters from 574 reflections
c = 17.605 (2) Å	θ = 2.0–25.0°
α = 69.96 (3)°	µ = 3.10 mm^−1
β = 86.70 (4)°	T = 150 K
γ = 74.80 (3)°	Block, colourless
V = 2323.5 (7) Å^3	0.25 × 0.25 × 0.15 mm

Data collection

Nonius KappaCCD area-detector diffractometer	10600 independent reflections
Radiation source: Rotating Anode	9970 reflections with I2σ(I)
Graphite monochromator	Rint = 0.041
Detector resolution: 18.4 pixels mm^-1	θmax = 27.5°, θmin = 1.2°
φ scans and ω scans with κ offset	h = −14→14
Absorption correction: multi-scan PLATON/MULABS (Spek, 2003)	k = −16→16
Tmin = 0.494, Tmax = 0.629	l = −22→22
57354 measured reflections

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.018	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.041	H-atom parameters not refined
S = 1.07	w = 1/[σ^2(Fo^2) + (0.0131P)^2 + 1.2P] where P = (Fo^2 + 2Fc^2)/3
10600 reflections	(Δ/σ)max = 0.001
558 parameters	Δρmax = 1.12 e Å^−3
0 restraints	Δρmin = −0.83 e Å^−3

Special details

Geometry. Bond distances, angles etc. have been calculated using the rounded fractional coordinates. All su's are estimated from the variances of the (full) variance-covariance matrix. The cell e.s.d.'s are taken into account in the estimation of distances, angles and torsion angles

Refinement. Refinement on F² for ALL reflections except those flagged by the user for potential systematic errors. Weighted R-factors wR and all goodnesses of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The observed criterion of F² σ(F²) is used only for calculating -R-factor-obs etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R-factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq
Pt1	0.19139 (1)	0.11162 (1)	0.21289 (1)	0.0155 (1)
P1	0.19795 (4)	−0.06938 (4)	0.29939 (3)	0.0167 (1)
O1	0.18000 (12)	0.16419 (11)	0.31018 (8)	0.0213 (4)
O2	0.20546 (12)	0.33197 (11)	0.21161 (8)	0.0227 (4)
O3	0.17583 (12)	0.28307 (11)	0.15109 (8)	0.0211 (4)
N1	0.13165 (14)	0.12918 (14)	0.04770 (10)	0.0237 (5)
N2	0.30967 (13)	0.01205 (14)	0.08714 (9)	0.0206 (5)
C1	0.21225 (15)	0.07994 (15)	0.11004 (11)	0.0172 (5)
C2	0.16762 (18)	0.0797 (2)	−0.01771 (13)	0.0330 (7)
C3	0.30100 (18)	0.02642 (19)	0.00086 (12)	0.0287 (6)
C4	0.02205 (16)	0.22184 (17)	0.03557 (11)	0.0222 (5)
C5	−0.08421 (17)	0.19856 (17)	0.07069 (12)	0.0227 (6)
C6	−0.08794 (18)	0.08252 (18)	0.13176 (14)	0.0320 (7)
C7	−0.18963 (17)	0.28843 (18)	0.04808 (12)	0.0263 (6)
C8	−0.19155 (18)	0.39836 (18)	−0.00682 (12)	0.0272 (6)
C9	−0.30834 (19)	0.4921 (2)	−0.03076 (15)	0.0383 (7)
C10	−0.08380 (18)	0.41958 (18)	−0.03866 (12)	0.0278 (6)
C11	0.02360 (17)	0.33250 (18)	−0.01836 (12)	0.0252 (6)
C12	0.13828 (19)	0.3602 (2)	−0.05479 (14)	0.0358 (7)
C13	0.42590 (16)	−0.03469 (17)	0.12816 (11)	0.0218 (5)
C14	0.48765 (17)	0.04085 (18)	0.13938 (11)	0.0249 (6)
C15	0.44340 (18)	0.17181 (18)	0.10358 (14)	0.0302 (7)
C16	0.59778 (18)	−0.0084 (2)	0.18217 (13)	0.0343 (7)
C17	0.6492 (2)	−0.1282 (2)	0.21008 (14)	0.0418 (8)
C18	0.7667 (2)	−0.1794 (3)	0.25923 (17)	0.0676 (10)
C19	0.5908 (2)	−0.1988 (2)	0.19125 (14)	0.0407 (7)
C20	0.48014 (18)	−0.15456 (18)	0.14916 (13)	0.0299 (6)
C21	0.4279 (2)	−0.23556 (19)	0.12406 (16)	0.0418 (8)
C22	0.21817 (16)	−0.19515 (15)	0.26597 (11)	0.0198 (5)
C23	0.14515 (19)	−0.18346 (18)	0.20212 (13)	0.0296 (6)
C24	0.1435 (2)	−0.27897 (19)	0.18006 (14)	0.0336 (7)
C25	0.2164 (2)	−0.38795 (17)	0.22188 (13)	0.0306 (7)
C26	0.2903 (2)	−0.40036 (18)	0.28465 (14)	0.0331 (7)
C27	0.29210 (19)	−0.30476 (17)	0.30702 (13)	0.0282 (6)
C28	0.31383 (16)	−0.11180 (15)	0.37796 (11)	0.0193 (5)
C29	0.41245 (18)	−0.06451 (18)	0.35970 (13)	0.0285 (6)
C30	0.4986 (2)	−0.0886 (2)	0.41906 (15)	0.0375 (7)
C31	0.4871 (2)	−0.15977 (19)	0.49729 (14)	0.0350 (7)
C32	0.39157 (19)	−0.20960 (19)	0.51602 (12)	0.0309 (6)
C33	0.30498 (18)	−0.18578 (17)	0.45626 (12)	0.0254 (6)
C34	0.06105 (16)	−0.07838 (16)	0.35730 (11)	0.0209 (5)
C35	0.01782 (19)	−0.17749 (19)	0.38206 (13)	0.0321 (7)
C36	−0.0820 (2)	−0.1820 (2)	0.43036 (14)	0.0396 (8)
C37	−0.13938 (19)	−0.0880 (2)	0.45351 (13)	0.0368 (7)
C38	−0.0976 (2)	0.0104 (2)	0.42873 (14)	0.0392 (7)
C39	0.00209 (19)	0.01602 (18)	0.38090 (13)	0.0311 (7)
C40	0.1874 (2)	0.32672 (19)	0.34606 (13)	0.0337 (7)
C41	0.14411 (17)	0.28543 (16)	0.28342 (12)	0.0230 (6)
C42	0.00918 (19)	0.33310 (19)	0.26663 (14)	0.0346 (7)
C43	0.4867 (2)	0.3457 (2)	0.22866 (15)	0.0404 (8)
C44	0.5267 (2)	0.2300 (2)	0.27523 (15)	0.0393 (8)
C45	0.6479 (2)	0.1797 (2)	0.29104 (14)	0.0398 (8)
C46	0.7292 (2)	0.2444 (2)	0.26045 (15)	0.0394 (8)
C47	0.6905 (2)	0.3607 (2)	0.21396 (16)	0.0425 (8)
C48	0.5686 (2)	0.4116 (2)	0.19811 (16)	0.0432 (8)
C49	0.1827 (2)	0.4898 (2)	0.51178 (17)	0.0508 (9)
C50	0.1565 (3)	0.5467 (3)	0.56686 (19)	0.0592 (10)
C51	0.2447 (2)	0.5382 (2)	0.61953 (18)	0.0528 (10)
C52	0.3583 (2)	0.4726 (2)	0.61781 (17)	0.0463 (9)
C53	0.3842 (3)	0.4154 (3)	0.56218 (19)	0.0599 (11)
C54	0.2962 (3)	0.4242 (3)	0.50956 (17)	0.0548 (10)
H2A	0.15200	0.14140	−0.07170	0.0400*
H2B	0.12550	0.01960	−0.01500	0.0400*
H3A	0.32780	−0.04970	−0.00790	0.0340*
H3B	0.34860	0.07950	−0.03230	0.0340*
H6A	−0.04440	0.07010	0.18150	0.0480*
H6B	−0.05030	0.02020	0.11000	0.0480*
H6C	−0.17150	0.08130	0.14370	0.0480*
H7	−0.26270	0.27370	0.07110	0.0320*
H9A	−0.36450	0.46460	−0.05430	0.0580*
H9B	−0.29340	0.56310	−0.07070	0.0580*
H9C	−0.34280	0.50940	0.01720	0.0580*
H10	−0.08330	0.49520	−0.07510	0.0330*
H12A	0.16270	0.32360	−0.09610	0.0540*
H12B	0.20150	0.32990	−0.01230	0.0540*
H12C	0.12500	0.44510	−0.07960	0.0540*
H15A	0.40470	0.19330	0.05040	0.0450*
H15B	0.51130	0.20670	0.09760	0.0450*
H15C	0.38540	0.20070	0.13940	0.0450*
H16	0.63890	0.04170	0.19250	0.0410*
H18A	0.79970	−0.11590	0.26060	0.1010*
H18B	0.82380	−0.22920	0.23430	0.1010*
H18C	0.75260	−0.22610	0.31450	0.1010*
H19	0.62710	−0.28050	0.20750	0.0490*
H21A	0.34050	−0.20540	0.11780	0.0630*
H21B	0.44830	−0.31350	0.16550	0.0630*
H21C	0.46090	−0.24050	0.07250	0.0630*
H23	0.09530	−0.10870	0.17290	0.0350*
H24	0.09250	−0.26940	0.13640	0.0400*
H25	0.21550	−0.45380	0.20740	0.0370*
H26	0.34090	−0.47510	0.31310	0.0400*
H27	0.34390	−0.31460	0.35030	0.0340*
H29	0.42070	−0.01540	0.30610	0.0340*
H30	0.56570	−0.05620	0.40600	0.0450*
H31	0.54510	−0.17430	0.53820	0.0420*
H32	0.38480	−0.26000	0.56940	0.0370*
H33	0.23940	−0.22040	0.46920	0.0300*
H35	0.05640	−0.24250	0.36600	0.0380*
H36	−0.11060	−0.25040	0.44740	0.0470*
H37	−0.20740	−0.09130	0.48640	0.0440*
H38	−0.13730	0.07550	0.44440	0.0470*
H39	0.03010	0.08470	0.36420	0.0370*
H40A	0.15580	0.29100	0.39890	0.0510*
H40B	0.15890	0.41200	0.32970	0.0510*
H40C	0.27530	0.30360	0.34980	0.0510*
H42A	−0.01460	0.30870	0.22400	0.0520*
H42B	−0.01180	0.41870	0.24900	0.0520*
H42C	−0.03280	0.30260	0.31610	0.0520*
D43	0.40330	0.38050	0.21740	0.0480*
D44	0.47090	0.18470	0.29660	0.0470*
D45	0.67540	0.09960	0.32330	0.0480*
D46	0.81260	0.20890	0.27140	0.0470*
D47	0.74680	0.40570	0.19300	0.0510*
D48	0.54110	0.49190	0.16620	0.0520*
D49	0.12190	0.49620	0.47520	0.0610*
D50	0.07720	0.59220	0.56870	0.0710*
D51	0.22620	0.57840	0.65730	0.0630*
D52	0.41900	0.46630	0.65440	0.0560*
D53	0.46330	0.36960	0.56030	0.0720*
D54	0.31450	0.38440	0.47150	0.0660*

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pt1	0.0177 (1)	0.0162 (1)	0.0133 (1)	−0.0050 (1)	0.0022 (1)	−0.0058 (1)
P1	0.0195 (2)	0.0165 (2)	0.0147 (2)	−0.0055 (2)	0.0020 (2)	−0.0057 (2)
O1	0.0324 (7)	0.0177 (6)	0.0155 (6)	−0.0063 (5)	0.0037 (5)	−0.0082 (5)
O2	0.0306 (7)	0.0238 (7)	0.0187 (7)	−0.0133 (6)	0.0030 (5)	−0.0092 (5)
O3	0.0305 (7)	0.0166 (6)	0.0171 (6)	−0.0065 (5)	−0.0016 (5)	−0.0062 (5)
N1	0.0212 (8)	0.0329 (9)	0.0196 (8)	−0.0026 (7)	−0.0007 (6)	−0.0153 (7)
N2	0.0206 (8)	0.0257 (8)	0.0175 (8)	−0.0044 (6)	0.0033 (6)	−0.0114 (6)
C1	0.0190 (8)	0.0185 (9)	0.0166 (9)	−0.0083 (7)	0.0040 (7)	−0.0071 (7)
C2	0.0293 (11)	0.0501 (14)	0.0257 (11)	−0.0039 (10)	−0.0013 (9)	−0.0249 (10)
C3	0.0283 (10)	0.0396 (12)	0.0204 (10)	−0.0042 (9)	0.0031 (8)	−0.0169 (9)
C4	0.0202 (9)	0.0306 (10)	0.0181 (9)	−0.0040 (8)	−0.0032 (7)	−0.0123 (8)
C5	0.0226 (9)	0.0274 (10)	0.0203 (10)	−0.0065 (8)	−0.0035 (7)	−0.0102 (8)
C6	0.0248 (10)	0.0299 (11)	0.0404 (13)	−0.0079 (9)	−0.0029 (9)	−0.0095 (9)
C7	0.0201 (9)	0.0330 (11)	0.0269 (11)	−0.0070 (8)	−0.0008 (8)	−0.0111 (9)
C8	0.0251 (10)	0.0307 (11)	0.0243 (10)	−0.0038 (8)	−0.0053 (8)	−0.0091 (9)
C9	0.0276 (11)	0.0353 (12)	0.0414 (14)	−0.0013 (9)	−0.0072 (10)	−0.0036 (10)
C10	0.0315 (11)	0.0300 (11)	0.0217 (10)	−0.0098 (9)	−0.0027 (8)	−0.0065 (8)
C11	0.0237 (10)	0.0358 (11)	0.0189 (10)	−0.0095 (8)	−0.0006 (7)	−0.0114 (8)
C12	0.0326 (11)	0.0448 (13)	0.0313 (12)	−0.0161 (10)	0.0056 (9)	−0.0109 (10)
C13	0.0202 (9)	0.0275 (10)	0.0154 (9)	−0.0047 (8)	0.0053 (7)	−0.0063 (8)
C14	0.0204 (9)	0.0378 (11)	0.0178 (9)	−0.0067 (8)	0.0066 (7)	−0.0127 (8)
C15	0.0258 (10)	0.0360 (12)	0.0354 (12)	−0.0140 (9)	0.0076 (9)	−0.0171 (10)
C16	0.0233 (10)	0.0590 (15)	0.0222 (11)	−0.0112 (10)	0.0046 (8)	−0.0161 (10)
C17	0.0237 (11)	0.0625 (17)	0.0228 (11)	−0.0009 (11)	0.0033 (9)	−0.0022 (11)
C18	0.0345 (14)	0.098 (2)	0.0400 (16)	0.0024 (15)	−0.0090 (12)	0.0011 (16)
C19	0.0330 (12)	0.0360 (13)	0.0301 (12)	0.0072 (10)	0.0093 (10)	0.0040 (10)
C20	0.0286 (11)	0.0288 (11)	0.0253 (11)	−0.0030 (8)	0.0126 (8)	−0.0056 (9)
C21	0.0495 (14)	0.0273 (12)	0.0483 (15)	−0.0102 (10)	0.0231 (12)	−0.0156 (11)
C22	0.0234 (9)	0.0186 (9)	0.0188 (9)	−0.0072 (7)	0.0031 (7)	−0.0070 (7)
C23	0.0336 (11)	0.0257 (11)	0.0278 (11)	−0.0010 (9)	−0.0071 (9)	−0.0108 (9)
C24	0.0368 (12)	0.0352 (12)	0.0345 (12)	−0.0076 (9)	−0.0085 (9)	−0.0186 (10)
C25	0.0415 (12)	0.0238 (11)	0.0336 (12)	−0.0142 (9)	0.0052 (9)	−0.0150 (9)
C26	0.0461 (13)	0.0179 (10)	0.0322 (12)	−0.0033 (9)	−0.0040 (10)	−0.0075 (9)
C27	0.0363 (11)	0.0221 (10)	0.0259 (11)	−0.0054 (8)	−0.0055 (9)	−0.0083 (8)
C28	0.0225 (9)	0.0182 (9)	0.0182 (9)	−0.0032 (7)	0.0004 (7)	−0.0091 (7)
C29	0.0286 (10)	0.0302 (11)	0.0249 (11)	−0.0117 (9)	−0.0009 (8)	−0.0037 (9)
C30	0.0309 (11)	0.0408 (13)	0.0408 (13)	−0.0155 (10)	−0.0074 (10)	−0.0080 (10)
C31	0.0339 (12)	0.0379 (12)	0.0325 (12)	−0.0030 (10)	−0.0129 (9)	−0.0136 (10)
C32	0.0361 (11)	0.0329 (11)	0.0183 (10)	−0.0017 (9)	−0.0027 (8)	−0.0068 (9)
C33	0.0258 (10)	0.0274 (10)	0.0224 (10)	−0.0061 (8)	0.0026 (8)	−0.0086 (8)
C34	0.0189 (9)	0.0255 (10)	0.0160 (9)	−0.0063 (7)	−0.0006 (7)	−0.0037 (7)
C35	0.0347 (11)	0.0332 (12)	0.0321 (12)	−0.0163 (9)	0.0083 (9)	−0.0114 (9)
C36	0.0375 (12)	0.0478 (14)	0.0361 (13)	−0.0264 (11)	0.0087 (10)	−0.0073 (11)
C37	0.0219 (10)	0.0500 (14)	0.0278 (12)	−0.0085 (10)	0.0059 (8)	−0.0014 (10)
C38	0.0330 (12)	0.0358 (13)	0.0376 (13)	−0.0005 (10)	0.0145 (10)	−0.0069 (10)
C39	0.0310 (11)	0.0263 (11)	0.0313 (12)	−0.0067 (9)	0.0114 (9)	−0.0063 (9)
C40	0.0514 (14)	0.0309 (11)	0.0268 (11)	−0.0193 (10)	0.0073 (10)	−0.0144 (9)
C41	0.0287 (10)	0.0223 (10)	0.0204 (10)	−0.0085 (8)	0.0056 (8)	−0.0097 (8)
C42	0.0285 (11)	0.0333 (12)	0.0403 (13)	−0.0052 (9)	0.0091 (9)	−0.0138 (10)
C43	0.0316 (12)	0.0501 (15)	0.0437 (14)	−0.0048 (10)	−0.0021 (10)	−0.0251 (12)
C44	0.0442 (13)	0.0467 (14)	0.0357 (13)	−0.0196 (11)	0.0021 (10)	−0.0192 (11)
C45	0.0485 (14)	0.0377 (13)	0.0325 (13)	−0.0071 (11)	−0.0068 (10)	−0.0129 (10)
C46	0.0329 (12)	0.0475 (14)	0.0380 (13)	−0.0037 (10)	−0.0030 (10)	−0.0191 (11)
C47	0.0411 (13)	0.0478 (15)	0.0433 (14)	−0.0173 (11)	0.0035 (11)	−0.0172 (12)
C48	0.0472 (14)	0.0325 (13)	0.0468 (15)	−0.0030 (11)	−0.0044 (11)	−0.0143 (11)
C49	0.0494 (15)	0.0519 (16)	0.0473 (16)	−0.0060 (12)	−0.0119 (12)	−0.0154 (13)
C50	0.0405 (15)	0.0650 (19)	0.069 (2)	0.0057 (13)	−0.0008 (14)	−0.0330 (16)
C51	0.0543 (16)	0.0576 (17)	0.0531 (17)	−0.0049 (13)	0.0057 (13)	−0.0347 (14)
C52	0.0424 (14)	0.0501 (15)	0.0490 (16)	−0.0090 (12)	−0.0037 (12)	−0.0216 (13)
C53	0.0417 (15)	0.074 (2)	0.067 (2)	0.0043 (14)	−0.0014 (14)	−0.0415 (17)
C54	0.0598 (17)	0.0591 (18)	0.0485 (17)	−0.0024 (14)	−0.0032 (13)	−0.0309 (14)

Geometric parameters (Å, º)

Pt1—P1	2.2517 (6)	C9—H9A	0.9800
Pt1—O1	2.0238 (14)	C9—H9B	0.9800
Pt1—O3	2.0231 (14)	C9—H9C	0.9800
Pt1—C1	1.9726 (19)	C10—H10	0.9500
P1—C22	1.828 (2)	C12—H12A	0.9800
P1—C28	1.8232 (19)	C12—H12B	0.9800
P1—C34	1.840 (2)	C12—H12C	0.9800
O1—C41	1.388 (3)	C15—H15A	0.9800
O2—O3	1.495 (2)	C15—H15B	0.9800
O2—C41	1.432 (2)	C15—H15C	0.9800
N1—C1	1.344 (2)	C16—H16	0.9500
N1—C2	1.480 (3)	C18—H18A	0.9800
N1—C4	1.449 (3)	C18—H18B	0.9800
N2—C1	1.357 (3)	C18—H18C	0.9800
N2—C3	1.473 (3)	C19—H19	0.9500
N2—C13	1.442 (2)	C21—H21A	0.9800
C2—C3	1.516 (3)	C21—H21B	0.9800
C4—C5	1.398 (3)	C21—H21C	0.9800
C4—C11	1.397 (3)	C23—H23	0.9500
C5—C6	1.499 (3)	C24—H24	0.9500
C5—C7	1.396 (3)	C25—H25	0.9500
C7—C8	1.387 (3)	C26—H26	0.9500
C8—C9	1.511 (3)	C27—H27	0.9500
C8—C10	1.389 (3)	C29—H29	0.9500
C10—C11	1.393 (3)	C30—H30	0.9500
C11—C12	1.511 (3)	C31—H31	0.9500
C13—C14	1.399 (3)	C32—H32	0.9500
C13—C20	1.400 (3)	C33—H33	0.9500
C14—C15	1.505 (3)	C35—H35	0.9500
C14—C16	1.396 (3)	C36—H36	0.9500
C16—C17	1.389 (4)	C37—H37	0.9500
C17—C18	1.517 (4)	C38—H38	0.9500
C17—C19	1.378 (4)	C39—H39	0.9500
C19—C20	1.396 (3)	C40—H40A	0.9800
C20—C21	1.505 (3)	C40—H40B	0.9800
C22—C23	1.389 (3)	C40—H40C	0.9800
C22—C27	1.389 (3)	C42—H42A	0.9800
C23—C24	1.391 (3)	C42—H42B	0.9800
C24—C25	1.382 (3)	C42—H42C	0.9800
C25—C26	1.377 (3)	C43—C44	1.372 (4)
C26—C27	1.395 (3)	C43—C48	1.387 (3)
C28—C29	1.393 (3)	C44—C45	1.378 (3)
C28—C33	1.390 (3)	C45—C46	1.371 (3)
C29—C30	1.386 (3)	C46—C47	1.376 (4)
C30—C31	1.383 (3)	C47—C48	1.387 (3)
C31—C32	1.379 (3)	C43—D43	0.9500
C32—C33	1.395 (3)	C44—D44	0.9500
C34—C35	1.389 (3)	C45—D45	0.9500
C34—C39	1.391 (3)	C46—D46	0.9500
C35—C36	1.395 (3)	C47—D47	0.9500
C36—C37	1.377 (4)	C48—D48	0.9500
C37—C38	1.371 (3)	C49—C50	1.369 (4)
C38—C39	1.390 (3)	C49—C54	1.361 (4)
C40—C41	1.527 (3)	C50—C51	1.376 (4)
C41—C42	1.523 (3)	C51—C52	1.361 (4)
C2—H2A	0.9900	C52—C53	1.380 (4)
C2—H2B	0.9900	C53—C54	1.373 (5)
C3—H3A	0.9900	C49—D49	0.9500
C3—H3B	0.9900	C50—D50	0.9500
C6—H6A	0.9800	C51—D51	0.9500
C6—H6B	0.9800	C52—D52	0.9500
C6—H6C	0.9800	C53—D53	0.9500
C7—H7	0.9500	C54—D54	0.9500
Pt1···C5	3.850 (2)	C33···H38^vii	2.9300
Pt1···C6	3.756 (2)	C34···H33	2.7300
Pt1···C14	3.588 (2)	C35···H33	2.8900
Pt1···C15	3.504 (2)	C36···H40A^vii	3.0200
Pt1···H6A	3.0200	C37···H40A^vii	3.0000
Pt1···H15C	2.8200	C38···D45^iv	3.0300
Pt1···H23	3.5300	C38···D46^iv	3.0400
Pt1···H29	2.9600	C39···D46^iv	2.9800
Pt1···H39	3.1300	C40···H25^i	3.0800
Pt1···H42A	3.0100	C40···D54	3.1000
P1···O1	2.9670 (15)	C41···H39	3.0400
P1···C1	3.2375 (19)	C42···D51^x	3.0700
O1···P1	2.9670 (15)	C42···H39	2.9600
O1···O2	2.307 (2)	C42···D46^iv	3.0600
O1···O3	2.6820 (19)	C45···H16	2.8700
O1···C28	3.235 (2)	C45···H32^vi	2.9300
O1···C29	3.282 (3)	C47···H7^v	3.0400
O1···C39	3.065 (3)	C47···D51^xi	2.9100
O2···O1	2.307 (2)	H2A···C12	2.8400
O2···C43	3.336 (3)	H2A···H12A	2.2200
O3···C41	2.347 (2)	H2A···C11	2.9000
O3···C1	2.815 (2)	H2B···H6B^viii	2.1900
O3···C4	3.178 (2)	H2B···C6^viii	2.8800
O3···C11	3.338 (2)	H3A···C20	3.0500
O3···C15	3.235 (3)	H3A···H21A	2.3800
O3···O1	2.6820 (19)	H3A···H21C	2.4800
O3···N1	3.222 (2)	H3A···C21	2.7200
O1···H39	2.2300	H3A···C14^iii	3.0500
O2···H15C	2.8300	H3A···C16^iii	3.0300
O2···H25^i	2.7100	H3B···H15A	2.5700
O2···D43	2.5300	H3B···C13^iii	3.0600
O2···H9B^ii	2.6600	H3B···C14^iii	3.0800
O2···H10^ii	2.7800	H3B···C16^iii	3.0500
O3···H12B	2.7500	H3B···C17^iii	2.9800
O3···H15C	2.4000	H3B···C20^iii	2.8700
O3···H42A	2.4900	H3B···C19^iii	2.8300
O3···H9B^ii	2.6200	H6A···H23	2.4500
O3···H10^ii	2.6000	H6A···Pt1	3.0200
N1···O3	3.222 (2)	H6B···N1	2.7800
N1···H6B	2.7800	H6B···H23	2.0600
N1···H12A	2.9400	H6B···C2^viii	2.9400
N1···H12B	2.7000	H6B···C23	2.9700
N2···H15A	2.6600	H6B···H2B^viii	2.1900
N2···H21A	2.5300	H6C···H16^iv	2.4200
C1···P1	3.2375 (19)	H6C···H7	2.3100
C1···O3	2.815 (2)	H7···C47^iv	3.0400
C1···C6	3.462 (3)	H7···H6C	2.3100
C1···C15	3.160 (3)	H9B···O3^ii	2.6200
C1···C22	3.597 (3)	H9B···H10	2.3600
C1···C23	3.430 (3)	H9B···O2^ii	2.6600
C2···C12	3.295 (4)	H10···H12C	2.3300
C3···C17^iii	3.556 (3)	H10···O2^ii	2.7800
C3···C14^iii	3.527 (3)	H10···O3^ii	2.6000
C3···C21	3.267 (3)	H10···H9B	2.3600
C3···C16^iii	3.425 (3)	H12A···N1	2.9400
C4···O3	3.178 (2)	H12A···H2A	2.2200
C5···Pt1	3.850 (2)	H12A···C2	2.8900
C6···C1	3.462 (3)	H12B···O3	2.7500
C6···C23	3.582 (3)	H12B···N1	2.7000
C6···Pt1	3.756 (2)	H12B···H15A	2.5600
C7···C47^iv	3.460 (3)	H12C···H10	2.3300
C10···C12^ii	3.592 (3)	H12C···C10^ii	3.0600
C11···O3	3.338 (2)	H15A···N2	2.6600
C12···C10^ii	3.592 (3)	H15A···C1	2.9100
C12···C2	3.295 (4)	H15A···C3	3.0500
C14···C3^iii	3.527 (3)	H15A···H12B	2.5600
C14···Pt1	3.588 (2)	H15A···H21C^iii	2.5800
C15···O3	3.235 (3)	H15A···H3B	2.5700
C15···C44	3.581 (3)	H15B···H16	2.3600
C15···C1	3.160 (3)	H15C···Pt1	2.8200
C15···Pt1	3.504 (2)	H15C···O3	2.4000
C16···C3^iii	3.425 (3)	H15C···C1	2.9700
C17···C3^iii	3.556 (3)	H15C···O2	2.8300
C18···C36^v	3.556 (4)	H16···H6C^v	2.4200
C21···C23	3.461 (3)	H16···H15B	2.3600
C21···C3	3.267 (3)	H16···C45	2.8700
C21···C27	3.437 (3)	H16···H18A	2.3500
C21···C24	3.504 (3)	H18A···H16	2.3500
C21···C25	3.513 (3)	H19···H21B	2.4100
C21···C26	3.468 (3)	H21A···C23	2.6400
C21···C22	3.450 (3)	H21A···C22	2.9200
C22···C21	3.450 (3)	H21A···N2	2.5300
C23···C21	3.461 (3)	H21A···C24	2.7100
C23···C35	3.432 (3)	H21A···C25	3.0400
C23···C6	3.582 (3)	H21A···H3A	2.3800
C23···C1	3.430 (3)	H21A···C3	2.8800
C24···C21	3.504 (3)	H21B···C25	3.0700
C25···C21	3.513 (3)	H21B···C27	3.0100
C26···C21	3.468 (3)	H21B···H19	2.4100
C27···C21	3.437 (3)	H21B···C26	2.8200
C27···C35	3.560 (3)	H21B···D48^ix	2.4000
C27···C33	3.469 (3)	H21C···H3A	2.4800
C29···O1	3.282 (3)	H21C···H15A^iii	2.5800
C32···C45^vi	3.535 (3)	H23···Pt1	3.5300
C33···C35	3.600 (3)	H23···C1	2.9000
C33···C27	3.469 (3)	H23···C6	2.6700
C35···C23	3.432 (3)	H23···H6A	2.4500
C35···C27	3.560 (3)	H23···H6B	2.0600
C35···C33	3.600 (3)	H24···C11^viii	2.9600
C36···C18^iv	3.556 (4)	H24···C10^viii	2.9800
C38···C38^vii	3.369 (3)	H25···O2^ix	2.7100
C38···C39^vii	3.469 (3)	H25···C40^ix	3.0800
C39···C38^vii	3.469 (3)	H25···D43^ix	2.5500
C39···O1	3.065 (3)	H25···H40B^ix	2.4200
C43···O2	3.336 (3)	H27···C28	2.6900
C44···C15	3.581 (3)	H27···C33	2.8100
C45···C32^vi	3.535 (3)	H29···C14	2.8800
C47···C7^v	3.460 (3)	H29···Pt1	2.9600
C1···H15A	2.9100	H29···C16	2.9000
C1···H23	2.9000	H30···D45	2.5900
C1···H15C	2.9700	H32···C45^vi	2.9300
C2···H6B^viii	2.9400	H33···C35	2.8900
C2···H12A	2.8900	H33···C34	2.7300
C3···H21A	2.8800	H35···C23	2.9200
C3···H15A	3.0500	H35···C27	2.8700
C6···H23	2.6700	H35···C22	2.5400
C6···H2B^viii	2.8800	H37···H40A^vii	2.5800
C10···H12C^ii	3.0600	H38···C33^vii	2.9300
C10···H24^viii	2.9800	H39···O1	2.2300
C11···H24^viii	2.9600	H39···C41	3.0400
C11···H2A	2.9000	H39···Pt1	3.1300
C12···H2A	2.8400	H39···C42	2.9600
C13···H3B^iii	3.0600	H39···H42C	2.4900
C14···H3A^iii	3.0500	H40A···C36^vii	3.0200
C14···H3B^iii	3.0800	H40A···C37^vii	3.0000
C14···H29	2.8800	H40A···H37^vii	2.5800
C16···H29	2.9000	H40B···C25^i	2.8000
C16···H3B^iii	3.0500	H40B···C26^i	3.0000
C16···H3A^iii	3.0300	H40B···H42B	2.4600
C17···H3B^iii	2.9800	H40B···H25^i	2.4200
C19···H3B^iii	2.8300	H42A···O3	2.4900
C20···H3A	3.0500	H42A···D46^iv	2.5800
C20···H3B^iii	2.8700	H42A···Pt1	3.0100
C21···H3A	2.7200	H42B···H40B	2.4600
C22···H21A	2.9200	H42C···H39	2.4900
C22···H35	2.5400	H42C···D51^x	2.4600
C23···H35	2.9200	D43···O2	2.5300
C23···H21A	2.6400	D43···H25^i	2.5500
C23···H6B	2.9700	D45···C38^v	3.0300
C24···H21A	2.7100	D45···H30	2.5900
C25···H21A	3.0400	D46···C38^v	3.0400
C25···H40B^ix	2.8000	D46···C39^v	2.9800
C25···H21B	3.0700	D46···C42^v	3.0600
C26···H40B^ix	3.0000	D46···H42A^v	2.5800
C26···H21B	2.8200	D48···H21B^i	2.4000
C27···H35	2.8700	D51···C42^x	3.0700
C27···H21B	3.0100	D51···C47^xi	2.9100
C28···H27	2.6900	D51···H42C^x	2.4600
C31···D54^vi	3.0400	D53···C31^vi	3.0500
C31···D53^vi	3.0500	D53···C32^vi	2.9200
C32···D53^vi	2.9200	D54···C40	3.1000
C33···H27	2.8100	D54···C31^vi	3.0400
P1—Pt1—O1	87.72 (6)	C8—C10—H10	119.00
P1—Pt1—O3	170.40 (6)	C11—C10—H10	119.00
P1—Pt1—C1	99.85 (7)	C11—C12—H12A	109.00
O1—Pt1—O3	83.02 (7)	C11—C12—H12B	109.00
O1—Pt1—C1	171.66 (8)	C11—C12—H12C	109.00
O3—Pt1—C1	89.55 (8)	H12A—C12—H12B	109.00
Pt1—P1—C22	122.59 (7)	H12A—C12—H12C	109.00
Pt1—P1—C28	109.63 (8)	H12B—C12—H12C	110.00
Pt1—P1—C34	113.40 (8)	C14—C15—H15A	109.00
C22—P1—C28	105.90 (10)	C14—C15—H15B	109.00
C22—P1—C34	100.32 (10)	C14—C15—H15C	109.00
C28—P1—C34	103.00 (9)	H15A—C15—H15B	109.00
Pt1—O1—C41	108.43 (12)	H15A—C15—H15C	109.00
O3—O2—C41	106.54 (14)	H15B—C15—H15C	109.00
Pt1—O3—O2	105.39 (10)	C14—C16—H16	119.00
C1—N1—C2	111.69 (17)	C17—C16—H16	119.00
C1—N1—C4	130.14 (17)	C17—C18—H18A	109.00
C2—N1—C4	118.14 (17)	C17—C18—H18B	109.00
C1—N2—C3	111.88 (16)	C17—C18—H18C	110.00
C1—N2—C13	125.48 (16)	H18A—C18—H18B	109.00
C3—N2—C13	118.99 (16)	H18A—C18—H18C	109.00
Pt1—C1—N1	124.43 (15)	H18B—C18—H18C	109.00
Pt1—C1—N2	127.63 (14)	C17—C19—H19	119.00
N1—C1—N2	107.85 (16)	C20—C19—H19	119.00
N1—C2—C3	101.80 (17)	C20—C21—H21A	109.00
N2—C3—C2	101.59 (17)	C20—C21—H21B	110.00
N1—C4—C5	120.95 (19)	C20—C21—H21C	109.00
N1—C4—C11	117.62 (18)	H21A—C21—H21B	109.00
C5—C4—C11	121.16 (19)	H21A—C21—H21C	109.00
C4—C5—C6	122.49 (19)	H21B—C21—H21C	109.00
C4—C5—C7	117.86 (19)	C22—C23—H23	119.00
C6—C5—C7	119.65 (19)	C24—C23—H23	119.00
C5—C7—C8	122.4 (2)	C23—C24—H24	120.00
C7—C8—C9	120.4 (2)	C25—C24—H24	120.00
C7—C8—C10	118.3 (2)	C24—C25—H25	120.00
C9—C8—C10	121.3 (2)	C26—C25—H25	120.00
C8—C10—C11	121.5 (2)	C25—C26—H26	119.00
C4—C11—C10	118.84 (19)	C27—C26—H26	119.00
C4—C11—C12	121.8 (2)	C22—C27—H27	120.00
C10—C11—C12	119.3 (2)	C26—C27—H27	120.00
N2—C13—C14	119.94 (19)	C28—C29—H29	120.00
N2—C13—C20	118.94 (19)	C30—C29—H29	120.00
C14—C13—C20	120.83 (19)	C29—C30—H30	120.00
C13—C14—C15	122.71 (19)	C31—C30—H30	120.00
C13—C14—C16	118.0 (2)	C30—C31—H31	120.00
C15—C14—C16	119.2 (2)	C32—C31—H31	120.00
C14—C16—C17	122.1 (2)	C31—C32—H32	120.00
C16—C17—C18	120.8 (2)	C33—C32—H32	120.00
C16—C17—C19	118.0 (2)	C28—C33—H33	120.00
C18—C17—C19	121.2 (2)	C32—C33—H33	120.00
C17—C19—C20	122.3 (2)	C34—C35—H35	120.00
C13—C20—C19	118.1 (2)	C36—C35—H35	120.00
C13—C20—C21	122.8 (2)	C35—C36—H36	120.00
C19—C20—C21	119.0 (2)	C37—C36—H36	120.00
P1—C22—C23	117.82 (16)	C36—C37—H37	120.00
P1—C22—C27	123.23 (16)	C38—C37—H37	120.00
C23—C22—C27	118.50 (19)	C37—C38—H38	120.00
C22—C23—C24	121.4 (2)	C39—C38—H38	120.00
C23—C24—C25	119.7 (2)	C34—C39—H39	120.00
C24—C25—C26	119.5 (2)	C38—C39—H39	120.00
C25—C26—C27	121.0 (2)	C41—C40—H40A	109.00
C22—C27—C26	120.0 (2)	C41—C40—H40B	109.00
P1—C28—C29	118.72 (15)	C41—C40—H40C	109.00
P1—C28—C33	122.42 (16)	H40A—C40—H40B	109.00
C29—C28—C33	118.82 (19)	H40A—C40—H40C	109.00
C28—C29—C30	120.5 (2)	H40B—C40—H40C	109.00
C29—C30—C31	120.1 (2)	C41—C42—H42A	109.00
C30—C31—C32	120.1 (2)	C41—C42—H42B	109.00
C31—C32—C33	119.8 (2)	C41—C42—H42C	109.00
C28—C33—C32	120.6 (2)	H42A—C42—H42B	109.00
P1—C34—C35	122.89 (17)	H42A—C42—H42C	110.00
P1—C34—C39	118.36 (16)	H42B—C42—H42C	109.00
C35—C34—C39	118.66 (19)	C44—C43—C48	119.7 (2)
C34—C35—C36	120.3 (2)	C43—C44—C45	119.9 (2)
C35—C36—C37	120.5 (2)	C44—C45—C46	120.5 (2)
C36—C37—C38	119.5 (2)	C45—C46—C47	120.3 (2)
C37—C38—C39	120.8 (2)	C46—C47—C48	119.4 (2)
C34—C39—C38	120.4 (2)	C43—C48—C47	120.2 (2)
O1—C41—O2	109.77 (16)	C44—C43—D43	120.00
O1—C41—C40	108.31 (17)	C48—C43—D43	120.00
O1—C41—C42	112.58 (18)	C43—C44—D44	120.00
O2—C41—C40	104.72 (17)	C45—C44—D44	120.00
O2—C41—C42	109.44 (17)	C44—C45—D45	120.00
C40—C41—C42	111.73 (18)	C46—C45—D45	120.00
N1—C2—H2A	111.00	C45—C46—D46	120.00
N1—C2—H2B	111.00	C47—C46—D46	120.00
C3—C2—H2A	111.00	C46—C47—D47	120.00
C3—C2—H2B	111.00	C48—C47—D47	120.00
H2A—C2—H2B	109.00	C43—C48—D48	120.00
N2—C3—H3A	111.00	C47—C48—D48	120.00
N2—C3—H3B	111.00	C50—C49—C54	119.8 (3)
C2—C3—H3A	111.00	C49—C50—C51	120.2 (3)
C2—C3—H3B	111.00	C50—C51—C52	120.4 (3)
H3A—C3—H3B	109.00	C51—C52—C53	119.2 (3)
C5—C6—H6A	109.00	C52—C53—C54	120.3 (3)
C5—C6—H6B	110.00	C49—C54—C53	120.1 (3)
C5—C6—H6C	109.00	C50—C49—D49	120.00
H6A—C6—H6B	109.00	C54—C49—D49	120.00
H6A—C6—H6C	110.00	C49—C50—D50	120.00
H6B—C6—H6C	109.00	C51—C50—D50	120.00
C5—C7—H7	119.00	C50—C51—D51	120.00
C8—C7—H7	119.00	C52—C51—D51	120.00
C8—C9—H9A	109.00	C51—C52—D52	120.00
C8—C9—H9B	109.00	C53—C52—D52	120.00
C8—C9—H9C	109.00	C52—C53—D53	120.00
H9A—C9—H9B	109.00	C54—C53—D53	120.00
H9A—C9—H9C	110.00	C49—C54—D54	120.00
H9B—C9—H9C	109.00	C53—C54—D54	120.00
O1—Pt1—P1—C22	−176.46 (9)	N1—C4—C11—C12	−7.9 (3)
O1—Pt1—P1—C28	−51.49 (9)	C5—C4—C11—C10	−1.7 (3)
O1—Pt1—P1—C34	62.99 (9)	C5—C4—C11—C12	178.0 (2)
C1—Pt1—P1—C22	0.00 (11)	N1—C4—C5—C6	9.1 (3)
C1—Pt1—P1—C28	124.98 (9)	C4—C5—C7—C8	−0.5 (3)
C1—Pt1—P1—C34	−120.53 (10)	C6—C5—C7—C8	178.7 (2)
P1—Pt1—O1—C41	−165.54 (13)	C5—C7—C8—C9	178.7 (2)
O3—Pt1—O1—C41	11.95 (13)	C5—C7—C8—C10	−1.5 (3)
O1—Pt1—O3—O2	17.73 (10)	C7—C8—C10—C11	1.9 (3)
C1—Pt1—O3—O2	−158.47 (11)	C9—C8—C10—C11	−178.3 (2)
P1—Pt1—C1—N1	119.21 (16)	C8—C10—C11—C4	−0.3 (3)
P1—Pt1—C1—N2	−64.74 (18)	C8—C10—C11—C12	179.9 (2)
O3—Pt1—C1—N1	−58.86 (17)	N2—C13—C14—C15	−5.8 (3)
O3—Pt1—C1—N2	117.19 (18)	C20—C13—C14—C15	167.9 (2)
Pt1—P1—C22—C23	−49.50 (19)	C20—C13—C14—C16	−8.7 (3)
Pt1—P1—C22—C27	138.37 (16)	N2—C13—C20—C19	−177.88 (19)
C28—P1—C22—C23	−176.12 (16)	N2—C13—C20—C21	5.9 (3)
C28—P1—C22—C27	11.8 (2)	C14—C13—C20—C19	8.3 (3)
C34—P1—C22—C23	77.04 (18)	C14—C13—C20—C21	−167.9 (2)
C34—P1—C22—C27	−95.09 (19)	N2—C13—C14—C16	177.55 (18)
Pt1—P1—C28—C29	−28.46 (19)	C13—C14—C16—C17	3.0 (3)
Pt1—P1—C28—C33	148.85 (16)	C15—C14—C16—C17	−173.7 (2)
C22—P1—C28—C29	105.66 (18)	C14—C16—C17—C19	2.9 (3)
C22—P1—C28—C33	−77.04 (19)	C14—C16—C17—C18	−177.6 (2)
C34—P1—C28—C29	−149.45 (17)	C16—C17—C19—C20	−3.3 (4)
C34—P1—C28—C33	27.9 (2)	C18—C17—C19—C20	177.2 (2)
Pt1—P1—C34—C35	147.85 (16)	C17—C19—C20—C21	174.2 (2)
Pt1—P1—C34—C39	−35.68 (18)	C17—C19—C20—C13	−2.2 (3)
C22—P1—C34—C35	15.37 (19)	C27—C22—C23—C24	1.2 (3)
C22—P1—C34—C39	−168.15 (16)	P1—C22—C27—C26	170.99 (17)
C28—P1—C34—C35	−93.76 (18)	C23—C22—C27—C26	−1.1 (3)
C28—P1—C34—C39	82.72 (18)	P1—C22—C23—C24	−171.33 (18)
Pt1—O1—C41—O2	−41.44 (18)	C22—C23—C24—C25	−0.5 (3)
Pt1—O1—C41—C40	−155.22 (14)	C23—C24—C25—C26	−0.4 (4)
Pt1—O1—C41—C42	80.74 (18)	C24—C25—C26—C27	0.4 (4)
C41—O2—O3—Pt1	−44.14 (15)	C25—C26—C27—C22	0.3 (3)
O3—O2—C41—O1	58.02 (18)	P1—C28—C29—C30	175.86 (19)
O3—O2—C41—C40	174.09 (15)	C33—C28—C29—C30	−1.5 (3)
O3—O2—C41—C42	−66.01 (19)	P1—C28—C33—C32	−175.52 (18)
C2—N1—C1—Pt1	−174.61 (15)	C29—C28—C33—C32	1.8 (3)
C2—N1—C1—N2	8.7 (2)	C28—C29—C30—C31	−0.2 (4)
C4—N1—C1—Pt1	7.5 (3)	C29—C30—C31—C32	1.8 (4)
C4—N1—C1—N2	−169.24 (19)	C30—C31—C32—C33	−1.5 (4)
C1—N1—C2—C3	−19.8 (2)	C31—C32—C33—C28	−0.3 (3)
C4—N1—C2—C3	158.40 (18)	C39—C34—C35—C36	−0.7 (3)
C1—N1—C4—C5	−81.5 (3)	P1—C34—C39—C38	−176.23 (17)
C1—N1—C4—C11	104.4 (2)	C35—C34—C39—C38	0.4 (3)
C2—N1—C4—C5	100.7 (2)	P1—C34—C35—C36	175.78 (17)
C2—N1—C4—C11	−73.4 (2)	C34—C35—C36—C37	0.5 (3)
C3—N2—C1—Pt1	−169.51 (15)	C35—C36—C37—C38	0.0 (3)
C3—N2—C1—N1	7.1 (2)	C36—C37—C38—C39	−0.3 (3)
C13—N2—C1—Pt1	−11.5 (3)	C37—C38—C39—C34	0.1 (3)
C13—N2—C1—N1	165.12 (18)	C48—C43—C44—C45	−0.4 (4)
C1—N2—C3—C2	−18.8 (2)	C44—C43—C48—C47	0.5 (4)
C13—N2—C3—C2	−178.43 (18)	C43—C44—C45—C46	−0.1 (4)
C1—N2—C13—C14	−57.9 (3)	C44—C45—C46—C47	0.4 (4)
C1—N2—C13—C20	128.3 (2)	C45—C46—C47—C48	−0.3 (4)
C3—N2—C13—C14	98.8 (2)	C46—C47—C48—C43	−0.2 (4)
C3—N2—C13—C20	−75.1 (2)	C54—C49—C50—C51	0.4 (5)
N1—C2—C3—N2	21.6 (2)	C50—C49—C54—C53	−0.2 (5)
C11—C4—C5—C6	−177.0 (2)	C49—C50—C51—C52	−0.5 (5)
N1—C4—C5—C7	−171.78 (19)	C50—C51—C52—C53	0.5 (4)
C11—C4—C5—C7	2.1 (3)	C51—C52—C53—C54	−0.3 (5)
N1—C4—C11—C10	172.35 (19)	C52—C53—C54—C49	0.2 (5)

Symmetry codes: (i) x, y+1, z; (ii) −x, −y+1, −z; (iii) −x+1, −y, −z; (iv) x−1, y, z; (v) x+1, y, z; (vi) −x+1, −y, −z+1; (vii) −x, −y, −z+1; (viii) −x, −y, −z; (ix) x, y−1, z; (x) −x, −y+1, −z+1; (xi) −x+1, −y+1, −z+1.

Hydrogen-bond geometry (Å, º)

D—H···A	D—H	H···A	D···A	D—H···A
C15—H15C···O3	0.98	2.40	3.235 (3)	143
C21—H21A···N2	0.98	2.53	2.916 (3)	103
C39—H39···O1	0.95	2.23	3.065 (3)	146
C42—H42A···O3	0.98	2.49	2.835 (3)	101
C43—D43···O2	0.95	2.53	3.336 (3)	142