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In the layer structure of the title polymeric complex, {[Ag2(C7H5O6S)2(H2O)3]·H2O}n, both substituted benzene­sulfonate anions use two of their sulfonyl O atoms to link to three Ag atoms and their double-bond carbonyl O atom to another Ag atom in a μ4-bonding mode. The two symmetry-independent Ag atoms are coordinated by water mol­ecules, one by one water mol­ecule and the other by two water mol­ecules so that one Ag atom is five- and the other six-coordinate.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536805000504/bt6578sup1.cif
Contains datablocks I, global

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536805000504/bt6578Isup2.hkl
Contains datablock I

CCDC reference: 263546

Key indicators

  • Single-crystal X-ray study
  • T = 295 K
  • Mean [sigma](C-C) = 0.004 Å
  • R factor = 0.028
  • wR factor = 0.074
  • Data-to-parameter ratio = 13.6

checkCIF/PLATON results

No syntax errors found



Alert level B ABSTM02_ALERT_3_B The ratio of expected to reported Tmax/Tmin(RR') is < 0.75 Tmin and Tmax reported: 0.316 0.668 Tmin' and Tmax expected: 0.439 0.669 RR' = 0.720 Please check that your absorption correction is appropriate. PLAT061_ALERT_3_B Tmax/Tmin Range Test RR' too Large ............. 0.70
Alert level C PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.03 Ratio PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 8 PLAT731_ALERT_1_C Bond Calc 0.86(4), Rep 0.850(10) ...... 4.00 su-Rat O4 -H4O 1.555 1.555 PLAT731_ALERT_1_C Bond Calc 0.85(3), Rep 0.850(10) ...... 3.00 su-Rat O6 -H6O 1.555 1.555 PLAT731_ALERT_1_C Bond Calc 0.85(4), Rep 0.850(10) ...... 4.00 su-Rat O10 -H10O 1.555 1.555 PLAT731_ALERT_1_C Bond Calc 0.85(3), Rep 0.850(10) ...... 3.00 su-Rat O12 -H12O 1.555 1.555 PLAT731_ALERT_1_C Bond Calc 0.85(4), Rep 0.850(10) ...... 4.00 su-Rat O1W -H1W2 1.555 1.555 PLAT731_ALERT_1_C Bond Calc 0.85(4), Rep 0.850(10) ...... 4.00 su-Rat O2W -H2W2 1.555 1.555 PLAT731_ALERT_1_C Bond Calc 0.85(4), Rep 0.850(10) ...... 4.00 su-Rat O3W -H3W2 1.555 1.555 PLAT731_ALERT_1_C Bond Calc 0.85(3), Rep 0.850(10) ...... 3.00 su-Rat O4W -H4W1 1.555 1.555 PLAT735_ALERT_1_C D-H Calc 0.86(4), Rep 0.850(10) ...... 4.00 su-Rat O4 -H4O 1.555 1.555 PLAT735_ALERT_1_C D-H Calc 0.85(3), Rep 0.850(10) ...... 3.00 su-Rat O6 -H6O 1.555 1.555 PLAT735_ALERT_1_C D-H Calc 0.85(4), Rep 0.850(10) ...... 4.00 su-Rat O10 -H10O 1.555 1.555 PLAT735_ALERT_1_C D-H Calc 0.85(3), Rep 0.850(10) ...... 3.00 su-Rat O12 -H12O 1.555 1.555 PLAT735_ALERT_1_C D-H Calc 0.85(4), Rep 0.850(10) ...... 4.00 su-Rat O1W -H2# 1.555 1.555 PLAT735_ALERT_1_C D-H Calc 0.85(4), Rep 0.850(10) ...... 4.00 su-Rat O2W -H4# 1.555 1.555 PLAT735_ALERT_1_C D-H Calc 0.85(4), Rep 0.850(10) ...... 4.00 su-Rat O3W -H6# 1.555 1.555 PLAT735_ALERT_1_C D-H Calc 0.85(3), Rep 0.850(10) ...... 3.00 su-Rat O4W -H7# 1.555 1.555 PLAT736_ALERT_1_C H...A Calc 1.77(3), Rep 1.770(10) ...... 3.00 su-Rat H6O -O3W 1.555 2.777 PLAT736_ALERT_1_C H...A Calc 1.88(4), Rep 1.890(10) ...... 4.00 su-Rat H6# -O1W 1.555 2.676 PLAT736_ALERT_1_C H...A Calc 2.00(3), Rep 2.000(10) ...... 3.00 su-Rat H7# -O9 1.555 1.455 PLAT804_ALERT_4_C ARU-Pack Problem in PLATON Analysis ............ ! PLAT804_ALERT_4_C ARU-Pack Problem in PLATON Analysis ............ !
0 ALERT level A = In general: serious problem 2 ALERT level B = Potentially serious problem 23 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 19 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 0 ALERT type 2 Indicator that the structure model may be wrong or deficient 3 ALERT type 3 Indicator that the structure quality may be low 3 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: RAPID-AUTO (Rigaku, 1998); cell refinement: RAPID-AUTO; data reduction: CrystalStructure (Rigaku/MSC, 2002); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

Poly[[triaquadisilver(I)]bis[µ4-3-carboxy-4-hydroxybenzenesulfonato] monohydrate] top
Crystal data top
[Ag2(C7H5O6S)2(H2O)3]·H2OZ = 2
Mr = 722.14F(000) = 712
Triclinic, P1Dx = 2.252 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 8.309 (1) ÅCell parameters from 8670 reflections
b = 11.264 (2) Åθ = 3.2–27.4°
c = 12.611 (2) ŵ = 2.12 mm1
α = 112.743 (6)°T = 295 K
β = 97.608 (7)°Block, colorless
γ = 95.516 (7)°0.38 × 0.26 × 0.19 mm
V = 1064.9 (3) Å3
Data collection top
Rigaku R-AXIS-RAPID
diffractometer
4829 independent reflections
Radiation source: fine-focus sealed tube4464 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.024
ω scansθmax = 27.4°, θmin = 3.2°
Absorption correction: multi-scan
(ABSCOR; Higashi, 1995)
h = 1010
Tmin = 0.316, Tmax = 0.668k = 1414
10379 measured reflectionsl = 1616
Refinement top
Refinement on F2Secondary atom site location: difference Fourier map
Least-squares matrix: fullHydrogen site location: inferred from neighbouring sites
R[F2 > 2σ(F2)] = 0.028H atoms treated by a mixture of independent and constrained refinement
wR(F2) = 0.074 w = 1/[σ2(Fo2) + (0.0411P)2 + 1.1907P]
where P = (Fo2 + 2Fc2)/3
S = 1.00(Δ/σ)max = 0.001
4829 reflectionsΔρmax = 1.11 e Å3
356 parametersΔρmin = 1.04 e Å3
16 restraintsExtinction correction: SHELXL97, Fc*=kFc[1+0.001xFc2λ3/sin(2θ)]-1/4
Primary atom site location: structure-invariant direct methodsExtinction coefficient: 0.070 (2)
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ag10.52516 (3)0.56586 (2)0.380653 (18)0.0414 (1)
Ag20.91174 (3)0.97340 (2)0.62508 (2)0.0398 (1)
S10.84399 (8)0.65784 (6)0.62869 (5)0.0290 (1)
S21.32987 (7)1.13100 (6)0.63031 (5)0.0280 (1)
O10.6839 (3)0.5850 (2)0.5591 (2)0.0395 (4)
O20.9252 (3)0.7361 (2)0.5757 (2)0.0400 (4)
O30.9500 (2)0.5747 (2)0.6581 (2)0.0365 (4)
O40.7099 (3)1.0423 (2)1.0677 (2)0.0479 (5)
O50.9347 (3)0.9642 (2)1.1794 (2)0.0389 (4)
O61.0574 (3)0.8000 (2)1.0750 (2)0.0404 (5)
O71.1689 (2)1.0499 (2)0.5705 (2)0.0400 (5)
O81.3978 (3)1.1925 (2)0.5608 (2)0.0420 (5)
O91.4407 (2)1.0572 (2)0.6696 (2)0.0381 (4)
O101.2007 (3)1.5483 (2)1.0521 (2)0.0484 (5)
O111.4136 (3)1.4757 (2)1.1741 (2)0.0425 (5)
O121.5437 (3)1.3111 (2)1.0824 (2)0.0404 (5)
O1w0.2464 (3)0.6562 (2)0.3676 (2)0.0502 (5)
O2w0.6997 (3)0.3771 (2)0.2946 (2)0.0414 (5)
O3w0.7707 (3)1.1588 (2)0.7207 (2)0.0380 (4)
O4w0.2744 (3)0.8000 (2)0.6073 (3)0.0549 (6)
C10.8036 (3)0.7688 (2)0.7616 (2)0.0275 (5)
C20.6848 (3)0.8493 (3)0.7593 (2)0.0330 (5)
C30.6554 (3)0.9392 (3)0.8624 (3)0.0377 (6)
C40.7429 (3)0.9518 (3)0.9699 (2)0.0330 (5)
C50.8606 (3)0.8706 (2)0.9723 (2)0.0277 (5)
C60.8898 (3)0.7796 (2)0.8669 (2)0.0274 (5)
C70.9545 (3)0.8822 (3)1.0847 (2)0.0299 (5)
C81.2953 (3)1.2560 (2)0.7580 (2)0.0269 (5)
C91.1806 (3)1.3366 (3)0.7483 (2)0.0331 (5)
C101.1508 (3)1.4332 (3)0.8477 (3)0.0372 (6)
C111.2344 (3)1.4521 (3)0.9582 (2)0.0316 (5)
C121.3503 (3)1.3713 (2)0.9675 (2)0.0279 (5)
C131.3789 (3)1.2735 (2)0.8661 (2)0.0275 (5)
C141.4386 (3)1.3902 (3)1.0836 (2)0.0304 (5)
H4o0.776 (4)1.033 (4)1.121 (3)0.05 (1)*
H6o1.116 (4)0.815 (4)1.141 (2)0.05 (1)*
H10o1.268 (4)1.542 (4)1.106 (3)0.05 (1)*
H12o1.600 (4)1.332 (4)1.150 (2)0.05 (1)*
H1w10.259 (5)0.700 (3)0.441 (1)0.06 (1)*
H1w20.178 (5)0.587 (3)0.347 (3)0.10 (2)*
H2w10.802 (2)0.400 (3)0.298 (3)0.06 (1)*
H2w20.688 (4)0.317 (3)0.319 (3)0.06 (1)*
H3w10.670 (2)1.128 (3)0.710 (3)0.04 (1)*
H3w20.779 (4)1.221 (3)0.698 (3)0.06 (1)*
H4w10.317 (4)0.877 (2)0.619 (4)0.08 (2)*
H4w20.170 (1)0.796 (4)0.600 (4)0.08 (2)*
H20.62640.84170.68810.040*
H30.57680.99210.86060.045*
H60.96780.72590.86790.033*
H91.12501.32490.67510.040*
H101.07441.48640.84130.045*
H131.45501.21980.87150.033*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ag10.0479 (2)0.0431 (1)0.0282 (1)0.0033 (1)0.0046 (1)0.0138 (1)
Ag20.0452 (1)0.0456 (2)0.0266 (1)0.0061 (1)0.0029 (1)0.0139 (1)
S10.0307 (3)0.0289 (3)0.0252 (3)0.0010 (2)0.0018 (2)0.0123 (2)
S20.0267 (3)0.0294 (3)0.0235 (3)0.0004 (2)0.0013 (2)0.0091 (2)
O10.041 (1)0.038 (1)0.031 (1)0.006 (1)0.009 (1)0.012 (1)
O20.047 (1)0.041 (1)0.038 (1)0.003 (1)0.012 (1)0.021 (1)
O30.039 (1)0.032 (1)0.036 (1)0.006 (1)0.001 (1)0.013 (1)
O40.048 (1)0.058 (1)0.038 (1)0.022 (1)0.013 (1)0.015 (1)
O50.042 (1)0.045 (1)0.027 (1)0.002 (1)0.002 (1)0.014 (1)
O60.048 (1)0.040 (1)0.031 (1)0.010 (1)0.004 (1)0.016 (1)
O70.033 (1)0.045 (1)0.029 (1)0.008 (1)0.005 (1)0.008 (1)
O80.049 (1)0.043 (1)0.039 (1)0.006 (1)0.016 (1)0.020 (1)
O90.041 (1)0.033 (1)0.034 (1)0.008 (1)0.004 (1)0.009 (1)
O100.050 (1)0.051 (1)0.039 (1)0.020 (1)0.009 (1)0.010 (1)
O110.048 (1)0.046 (1)0.027 (1)0.005 (1)0.003 (1)0.010 (1)
O120.048 (1)0.041 (1)0.029 (1)0.009 (1)0.004 (1)0.014 (1)
O1w0.055 (1)0.038 (1)0.056 (2)0.002 (1)0.004 (1)0.022 (1)
O2w0.043 (1)0.048 (1)0.036 (1)0.003 (1)0.002 (1)0.023 (1)
O3w0.037 (1)0.043 (1)0.036 (1)0.006 (1)0.002 (1)0.021 (1)
O4w0.048 (1)0.044 (1)0.079 (2)0.004 (1)0.003 (1)0.035 (1)
C10.027 (1)0.028 (1)0.0258 (11)0.002 (1)0.001 (1)0.0122 (9)
C20.026 (1)0.043 (1)0.032 (1)0.004 (1)0.000 (1)0.020 (1)
C30.029 (1)0.046 (2)0.044 (2)0.010 (1)0.005 (1)0.024 (1)
C40.029 (1)0.036 (1)0.034 (1)0.004 (1)0.009 (1)0.014 (1)
C50.025 (1)0.030 (1)0.027 (1)0.002 (1)0.000 (1)0.014 (1)
C60.028 (1)0.027 (1)0.027 (1)0.001 (1)0.001 (1)0.013 (1)
C70.029 (1)0.031 (1)0.029 (1)0.005 (1)0.001 (1)0.015 (1)
C80.028 (1)0.026 (1)0.025 (1)0.001 (1)0.002 (1)0.010 (1)
C90.029 (1)0.038 (1)0.032 (1)0.004 (1)0.002 (1)0.016 (1)
C100.034 (1)0.043 (2)0.040 (1)0.014 (1)0.006 (1)0.020 (1)
C110.030 (1)0.031 (1)0.033 (1)0.004 (1)0.006 (1)0.012 (1)
C120.028 (1)0.028 (1)0.027 (1)0.001 (1)0.001 (1)0.013 (1)
C130.027 (1)0.024 (1)0.028 (1)0.001 (1)0.001 (1)0.010 (1)
C140.031 (1)0.031 (1)0.027 (1)0.003 (1)0.002 (1)0.013 (1)
Geometric parameters (Å, º) top
Ag1—O12.374 (2)C4—C51.406 (4)
Ag1—O1i2.695 (2)C5—C61.398 (4)
Ag1—O8ii2.520 (2)C5—C71.477 (3)
Ag1—O11iii2.411 (2)C8—C131.376 (3)
Ag1—O1w2.629 (3)C8—C91.404 (4)
Ag1—O2w2.651 (2)C9—C101.377 (4)
Ag2—O22.517 (2)C10—C111.399 (4)
Ag2—O5iv2.420 (2)C11—C121.410 (4)
Ag2—O72.505 (2)C12—C131.396 (4)
Ag2—O7ii2.373 (2)C12—C141.474 (3)
Ag2—O3w2.467 (2)O4—H4o0.85 (1)
S1—O31.460 (2)O6—H6o0.85 (1)
S1—O11.462 (2)O10—H10o0.85 (1)
S1—O21.463 (2)O12—H12o0.85 (1)
S1—C11.759 (3)O1w—H1w10.85 (1)
S2—O81.446 (2)O1w—H1w20.85 (1)
S2—O91.459 (2)O2w—H2w10.85 (1)
S2—O71.469 (2)O2w—H2w20.85 (1)
S2—C81.762 (3)O3w—H3w10.85 (1)
O4—C41.345 (3)O3w—H3w20.85 (1)
O5—C71.239 (3)O4w—H4w10.85 (1)
O6—C71.302 (3)O4w—H4w20.85 (1)
O10—C111.345 (3)C2—H20.93
O11—C141.235 (3)C3—H30.93
O12—C141.304 (3)C6—H60.93
C1—C61.377 (3)C9—H90.93
C1—C21.408 (4)C10—H100.93
C2—C31.374 (4)C13—H130.93
C3—C41.399 (4)
O1—Ag1—O1i80.07 (7)O4—C4—C5122.6 (2)
O1—Ag1—O8ii90.15 (7)C3—C4—C5119.6 (2)
O1—Ag1—O11iii158.51 (8)C6—C5—C4119.4 (2)
O1—Ag1—O1w123.46 (8)C6—C5—C7120.0 (2)
O1—Ag1—O2w81.31 (7)C4—C5—C7120.5 (2)
O1i—Ag1—O8ii135.29 (7)C1—C6—C5120.4 (2)
O1i—Ag1—O11iii97.81 (7)O5—C7—O6123.9 (2)
O1i—Ag1—O1w75.70 (7)O5—C7—C5121.6 (2)
O1i—Ag1—O2w92.68 (7)O6—C7—C5114.5 (2)
O8ii—Ag1—O11iii105.60 (7)C13—C8—C9120.4 (2)
O8ii—Ag1—O1w73.95 (7)C13—C8—S2120.3 (2)
O8ii—Ag1—O2w129.05 (7)C9—C8—S2119.3 (2)
O11iii—Ag1—O1w75.84 (8)C10—C9—C8119.7 (2)
O11iii—Ag1—O2w77.42 (7)C9—C10—C11120.6 (2)
O1w—Ag1—O2w148.95 (7)O10—C11—C10117.9 (2)
O2—Ag2—O5iv91.56 (7)O10—C11—C12122.6 (2)
O2—Ag2—O7102.94 (7)C10—C11—C12119.5 (2)
O2—Ag2—O7ii96.13 (7)C13—C12—C11119.3 (2)
O2—Ag2—O3w146.10 (7)C13—C12—C14120.8 (2)
O5iv—Ag2—O788.40 (7)C11—C12—C14119.9 (2)
O5iv—Ag2—O7ii162.89 (7)C8—C13—C12120.5 (2)
O5iv—Ag2—O3w83.95 (7)O11—C14—O12123.5 (2)
O7—Ag2—O7ii75.01 (7)O11—C14—C12121.5 (2)
O7—Ag2—O3w110.47 (7)O12—C14—C12115.0 (2)
O7ii—Ag2—O3w97.79 (7)C4—O4—H4o102 (3)
O3—S1—O1112.3 (1)C7—O6—H6o111 (3)
O3—S1—O2112.5 (1)C11—O10—H10o100 (3)
O1—S1—O2112.6 (1)C14—O12—H12o111 (3)
O3—S1—C1106.6 (1)Ag1—O1w—H1w194 (3)
O1—S1—C1105.9 (1)Ag1—O1w—H1w2100 (4)
O2—S1—C1106.4 (1)H1w1—O1w—H1w2110 (2)
O8—S2—O9113.8 (1)Ag1—O2w—H2w1117 (3)
O8—S2—O7112.0 (1)Ag1—O2w—H2w2115 (3)
O9—S2—O7110.8 (1)H2w1—O2w—H2w2109 (2)
O8—S2—C8107.5 (1)Ag2—O3w—H3w1107 (2)
O9—S2—C8106.1 (1)Ag2—O3w—H3w2117 (3)
O7—S2—C8106.3 (1)H3w1—O3w—H3w2109 (2)
S1—O1—Ag1134.6 (1)H4w1—O4w—H4w2109 (2)
S1—O2—Ag2125.0 (1)C3—C2—H2120.1
C7—O5—Ag2iv130.0 (2)C1—C2—H2120.1
S2—O7—Ag2ii114.6 (1)C2—C3—H3119.7
S2—O7—Ag2137.9 (1)C4—C3—H3119.7
Ag2ii—O7—Ag2104.99 (7)C1—C6—H6119.8
S2—O8—Ag1ii126.2 (1)C5—C6—H6119.8
C14—O11—Ag1v137.8 (2)C10—C9—H9120.2
C6—C1—C2120.2 (2)C8—C9—H9120.2
C6—C1—S1120.6 (2)C9—C10—H10119.7
C2—C1—S1119.15 (19)C11—C10—H10119.7
C3—C2—C1119.8 (2)C8—C13—H13119.8
C2—C3—C4120.6 (3)C12—C13—H13119.8
O4—C4—C3117.9 (3)
O3—S1—O1—Ag1128.7 (2)C2—C3—C4—O4179.4 (3)
O2—S1—O1—Ag10.5 (2)C2—C3—C4—C50.6 (4)
C1—S1—O1—Ag1115.4 (2)O4—C4—C5—C6179.3 (2)
O11iii—Ag1—O1—S196.8 (2)C3—C4—C5—C60.7 (4)
O8ii—Ag1—O1—S141.0 (2)O4—C4—C5—C70.0 (4)
O1w—Ag1—O1—S1111.7 (2)C3—C4—C5—C7180.0 (2)
O2w—Ag1—O1—S188.6 (2)C2—C1—C6—C50.2 (4)
O1i—Ag1—O1—S1177.1 (2)S1—C1—C6—C5178.07 (18)
O3—S1—O2—Ag2136.8 (1)C4—C5—C6—C10.3 (4)
O1—S1—O2—Ag295.1 (2)C7—C5—C6—C1179.6 (2)
C1—S1—O2—Ag220.5 (2)Ag2iv—O5—C7—O68.3 (4)
O7ii—Ag2—O2—S1128.5 (2)Ag2iv—O5—C7—C5171.7 (2)
O5iv—Ag2—O2—S166.8 (2)C6—C5—C7—O5178.1 (2)
O3w—Ag2—O2—S114.7 (2)C4—C5—C7—O51.2 (4)
O7—Ag2—O2—S1155.5 (1)C6—C5—C7—O61.9 (3)
O8—S2—O7—Ag2ii6.65 (17)C4—C5—C7—O6178.8 (2)
O9—S2—O7—Ag2ii121.5 (1)O8—S2—C8—C13116.9 (2)
C8—S2—O7—Ag2ii123.7 (1)O9—S2—C8—C135.2 (2)
O8—S2—O7—Ag2151.8 (2)O7—S2—C8—C13123.1 (2)
O9—S2—O7—Ag280.1 (2)O8—S2—C8—C963.7 (2)
C8—S2—O7—Ag234.8 (2)O9—S2—C8—C9174.3 (2)
O7ii—Ag2—O7—S2159.8 (3)O7—S2—C8—C956.4 (2)
O5iv—Ag2—O7—S216.0 (2)C13—C8—C9—C100.5 (4)
O3w—Ag2—O7—S266.9 (2)S2—C8—C9—C10179.0 (2)
O2—Ag2—O7—S2107.2 (2)C8—C9—C10—C110.3 (4)
O7ii—Ag2—O7—Ag2ii0.0C9—C10—C11—O10179.7 (3)
O5iv—Ag2—O7—Ag2ii175.79 (9)C9—C10—C11—C120.1 (4)
O3w—Ag2—O7—Ag2ii92.86 (9)O10—C11—C12—C13179.9 (2)
O2—Ag2—O7—Ag2ii92.98 (9)C10—C11—C12—C130.3 (4)
O9—S2—O8—Ag1ii112.5 (2)O10—C11—C12—C140.5 (4)
O7—S2—O8—Ag1ii121.0 (2)C10—C11—C12—C14179.9 (2)
C8—S2—O8—Ag1ii4.7 (2)C9—C8—C13—C120.3 (4)
O3—S1—C1—C610.8 (2)S2—C8—C13—C12179.17 (18)
O1—S1—C1—C6130.6 (2)C11—C12—C13—C80.1 (4)
O2—S1—C1—C6109.4 (2)C14—C12—C13—C8179.6 (2)
O3—S1—C1—C2170.9 (2)Ag1v—O11—C14—O125.6 (4)
O1—S1—C1—C251.1 (2)Ag1v—O11—C14—C12174.1 (2)
O2—S1—C1—C268.9 (2)C13—C12—C14—O11179.4 (2)
C6—C1—C2—C30.2 (4)C11—C12—C14—O110.1 (4)
S1—C1—C2—C3178.0 (2)C13—C12—C14—O120.8 (3)
C1—C2—C3—C40.2 (4)C11—C12—C14—O12179.6 (2)
Symmetry codes: (i) x+1, y+1, z+1; (ii) x+2, y+2, z+1; (iii) x1, y1, z1; (iv) x+2, y+2, z+2; (v) x+1, y+1, z+1.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O4—H4o···O50.85 (1)1.81 (2)2.612 (3)156 (4)
O6—H6o···O3wiv0.85 (1)1.77 (1)2.621 (3)177 (4)
O10—H10o···O110.85 (1)1.77 (2)2.587 (3)159 (4)
O12—H12o···O2wv0.85 (1)1.76 (1)2.599 (3)174 (4)
O1w—H1w1···O4w0.85 (1)1.94 (1)2.787 (4)177 (4)
O1w—H1w2···O3i0.85 (1)1.99 (2)2.815 (3)164 (5)
O2w—H2w1···O3vi0.85 (1)2.03 (2)2.847 (3)162 (3)
O2w—H2w2···O4wi0.85 (1)1.91 (2)2.734 (3)164 (3)
O3w—H3w1···O9vii0.85 (1)1.91 (1)2.757 (3)174 (3)
O3w—H3w2···O1wviii0.85 (1)1.89 (1)2.722 (3)169 (3)
O4w—H4w2···O2vii0.85 (1)2.03 (1)2.858 (3)165 (4)
O4w—H4w1···O9vii0.85 (1)2.00 (1)2.847 (3)170 (5)
Symmetry codes: (i) x+1, y+1, z+1; (iv) x+2, y+2, z+2; (v) x+1, y+1, z+1; (vi) x+2, y+1, z+1; (vii) x1, y, z; (viii) x+1, y+2, z+1.
 

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