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metal-organic compounds
The Ag atoms and the ligands of the dication in the title compound, [Ag2(C20H14N4)2](PF6)2, are disordered; the dication lies on a center of symmetry. The major component is chelated by two N atoms of the heterocycle and is coordinated by the N atom of the pyridyl substituent of the other heterocycle; the geometry is trigonal planar distorted towards tetrahedral owing to a weak AgF interaction. The minor component is chelated by three N atoms and is also coordinated by the N atom of the pyridyl substituent of the inversion-related heterocycle; its geometry is octahedral owing to two AgF interactions. One anion lies on a special position of site symmetry 2 and the other on a special position of site symmetry . The disorder in the centrosymmetric dication is best described in terms of the Ag atom being disordered over two sites and the C5H2N ring of the heterocycle being rotated by about 180°; the two dications are superimposed in the crystal structure.
Supporting information
Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805002618/bt6584sup1.cif | |
Structure factor file (CIF format) https://doi.org/10.1107/S1600536805002618/bt6584Isup2.hkl |
CCDC reference: 263648
Key indicators
- Single-crystal X-ray study
- T = 295 K
- Mean (C-C) = 0.009 Å
- R factor = 0.068
- wR factor = 0.203
- Data-to-parameter ratio = 15.5
checkCIF/PLATON results
No syntax errors found
Alert level C PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for P1 PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for P2 PLAT301_ALERT_3_C Main Residue Disorder ......................... 10.00 Perc. PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 9 PLAT366_ALERT_2_C Short? C(sp?)-C(sp?) Bond C6 - C7 ... 1.39 Ang.
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 6 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 1 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 2 ALERT type 4 Improvement, methodology, query or suggestion
Computing details top
Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.
Bis[µ-4'-(2-pyridyl)-2,2':6',2''-terpyridine]disilver(I)
bis(hexafluorophosphate) top
Crystal data top
[Ag2(C20H14N4)2](PF6)2 | F(000) = 2224 |
Mr = 1126.38 | Dx = 1.837 Mg m−3 |
Monoclinic, C2/c | Melting point: 598 K |
Hall symbol: -C 2yc | Mo Kα radiation, λ = 0.71073 Å |
a = 20.454 (3) Å | Cell parameters from 3734 reflections |
b = 15.749 (3) Å | θ = 2.3–23.6° |
c = 14.603 (3) Å | µ = 1.14 mm−1 |
β = 120.050 (4)° | T = 295 K |
V = 4071.9 (12) Å3 | Block, colorless |
Z = 4 | 0.25 × 0.20 × 0.15 mm |
Data collection top
Bruker APEX area-detector diffractometer | 4656 independent reflections |
Radiation source: fine-focus sealed tube | 3706 reflections with I > 2σ(I) |
Graphite monochromator | Rint = 0.034 |
φ and ω scans | θmax = 27.5°, θmin = 1.7° |
Absorption correction: multi-scan (SADABS; Bruker, 2002) | h = −25→26 |
Tmin = 0.709, Tmax = 0.848 | k = −20→20 |
17230 measured reflections | l = −18→18 |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.068 | Hydrogen site location: inferred from neighbouring sites |
wR(F2) = 0.203 | H-atom parameters constrained |
S = 1.17 | w = 1/[σ2(Fo2) + (0.0875P)2 + 15.7707P] where P = (Fo2 + 2Fc2)/3 |
4656 reflections | (Δ/σ)max = 0.001 |
301 parameters | Δρmax = 0.68 e Å−3 |
16 restraints | Δρmin = −0.62 e Å−3 |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
x | y | z | Uiso*/Ueq | Occ. (<1) | |
Ag1 | 0.41574 (9) | 0.32929 (8) | 0.38846 (10) | 0.0610 (6) | 0.3534 (18) |
Ag1' | 0.62377 (4) | 0.64061 (4) | 0.58039 (5) | 0.0486 (3) | 0.6466 (18) |
P1 | 0.5000 | 0.13764 (15) | 0.2500 | 0.0679 (7) | |
P2 | 0.7500 | 0.7500 | 0.5000 | 0.0491 (5) | |
F1 | 0.4483 (4) | 0.2082 (5) | 0.2538 (7) | 0.155 (3) | |
F2 | 0.4565 (6) | 0.1378 (7) | 0.1304 (5) | 0.219 (5) | |
F3 | 0.4459 (5) | 0.0704 (5) | 0.2521 (9) | 0.204 (4) | |
F4 | 0.6750 (2) | 0.6949 (3) | 0.4424 (3) | 0.0730 (11) | |
F5 | 0.7369 (3) | 0.7683 (3) | 0.5969 (3) | 0.0885 (14) | |
F6 | 0.7963 (3) | 0.6668 (3) | 0.5570 (4) | 0.0922 (14) | |
N1 | 0.5353 (3) | 0.7496 (3) | 0.4764 (4) | 0.0548 (12) | |
N2 | 0.5334 (2) | 0.5816 (3) | 0.4152 (3) | 0.0341 (9) | 0.3534 (18) |
C2' | 0.5334 (2) | 0.5816 (3) | 0.4152 (3) | 0.0341 (9) | 0.6466 (18) |
H2' | 0.5798 | 0.6059 | 0.4621 | 0.041* | 0.6466 (18) |
N3 | 0.6559 (2) | 0.4861 (3) | 0.5439 (3) | 0.0455 (10) | |
N4 | 0.3080 (3) | 0.3940 (3) | 0.2498 (3) | 0.0488 (11) | |
C1 | 0.5476 (4) | 0.8328 (4) | 0.4934 (5) | 0.0663 (17) | |
H1 | 0.5858 | 0.8507 | 0.5594 | 0.080* | |
C2 | 0.5066 (4) | 0.8940 (4) | 0.4182 (6) | 0.0631 (16) | |
H2 | 0.5155 | 0.9515 | 0.4343 | 0.076* | |
C3 | 0.4531 (4) | 0.8679 (4) | 0.3202 (6) | 0.0627 (16) | |
H3 | 0.4259 | 0.9074 | 0.2671 | 0.075* | |
C4 | 0.4394 (3) | 0.7822 (3) | 0.3007 (5) | 0.0539 (13) | |
H4 | 0.4019 | 0.7633 | 0.2347 | 0.065* | |
C5 | 0.4820 (3) | 0.7246 (3) | 0.3798 (4) | 0.0419 (11) | |
C6 | 0.4718 (3) | 0.6317 (3) | 0.3609 (4) | 0.0396 (10) | |
C7 | 0.4023 (3) | 0.5949 (3) | 0.2915 (4) | 0.0377 (10) | |
H7 | 0.3600 | 0.6289 | 0.2531 | 0.045* | |
C8 | 0.3965 (3) | 0.5071 (3) | 0.2799 (4) | 0.0376 (10) | |
C9 | 0.4596 (2) | 0.4575 (3) | 0.3358 (4) | 0.0422 (10) | 0.3534 (18) |
H9 | 0.4562 | 0.3987 | 0.3293 | 0.051* | 0.3534 (18) |
N9' | 0.4596 (2) | 0.4575 (3) | 0.3358 (4) | 0.0422 (10) | 0.6466 (18) |
C10 | 0.5279 (3) | 0.4957 (3) | 0.4015 (4) | 0.0376 (10) | |
C11 | 0.5981 (3) | 0.4454 (3) | 0.4632 (4) | 0.0394 (10) | |
C12 | 0.6032 (3) | 0.3616 (3) | 0.4384 (5) | 0.0559 (14) | |
H12 | 0.5622 | 0.3347 | 0.3823 | 0.067* | |
C13 | 0.6705 (4) | 0.3189 (4) | 0.4990 (6) | 0.0699 (18) | |
H13 | 0.6755 | 0.2627 | 0.4840 | 0.084* | |
C14 | 0.7305 (4) | 0.3605 (4) | 0.5824 (6) | 0.0717 (19) | |
H14 | 0.7764 | 0.3332 | 0.6241 | 0.086* | |
C15 | 0.7201 (3) | 0.4435 (4) | 0.6016 (5) | 0.0613 (16) | |
H15 | 0.7601 | 0.4714 | 0.6580 | 0.074* | |
C16 | 0.3219 (3) | 0.4672 (3) | 0.2137 (4) | 0.0400 (10) | |
C17 | 0.2672 (3) | 0.5031 (4) | 0.1200 (4) | 0.0496 (12) | |
H17 | 0.2776 | 0.5531 | 0.0959 | 0.060* | |
C18 | 0.1972 (3) | 0.4655 (4) | 0.0620 (5) | 0.0609 (15) | |
H18 | 0.1603 | 0.4893 | −0.0013 | 0.073* | |
C19 | 0.1834 (3) | 0.3920 (4) | 0.1000 (5) | 0.0610 (16) | |
H19 | 0.1367 | 0.3651 | 0.0635 | 0.073* | |
C20 | 0.2389 (4) | 0.3597 (4) | 0.1913 (5) | 0.0645 (16) | |
H20 | 0.2288 | 0.3097 | 0.2158 | 0.077* |
Atomic displacement parameters (Å2) top
U11 | U22 | U33 | U12 | U13 | U23 | |
Ag1 | 0.0744 (10) | 0.0429 (7) | 0.0433 (7) | −0.0028 (6) | 0.0129 (6) | 0.0067 (5) |
Ag1' | 0.0447 (4) | 0.0498 (4) | 0.0374 (4) | −0.0081 (3) | 0.0103 (3) | 0.0058 (3) |
P1 | 0.0765 (16) | 0.0492 (12) | 0.0508 (13) | 0.000 | 0.0115 (12) | 0.000 |
P2 | 0.0546 (11) | 0.0495 (11) | 0.0368 (10) | −0.0211 (9) | 0.0181 (9) | −0.0069 (8) |
F1 | 0.161 (6) | 0.130 (5) | 0.208 (8) | 0.059 (5) | 0.118 (6) | 0.047 (5) |
F2 | 0.202 (8) | 0.317 (14) | 0.058 (4) | −0.051 (8) | 0.006 (5) | −0.025 (5) |
F3 | 0.204 (8) | 0.117 (6) | 0.267 (11) | −0.053 (5) | 0.101 (8) | 0.041 (6) |
F4 | 0.067 (2) | 0.081 (3) | 0.064 (2) | −0.037 (2) | 0.0276 (19) | −0.0151 (19) |
F5 | 0.104 (3) | 0.117 (4) | 0.057 (2) | −0.043 (3) | 0.050 (2) | −0.024 (2) |
F6 | 0.093 (3) | 0.063 (2) | 0.071 (3) | −0.007 (2) | 0.004 (2) | −0.003 (2) |
N1 | 0.052 (3) | 0.052 (3) | 0.047 (3) | −0.012 (2) | 0.015 (2) | 0.004 (2) |
N2 | 0.031 (2) | 0.032 (2) | 0.035 (2) | −0.0013 (16) | 0.0134 (18) | 0.0015 (16) |
C2' | 0.031 (2) | 0.032 (2) | 0.035 (2) | −0.0013 (16) | 0.0134 (18) | 0.0015 (16) |
N3 | 0.038 (2) | 0.051 (3) | 0.043 (2) | 0.0024 (18) | 0.0171 (19) | 0.0014 (19) |
N4 | 0.057 (3) | 0.044 (2) | 0.037 (2) | −0.012 (2) | 0.017 (2) | −0.0043 (18) |
C1 | 0.074 (4) | 0.058 (4) | 0.059 (4) | −0.023 (3) | 0.028 (3) | −0.014 (3) |
C2 | 0.066 (4) | 0.035 (3) | 0.094 (5) | −0.009 (3) | 0.044 (4) | −0.006 (3) |
C3 | 0.058 (4) | 0.049 (3) | 0.075 (4) | 0.013 (3) | 0.029 (3) | 0.018 (3) |
C4 | 0.055 (3) | 0.039 (3) | 0.056 (3) | 0.002 (2) | 0.018 (3) | 0.003 (2) |
C5 | 0.039 (2) | 0.040 (3) | 0.048 (3) | −0.002 (2) | 0.023 (2) | 0.002 (2) |
C6 | 0.044 (3) | 0.041 (3) | 0.035 (2) | 0.004 (2) | 0.021 (2) | 0.0052 (19) |
C7 | 0.038 (2) | 0.037 (2) | 0.041 (3) | 0.0047 (19) | 0.022 (2) | 0.0065 (19) |
C8 | 0.042 (2) | 0.041 (2) | 0.033 (2) | 0.003 (2) | 0.021 (2) | 0.0053 (19) |
C9 | 0.042 (2) | 0.038 (2) | 0.047 (2) | −0.0009 (18) | 0.023 (2) | 0.0006 (19) |
N9' | 0.042 (2) | 0.038 (2) | 0.047 (2) | −0.0009 (18) | 0.023 (2) | 0.0006 (19) |
C10 | 0.042 (2) | 0.041 (2) | 0.035 (2) | 0.000 (2) | 0.022 (2) | 0.0009 (19) |
C11 | 0.037 (2) | 0.041 (3) | 0.045 (3) | 0.0045 (19) | 0.023 (2) | 0.003 (2) |
C12 | 0.052 (3) | 0.043 (3) | 0.067 (4) | 0.005 (2) | 0.025 (3) | −0.001 (3) |
C13 | 0.073 (4) | 0.052 (4) | 0.082 (5) | 0.024 (3) | 0.037 (4) | 0.009 (3) |
C14 | 0.055 (4) | 0.081 (5) | 0.074 (5) | 0.028 (3) | 0.028 (3) | 0.023 (4) |
C15 | 0.044 (3) | 0.078 (4) | 0.055 (3) | 0.014 (3) | 0.019 (3) | 0.002 (3) |
C16 | 0.044 (3) | 0.038 (2) | 0.040 (3) | −0.002 (2) | 0.023 (2) | −0.002 (2) |
C17 | 0.047 (3) | 0.046 (3) | 0.046 (3) | 0.008 (2) | 0.016 (2) | 0.010 (2) |
C18 | 0.043 (3) | 0.072 (4) | 0.055 (3) | 0.008 (3) | 0.015 (3) | 0.007 (3) |
C19 | 0.042 (3) | 0.085 (5) | 0.051 (3) | −0.016 (3) | 0.020 (3) | −0.013 (3) |
C20 | 0.068 (4) | 0.066 (4) | 0.055 (4) | −0.026 (3) | 0.028 (3) | −0.010 (3) |
Geometric parameters (Å, º) top
Ag1—N1i | 2.112 (5) | C1—H1 | 0.9300 |
Ag1—N4 | 2.351 (5) | C2—C3 | 1.359 (9) |
Ag1—N9' | 2.483 (5) | C2—H2 | 0.9300 |
Ag1—F1 | 3.044 (8) | C3—C4 | 1.380 (8) |
Ag1'—N1 | 2.403 (5) | C3—H3 | 0.9300 |
Ag1'—N2 | 2.374 (4) | C4—C5 | 1.382 (7) |
Ag1'—N3 | 2.643 (5) | C4—H4 | 0.9300 |
Ag1'—N4i | 2.220 (4) | C5—C6 | 1.483 (7) |
Ag1'—F4 | 2.829 (4) | C6—C7 | 1.393 (7) |
Ag1'—F5 | 2.983 (4) | C7—C8 | 1.391 (6) |
P1—F2ii | 1.512 (7) | C7—H7 | 0.9300 |
P1—F2 | 1.512 (7) | C8—C9 | 1.373 (6) |
P1—F3ii | 1.542 (7) | C8—C16 | 1.477 (7) |
P1—F3 | 1.542 (7) | C9—C10 | 1.376 (6) |
P1—F1ii | 1.554 (6) | C9—H9 | 0.9300 |
P1—F1 | 1.554 (6) | C10—C11 | 1.485 (7) |
P2—F6 | 1.586 (4) | C11—C12 | 1.385 (7) |
P2—F6iii | 1.586 (4) | C12—C13 | 1.383 (8) |
P2—F4iii | 1.588 (3) | C12—H12 | 0.9300 |
P2—F4 | 1.588 (3) | C13—C14 | 1.387 (9) |
P2—F5 | 1.592 (4) | C13—H13 | 0.9300 |
P2—F5iii | 1.592 (4) | C14—C15 | 1.374 (9) |
N1—C1 | 1.334 (8) | C14—H14 | 0.9300 |
N1—C5 | 1.339 (7) | C15—H15 | 0.9300 |
N1—Ag1i | 2.112 (5) | C16—C17 | 1.382 (7) |
N2—C6 | 1.357 (6) | C17—C18 | 1.380 (8) |
N2—C10 | 1.363 (6) | C17—H17 | 0.9300 |
N3—C15 | 1.333 (7) | C18—C19 | 1.374 (9) |
N3—C11 | 1.343 (6) | C18—H18 | 0.9300 |
N4—C20 | 1.345 (7) | C19—C20 | 1.345 (9) |
N4—C16 | 1.356 (6) | C19—H19 | 0.9300 |
N4—Ag1'i | 2.220 (4) | C20—H20 | 0.9300 |
C1—C2 | 1.384 (9) | ||
N1i—Ag1—N4 | 149.5 (2) | C20—N4—Ag1'i | 119.0 (4) |
N1i—Ag1—N9' | 133.8 (2) | C16—N4—Ag1'i | 120.4 (3) |
N1i—Ag1—F1 | 94.6 (2) | C20—N4—Ag1 | 127.4 (4) |
N4—Ag1—N9' | 73.1 (2) | C16—N4—Ag1 | 114.5 (3) |
N4—Ag1—F1 | 97.4 (2) | N1—C1—C2 | 123.6 (6) |
N9'—Ag1—F1 | 94.6 (2) | N1—C1—H1 | 118.2 |
N1—Ag1'—N2 | 71.4 (2) | C2—C1—H1 | 118.2 |
N1—Ag1'—N3 | 135.6 (2) | C3—C2—C1 | 118.2 (5) |
N1—Ag1'—N4i | 137.2 (2) | C3—C2—H2 | 120.9 |
N1—Ag1'—F4 | 76.4 (2) | C1—C2—H2 | 120.9 |
N1—Ag1'—F5 | 83.0 (2) | C2—C3—C4 | 119.1 (6) |
N2—Ag1'—N3 | 65.2 (1) | C2—C3—H3 | 120.4 |
N2—Ag1'—N4i | 140.7 (2) | C4—C3—H3 | 120.4 |
N2—Ag1'—F4 | 76.8 (1) | C3—C4—C5 | 119.5 (6) |
N2—Ag1'—F5 | 121.6 (1) | C3—C4—H4 | 120.3 |
N3—Ag1'—N4i | 85.3 (2) | C5—C4—H4 | 120.3 |
N3—Ag1'—F4 | 85.2 (1) | N1—C5—C4 | 121.9 (5) |
N3—Ag1'—F5 | 112.1 (1) | N1—C5—C6 | 116.8 (4) |
N4i—Ag1'—F4 | 128.3 (2) | C4—C5—C6 | 121.3 (5) |
N4i—Ag1'—F5 | 92.7 (1) | N2—C6—C7 | 119.5 (4) |
F4—Ag1'—F5 | 46.0 (1) | N2—C6—C5 | 117.6 (4) |
F2ii—P1—F2 | 179.8 (9) | C7—C6—C5 | 122.9 (4) |
F2ii—P1—F3ii | 90.7 (6) | C8—C7—C6 | 119.8 (4) |
F2—P1—F3ii | 89.5 (6) | C8—C7—H7 | 120.1 |
F2ii—P1—F3 | 89.5 (6) | C6—C7—H7 | 120.1 |
F2—P1—F3 | 90.7 (6) | C9—C8—C7 | 119.6 (4) |
F3ii—P1—F3 | 93.3 (8) | C9—C8—C16 | 120.2 (4) |
F2ii—P1—F1ii | 91.3 (6) | C7—C8—C16 | 120.0 (4) |
F2—P1—F1ii | 88.5 (5) | C8—C9—C10 | 119.4 (4) |
F3ii—P1—F1ii | 89.0 (5) | C8—N9'—Ag1 | 105.6 (3) |
F3—P1—F1ii | 177.6 (5) | C10—N9'—Ag1 | 122.5 (3) |
F2ii—P1—F1 | 88.5 (5) | C8—C9—H9 | 120.3 |
F2—P1—F1 | 91.3 (6) | C10—C9—H9 | 120.3 |
F3ii—P1—F1 | 177.6 (5) | N2—C10—C9 | 121.1 (4) |
F3—P1—F1 | 89.0 (5) | N2—C10—C11 | 117.2 (4) |
F1ii—P1—F1 | 88.7 (6) | C9—C10—C11 | 121.7 (4) |
F6—P2—F6iii | 180.000 (1) | N3—C11—C12 | 122.4 (5) |
F6—P2—F4iii | 90.5 (2) | N3—C11—C10 | 115.8 (4) |
F6iii—P2—F4iii | 89.5 (2) | C12—C11—C10 | 121.8 (5) |
F6—P2—F4 | 89.5 (2) | C13—C12—C11 | 118.6 (6) |
F6iii—P2—F4 | 90.5 (2) | C13—C12—H12 | 120.7 |
F4iii—P2—F4 | 180.0 (3) | C11—C12—H12 | 120.7 |
F6—P2—F5 | 90.3 (3) | C12—C13—C14 | 119.4 (6) |
F6iii—P2—F5 | 89.7 (3) | C12—C13—H13 | 120.3 |
F4iii—P2—F5 | 88.7 (2) | C14—C13—H13 | 120.3 |
F4—P2—F5 | 91.3 (2) | C15—C14—C13 | 118.0 (6) |
F6—P2—F5iii | 89.7 (3) | C15—C14—H14 | 121.0 |
F6iii—P2—F5iii | 90.3 (3) | C13—C14—H14 | 121.0 |
F4iii—P2—F5iii | 91.3 (2) | N3—C15—C14 | 123.6 (6) |
F4—P2—F5iii | 88.7 (2) | N3—C15—H15 | 118.2 |
F5—P2—F5iii | 180.000 (1) | C14—C15—H15 | 118.2 |
P1—F1—Ag1 | 147.6 (5) | N4—C16—C17 | 120.7 (5) |
P2—F4—Ag1' | 113.08 (18) | N4—C16—C8 | 117.1 (4) |
P2—F5—Ag1' | 105.96 (19) | C17—C16—C8 | 122.2 (4) |
C1—N1—C5 | 117.6 (5) | C18—C17—C16 | 120.6 (5) |
C1—N1—Ag1i | 116.6 (4) | C18—C17—H17 | 119.7 |
C5—N1—Ag1i | 124.5 (4) | C16—C17—H17 | 119.7 |
C1—N1—Ag1' | 124.9 (4) | C19—C18—C17 | 118.3 (5) |
C5—N1—Ag1' | 114.4 (4) | C19—C18—H18 | 120.9 |
C6—N2—C10 | 120.5 (4) | C17—C18—H18 | 120.9 |
C6—N2—Ag1' | 112.8 (3) | C20—C19—C18 | 118.5 (5) |
C10—N2—Ag1' | 120.2 (3) | C20—C19—H19 | 120.8 |
C15—N3—C11 | 118.0 (5) | C18—C19—H19 | 120.8 |
C15—N3—Ag1' | 127.0 (4) | N4—C20—C19 | 125.1 (6) |
C11—N3—Ag1' | 114.7 (3) | N4—C20—H20 | 117.4 |
C20—N4—C16 | 116.9 (5) | C19—C20—H20 | 117.4 |
F2ii—P1—F1—Ag1 | 4.9 (9) | C1—C2—C3—C4 | 2.6 (10) |
F2—P1—F1—Ag1 | −175.0 (8) | C2—C3—C4—C5 | −2.0 (9) |
F3—P1—F1—Ag1 | 94.4 (8) | C1—N1—C5—C4 | −1.7 (8) |
F1ii—P1—F1—Ag1 | −86.4 (8) | Ag1i—N1—C5—C4 | 164.4 (4) |
N1i—Ag1—F1—P1 | −28.9 (8) | Ag1'—N1—C5—C4 | −162.8 (4) |
N4—Ag1—F1—P1 | 179.3 (8) | C1—N1—C5—C6 | 177.0 (5) |
N9'—Ag1—F1—P1 | 105.8 (8) | Ag1i—N1—C5—C6 | −16.9 (7) |
F6—P2—F4—Ag1' | 72.1 (3) | Ag1'—N1—C5—C6 | 15.9 (6) |
F6iii—P2—F4—Ag1' | −107.9 (3) | C3—C4—C5—N1 | 1.6 (9) |
F5—P2—F4—Ag1' | −18.2 (3) | C3—C4—C5—C6 | −177.1 (5) |
F5iii—P2—F4—Ag1' | 161.8 (3) | C10—N2—C6—C7 | 0.7 (7) |
N4i—Ag1'—F4—P2 | −33.7 (3) | Ag1'—N2—C6—C7 | −151.2 (4) |
N2—Ag1'—F4—P2 | −179.5 (3) | C10—N2—C6—C5 | 180.0 (4) |
N1—Ag1'—F4—P2 | 106.8 (3) | Ag1'—N2—C6—C5 | 28.1 (5) |
N3—Ag1'—F4—P2 | −113.9 (2) | N1—C5—C6—N2 | −30.7 (7) |
F5—Ag1'—F4—P2 | 13.4 (2) | C4—C5—C6—N2 | 148.0 (5) |
F6—P2—F5—Ag1' | −73.0 (2) | N1—C5—C6—C7 | 148.6 (5) |
F6iii—P2—F5—Ag1' | 107.0 (2) | C4—C5—C6—C7 | −32.7 (7) |
F4iii—P2—F5—Ag1' | −163.5 (2) | N2—C6—C7—C8 | 1.1 (7) |
F4—P2—F5—Ag1' | 16.5 (2) | C5—C6—C7—C8 | −178.2 (4) |
N4i—Ag1'—F5—P2 | 132.1 (3) | C6—C7—C8—C9 | −1.0 (7) |
N2—Ag1'—F5—P2 | −27.5 (3) | C6—C7—C8—C16 | 174.7 (4) |
N1—Ag1'—F5—P2 | −90.6 (3) | C7—C8—C9—C10 | −0.9 (7) |
N3—Ag1'—F5—P2 | 46.1 (3) | C16—C8—C9—C10 | −176.5 (4) |
F4—Ag1'—F5—P2 | −12.78 (19) | C7—C8—N9'—Ag1 | 142.0 (4) |
N4i—Ag1'—N1—C1 | 52.2 (6) | C16—C8—N9'—Ag1 | −33.6 (5) |
N2—Ag1'—N1—C1 | −160.9 (6) | N1i—Ag1—N9'—C8 | −144.9 (3) |
N3—Ag1'—N1—C1 | −148.7 (5) | N4—Ag1—N9'—C8 | 17.9 (3) |
F4—Ag1'—N1—C1 | −80.4 (5) | F1—Ag1—N9'—C8 | 114.3 (3) |
F5—Ag1'—N1—C1 | −34.1 (5) | N1i—Ag1—N9'—C10 | −3.4 (5) |
N4i—Ag1'—N1—C5 | −148.3 (3) | N4—Ag1—N9'—C10 | 159.4 (4) |
N2—Ag1'—N1—C5 | −1.4 (3) | F1—Ag1—N9'—C10 | −104.3 (4) |
N3—Ag1'—N1—C5 | 10.8 (5) | C6—N2—C10—C9 | −2.6 (7) |
F4—Ag1'—N1—C5 | 79.1 (4) | Ag1'—N2—C10—C9 | 147.2 (4) |
F5—Ag1'—N1—C5 | 125.4 (4) | C6—N2—C10—C11 | 179.5 (4) |
N4i—Ag1'—N1—Ag1i | −31.1 (3) | Ag1'—N2—C10—C11 | −30.7 (5) |
N2—Ag1'—N1—Ag1i | 115.78 (16) | C8—C9—C10—N2 | 2.7 (7) |
N3—Ag1'—N1—Ag1i | 127.94 (19) | C8—C9—C10—C11 | −179.5 (4) |
F4—Ag1'—N1—Ag1i | −163.77 (14) | Ag1—N9'—C10—C11 | 44.0 (6) |
F5—Ag1'—N1—Ag1i | −117.48 (13) | C15—N3—C11—C12 | 0.0 (8) |
N4i—Ag1'—N2—C6 | 130.0 (3) | Ag1'—N3—C11—C12 | −174.8 (4) |
N1—Ag1'—N2—C6 | −14.2 (3) | C15—N3—C11—C10 | −180.0 (5) |
N3—Ag1'—N2—C6 | 175.2 (4) | Ag1'—N3—C11—C10 | 5.2 (5) |
F4—Ag1'—N2—C6 | −94.0 (3) | N2—C10—C11—N3 | 14.9 (6) |
F5—Ag1'—N2—C6 | −83.2 (4) | C9—C10—C11—N3 | −163.0 (4) |
N4i—Ag1'—N2—C10 | −21.9 (5) | N2—C10—C11—C12 | −165.1 (5) |
N1—Ag1'—N2—C10 | −166.1 (4) | C9—C10—C11—C12 | 17.0 (7) |
N3—Ag1'—N2—C10 | 23.2 (3) | N3—C11—C12—C13 | −0.4 (9) |
F4—Ag1'—N2—C10 | 114.0 (4) | C10—C11—C12—C13 | 179.6 (5) |
F5—Ag1'—N2—C10 | 124.8 (3) | C11—C12—C13—C14 | 0.2 (10) |
N4i—Ag1'—N3—C15 | −35.3 (5) | C12—C13—C14—C15 | 0.3 (11) |
N2—Ag1'—N3—C15 | 171.5 (5) | C11—N3—C15—C14 | 0.5 (9) |
N1—Ag1'—N3—C15 | 158.8 (4) | Ag1'—N3—C15—C14 | 174.6 (5) |
F4—Ag1'—N3—C15 | 93.8 (5) | C13—C14—C15—N3 | −0.7 (11) |
F5—Ag1'—N3—C15 | 55.7 (5) | C20—N4—C16—C17 | −1.0 (8) |
N4i—Ag1'—N3—C11 | 139.0 (4) | Ag1'i—N4—C16—C17 | −159.0 (4) |
N2—Ag1'—N3—C11 | −14.3 (3) | Ag1—N4—C16—C17 | 167.3 (4) |
N1—Ag1'—N3—C11 | −27.0 (4) | C20—N4—C16—C8 | 177.5 (5) |
F4—Ag1'—N3—C11 | −91.9 (3) | Ag1'i—N4—C16—C8 | 19.5 (6) |
F5—Ag1'—N3—C11 | −130.0 (3) | Ag1—N4—C16—C8 | −14.3 (5) |
N1i—Ag1—N4—C20 | −40.1 (7) | C9—C8—C16—N4 | 35.5 (6) |
N9'—Ag1—N4—C20 | 164.8 (5) | C7—C8—C16—N4 | −140.2 (5) |
F1—Ag1—N4—C20 | 72.2 (5) | C9—C8—C16—C17 | −146.1 (5) |
N1i—Ag1—N4—C16 | 153.1 (4) | C7—C8—C16—C17 | 38.3 (7) |
N9'—Ag1—N4—C16 | −2.0 (3) | N4—C16—C17—C18 | 0.5 (8) |
F1—Ag1—N4—C16 | −94.6 (4) | C8—C16—C17—C18 | −177.9 (5) |
N1i—Ag1—N4—Ag1'i | 44.4 (4) | C16—C17—C18—C19 | 0.3 (9) |
N9'—Ag1—N4—Ag1'i | −110.80 (14) | C17—C18—C19—C20 | −0.7 (10) |
F1—Ag1—N4—Ag1'i | 156.65 (18) | C16—N4—C20—C19 | 0.6 (9) |
C5—N1—C1—C2 | 2.4 (10) | Ag1'i—N4—C20—C19 | 158.9 (6) |
Ag1i—N1—C1—C2 | −164.8 (5) | Ag1—N4—C20—C19 | −165.9 (5) |
Ag1'—N1—C1—C2 | 161.3 (5) | C18—C19—C20—N4 | 0.3 (11) |
N1—C1—C2—C3 | −2.9 (11) |
Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+1, y, −z+1/2; (iii) −x+3/2, −y+3/2, −z+1. |
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