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The Ag atoms and the ligands of the dication in the title compound, [Ag2(C20H14N4)2](PF6)2, are disordered; the dication lies on a center of symmetry. The major component is chelated by two N atoms of the heterocycle and is coordinated by the N atom of the pyridyl substituent of the other heterocycle; the geometry is trigonal planar distorted towards tetrahedral owing to a weak Ag...F interaction. The minor component is chelated by three N atoms and is also coordinated by the N atom of the pyridyl substituent of the inversion-related heterocycle; its geometry is octahedral owing to two Ag...F interactions. One anion lies on a special position of site symmetry 2 and the other on a special position of site symmetry \overline 1 . The disorder in the centrosymmetric dication is best described in terms of the Ag atom being disordered over two sites and the C5H2N ring of the heterocycle being rotated by about 180°; the two dications are superimposed in the crystal structure.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805002618/bt6584sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536805002618/bt6584Isup2.hkl
Contains datablock I

CCDC reference: 263648

Key indicators

  • Single-crystal X-ray study
  • T = 295 K
  • Mean [sigma](C-C) = 0.009 Å
  • R factor = 0.068
  • wR factor = 0.203
  • Data-to-parameter ratio = 15.5

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for P1 PLAT244_ALERT_4_C Low 'Solvent' Ueq as Compared to Neighbors for P2 PLAT301_ALERT_3_C Main Residue Disorder ......................... 10.00 Perc. PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 9 PLAT366_ALERT_2_C Short? C(sp?)-C(sp?) Bond C6 - C7 ... 1.39 Ang.
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 6 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 1 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 2 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 2002); cell refinement: SAINT (Bruker, 2002); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

Bis[µ-4'-(2-pyridyl)-2,2':6',2''-terpyridine]disilver(I) bis(hexafluorophosphate) top
Crystal data top
[Ag2(C20H14N4)2](PF6)2F(000) = 2224
Mr = 1126.38Dx = 1.837 Mg m3
Monoclinic, C2/cMelting point: 598 K
Hall symbol: -C 2ycMo Kα radiation, λ = 0.71073 Å
a = 20.454 (3) ÅCell parameters from 3734 reflections
b = 15.749 (3) Åθ = 2.3–23.6°
c = 14.603 (3) ŵ = 1.14 mm1
β = 120.050 (4)°T = 295 K
V = 4071.9 (12) Å3Block, colorless
Z = 40.25 × 0.20 × 0.15 mm
Data collection top
Bruker APEX area-detector
diffractometer
4656 independent reflections
Radiation source: fine-focus sealed tube3706 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.034
φ and ω scansθmax = 27.5°, θmin = 1.7°
Absorption correction: multi-scan
(SADABS; Bruker, 2002)
h = 2526
Tmin = 0.709, Tmax = 0.848k = 2020
17230 measured reflectionsl = 1818
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.068Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.203H-atom parameters constrained
S = 1.17 w = 1/[σ2(Fo2) + (0.0875P)2 + 15.7707P]
where P = (Fo2 + 2Fc2)/3
4656 reflections(Δ/σ)max = 0.001
301 parametersΔρmax = 0.68 e Å3
16 restraintsΔρmin = 0.62 e Å3
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/UeqOcc. (<1)
Ag10.41574 (9)0.32929 (8)0.38846 (10)0.0610 (6)0.3534 (18)
Ag1'0.62377 (4)0.64061 (4)0.58039 (5)0.0486 (3)0.6466 (18)
P10.50000.13764 (15)0.25000.0679 (7)
P20.75000.75000.50000.0491 (5)
F10.4483 (4)0.2082 (5)0.2538 (7)0.155 (3)
F20.4565 (6)0.1378 (7)0.1304 (5)0.219 (5)
F30.4459 (5)0.0704 (5)0.2521 (9)0.204 (4)
F40.6750 (2)0.6949 (3)0.4424 (3)0.0730 (11)
F50.7369 (3)0.7683 (3)0.5969 (3)0.0885 (14)
F60.7963 (3)0.6668 (3)0.5570 (4)0.0922 (14)
N10.5353 (3)0.7496 (3)0.4764 (4)0.0548 (12)
N20.5334 (2)0.5816 (3)0.4152 (3)0.0341 (9)0.3534 (18)
C2'0.5334 (2)0.5816 (3)0.4152 (3)0.0341 (9)0.6466 (18)
H2'0.57980.60590.46210.041*0.6466 (18)
N30.6559 (2)0.4861 (3)0.5439 (3)0.0455 (10)
N40.3080 (3)0.3940 (3)0.2498 (3)0.0488 (11)
C10.5476 (4)0.8328 (4)0.4934 (5)0.0663 (17)
H10.58580.85070.55940.080*
C20.5066 (4)0.8940 (4)0.4182 (6)0.0631 (16)
H20.51550.95150.43430.076*
C30.4531 (4)0.8679 (4)0.3202 (6)0.0627 (16)
H30.42590.90740.26710.075*
C40.4394 (3)0.7822 (3)0.3007 (5)0.0539 (13)
H40.40190.76330.23470.065*
C50.4820 (3)0.7246 (3)0.3798 (4)0.0419 (11)
C60.4718 (3)0.6317 (3)0.3609 (4)0.0396 (10)
C70.4023 (3)0.5949 (3)0.2915 (4)0.0377 (10)
H70.36000.62890.25310.045*
C80.3965 (3)0.5071 (3)0.2799 (4)0.0376 (10)
C90.4596 (2)0.4575 (3)0.3358 (4)0.0422 (10)0.3534 (18)
H90.45620.39870.32930.051*0.3534 (18)
N9'0.4596 (2)0.4575 (3)0.3358 (4)0.0422 (10)0.6466 (18)
C100.5279 (3)0.4957 (3)0.4015 (4)0.0376 (10)
C110.5981 (3)0.4454 (3)0.4632 (4)0.0394 (10)
C120.6032 (3)0.3616 (3)0.4384 (5)0.0559 (14)
H120.56220.33470.38230.067*
C130.6705 (4)0.3189 (4)0.4990 (6)0.0699 (18)
H130.67550.26270.48400.084*
C140.7305 (4)0.3605 (4)0.5824 (6)0.0717 (19)
H140.77640.33320.62410.086*
C150.7201 (3)0.4435 (4)0.6016 (5)0.0613 (16)
H150.76010.47140.65800.074*
C160.3219 (3)0.4672 (3)0.2137 (4)0.0400 (10)
C170.2672 (3)0.5031 (4)0.1200 (4)0.0496 (12)
H170.27760.55310.09590.060*
C180.1972 (3)0.4655 (4)0.0620 (5)0.0609 (15)
H180.16030.48930.00130.073*
C190.1834 (3)0.3920 (4)0.1000 (5)0.0610 (16)
H190.13670.36510.06350.073*
C200.2389 (4)0.3597 (4)0.1913 (5)0.0645 (16)
H200.22880.30970.21580.077*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0744 (10)0.0429 (7)0.0433 (7)0.0028 (6)0.0129 (6)0.0067 (5)
Ag1'0.0447 (4)0.0498 (4)0.0374 (4)0.0081 (3)0.0103 (3)0.0058 (3)
P10.0765 (16)0.0492 (12)0.0508 (13)0.0000.0115 (12)0.000
P20.0546 (11)0.0495 (11)0.0368 (10)0.0211 (9)0.0181 (9)0.0069 (8)
F10.161 (6)0.130 (5)0.208 (8)0.059 (5)0.118 (6)0.047 (5)
F20.202 (8)0.317 (14)0.058 (4)0.051 (8)0.006 (5)0.025 (5)
F30.204 (8)0.117 (6)0.267 (11)0.053 (5)0.101 (8)0.041 (6)
F40.067 (2)0.081 (3)0.064 (2)0.037 (2)0.0276 (19)0.0151 (19)
F50.104 (3)0.117 (4)0.057 (2)0.043 (3)0.050 (2)0.024 (2)
F60.093 (3)0.063 (2)0.071 (3)0.007 (2)0.004 (2)0.003 (2)
N10.052 (3)0.052 (3)0.047 (3)0.012 (2)0.015 (2)0.004 (2)
N20.031 (2)0.032 (2)0.035 (2)0.0013 (16)0.0134 (18)0.0015 (16)
C2'0.031 (2)0.032 (2)0.035 (2)0.0013 (16)0.0134 (18)0.0015 (16)
N30.038 (2)0.051 (3)0.043 (2)0.0024 (18)0.0171 (19)0.0014 (19)
N40.057 (3)0.044 (2)0.037 (2)0.012 (2)0.017 (2)0.0043 (18)
C10.074 (4)0.058 (4)0.059 (4)0.023 (3)0.028 (3)0.014 (3)
C20.066 (4)0.035 (3)0.094 (5)0.009 (3)0.044 (4)0.006 (3)
C30.058 (4)0.049 (3)0.075 (4)0.013 (3)0.029 (3)0.018 (3)
C40.055 (3)0.039 (3)0.056 (3)0.002 (2)0.018 (3)0.003 (2)
C50.039 (2)0.040 (3)0.048 (3)0.002 (2)0.023 (2)0.002 (2)
C60.044 (3)0.041 (3)0.035 (2)0.004 (2)0.021 (2)0.0052 (19)
C70.038 (2)0.037 (2)0.041 (3)0.0047 (19)0.022 (2)0.0065 (19)
C80.042 (2)0.041 (2)0.033 (2)0.003 (2)0.021 (2)0.0053 (19)
C90.042 (2)0.038 (2)0.047 (2)0.0009 (18)0.023 (2)0.0006 (19)
N9'0.042 (2)0.038 (2)0.047 (2)0.0009 (18)0.023 (2)0.0006 (19)
C100.042 (2)0.041 (2)0.035 (2)0.000 (2)0.022 (2)0.0009 (19)
C110.037 (2)0.041 (3)0.045 (3)0.0045 (19)0.023 (2)0.003 (2)
C120.052 (3)0.043 (3)0.067 (4)0.005 (2)0.025 (3)0.001 (3)
C130.073 (4)0.052 (4)0.082 (5)0.024 (3)0.037 (4)0.009 (3)
C140.055 (4)0.081 (5)0.074 (5)0.028 (3)0.028 (3)0.023 (4)
C150.044 (3)0.078 (4)0.055 (3)0.014 (3)0.019 (3)0.002 (3)
C160.044 (3)0.038 (2)0.040 (3)0.002 (2)0.023 (2)0.002 (2)
C170.047 (3)0.046 (3)0.046 (3)0.008 (2)0.016 (2)0.010 (2)
C180.043 (3)0.072 (4)0.055 (3)0.008 (3)0.015 (3)0.007 (3)
C190.042 (3)0.085 (5)0.051 (3)0.016 (3)0.020 (3)0.013 (3)
C200.068 (4)0.066 (4)0.055 (4)0.026 (3)0.028 (3)0.010 (3)
Geometric parameters (Å, º) top
Ag1—N1i2.112 (5)C1—H10.9300
Ag1—N42.351 (5)C2—C31.359 (9)
Ag1—N9'2.483 (5)C2—H20.9300
Ag1—F13.044 (8)C3—C41.380 (8)
Ag1'—N12.403 (5)C3—H30.9300
Ag1'—N22.374 (4)C4—C51.382 (7)
Ag1'—N32.643 (5)C4—H40.9300
Ag1'—N4i2.220 (4)C5—C61.483 (7)
Ag1'—F42.829 (4)C6—C71.393 (7)
Ag1'—F52.983 (4)C7—C81.391 (6)
P1—F2ii1.512 (7)C7—H70.9300
P1—F21.512 (7)C8—C91.373 (6)
P1—F3ii1.542 (7)C8—C161.477 (7)
P1—F31.542 (7)C9—C101.376 (6)
P1—F1ii1.554 (6)C9—H90.9300
P1—F11.554 (6)C10—C111.485 (7)
P2—F61.586 (4)C11—C121.385 (7)
P2—F6iii1.586 (4)C12—C131.383 (8)
P2—F4iii1.588 (3)C12—H120.9300
P2—F41.588 (3)C13—C141.387 (9)
P2—F51.592 (4)C13—H130.9300
P2—F5iii1.592 (4)C14—C151.374 (9)
N1—C11.334 (8)C14—H140.9300
N1—C51.339 (7)C15—H150.9300
N1—Ag1i2.112 (5)C16—C171.382 (7)
N2—C61.357 (6)C17—C181.380 (8)
N2—C101.363 (6)C17—H170.9300
N3—C151.333 (7)C18—C191.374 (9)
N3—C111.343 (6)C18—H180.9300
N4—C201.345 (7)C19—C201.345 (9)
N4—C161.356 (6)C19—H190.9300
N4—Ag1'i2.220 (4)C20—H200.9300
C1—C21.384 (9)
N1i—Ag1—N4149.5 (2)C20—N4—Ag1'i119.0 (4)
N1i—Ag1—N9'133.8 (2)C16—N4—Ag1'i120.4 (3)
N1i—Ag1—F194.6 (2)C20—N4—Ag1127.4 (4)
N4—Ag1—N9'73.1 (2)C16—N4—Ag1114.5 (3)
N4—Ag1—F197.4 (2)N1—C1—C2123.6 (6)
N9'—Ag1—F194.6 (2)N1—C1—H1118.2
N1—Ag1'—N271.4 (2)C2—C1—H1118.2
N1—Ag1'—N3135.6 (2)C3—C2—C1118.2 (5)
N1—Ag1'—N4i137.2 (2)C3—C2—H2120.9
N1—Ag1'—F476.4 (2)C1—C2—H2120.9
N1—Ag1'—F583.0 (2)C2—C3—C4119.1 (6)
N2—Ag1'—N365.2 (1)C2—C3—H3120.4
N2—Ag1'—N4i140.7 (2)C4—C3—H3120.4
N2—Ag1'—F476.8 (1)C3—C4—C5119.5 (6)
N2—Ag1'—F5121.6 (1)C3—C4—H4120.3
N3—Ag1'—N4i85.3 (2)C5—C4—H4120.3
N3—Ag1'—F485.2 (1)N1—C5—C4121.9 (5)
N3—Ag1'—F5112.1 (1)N1—C5—C6116.8 (4)
N4i—Ag1'—F4128.3 (2)C4—C5—C6121.3 (5)
N4i—Ag1'—F592.7 (1)N2—C6—C7119.5 (4)
F4—Ag1'—F546.0 (1)N2—C6—C5117.6 (4)
F2ii—P1—F2179.8 (9)C7—C6—C5122.9 (4)
F2ii—P1—F3ii90.7 (6)C8—C7—C6119.8 (4)
F2—P1—F3ii89.5 (6)C8—C7—H7120.1
F2ii—P1—F389.5 (6)C6—C7—H7120.1
F2—P1—F390.7 (6)C9—C8—C7119.6 (4)
F3ii—P1—F393.3 (8)C9—C8—C16120.2 (4)
F2ii—P1—F1ii91.3 (6)C7—C8—C16120.0 (4)
F2—P1—F1ii88.5 (5)C8—C9—C10119.4 (4)
F3ii—P1—F1ii89.0 (5)C8—N9'—Ag1105.6 (3)
F3—P1—F1ii177.6 (5)C10—N9'—Ag1122.5 (3)
F2ii—P1—F188.5 (5)C8—C9—H9120.3
F2—P1—F191.3 (6)C10—C9—H9120.3
F3ii—P1—F1177.6 (5)N2—C10—C9121.1 (4)
F3—P1—F189.0 (5)N2—C10—C11117.2 (4)
F1ii—P1—F188.7 (6)C9—C10—C11121.7 (4)
F6—P2—F6iii180.000 (1)N3—C11—C12122.4 (5)
F6—P2—F4iii90.5 (2)N3—C11—C10115.8 (4)
F6iii—P2—F4iii89.5 (2)C12—C11—C10121.8 (5)
F6—P2—F489.5 (2)C13—C12—C11118.6 (6)
F6iii—P2—F490.5 (2)C13—C12—H12120.7
F4iii—P2—F4180.0 (3)C11—C12—H12120.7
F6—P2—F590.3 (3)C12—C13—C14119.4 (6)
F6iii—P2—F589.7 (3)C12—C13—H13120.3
F4iii—P2—F588.7 (2)C14—C13—H13120.3
F4—P2—F591.3 (2)C15—C14—C13118.0 (6)
F6—P2—F5iii89.7 (3)C15—C14—H14121.0
F6iii—P2—F5iii90.3 (3)C13—C14—H14121.0
F4iii—P2—F5iii91.3 (2)N3—C15—C14123.6 (6)
F4—P2—F5iii88.7 (2)N3—C15—H15118.2
F5—P2—F5iii180.000 (1)C14—C15—H15118.2
P1—F1—Ag1147.6 (5)N4—C16—C17120.7 (5)
P2—F4—Ag1'113.08 (18)N4—C16—C8117.1 (4)
P2—F5—Ag1'105.96 (19)C17—C16—C8122.2 (4)
C1—N1—C5117.6 (5)C18—C17—C16120.6 (5)
C1—N1—Ag1i116.6 (4)C18—C17—H17119.7
C5—N1—Ag1i124.5 (4)C16—C17—H17119.7
C1—N1—Ag1'124.9 (4)C19—C18—C17118.3 (5)
C5—N1—Ag1'114.4 (4)C19—C18—H18120.9
C6—N2—C10120.5 (4)C17—C18—H18120.9
C6—N2—Ag1'112.8 (3)C20—C19—C18118.5 (5)
C10—N2—Ag1'120.2 (3)C20—C19—H19120.8
C15—N3—C11118.0 (5)C18—C19—H19120.8
C15—N3—Ag1'127.0 (4)N4—C20—C19125.1 (6)
C11—N3—Ag1'114.7 (3)N4—C20—H20117.4
C20—N4—C16116.9 (5)C19—C20—H20117.4
F2ii—P1—F1—Ag14.9 (9)C1—C2—C3—C42.6 (10)
F2—P1—F1—Ag1175.0 (8)C2—C3—C4—C52.0 (9)
F3—P1—F1—Ag194.4 (8)C1—N1—C5—C41.7 (8)
F1ii—P1—F1—Ag186.4 (8)Ag1i—N1—C5—C4164.4 (4)
N1i—Ag1—F1—P128.9 (8)Ag1'—N1—C5—C4162.8 (4)
N4—Ag1—F1—P1179.3 (8)C1—N1—C5—C6177.0 (5)
N9'—Ag1—F1—P1105.8 (8)Ag1i—N1—C5—C616.9 (7)
F6—P2—F4—Ag1'72.1 (3)Ag1'—N1—C5—C615.9 (6)
F6iii—P2—F4—Ag1'107.9 (3)C3—C4—C5—N11.6 (9)
F5—P2—F4—Ag1'18.2 (3)C3—C4—C5—C6177.1 (5)
F5iii—P2—F4—Ag1'161.8 (3)C10—N2—C6—C70.7 (7)
N4i—Ag1'—F4—P233.7 (3)Ag1'—N2—C6—C7151.2 (4)
N2—Ag1'—F4—P2179.5 (3)C10—N2—C6—C5180.0 (4)
N1—Ag1'—F4—P2106.8 (3)Ag1'—N2—C6—C528.1 (5)
N3—Ag1'—F4—P2113.9 (2)N1—C5—C6—N230.7 (7)
F5—Ag1'—F4—P213.4 (2)C4—C5—C6—N2148.0 (5)
F6—P2—F5—Ag1'73.0 (2)N1—C5—C6—C7148.6 (5)
F6iii—P2—F5—Ag1'107.0 (2)C4—C5—C6—C732.7 (7)
F4iii—P2—F5—Ag1'163.5 (2)N2—C6—C7—C81.1 (7)
F4—P2—F5—Ag1'16.5 (2)C5—C6—C7—C8178.2 (4)
N4i—Ag1'—F5—P2132.1 (3)C6—C7—C8—C91.0 (7)
N2—Ag1'—F5—P227.5 (3)C6—C7—C8—C16174.7 (4)
N1—Ag1'—F5—P290.6 (3)C7—C8—C9—C100.9 (7)
N3—Ag1'—F5—P246.1 (3)C16—C8—C9—C10176.5 (4)
F4—Ag1'—F5—P212.78 (19)C7—C8—N9'—Ag1142.0 (4)
N4i—Ag1'—N1—C152.2 (6)C16—C8—N9'—Ag133.6 (5)
N2—Ag1'—N1—C1160.9 (6)N1i—Ag1—N9'—C8144.9 (3)
N3—Ag1'—N1—C1148.7 (5)N4—Ag1—N9'—C817.9 (3)
F4—Ag1'—N1—C180.4 (5)F1—Ag1—N9'—C8114.3 (3)
F5—Ag1'—N1—C134.1 (5)N1i—Ag1—N9'—C103.4 (5)
N4i—Ag1'—N1—C5148.3 (3)N4—Ag1—N9'—C10159.4 (4)
N2—Ag1'—N1—C51.4 (3)F1—Ag1—N9'—C10104.3 (4)
N3—Ag1'—N1—C510.8 (5)C6—N2—C10—C92.6 (7)
F4—Ag1'—N1—C579.1 (4)Ag1'—N2—C10—C9147.2 (4)
F5—Ag1'—N1—C5125.4 (4)C6—N2—C10—C11179.5 (4)
N4i—Ag1'—N1—Ag1i31.1 (3)Ag1'—N2—C10—C1130.7 (5)
N2—Ag1'—N1—Ag1i115.78 (16)C8—C9—C10—N22.7 (7)
N3—Ag1'—N1—Ag1i127.94 (19)C8—C9—C10—C11179.5 (4)
F4—Ag1'—N1—Ag1i163.77 (14)Ag1—N9'—C10—C1144.0 (6)
F5—Ag1'—N1—Ag1i117.48 (13)C15—N3—C11—C120.0 (8)
N4i—Ag1'—N2—C6130.0 (3)Ag1'—N3—C11—C12174.8 (4)
N1—Ag1'—N2—C614.2 (3)C15—N3—C11—C10180.0 (5)
N3—Ag1'—N2—C6175.2 (4)Ag1'—N3—C11—C105.2 (5)
F4—Ag1'—N2—C694.0 (3)N2—C10—C11—N314.9 (6)
F5—Ag1'—N2—C683.2 (4)C9—C10—C11—N3163.0 (4)
N4i—Ag1'—N2—C1021.9 (5)N2—C10—C11—C12165.1 (5)
N1—Ag1'—N2—C10166.1 (4)C9—C10—C11—C1217.0 (7)
N3—Ag1'—N2—C1023.2 (3)N3—C11—C12—C130.4 (9)
F4—Ag1'—N2—C10114.0 (4)C10—C11—C12—C13179.6 (5)
F5—Ag1'—N2—C10124.8 (3)C11—C12—C13—C140.2 (10)
N4i—Ag1'—N3—C1535.3 (5)C12—C13—C14—C150.3 (11)
N2—Ag1'—N3—C15171.5 (5)C11—N3—C15—C140.5 (9)
N1—Ag1'—N3—C15158.8 (4)Ag1'—N3—C15—C14174.6 (5)
F4—Ag1'—N3—C1593.8 (5)C13—C14—C15—N30.7 (11)
F5—Ag1'—N3—C1555.7 (5)C20—N4—C16—C171.0 (8)
N4i—Ag1'—N3—C11139.0 (4)Ag1'i—N4—C16—C17159.0 (4)
N2—Ag1'—N3—C1114.3 (3)Ag1—N4—C16—C17167.3 (4)
N1—Ag1'—N3—C1127.0 (4)C20—N4—C16—C8177.5 (5)
F4—Ag1'—N3—C1191.9 (3)Ag1'i—N4—C16—C819.5 (6)
F5—Ag1'—N3—C11130.0 (3)Ag1—N4—C16—C814.3 (5)
N1i—Ag1—N4—C2040.1 (7)C9—C8—C16—N435.5 (6)
N9'—Ag1—N4—C20164.8 (5)C7—C8—C16—N4140.2 (5)
F1—Ag1—N4—C2072.2 (5)C9—C8—C16—C17146.1 (5)
N1i—Ag1—N4—C16153.1 (4)C7—C8—C16—C1738.3 (7)
N9'—Ag1—N4—C162.0 (3)N4—C16—C17—C180.5 (8)
F1—Ag1—N4—C1694.6 (4)C8—C16—C17—C18177.9 (5)
N1i—Ag1—N4—Ag1'i44.4 (4)C16—C17—C18—C190.3 (9)
N9'—Ag1—N4—Ag1'i110.80 (14)C17—C18—C19—C200.7 (10)
F1—Ag1—N4—Ag1'i156.65 (18)C16—N4—C20—C190.6 (9)
C5—N1—C1—C22.4 (10)Ag1'i—N4—C20—C19158.9 (6)
Ag1i—N1—C1—C2164.8 (5)Ag1—N4—C20—C19165.9 (5)
Ag1'—N1—C1—C2161.3 (5)C18—C19—C20—N40.3 (11)
N1—C1—C2—C32.9 (11)
Symmetry codes: (i) x+1, y+1, z+1; (ii) x+1, y, z+1/2; (iii) x+3/2, y+3/2, z+1.
 

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