Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806044606/bv2037sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536806044606/bv2037Isup2.hkl |
CCDC reference: 629454
Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL, Sheldrick (2001); software used to prepare material for publication: SHELXTL.
[Mn(C19H27N6O3S)2]·2CH2Cl2 | F(000) = 1110 |
Mr = 1063.84 | Dx = 1.441 Mg m−3 |
Monoclinic, P21/c | Mo Kα radiation, λ = 0.71073 Å |
Hall symbol: -P 2ybc | Cell parameters from 994 reflections |
a = 10.437 (6) Å | θ = 2.7–24.3° |
b = 21.860 (8) Å | µ = 0.63 mm−1 |
c = 11.341 (6) Å | T = 120 K |
β = 108.626 (7)° | Block, colourless |
V = 2452 (2) Å3 | 0.20 × 0.10 × 0.05 mm |
Z = 2 |
Bruker APEX diffractometer | 4285 independent reflections |
Radiation source: fine-focus sealed tube | 3243 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.092 |
Detector resolution: 835.6 pixels mm-1 | θmax = 25.0°, θmin = 1.9° |
ω scans | h = −11→12 |
Absorption correction: multi-scan (SADABS; Sheldrick, 2003) | k = −25→25 |
Tmin = 0.884, Tmax = 0.969 | l = −13→13 |
11367 measured reflections |
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.076 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.209 | H-atom parameters constrained |
S = 1.05 | w = 1/[σ2(Fo2) + (0.1003P)2 + 2.0495P] where P = (Fo2 + 2Fc2)/3 |
4285 reflections | (Δ/σ)max = 0.002 |
301 parameters | Δρmax = 1.64 e Å−3 |
0 restraints | Δρmin = −1.11 e Å−3 |
Experimental. Data collection is performed with four batch runs at φ = 0.00 ° (600 frames), at φ = 90.00 ° (600 frames), at φ = 180 ° (600 frames) and at φ = 270 ° (600 frames). Frame width = 0.30 \& in ω. Data is merged, corrected for decay, and treated with multi-scan absorption corrections. |
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. |
x | y | z | Uiso*/Ueq | ||
Mn | 0.0000 | 0.0000 | 0.0000 | 0.0141 (3) | |
S1 | −0.08215 (12) | −0.00068 (5) | 0.25618 (9) | 0.0168 (3) | |
O1 | −0.0261 (3) | 0.02936 (13) | 0.1691 (3) | 0.0184 (7) | |
O2 | 0.0191 (3) | −0.01686 (15) | 0.3710 (3) | 0.0220 (8) | |
O3 | −0.2020 (3) | 0.02863 (15) | 0.2642 (3) | 0.0238 (8) | |
N1 | −0.2124 (4) | −0.03593 (15) | −0.0369 (3) | 0.0142 (8) | |
N2 | −0.2463 (4) | −0.06339 (16) | 0.0575 (3) | 0.0140 (8) | |
N3 | 0.0378 (3) | −0.09350 (16) | 0.0876 (3) | 0.0145 (8) | |
N4 | −0.0332 (4) | −0.11151 (16) | 0.1651 (3) | 0.0143 (8) | |
N5 | −0.2617 (4) | −0.16620 (17) | 0.2121 (3) | 0.0212 (9) | |
N6 | −0.2076 (4) | −0.10980 (16) | 0.2547 (3) | 0.0161 (8) | |
C1 | −0.1458 (4) | −0.07549 (19) | 0.1790 (4) | 0.0148 (9) | |
C2 | −0.3280 (4) | −0.02938 (19) | −0.1301 (4) | 0.0150 (9) | |
C3 | −0.4367 (5) | −0.0514 (2) | −0.0953 (4) | 0.0193 (10) | |
H3A | −0.5293 | −0.0523 | −0.1447 | 0.023* | |
C4 | −0.3818 (4) | −0.0712 (2) | 0.0245 (4) | 0.0188 (10) | |
H4A | −0.4300 | −0.0875 | 0.0755 | 0.023* | |
C5 | −0.3289 (5) | −0.0036 (2) | −0.2544 (4) | 0.0214 (11) | |
H5A | −0.2561 | 0.0280 | −0.2393 | 0.026* | |
C6 | −0.3004 (5) | −0.0540 (2) | −0.3356 (4) | 0.0279 (12) | |
H6A | −0.2117 | −0.0721 | −0.2934 | 0.042* | |
H6B | −0.3010 | −0.0366 | −0.4154 | 0.042* | |
H6C | −0.3703 | −0.0856 | −0.3501 | 0.042* | |
C7 | −0.4650 (5) | 0.0268 (2) | −0.3206 (4) | 0.0299 (12) | |
H7A | −0.4834 | 0.0581 | −0.2663 | 0.045* | |
H7B | −0.5367 | −0.0041 | −0.3399 | 0.045* | |
H7C | −0.4619 | 0.0458 | −0.3979 | 0.045* | |
C8 | 0.1312 (4) | −0.13703 (19) | 0.0981 (4) | 0.0160 (10) | |
C9 | 0.1240 (5) | −0.1812 (2) | 0.1858 (4) | 0.0205 (10) | |
H9A | 0.1802 | −0.2161 | 0.2117 | 0.025* | |
C10 | 0.0193 (5) | −0.1636 (2) | 0.2259 (4) | 0.0179 (10) | |
H10A | −0.0111 | −0.1842 | 0.2858 | 0.022* | |
C11 | 0.2227 (5) | −0.1366 (2) | 0.0192 (4) | 0.0206 (10) | |
H11A | 0.2422 | −0.0931 | 0.0032 | 0.025* | |
C12 | 0.1527 (5) | −0.1677 (2) | −0.1055 (4) | 0.0264 (11) | |
H12A | 0.0674 | −0.1467 | −0.1476 | 0.040* | |
H12B | 0.1343 | −0.2106 | −0.0911 | 0.040* | |
H12C | 0.2115 | −0.1659 | −0.1577 | 0.040* | |
C13 | 0.3557 (5) | −0.1684 (2) | 0.0858 (5) | 0.0283 (12) | |
H13A | 0.4001 | −0.1478 | 0.1650 | 0.042* | |
H13B | 0.4146 | −0.1669 | 0.0337 | 0.042* | |
H13C | 0.3382 | −0.2112 | 0.1016 | 0.042* | |
C14 | −0.2936 (5) | −0.1904 (2) | 0.3065 (4) | 0.0177 (10) | |
C15 | −0.2621 (5) | −0.1496 (2) | 0.4085 (4) | 0.0259 (11) | |
H15A | −0.2781 | −0.1560 | 0.4855 | 0.031* | |
C16 | −0.2045 (5) | −0.0996 (2) | 0.3751 (4) | 0.0207 (10) | |
H16A | −0.1692 | −0.0647 | 0.4248 | 0.025* | |
C17 | −0.3467 (5) | −0.2546 (2) | 0.2996 (4) | 0.0228 (11) | |
H17A | −0.3918 | −0.2650 | 0.2101 | 0.027* | |
C18 | −0.2275 (6) | −0.2978 (3) | 0.3514 (6) | 0.0473 (16) | |
H18A | −0.1649 | −0.2934 | 0.3034 | 0.071* | |
H18B | −0.2603 | −0.3400 | 0.3454 | 0.071* | |
H18C | −0.1806 | −0.2877 | 0.4388 | 0.071* | |
C19 | −0.4487 (6) | −0.2628 (3) | 0.3676 (5) | 0.0344 (13) | |
H19A | −0.5242 | −0.2344 | 0.3335 | 0.052* | |
H19B | −0.4055 | −0.2543 | 0.4563 | 0.052* | |
H19C | −0.4826 | −0.3049 | 0.3569 | 0.052* | |
C20 | 0.7734 (6) | 0.3825 (2) | −0.0264 (5) | 0.0355 (13) | |
H20A | 0.7489 | 0.4138 | −0.0929 | 0.043* | |
H20B | 0.8160 | 0.4036 | 0.0538 | 0.043* | |
Cl1 | 0.89005 (15) | 0.33138 (7) | −0.05427 (12) | 0.0411 (4) | |
Cl2 | 0.62625 (18) | 0.34507 (8) | −0.0215 (2) | 0.0694 (6) |
U11 | U22 | U33 | U12 | U13 | U23 | |
Mn | 0.0198 (6) | 0.0126 (5) | 0.0105 (5) | −0.0005 (4) | 0.0055 (4) | 0.0010 (3) |
S1 | 0.0244 (7) | 0.0145 (6) | 0.0130 (5) | −0.0010 (5) | 0.0078 (5) | −0.0012 (4) |
O1 | 0.0266 (18) | 0.0141 (16) | 0.0152 (14) | −0.0042 (13) | 0.0076 (13) | −0.0030 (13) |
O2 | 0.0310 (19) | 0.0217 (17) | 0.0127 (15) | −0.0050 (15) | 0.0061 (14) | −0.0015 (12) |
O3 | 0.0312 (19) | 0.0186 (18) | 0.0249 (17) | 0.0020 (15) | 0.0138 (15) | −0.0040 (13) |
N1 | 0.020 (2) | 0.0111 (19) | 0.0122 (17) | −0.0017 (15) | 0.0070 (15) | 0.0008 (14) |
N2 | 0.018 (2) | 0.0138 (19) | 0.0122 (16) | −0.0009 (15) | 0.0072 (15) | 0.0007 (14) |
N3 | 0.0151 (19) | 0.018 (2) | 0.0116 (16) | 0.0010 (15) | 0.0058 (14) | −0.0003 (14) |
N4 | 0.023 (2) | 0.0127 (19) | 0.0099 (16) | −0.0014 (16) | 0.0085 (15) | 0.0000 (14) |
N5 | 0.030 (2) | 0.018 (2) | 0.0181 (18) | −0.0028 (17) | 0.0120 (17) | −0.0019 (16) |
N6 | 0.023 (2) | 0.0138 (19) | 0.0132 (17) | −0.0020 (16) | 0.0081 (16) | −0.0002 (14) |
C1 | 0.019 (2) | 0.015 (2) | 0.0125 (19) | 0.0026 (18) | 0.0088 (17) | −0.0006 (17) |
C2 | 0.018 (2) | 0.009 (2) | 0.016 (2) | −0.0002 (18) | 0.0029 (18) | −0.0015 (17) |
C3 | 0.020 (2) | 0.017 (2) | 0.017 (2) | 0.0021 (19) | 0.0010 (18) | 0.0030 (18) |
C4 | 0.020 (2) | 0.017 (2) | 0.022 (2) | −0.0027 (19) | 0.0097 (19) | −0.0019 (18) |
C5 | 0.027 (3) | 0.022 (3) | 0.012 (2) | 0.001 (2) | 0.0012 (19) | 0.0029 (17) |
C6 | 0.034 (3) | 0.033 (3) | 0.017 (2) | −0.003 (2) | 0.009 (2) | −0.001 (2) |
C7 | 0.031 (3) | 0.031 (3) | 0.023 (2) | 0.002 (2) | 0.003 (2) | 0.004 (2) |
C8 | 0.019 (2) | 0.012 (2) | 0.015 (2) | 0.0008 (18) | 0.0026 (18) | −0.0011 (17) |
C9 | 0.029 (3) | 0.018 (2) | 0.016 (2) | 0.007 (2) | 0.011 (2) | 0.0057 (18) |
C10 | 0.026 (3) | 0.014 (2) | 0.013 (2) | 0.0025 (19) | 0.0061 (19) | 0.0044 (17) |
C11 | 0.025 (3) | 0.012 (2) | 0.028 (2) | −0.0011 (19) | 0.013 (2) | 0.0005 (19) |
C12 | 0.038 (3) | 0.024 (3) | 0.023 (2) | 0.000 (2) | 0.017 (2) | −0.001 (2) |
C13 | 0.029 (3) | 0.029 (3) | 0.031 (3) | 0.000 (2) | 0.016 (2) | 0.001 (2) |
C14 | 0.022 (2) | 0.015 (2) | 0.021 (2) | 0.0059 (19) | 0.0125 (19) | 0.0060 (18) |
C15 | 0.042 (3) | 0.023 (3) | 0.019 (2) | 0.000 (2) | 0.018 (2) | 0.002 (2) |
C16 | 0.029 (3) | 0.019 (2) | 0.018 (2) | 0.003 (2) | 0.014 (2) | −0.0018 (18) |
C17 | 0.031 (3) | 0.017 (2) | 0.022 (2) | −0.006 (2) | 0.010 (2) | 0.0035 (19) |
C18 | 0.055 (4) | 0.022 (3) | 0.068 (4) | 0.003 (3) | 0.024 (3) | 0.008 (3) |
C19 | 0.045 (3) | 0.029 (3) | 0.036 (3) | −0.009 (2) | 0.021 (3) | 0.007 (2) |
C20 | 0.047 (3) | 0.028 (3) | 0.030 (3) | −0.005 (3) | 0.010 (3) | 0.006 (2) |
Cl1 | 0.0509 (9) | 0.0486 (9) | 0.0255 (7) | 0.0045 (7) | 0.0145 (6) | 0.0007 (6) |
Cl2 | 0.0451 (10) | 0.0409 (10) | 0.1214 (17) | −0.0059 (8) | 0.0252 (10) | −0.0126 (10) |
Mn—O1 | 2.121 (3) | C7—H7B | 0.9800 |
Mn—O1i | 2.121 (3) | C7—H7C | 0.9800 |
Mn—N3 | 2.252 (4) | C8—C9 | 1.405 (6) |
Mn—N3i | 2.252 (4) | C8—C11 | 1.503 (6) |
Mn—N1 | 2.261 (4) | C9—C10 | 1.367 (6) |
Mn—N1i | 2.261 (4) | C9—H9A | 0.9500 |
S1—O3 | 1.434 (3) | C10—H10A | 0.9500 |
S1—O2 | 1.434 (3) | C11—C13 | 1.521 (6) |
S1—O1 | 1.455 (3) | C11—C12 | 1.529 (6) |
S1—C1 | 1.873 (4) | C11—H11A | 1.0000 |
N1—C2 | 1.334 (5) | C12—H12A | 0.9800 |
N1—N2 | 1.369 (5) | C12—H12B | 0.9800 |
N2—C4 | 1.353 (6) | C12—H12C | 0.9800 |
N2—C1 | 1.466 (5) | C13—H13A | 0.9800 |
N3—C8 | 1.340 (5) | C13—H13B | 0.9800 |
N3—N4 | 1.376 (5) | C13—H13C | 0.9800 |
N4—C10 | 1.353 (5) | C14—C15 | 1.413 (6) |
N4—C1 | 1.464 (5) | C14—C17 | 1.503 (6) |
N5—C14 | 1.328 (6) | C15—C16 | 1.359 (7) |
N5—N6 | 1.378 (5) | C15—H15A | 0.9500 |
N6—C16 | 1.373 (5) | C16—H16A | 0.9500 |
N6—C1 | 1.439 (5) | C17—C19 | 1.510 (7) |
C2—C3 | 1.399 (6) | C17—C18 | 1.522 (7) |
C2—C5 | 1.515 (6) | C17—H17A | 1.0000 |
C3—C4 | 1.366 (6) | C18—H18A | 0.9800 |
C3—H3A | 0.9500 | C18—H18B | 0.9800 |
C4—H4A | 0.9500 | C18—H18C | 0.9800 |
C5—C6 | 1.524 (7) | C19—H19A | 0.9800 |
C5—C7 | 1.530 (7) | C19—H19B | 0.9800 |
C5—H5A | 1.0000 | C19—H19C | 0.9800 |
C6—H6A | 0.9800 | C20—Cl1 | 1.753 (6) |
C6—H6B | 0.9800 | C20—Cl2 | 1.756 (6) |
C6—H6C | 0.9800 | C20—H20A | 0.9900 |
C7—H7A | 0.9800 | C20—H20B | 0.9900 |
O1—Mn—O1i | 180.00 (16) | C5—C7—H7B | 109.5 |
O1—Mn—N3 | 86.02 (12) | H7A—C7—H7B | 109.5 |
O1i—Mn—N3 | 93.98 (12) | C5—C7—H7C | 109.5 |
O1—Mn—N3i | 93.98 (12) | H7A—C7—H7C | 109.5 |
O1i—Mn—N3i | 86.02 (12) | H7B—C7—H7C | 109.5 |
N3—Mn—N3i | 180.0 (3) | N3—C8—C9 | 110.4 (4) |
O1—Mn—N1 | 82.60 (12) | N3—C8—C11 | 121.7 (4) |
O1i—Mn—N1 | 97.40 (12) | C9—C8—C11 | 127.8 (4) |
N3—Mn—N1 | 77.86 (12) | C10—C9—C8 | 105.7 (4) |
N3i—Mn—N1 | 102.14 (12) | C10—C9—H9A | 127.1 |
O1—Mn—N1i | 97.40 (12) | C8—C9—H9A | 127.1 |
O1i—Mn—N1i | 82.60 (12) | N4—C10—C9 | 107.7 (4) |
N3—Mn—N1i | 102.14 (12) | N4—C10—H10A | 126.1 |
N3i—Mn—N1i | 77.86 (12) | C9—C10—H10A | 126.1 |
N1—Mn—N1i | 180.00 (18) | C8—C11—C13 | 110.8 (4) |
O3—S1—O2 | 117.24 (19) | C8—C11—C12 | 109.9 (4) |
O3—S1—O1 | 112.91 (19) | C13—C11—C12 | 110.3 (4) |
O2—S1—O1 | 112.8 (2) | C8—C11—H11A | 108.6 |
O3—S1—C1 | 103.5 (2) | C13—C11—H11A | 108.6 |
O2—S1—C1 | 104.90 (19) | C12—C11—H11A | 108.6 |
O1—S1—C1 | 103.68 (18) | C11—C12—H12A | 109.5 |
S1—O1—Mn | 132.26 (18) | C11—C12—H12B | 109.5 |
C2—N1—N2 | 105.8 (3) | H12A—C12—H12B | 109.5 |
C2—N1—Mn | 134.0 (3) | C11—C12—H12C | 109.5 |
N2—N1—Mn | 119.4 (2) | H12A—C12—H12C | 109.5 |
C4—N2—N1 | 110.4 (3) | H12B—C12—H12C | 109.5 |
C4—N2—C1 | 127.5 (4) | C11—C13—H13A | 109.5 |
N1—N2—C1 | 121.9 (3) | C11—C13—H13B | 109.5 |
C8—N3—N4 | 105.4 (3) | H13A—C13—H13B | 109.5 |
C8—N3—Mn | 134.7 (3) | C11—C13—H13C | 109.5 |
N4—N3—Mn | 119.2 (3) | H13A—C13—H13C | 109.5 |
C10—N4—N3 | 110.7 (4) | H13B—C13—H13C | 109.5 |
C10—N4—C1 | 127.3 (4) | N5—C14—C15 | 110.9 (4) |
N3—N4—C1 | 122.0 (3) | N5—C14—C17 | 120.9 (4) |
C14—N5—N6 | 104.7 (3) | C15—C14—C17 | 128.1 (4) |
C16—N6—N5 | 111.8 (4) | C16—C15—C14 | 106.7 (4) |
C16—N6—C1 | 129.5 (4) | C16—C15—H15A | 126.7 |
N5—N6—C1 | 118.0 (3) | C14—C15—H15A | 126.7 |
N6—C1—N4 | 108.2 (3) | C15—C16—N6 | 105.9 (4) |
N6—C1—N2 | 109.4 (3) | C15—C16—H16A | 127.0 |
N4—C1—N2 | 110.7 (3) | N6—C16—H16A | 127.0 |
N6—C1—S1 | 109.6 (3) | C14—C17—C19 | 113.1 (4) |
N4—C1—S1 | 110.1 (3) | C14—C17—C18 | 108.5 (4) |
N2—C1—S1 | 108.8 (3) | C19—C17—C18 | 110.6 (4) |
N1—C2—C3 | 110.4 (4) | C14—C17—H17A | 108.2 |
N1—C2—C5 | 120.8 (4) | C19—C17—H17A | 108.2 |
C3—C2—C5 | 128.7 (4) | C18—C17—H17A | 108.2 |
C4—C3—C2 | 105.6 (4) | C17—C18—H18A | 109.5 |
C4—C3—H3A | 127.2 | C17—C18—H18B | 109.5 |
C2—C3—H3A | 127.2 | H18A—C18—H18B | 109.5 |
N2—C4—C3 | 107.7 (4) | C17—C18—H18C | 109.5 |
N2—C4—H4A | 126.1 | H18A—C18—H18C | 109.5 |
C3—C4—H4A | 126.1 | H18B—C18—H18C | 109.5 |
C2—C5—C6 | 110.4 (4) | C17—C19—H19A | 109.5 |
C2—C5—C7 | 110.3 (4) | C17—C19—H19B | 109.5 |
C6—C5—C7 | 110.3 (4) | H19A—C19—H19B | 109.5 |
C2—C5—H5A | 108.6 | C17—C19—H19C | 109.5 |
C6—C5—H5A | 108.6 | H19A—C19—H19C | 109.5 |
C7—C5—H5A | 108.6 | H19B—C19—H19C | 109.5 |
C5—C6—H6A | 109.5 | Cl1—C20—Cl2 | 112.0 (3) |
C5—C6—H6B | 109.5 | Cl1—C20—H20A | 109.2 |
H6A—C6—H6B | 109.5 | Cl2—C20—H20A | 109.2 |
C5—C6—H6C | 109.5 | Cl1—C20—H20B | 109.2 |
H6A—C6—H6C | 109.5 | Cl2—C20—H20B | 109.2 |
H6B—C6—H6C | 109.5 | H20A—C20—H20B | 107.9 |
C5—C7—H7A | 109.5 | ||
O3—S1—O1—Mn | −115.8 (3) | C4—N2—C1—S1 | −107.5 (4) |
O2—S1—O1—Mn | 108.4 (3) | N1—N2—C1—S1 | 65.8 (4) |
C1—S1—O1—Mn | −4.5 (3) | O3—S1—C1—N6 | −60.6 (3) |
N3—Mn—O1—S1 | −34.2 (3) | O2—S1—C1—N6 | 62.9 (3) |
N3i—Mn—O1—S1 | 145.8 (3) | O1—S1—C1—N6 | −178.6 (3) |
N1—Mn—O1—S1 | 44.1 (3) | O3—S1—C1—N4 | −179.5 (3) |
N1i—Mn—O1—S1 | −135.9 (3) | O2—S1—C1—N4 | −56.1 (3) |
O1—Mn—N1—C2 | 126.9 (4) | O1—S1—C1—N4 | 62.4 (3) |
O1i—Mn—N1—C2 | −53.1 (4) | O3—S1—C1—N2 | 59.0 (3) |
N3—Mn—N1—C2 | −145.6 (4) | O2—S1—C1—N2 | −177.5 (3) |
N3i—Mn—N1—C2 | 34.4 (4) | O1—S1—C1—N2 | −59.0 (3) |
O1—Mn—N1—N2 | −41.1 (3) | N2—N1—C2—C3 | 1.2 (5) |
O1i—Mn—N1—N2 | 138.9 (3) | Mn—N1—C2—C3 | −168.0 (3) |
N3—Mn—N1—N2 | 46.4 (3) | N2—N1—C2—C5 | −176.4 (4) |
N3i—Mn—N1—N2 | −133.6 (3) | Mn—N1—C2—C5 | 14.4 (6) |
C2—N1—N2—C4 | −2.6 (5) | N1—C2—C3—C4 | 0.6 (5) |
Mn—N1—N2—C4 | 168.5 (3) | C5—C2—C3—C4 | 178.0 (4) |
C2—N1—N2—C1 | −176.9 (4) | N1—N2—C4—C3 | 3.0 (5) |
Mn—N1—N2—C1 | −5.9 (5) | C1—N2—C4—C3 | 177.0 (4) |
O1—Mn—N3—C8 | −133.0 (4) | C2—C3—C4—N2 | −2.2 (5) |
O1i—Mn—N3—C8 | 47.0 (4) | N1—C2—C5—C6 | 84.4 (5) |
N1—Mn—N3—C8 | 143.7 (4) | C3—C2—C5—C6 | −92.8 (6) |
N1i—Mn—N3—C8 | −36.3 (4) | N1—C2—C5—C7 | −153.5 (4) |
O1—Mn—N3—N4 | 35.6 (3) | C3—C2—C5—C7 | 29.3 (6) |
O1i—Mn—N3—N4 | −144.4 (3) | N4—N3—C8—C9 | −2.6 (5) |
N1—Mn—N3—N4 | −47.6 (3) | Mn—N3—C8—C9 | 167.1 (3) |
N1i—Mn—N3—N4 | 132.4 (3) | N4—N3—C8—C11 | 174.9 (4) |
C8—N3—N4—C10 | 2.7 (4) | Mn—N3—C8—C11 | −15.3 (6) |
Mn—N3—N4—C10 | −169.0 (3) | N3—C8—C9—C10 | 1.6 (5) |
C8—N3—N4—C1 | −179.7 (3) | C11—C8—C9—C10 | −175.7 (4) |
Mn—N3—N4—C1 | 8.6 (5) | N3—N4—C10—C9 | −1.7 (5) |
C14—N5—N6—C16 | 0.8 (5) | C1—N4—C10—C9 | −179.1 (4) |
C14—N5—N6—C1 | 171.6 (4) | C8—C9—C10—N4 | 0.1 (5) |
C16—N6—C1—N4 | 108.4 (5) | N3—C8—C11—C13 | 152.5 (4) |
N5—N6—C1—N4 | −60.5 (4) | C9—C8—C11—C13 | −30.4 (6) |
C16—N6—C1—N2 | −130.9 (4) | N3—C8—C11—C12 | −85.4 (5) |
N5—N6—C1—N2 | 60.2 (5) | C9—C8—C11—C12 | 91.7 (5) |
C16—N6—C1—S1 | −11.7 (6) | N6—N5—C14—C15 | 0.8 (5) |
N5—N6—C1—S1 | 179.4 (3) | N6—N5—C14—C17 | −175.4 (4) |
C10—N4—C1—N6 | −9.2 (5) | N5—C14—C15—C16 | −2.1 (6) |
N3—N4—C1—N6 | 173.6 (3) | C17—C14—C15—C16 | 173.8 (5) |
C10—N4—C1—N2 | −129.1 (4) | C14—C15—C16—N6 | 2.5 (5) |
N3—N4—C1—N2 | 53.7 (5) | N5—N6—C16—C15 | −2.1 (5) |
C10—N4—C1—S1 | 110.6 (4) | C1—N6—C16—C15 | −171.6 (4) |
N3—N4—C1—S1 | −66.6 (4) | N5—C14—C17—C19 | −146.2 (4) |
C4—N2—C1—N6 | 12.2 (6) | C15—C14—C17—C19 | 38.4 (7) |
N1—N2—C1—N6 | −174.4 (3) | N5—C14—C17—C18 | 90.7 (5) |
C4—N2—C1—N4 | 131.4 (4) | C15—C14—C17—C18 | −84.8 (6) |
N1—N2—C1—N4 | −55.3 (5) |
Symmetry code: (i) −x, −y, −z. |