metal-organic compounds\(\def\hfill{\hskip 5em}\def\hfil{\hskip 3em}\def\eqno#1{\hfil {#1}}\)

Journal logoCRYSTALLOGRAPHIC
COMMUNICATIONS
ISSN: 2056-9890
Volume 70| Part 4| April 2014| Pages m134-m135

{2,6-Bis[(pyridin-2-yl)sulfanylmeth­yl]pyridine-κ2N,N′}(η3-prop-2-en­yl)palladium(II) hexa­fluoro­phosphate

aDipartimento di Scienze Chimiche, Universita di Messina, Messina, Italy
*Correspondence e-mail: gbruno@unime.it

(Received 7 December 2013; accepted 20 February 2014; online 15 March 2014)

The title compound, [Pd(C3H5)(C17H15N3S2)]PF6, is built up by a [(η3-all­yl)Pd]2+ fragment coordinated by a 2,6-bis­[(pyridin-2-yl)sulfanylmeth­yl]pyridine ligand coordinated through the N atoms. One of the S atoms is at a close distance to the metal centeratom [3.2930 (8) Å]. The PdII atom is tetra­coordinated in a strongly distorted square-planar environment mainly determined by the η3-allyl anion in which the central C atom is disordered over two equally occupied positions. The crystal packing is very compact and is characterized by a three-dimensional network of C—H⋯F interactions between the F atoms of each anion and several H atoms of the surrounding cationic complexes.

Related literature

For the catalitic use of palladium η3-allyl complexes, see: De Vries (2012[De Vries, J. G. (2012). Top. Organomet. Chem. 42, 1-34.]). For multidentate nitro­gen/sulfur ligands, see: Betz et al. (2008[Betz, A., Yu, L., Reiher, M., Gaumont, A. C., Jaffres, P. A. & Gulea, M. (2008). J. Organomet. Chem. 93, 2499-2508.]). For the η3η1η3 mechanism and syn--syn anti–anti isomerism, see: Solin & Szabo (2001[Solin, N. & Szabo, K. J. (2001). Organometallics, 20, 5464-5471.]); Takao et al. (2003[Takao, Y., Takeda, T. & Watanabe, J. Y. (2003). Organometallics, 22, 233-241.]); Barloy et al. (2000[Barloy, L., Ramdeeshul, S., Osborn, J. A., Carlotti, C., Taulelle, F., De Cian, A. & Fisher, J. (2000). Eur. J. Chem. pp. 2523-2532.]); Gogoll et al. (1997[Gogoll, A., Grennberg, H. & Axen, A. (1997). Organometallics, 16, 1167-1178.]); Tresoldi et al. (2008[Tresoldi, G., Lanza, S., Di Pietro, S. & Drommi, D. (2008). Eur. J. Inorg. Chem. pp. 4807-4815.], 2010[Tresoldi, G., Di Pietro, S., Drommi, D. & Lanza, S. (2010). Transition Met. Chem. 35, 151-158.]). For the synthesis and structural properties of palladium–allyl complexes, see: Scopelliti et al. (2001[Scopelliti, R., Bruno, G., Donato, C. & Tresoldi, G. (2001). Inorg. Chim. Acta, 313, 43-55.]); Tresoldi et al. (2002[Tresoldi, G., Lo Schiavo, S., Lanza, S. & Cardiano, P. (2002). Eur. J. Inorg. Chem. pp. 181-191.]); Baradello et al. (2004[Baradello, L., Lo Schiavo, S., Nicolò, F., Lanza, S., Alibrandi, G. & Tresoldi, G. (2004). Eur. J. Inorg. Chem. pp. 3358-3369.]).

[Scheme 1]

Experimental

Crystal data
  • [Pd(C3H5)(C17H15N3S2)]PF6

  • Mr = 617.88

  • Monoclinic, P 21 /n

  • a = 13.663 (1) Å

  • b = 13.667 (1) Å

  • c = 13.727 (1) Å

  • β = 113.01 (1)°

  • V = 2359.3 (3) Å3

  • Z = 4

  • Mo Kα radiation

  • μ = 1.09 mm−1

  • T = 293 K

  • 0.4 × 0.32 × 0.29 mm

Data collection
  • Bruker APEXII CCD diffractometer

  • Absorption correction: integration (SADABS; Bruker, 2005[Bruker (2005). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]) Tmin = 0.634, Tmax = 0.666

  • 74899 measured reflections

  • 5419 independent reflections

  • 4912 reflections with I > 2σ(I)

  • Rint = 0.028

Refinement
  • R[F2 > 2σ(F2)] = 0.038

  • wR(F2) = 0.114

  • S = 1.07

  • 5419 reflections

  • 307 parameters

  • H-atom parameters constrained

  • Δρmax = 0.57 e Å−3

  • Δρmin = −0.69 e Å−3

Table 1
Hydrogen-bond geometry (Å, °)

D—H⋯A D—H H⋯A DA D—H⋯A
C3—H3⋯F3i 0.93 2.42 3.270 (8) 151
C4—H4⋯F2ii 0.93 2.47 3.358 (6) 161
C8—H8⋯F4iii 0.93 2.44 3.317 (8) 157
C12—H12A⋯F3iv 0.97 2.45 3.126 (8) 126
Symmetry codes: (i) -x+1, -y+1, -z+1; (ii) [-x+{\script{3\over 2}}, y+{\script{1\over 2}}, -z+{\script{3\over 2}}]; (iii) [x+{\script{1\over 2}}, -y+{\script{1\over 2}}, z+{\script{1\over 2}}]; (iv) [x+{\script{1\over 2}}, -y+{\script{1\over 2}}, z-{\script{1\over 2}}].

Data collection: APEX2 (Bruker, 2005[Bruker (2005). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); cell refinement: SAINT (Bruker, 2005[Bruker (2005). APEX2, SAINT and SADABS. Bruker AXS Inc., Madison, Wisconsin, USA.]); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); molecular graphics: SHELXTL (Sheldrick, 2008[Sheldrick, G. M. (2008). Acta Cryst. A64, 112-122.]); software used to prepare material for publication: SHELXTL.

Supporting information


Comment top

The chemistry of palladium-allyl complexes has been reported extensively. This interest has stemmed from the relevance to palladium-catalyzed allylic substitution reactions. Attack of the nucleophile on a cationic palladium η3-allyl complex is conventionally accepted as the crucial step in the catalytic cycle (De Vries 2012). Multidentate nitrogen ligands or multidentate sulfur nitrogen ligands have been used for the structure analysis of (η3-allyl)palladium complexes and the study of their influence upon the dynamic behaviour (Betz et al., 2008). One process encountered in (η3-allyl)palladium complexes is a syn anti isomerism which has been subject of research for many years. The η3-η1-η3 mechanism is well established for many [Pd(η3-allyl)L1L2]+ cations (Solin et al., 2001). Other process usually observed is apparent allyl rotation or syn-syn anti-anti isomerism (Takao et al., 2003). Mechanisms proposed for this process include: i) an associative mechanism, involving a non-rigid five-coordinated intermediate (Barloy et al., 2000), ii) a dissociative mechanism with stabilization of tricoordinate intermediate, mostly, in some complexes with N-donor ligands (Gogoll et al., 1997). We have lately been interested in the use of potentially tridentate N, S, N ligands in coordination chemistry towards congested ruthenium(II)substrates. The contemporary presence of the congested substrate and sterically demanding ligand favoured the N,S-chelation of the thioether with formation of the four membered chelate ring (Scopelliti et al., 2001; Tresoldi et al., 2002) and the five membered chelate ring, (Baradello et al., 2004). However the exchange between these isomers was hampered by the very low abundance of the four membered species and the large value of the activation energy of the process (Tresoldi et al., 2008). The potentially polidentate N3S2 or N5S2 dithioethers, containing a 2,6-substitute linker with two thioether-heterocycle arms, were prepared and their reactions with some congested ruthenium substrates explored. Only the four membered species was obtained and the sulfur inversion observed. (Tresoldi et al., 2010) With the aim of favouring different modes of coordination of dithioethers and as extension of our stereodynamic studies, we have examined the reactions of the dithioethers with the solvate species [Pd(allyl)(acetone)2]+, obtaining the species [Pd(allyl)(dithioether)]PF6 stereo-chemically no-rigid. The Nouter, Ncentral-coordination of dithioether ligand with formation of seven membered chelate ring is favoured in the solid state while in solution the dynamic behaviour of the compounds involves the dithioether attempt to coordinate with all the donor atoms. In this paper the reaction of 2,6-bis(2-pyridylsulfanylmethyl)pyridine(psmp) with [Pd(C3H5)(acetone)]+, generate in situ from [Pd(C3H5)Cl]2 and AgPF6, led to the title compound,[Pd(C3H5)(psmp)]PF6 (I).

Related literature top

For the catalitic use of palladium η3-allyl complexes, see: De Vries (2012). For multidentate nitrogen/sulfur ligands, see: Betz et al. (2008). For the η3η1η3 mechanism and syn--syn anti–anti isomerism, see: Solin & Szabo (2001); Takao et al. (2003); Barloy et al. (2000); Gogoll et al. (1997); Tresoldi et al. (2008, 2010). For the synthesis and structural properties of palladium–allyl complexes, see: Scopelliti et al. (2001); Tresoldi et al. (2002); Baradello et al. (2004).

Experimental top

To a stirred solution, of [Pd(C3H5)Cl]2 (91,5 mg, 0.25 mmol) in acetone (20 ml) was added AgPF6 (126.4 mg, 0.5 mmol). After 30 m silver chloride was filtered. The solution of the solvento species was added to 15 ml of acetone containing 162.7 mg (0.5 mmol) of psmp and stirred for 2 h. The resulting solution was filterd on diethyl ether (120 ml) and a white precipitate was obtained, which was filtered, washed with diethyl ether (30 ml) and dried overnight. Yield 247 mg (80%). White crystals of I suitable for X-ray structure investigation were obtained from a solution in acetone-ether (1:3) on standing for ca 4 d at 253 K°. C20H20F6N3PPdS2 (617.9) requires: C 38.88, H 3.26, N 6.80, S 10.38%; found: C 38.80, H 3.30, N 6.90, S 10.70%. Conductivity: ΛM(MeCN, 5x10–4 mol L-1, 20 °C) = 146 S cm2 mol-1. 1H NMR (500 MHz, [D6]acetone, 323 °C): δ8.65 (dd, J6,4 = 1.6 Hz, J6,5 = 5.4 Hz, 2H, H6),8.02 (t, J = 7.8 Hz, 1H, H4'), 7.76 (d, 2H, H3', H5'), 7.67 (ddd, J4,5 = 7.8 Hz, J4,3 = 8.2 Hz, 2H, H4), 7.38 (ddd, J5,3 = 1.0 Hz, 2H, H3), 7.19 (ddd, 2H, H5), 6.13 (m, 1H, allyl CH), 5.14 (s, 4H, S—CH2), 3.97 (br, 4H, allyl syn-anti).

Refinement top

H atoms were included in the refinement using a riding model method with the X—H bond geometry and the H isotropic displacement parameter depending on the parent atom X. One C atom of the allyl moiety is disordered over two equally occupied positions.

Computing details top

Data collection: APEX2 (Bruker, 2005); cell refinement: SAINT (Bruker, 2005); data reduction: SAINT (Bruker, 2005); program(s) used to solve structure: SHELXS97 (Sheldrick, 2008); program(s) used to refine structure: SHELXL97 (Sheldrick, 2008); molecular graphics: SHELXTL (Sheldrick, 2008); software used to prepare material for publication: SHELXTL (Sheldrick, 2008).

Figures top
[Figure 1] Fig. 1. Perspective view of the title molecule with numbering of the atoms. Non H-atoms represented as displacement ellipsoids are plotted at the 30% probability level, while H atoms are shown as small spheres of arbitrary radius. The PF6- anion and one of the disordered C atoms have been omitted for clarity.
{2,6-Bis[(pyridin-2-yl)sulfanylmethyl]pyridine-κ2N,N'}(η3-prop-2-enyl)palladium(II) hexafluorophosphate top
Crystal data top
[Pd(C3H5)(C17H15N3S2)]PF6F(000) = 1232
Mr = 617.88Dx = 1.739 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 136 reflections
a = 13.663 (1) Åθ = 2.2–30.0°
b = 13.667 (1) ŵ = 1.09 mm1
c = 13.727 (1) ÅT = 293 K
β = 113.01 (1)°Prismatic, yellow
V = 2359.3 (3) Å30.4 × 0.32 × 0.29 mm
Z = 4
Data collection top
Bruker APEXII CCD
diffractometer
5419 independent reflections
Radiation source: fine-focus sealed tube4912 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.028
ϕ and ω scansθmax = 27.5°, θmin = 2.2°
Absorption correction: integration
(SADABS; Bruker, 2005)
h = 1717
Tmin = 0.634, Tmax = 0.666k = 1717
74899 measured reflectionsl = 1717
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.038Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.114H-atom parameters constrained
S = 1.07 w = 1/[σ2(Fo2) + (0.0579P)2 + 2.4402P]
where P = (Fo2 + 2Fc2)/3
5419 reflections(Δ/σ)max = 0.002
307 parametersΔρmax = 0.57 e Å3
0 restraintsΔρmin = 0.69 e Å3
Crystal data top
[Pd(C3H5)(C17H15N3S2)]PF6V = 2359.3 (3) Å3
Mr = 617.88Z = 4
Monoclinic, P21/nMo Kα radiation
a = 13.663 (1) ŵ = 1.09 mm1
b = 13.667 (1) ÅT = 293 K
c = 13.727 (1) Å0.4 × 0.32 × 0.29 mm
β = 113.01 (1)°
Data collection top
Bruker APEXII CCD
diffractometer
5419 independent reflections
Absorption correction: integration
(SADABS; Bruker, 2005)
4912 reflections with I > 2σ(I)
Tmin = 0.634, Tmax = 0.666Rint = 0.028
74899 measured reflections
Refinement top
R[F2 > 2σ(F2)] = 0.0380 restraints
wR(F2) = 0.114H-atom parameters constrained
S = 1.07Δρmax = 0.57 e Å3
5419 reflectionsΔρmin = 0.69 e Å3
307 parameters
Special details top

Geometry. All esds (except the esd in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell esds are taken into account individually in the estimation of esds in distances, angles and torsion angles; correlations between esds in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell esds is used for estimating esds involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > 2σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Pd10.88269 (2)0.24170 (2)0.51700 (2)0.04910 (10)
S10.92247 (8)0.38395 (7)0.76617 (7)0.0673 (2)
S20.63967 (7)0.29098 (8)0.34786 (9)0.0729 (3)
P10.33006 (8)0.11910 (9)0.58509 (8)0.0708 (3)
N20.8081 (2)0.23926 (19)0.6281 (3)0.0568 (6)
N10.85839 (18)0.39548 (17)0.49428 (18)0.0434 (5)
C60.9869 (2)0.4005 (2)0.6749 (2)0.0540 (7)
H6A1.05160.43810.70900.065*
H6B1.00640.33720.65610.065*
C50.9163 (2)0.4522 (2)0.5770 (2)0.0472 (6)
C10.7881 (2)0.4391 (2)0.4067 (2)0.0520 (6)
C70.8199 (3)0.2976 (3)0.7103 (3)0.0589 (8)
C20.7764 (3)0.5391 (3)0.4006 (3)0.0678 (9)
H20.72730.56770.33960.081*
C30.8370 (3)0.5967 (3)0.4841 (4)0.0737 (10)
H30.83030.66450.48010.088*
C120.7244 (3)0.3743 (3)0.3162 (3)0.0686 (9)
H12A0.77260.33710.29410.082*
H12B0.68100.41480.25700.082*
C140.4859 (3)0.3416 (4)0.4160 (3)0.0794 (11)
H140.50130.28250.45240.095*
C130.5421 (3)0.3717 (3)0.3584 (3)0.0688 (9)
C40.9077 (3)0.5525 (2)0.5735 (3)0.0626 (8)
H40.94950.59000.63130.075*
C150.4064 (4)0.4005 (5)0.4192 (5)0.1015 (16)
H150.36640.38210.45760.122*
C110.7291 (3)0.1721 (3)0.6012 (4)0.0767 (10)
H110.72090.12990.54540.092*
C90.6727 (4)0.2240 (5)0.7335 (5)0.0987 (17)
H90.62690.21920.76870.118*
N30.5268 (3)0.4554 (3)0.3068 (3)0.0924 (11)
C80.7514 (4)0.2918 (4)0.7639 (4)0.0842 (12)
H80.75970.33410.81970.101*
C100.6609 (4)0.1628 (4)0.6513 (5)0.0942 (15)
H100.60760.11570.62980.113*
C170.4487 (5)0.5119 (5)0.3121 (6)0.118 (2)
H170.43620.57200.27760.141*
C160.3869 (4)0.4866 (5)0.3648 (6)0.1136 (19)
H160.33210.52740.36400.136*
F10.2921 (4)0.0312 (3)0.6341 (3)0.1496 (15)
F60.3721 (4)0.2025 (4)0.5351 (4)0.175 (2)
F20.4174 (3)0.1344 (4)0.6926 (3)0.1620 (18)
F30.2562 (5)0.1880 (5)0.6114 (5)0.225 (3)
F50.3954 (5)0.0555 (5)0.5459 (5)0.218 (3)
F40.2372 (4)0.1053 (6)0.4768 (4)0.248 (4)
C180.9545 (4)0.2038 (3)0.4089 (4)0.0780 (11)
H18A1.00230.23990.46470.094*0.5
H18B0.93840.22340.33950.094*0.5
H18C0.88320.21960.37250.094*0.5
H18D1.00600.23220.38940.094*0.5
C190.9081 (6)0.1225 (5)0.4289 (6)0.0578 (16)0.5
H190.86030.08660.37290.069*0.5
C19A0.9822 (11)0.1423 (7)0.4872 (13)0.111 (4)0.5
H19A1.05520.13180.51800.133*0.5
C200.9312 (4)0.0929 (3)0.5311 (4)0.0826 (12)
H20A0.97890.12860.58730.099*0.5
H20B0.89910.03720.54410.099*0.5
H20C0.85750.09800.50640.099*0.5
H20D0.96760.05190.58780.099*0.5
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Pd10.05044 (15)0.03748 (13)0.06055 (17)0.00211 (8)0.02296 (11)0.00752 (8)
S10.0830 (6)0.0675 (5)0.0497 (4)0.0056 (4)0.0242 (4)0.0034 (4)
S20.0549 (5)0.0693 (6)0.0831 (6)0.0076 (4)0.0145 (4)0.0209 (5)
P10.0635 (5)0.0844 (7)0.0655 (5)0.0011 (5)0.0264 (4)0.0102 (5)
N20.0555 (15)0.0507 (14)0.0676 (17)0.0019 (11)0.0279 (13)0.0082 (12)
N10.0420 (11)0.0404 (11)0.0485 (11)0.0026 (9)0.0184 (9)0.0029 (9)
C60.0487 (15)0.0502 (16)0.0546 (16)0.0003 (12)0.0110 (12)0.0052 (13)
C50.0454 (13)0.0422 (14)0.0543 (15)0.0037 (11)0.0198 (12)0.0038 (11)
C10.0463 (14)0.0601 (17)0.0497 (14)0.0007 (12)0.0190 (12)0.0035 (13)
C70.0612 (18)0.0620 (19)0.0571 (17)0.0161 (15)0.0271 (14)0.0180 (15)
C20.0612 (19)0.064 (2)0.073 (2)0.0070 (16)0.0207 (17)0.0240 (17)
C30.075 (2)0.0418 (16)0.101 (3)0.0021 (16)0.030 (2)0.0125 (17)
C120.0597 (19)0.089 (3)0.0497 (17)0.0001 (18)0.0132 (14)0.0067 (17)
C140.071 (2)0.080 (3)0.082 (3)0.011 (2)0.025 (2)0.018 (2)
C130.0490 (16)0.074 (2)0.068 (2)0.0065 (16)0.0065 (15)0.0186 (18)
C40.0656 (19)0.0416 (15)0.078 (2)0.0077 (14)0.0252 (17)0.0061 (15)
C150.080 (3)0.113 (4)0.121 (4)0.014 (3)0.049 (3)0.031 (3)
C110.072 (2)0.064 (2)0.096 (3)0.0087 (18)0.035 (2)0.010 (2)
C90.082 (3)0.123 (4)0.114 (4)0.019 (3)0.063 (3)0.048 (4)
N30.074 (2)0.093 (3)0.100 (3)0.015 (2)0.0233 (19)0.010 (2)
C80.087 (3)0.106 (3)0.072 (2)0.027 (3)0.045 (2)0.026 (2)
C100.072 (3)0.094 (3)0.126 (4)0.003 (2)0.048 (3)0.036 (3)
C170.089 (3)0.102 (4)0.153 (5)0.028 (3)0.039 (4)0.022 (4)
C160.079 (3)0.112 (5)0.147 (5)0.019 (3)0.041 (3)0.012 (4)
F10.173 (4)0.129 (3)0.151 (3)0.037 (3)0.068 (3)0.034 (2)
F60.203 (5)0.191 (5)0.145 (3)0.071 (4)0.083 (3)0.039 (3)
F20.135 (3)0.210 (5)0.094 (2)0.044 (3)0.006 (2)0.003 (3)
F30.278 (6)0.211 (5)0.264 (6)0.164 (5)0.192 (6)0.149 (5)
F50.234 (6)0.219 (6)0.264 (6)0.033 (5)0.167 (5)0.062 (5)
F40.142 (4)0.448 (11)0.115 (3)0.104 (5)0.009 (3)0.073 (5)
C180.089 (3)0.069 (2)0.092 (3)0.005 (2)0.053 (2)0.017 (2)
C190.056 (4)0.047 (3)0.070 (4)0.001 (3)0.024 (3)0.025 (3)
C19A0.134 (10)0.057 (5)0.189 (13)0.028 (6)0.115 (10)0.002 (7)
C200.106 (3)0.0407 (17)0.105 (3)0.0147 (19)0.046 (3)0.0080 (18)
Geometric parameters (Å, º) top
Pd1—C19A2.073 (8)C14—C131.364 (6)
Pd1—C202.124 (4)C14—C151.365 (7)
Pd1—N12.132 (2)C14—H140.9300
Pd1—C182.137 (4)C13—N31.318 (6)
Pd1—C192.136 (6)C4—H40.9300
Pd1—N22.141 (3)C15—C161.364 (8)
S1—C71.761 (4)C15—H150.9300
S1—C61.805 (3)C11—C101.363 (6)
S2—C131.779 (4)C11—H110.9300
S2—C121.795 (4)C9—C81.357 (8)
P1—F51.489 (4)C9—C101.363 (8)
P1—F21.506 (3)C9—H90.9300
P1—F31.523 (5)N3—C171.344 (7)
P1—F41.543 (4)C8—H80.9300
P1—F61.553 (4)C10—H100.9300
P1—F11.561 (4)C17—C161.353 (8)
N2—C71.339 (5)C17—H170.9300
N2—C111.353 (5)C16—H160.9300
N1—C51.347 (4)C18—C19A1.299 (14)
N1—C11.350 (4)C18—C191.360 (9)
C6—C51.490 (4)C18—H18A0.9300
C6—H6A0.9700C18—H18B0.9300
C6—H6B0.9700C18—H18C0.9300
C5—C41.375 (4)C18—H18D0.9300
C1—C21.374 (5)C19—C201.373 (9)
C1—C121.497 (5)C19—H190.9300
C7—C81.401 (5)C19A—C201.278 (12)
C2—C31.370 (6)C19A—H19A0.9300
C2—H20.9300C20—H20A0.9300
C3—C41.370 (5)C20—H20B0.9300
C3—H30.9300C20—H20C0.9300
C12—H12A0.9700C20—H20D0.9300
C12—H12B0.9700
C19A—Pd1—C2035.4 (3)C15—C14—H14120.8
C19A—Pd1—N1134.0 (3)N3—C13—C14124.5 (4)
C20—Pd1—N1169.28 (15)N3—C13—S2117.4 (3)
C19A—Pd1—C1835.9 (4)C14—C13—S2118.1 (4)
C20—Pd1—C1867.68 (19)C3—C4—C5119.5 (3)
N1—Pd1—C18102.98 (14)C3—C4—H4120.3
C20—Pd1—C1937.6 (2)C5—C4—H4120.3
N1—Pd1—C19136.0 (2)C16—C15—C14118.6 (5)
C18—Pd1—C1937.1 (2)C16—C15—H15120.7
C19A—Pd1—N2131.5 (4)C14—C15—H15120.7
C20—Pd1—N297.96 (15)N2—C11—C10123.7 (5)
N1—Pd1—N291.68 (9)N2—C11—H11118.2
C18—Pd1—N2165.10 (15)C10—C11—H11118.2
C19—Pd1—N2128.3 (2)C8—C9—C10119.8 (4)
C7—S1—C6107.62 (15)C8—C9—H9120.1
C13—S2—C12101.6 (2)C10—C9—H9120.1
F5—P1—F294.4 (3)C13—N3—C17115.6 (5)
F5—P1—F3173.1 (4)C9—C8—C7119.3 (5)
F2—P1—F391.5 (4)C9—C8—H8120.3
F5—P1—F488.0 (4)C7—C8—H8120.3
F2—P1—F4177.5 (4)C9—C10—C11118.6 (5)
F3—P1—F486.1 (4)C9—C10—H10120.7
F5—P1—F683.8 (4)C11—C10—H10120.7
F2—P1—F692.4 (3)N3—C17—C16123.8 (6)
F3—P1—F692.6 (3)N3—C17—H17118.1
F4—P1—F688.3 (3)C16—C17—H17118.1
F5—P1—F193.0 (3)C17—C16—C15119.0 (5)
F2—P1—F187.4 (2)C17—C16—H16120.5
F3—P1—F190.7 (3)C15—C16—H16120.5
F4—P1—F192.0 (3)C19A—C18—Pd169.3 (4)
F6—P1—F1176.8 (3)C19—C18—Pd171.4 (3)
C7—N2—C11117.1 (3)C19—C18—H18A120.0
C7—N2—Pd1131.0 (2)Pd1—C18—H18A70.5
C11—N2—Pd1111.5 (3)C19—C18—H18B120.0
C5—N1—C1118.4 (3)Pd1—C18—H18B130.8
C5—N1—Pd1115.92 (19)H18A—C18—H18B120.0
C1—N1—Pd1125.6 (2)C19A—C18—H18C120.0
C5—C6—S1111.5 (2)Pd1—C18—H18C69.5
C5—C6—H6A109.3C19A—C18—H18D120.0
S1—C6—H6A109.3Pd1—C18—H18D134.7
C5—C6—H6B109.3H18C—C18—H18D120.0
S1—C6—H6B109.3C18—C19—C20120.5 (6)
H6A—C6—H6B108.0C18—C19—Pd171.5 (3)
N1—C5—C4122.0 (3)C20—C19—Pd170.7 (3)
N1—C5—C6116.6 (3)C18—C19—H19119.7
C4—C5—C6121.4 (3)C20—C19—H19119.7
N1—C1—C2121.2 (3)Pd1—C19—H19130.8
N1—C1—C12117.3 (3)C20—C19A—C18134.1 (12)
C2—C1—C12121.5 (3)C20—C19A—Pd174.5 (4)
N2—C7—C8121.5 (4)C18—C19A—Pd174.7 (5)
N2—C7—S1125.4 (3)C20—C19A—H19A113.0
C8—C7—S1113.0 (3)C18—C19A—H19A113.0
C3—C2—C1120.2 (3)Pd1—C19A—H19A132.9
C3—C2—H2119.9C19A—C20—Pd170.1 (4)
C1—C2—H2119.9C19—C20—Pd171.7 (3)
C4—C3—C2118.7 (3)C19—C20—H20A120.0
C4—C3—H3120.7Pd1—C20—H20A70.5
C2—C3—H3120.7C19—C20—H20B120.0
C1—C12—S2113.3 (2)Pd1—C20—H20B130.4
C1—C12—H12A108.9H20A—C20—H20B120.0
S2—C12—H12A108.9C19A—C20—H20C120.0
C1—C12—H12B108.9Pd1—C20—H20C69.0
S2—C12—H12B108.9C19A—C20—H20D120.0
H12A—C12—H12B107.7Pd1—C20—H20D134.3
C13—C14—C15118.4 (5)H20C—C20—H20D120.0
C13—C14—H14120.8
C7—S1—C6—C569.5 (2)N1—C5—C4—C31.1 (5)
C1—N1—C5—C41.7 (4)C6—C5—C4—C3176.0 (3)
Pd1—N1—C5—C4179.3 (2)C13—C14—C15—C160.2 (7)
C1—N1—C5—C6175.5 (3)C7—N2—C11—C101.5 (6)
Pd1—N1—C5—C62.1 (3)Pd1—N2—C11—C10172.4 (4)
S1—C6—C5—N194.4 (3)C14—C13—N3—C171.1 (7)
S1—C6—C5—C482.8 (3)S2—C13—N3—C17176.6 (4)
C5—N1—C1—C20.9 (4)C10—C9—C8—C70.3 (7)
Pd1—N1—C1—C2178.4 (2)N2—C7—C8—C91.6 (6)
C5—N1—C1—C12179.7 (3)S1—C7—C8—C9175.9 (4)
Pd1—N1—C1—C122.3 (4)C8—C9—C10—C110.3 (8)
C11—N2—C7—C82.2 (5)N2—C11—C10—C90.3 (7)
Pd1—N2—C7—C8170.3 (3)C13—N3—C17—C160.9 (9)
C11—N2—C7—S1175.0 (3)N3—C17—C16—C152.3 (10)
Pd1—N2—C7—S112.5 (4)C14—C15—C16—C171.7 (9)
C6—S1—C7—N213.8 (3)C19A—C18—C19—C2025.8 (6)
C6—S1—C7—C8168.8 (3)Pd1—C18—C19—C2053.0 (5)
N1—C1—C2—C30.4 (5)C19A—C18—C19—Pd178.8 (6)
C12—C1—C2—C3179.0 (3)C19—C18—C19A—C2034.2 (11)
C1—C2—C3—C41.0 (6)Pd1—C18—C19A—C2049.4 (11)
N1—C1—C12—S262.6 (4)C19—C18—C19A—Pd183.6 (6)
C2—C1—C12—S2118.1 (3)C18—C19A—C20—C1933.8 (12)
C13—S2—C12—C170.3 (3)Pd1—C19A—C20—C1983.2 (6)
C15—C14—C13—N31.7 (6)C18—C19A—C20—Pd149.5 (11)
C15—C14—C13—S2176.0 (3)C18—C19—C20—C19A26.3 (6)
C12—S2—C13—N324.4 (3)Pd1—C19—C20—C19A79.6 (6)
C12—S2—C13—C14157.8 (3)C18—C19—C20—Pd153.4 (5)
C2—C3—C4—C50.3 (6)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C3—H3···F3i0.932.423.270 (8)151
C4—H4···F2ii0.932.473.358 (6)161
C8—H8···F4iii0.932.443.317 (8)157
C12—H12A···F3iv0.972.453.126 (8)126
Symmetry codes: (i) x+1, y+1, z+1; (ii) x+3/2, y+1/2, z+3/2; (iii) x+1/2, y+1/2, z+1/2; (iv) x+1/2, y+1/2, z1/2.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
C3—H3···F3i0.932.423.270 (8)151
C4—H4···F2ii0.932.473.358 (6)161
C8—H8···F4iii0.932.443.317 (8)157
C12—H12A···F3iv0.972.453.126 (8)126
Symmetry codes: (i) x+1, y+1, z+1; (ii) x+3/2, y+1/2, z+3/2; (iii) x+1/2, y+1/2, z+1/2; (iv) x+1/2, y+1/2, z1/2.
 

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Volume 70| Part 4| April 2014| Pages m134-m135
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