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The six-coordinate Sn atom in bis­(diiso­propyl­ammonium) di­phenyl­dioxalatostannate(IV), [(C3H7)2NH2]2+ [(C6H5)2Sn(O2CCO2)]2-, exists in a cis-C2SnO4 octahedral coordination sphere [Sn-C 2.139 (7) and 2.144 (7) Å; C-Sn-C 103.8 (3)°]. The ammonium cations and the stannate anions are linked by hydrogen bonds into a zigzag chain, running along the c axis of the monoclinic cell.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536803019457/bt6339sup1.cif
Contains datablocks I, bt6339

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536803019457/bt6339Isup2.hkl
Contains datablock I

CCDC reference: 225660

Key indicators

  • Single-crystal X-ray study
  • T = 298 K
  • Mean [sigma](C-C) = 0.014 Å
  • R factor = 0.080
  • wR factor = 0.166
  • Data-to-parameter ratio = 15.8

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT220_ALERT_2_B Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.56 Ratio PLAT223_ALERT_4_B Large Solvent/Anion H Ueq(max)/Ueq(min) ... 4.11 Ratio PLAT331_ALERT_2_B Small Av. Phenyl C-C Dist. C7 - C12 = 1.36 Ang.
Alert level C PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT125_ALERT_4_C No _symmetry_space_group_name_Hall Given ....... ? PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors .... C8 PLAT241_ALERT_2_C Check High U(eq) as Compared to Neighbors .... C9 PLAT242_ALERT_2_C Check Low U(eq) as Compared to Neighbors .... C1 PLAT242_ALERT_2_C Check Low U(eq) as Compared to Neighbors .... C7 PLAT244_ALERT_4_C Low Solvent U(eq) as Compared to Neighbors .... C17 PLAT244_ALERT_4_C Low Solvent U(eq) as Compared to Neighbors .... C20 PLAT331_ALERT_2_C Small Av. Phenyl C-C Dist. C1 - C6 = 1.37 Ang. PLAT342_ALERT_3_C Low Bond Precision on C-C bonds (x 1000) Ang ... 14 PLAT369_ALERT_2_C Long C(sp2)-C(sp2) Bond C13 - C14 = 1.54 Ang. PLAT369_ALERT_2_C Long C(sp2)-C(sp2) Bond C15 - C16 = 1.55 Ang. PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 4
0 ALERT level A = In general: serious problem 3 ALERT level B = Potentially serious problem 13 ALERT level C = Check and explain 0 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 9 ALERT type 2 Indicator that the structure model may be wrong or deficient 1 ALERT type 3 Indicator that the structure quality may be low 5 ALERT type 4 Improvement, methodology, query or suggestion

Computing details top

Data collection: SMART (Bruker, 2001); cell refinement: SMART; data reduction: SAINT (Bruker, 2001); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPII (Johnson, 1976); software used to prepare material for publication: SHELXL97.

Bis(diisopropylammonium) diphenyldioxalatostannate top
Crystal data top
[Sn(C6H5)2(C2O4)2]2C6H16NF(000) = 1352
Mr = 653.33Dx = 1.374 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
a = 9.4647 (5) ÅCell parameters from 5007 reflections
b = 20.901 (1) Åθ = 2.5–27.6°
c = 15.9940 (8) ŵ = 0.86 mm1
β = 93.364 (1)°T = 298 K
V = 3158.6 (3) Å3Parallelepiped, colorless
Z = 40.29 × 0.18 × 0.12 mm
Data collection top
Bruker APEX area-detector
diffractometer
5563 independent reflections
Radiation source: fine-focus sealed tube5505 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.039
φ and ω scanθmax = 25.0°, θmin = 1.0°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 1111
Tmin = 0.705, Tmax = 0.905k = 2424
23125 measured reflectionsl = 1919
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.080Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.166H-atom parameters constrained
S = 1.30 w = 1/[σ2(Fo2) + (0.0485P)2 + 12.4071P]
where P = (Fo2 + 2Fc2)/3
5563 reflections(Δ/σ)max = 0.001
352 parametersΔρmax = 1.14 e Å3
0 restraintsΔρmin = 1.40 e Å3
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Sn10.27877 (5)0.33312 (2)0.24929 (3)0.0380 (2)
O10.1871 (5)0.4262 (2)0.2226 (3)0.048 (1)
O20.2052 (7)0.5109 (3)0.1410 (4)0.070 (2)
O30.3927 (5)0.3677 (2)0.1478 (3)0.050 (1)
O40.4152 (7)0.4505 (3)0.0633 (4)0.074 (2)
O50.4193 (5)0.3950 (2)0.3273 (3)0.044 (1)
O60.4422 (5)0.4365 (3)0.4547 (3)0.055 (1)
O70.1722 (5)0.3440 (2)0.3617 (3)0.040 (1)
O80.1684 (5)0.4050 (3)0.4757 (3)0.050 (1)
N10.3349 (6)0.5865 (3)0.0161 (4)0.045 (1)
N20.2759 (5)0.5230 (3)0.5553 (3)0.039 (1)
C10.4210 (7)0.2561 (3)0.2808 (4)0.040 (2)
C20.3788 (9)0.1941 (4)0.2688 (5)0.060 (2)
C30.465 (1)0.1425 (4)0.2920 (7)0.076 (3)
C40.596 (1)0.1530 (5)0.3264 (6)0.076 (3)
C50.642 (1)0.2130 (5)0.3401 (8)0.090 (3)
C60.554 (1)0.2644 (4)0.3156 (7)0.075 (3)
C70.1025 (8)0.2871 (3)0.1840 (5)0.046 (2)
C80.119 (1)0.2565 (6)0.1107 (7)0.105 (4)
C90.011 (2)0.2240 (6)0.0670 (9)0.125 (6)
C100.115 (2)0.2208 (5)0.0973 (9)0.100 (4)
C110.136 (1)0.2495 (7)0.1701 (8)0.102 (4)
C120.027 (1)0.2833 (5)0.2128 (5)0.072 (3)
C130.2409 (8)0.4580 (3)0.1644 (5)0.046 (2)
C140.3590 (8)0.4229 (3)0.1202 (4)0.046 (2)
C150.3755 (6)0.4078 (3)0.3983 (4)0.036 (1)
C160.2245 (6)0.3843 (3)0.4146 (4)0.035 (1)
C170.221 (1)0.5944 (4)0.0521 (5)0.062 (2)
C180.219 (2)0.5357 (8)0.1048 (9)0.148 (7)
C190.083 (1)0.6058 (6)0.0181 (7)0.099 (4)
C200.3693 (9)0.6434 (4)0.0707 (5)0.056 (2)
C210.470 (1)0.6221 (6)0.1418 (6)0.091 (3)
C220.428 (1)0.6979 (4)0.0218 (7)0.085 (3)
C230.2518 (8)0.5130 (4)0.6461 (4)0.050 (2)
C240.1006 (9)0.4960 (5)0.6579 (5)0.073 (3)
C250.356 (1)0.4641 (5)0.6786 (6)0.074 (3)
C260.1860 (7)0.5697 (4)0.5071 (5)0.050 (2)
C270.2337 (9)0.5731 (4)0.4193 (5)0.064 (2)
C280.188 (1)0.6340 (4)0.5487 (7)0.076 (3)
H1n10.41460.57440.00750.054*
H1n20.30960.55420.04930.054*
H2n10.36660.53510.55160.047*
H2n20.26590.48490.52950.047*
H20.28910.18620.24410.072*
H30.43220.10090.28380.091*
H40.65430.11860.34070.091*
H50.73070.22030.36580.108*
H60.58820.30580.32340.090*
H80.20810.25730.08870.125*
H90.02760.20440.01620.150*
H100.18820.19890.06840.120*
H110.22460.24700.19250.123*
H120.04540.30380.26270.087*
H170.24500.63110.08670.075*
H18a0.14730.53970.14930.222*
H18b0.19960.49910.07100.222*
H18c0.30980.53040.12810.222*
H19a0.08730.64410.01500.149*
H19b0.05910.57020.01620.149*
H19c0.01280.61060.06340.149*
H200.28160.65790.09440.067*
H21a0.42820.58750.17120.136*
H21b0.48830.65730.17960.136*
H21c0.55690.60810.12000.136*
H22a0.36020.70990.02260.127*
H22b0.51430.68480.00150.127*
H22c0.44560.73380.05830.127*
H230.27260.55330.67570.060*
H24a0.08730.49020.71640.109*
H24b0.07740.45700.62840.109*
H24c0.04020.52970.63630.109*
H25a0.34380.45680.73700.111*
H25b0.45030.47910.67140.111*
H25c0.34070.42480.64830.111*
H260.08840.55380.50440.059*
H27a0.23130.53110.39500.096*
H27b0.32850.58950.42030.096*
H27c0.17170.60090.38640.096*
H28a0.15840.62970.60480.114*
H28b0.12510.66250.51770.114*
H28c0.28250.65110.55030.114*
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Sn10.0440 (3)0.0331 (3)0.0375 (3)0.0003 (2)0.006 (2)0.0027 (2)
O10.052 (3)0.033 (3)0.061 (3)0.009 (2)0.015 (2)0.001 (2)
O20.091 (4)0.043 (3)0.076 (4)0.019 (3)0.026 (3)0.015 (3)
O30.061 (3)0.039 (3)0.053 (3)0.009 (2)0.023 (2)0.004 (2)
O40.085 (4)0.057 (4)0.083 (4)0.015 (3)0.040 (4)0.024 (3)
O50.039 (3)0.043 (3)0.051 (3)0.008 (2)0.013 (2)0.012 (2)
O60.032 (3)0.071 (4)0.060 (3)0.004 (2)0.001 (2)0.021 (3)
O70.042 (3)0.040 (3)0.037 (2)0.008 (2)0.010 (2)0.006 (2)
O80.038 (3)0.064 (3)0.049 (3)0.004 (2)0.011 (2)0.016 (3)
N10.045 (3)0.043 (3)0.048 (3)0.008 (3)0.006 (3)0.005 (3)
N20.030 (3)0.045 (3)0.042 (3)0.004 (2)0.006 (2)0.008 (3)
C10.041 (4)0.040 (4)0.039 (4)0.002 (3)0.002 (3)0.001 (3)
C20.061 (5)0.049 (5)0.070 (6)0.001 (4)0.002 (4)0.001 (4)
C30.080 (7)0.042 (5)0.107 (8)0.004 (4)0.018 (6)0.004 (5)
C40.076 (7)0.062 (6)0.089 (7)0.030 (5)0.009 (5)0.017 (5)
C50.061 (6)0.086 (8)0.121 (9)0.023 (5)0.020 (6)0.011 (7)
C60.078 (7)0.045 (5)0.101 (8)0.006 (4)0.007 (5)0.008 (5)
C70.050 (4)0.036 (4)0.051 (4)0.003 (3)0.020 (3)0.016 (3)
C80.074 (7)0.12 (1)0.113 (9)0.025 (6)0.026 (6)0.070 (8)
C90.099 (9)0.13 (1)0.14 (1)0.032 (8)0.049 (9)0.10 (1)
C100.11 (1)0.061 (6)0.1391)0.002 (6)0.058 (8)0.015 (7)
C110.066 (7)0.14 (1)0.095 (8)0.039 (7)0.023 (6)0.034 (8)
C120.068 (6)0.099 (7)0.049 (5)0.018 (5)0.008 (4)0.003 (5)
C130.055 (5)0.038 (4)0.047 (4)0.002 (3)0.007 (3)0.005 (3)
C140.054 (4)0.045 (4)0.038 (4)0.003 (3)0.009 (3)0.009 (3)
C150.028 (3)0.038 (4)0.041 (4)0.005 (3)0.007 (3)0.008 (3)
C160.030 (3)0.036 (3)0.039 (4)0.004 (3)0.001 (3)0.000 (3)
C170.072 (6)0.060 (5)0.053 (5)0.002 (4)0.008 (4)0.008 (4)
C180.15 (1)0.17 (2)0.12 (1)0.03 (1)0.037 (9)0.09 (1)
C190.068 (7)0.13 (1)0.097 (8)0.013 (7)0.010 (6)0.016 (8)
C200.059 (5)0.052 (4)0.057 (5)0.004 (4)0.005 (4)0.009 (4)
C210.091 (8)0.100 (8)0.079 (7)0.010 (6)0.023 (6)0.001 (6)
C220.104 (8)0.049 (5)0.101 (8)0.004 (5)0.004 (6)0.015 (5)
C230.054 (5)0.060 (5)0.035 (4)0.007 (4)0.001 (3)0.011 (3)
C240.051 (5)0.117 (8)0.051 (5)0.017 (5)0.009 (4)0.003 (5)
C250.083 (7)0.083 (7)0.055 (5)0.004 (5)0.006 (5)0.010 (5)
C260.029 (4)0.051 (4)0.068 (5)0.005 (3)0.001 (3)0.008 (4)
C270.062 (5)0.068 (6)0.061 (5)0.001 (4)0.000 (4)0.021 (4)
C280.066 (6)0.052 (5)0.110 (8)0.006 (4)0.003 (5)0.014 (5)
Geometric parameters (Å, º) top
Sn1—C12.139 (7)N1—H1n20.90
Sn1—C72.144 (7)N2—H2n10.90
Sn1—O12.162 (5)N2—H2n20.90
Sn1—O32.128 (5)C2—H20.93
Sn1—O52.191 (5)C3—H30.93
Sn1—O72.124 (4)C4—H40.93
O1—C131.275 (8)C5—H50.93
O2—C131.209 (9)C6—H60.93
O3—C141.269 (8)C8—H80.93
O4—C141.226 (8)C9—H90.93
O5—C151.261 (8)C10—H100.93
O6—C151.227 (8)C11—H110.93
O7—C161.272 (8)C12—H120.93
O8—C161.219 (8)C17—H170.98
N1—C171.50 (1)C18—H18a0.96
N1—C201.499 (9)C18—H18b0.96
N2—C231.499 (8)C18—H18c0.96
N2—C261.481 (9)C19—H19a0.96
C1—C61.36 (1)C19—H19b0.96
C1—C21.37 (1)C19—H19c0.96
C2—C31.39 (1)C20—H200.98
C3—C41.34 (1)C21—H21a0.96
C4—C51.34 (1)C21—H21b0.96
C5—C61.40 (1)C21—H21c0.96
C7—C121.34 (1)C22—H22a0.96
C7—C81.35 (1)C22—H22b0.96
C8—C91.38 (2)C22—H22c0.96
C9—C101.32 (2)C23—H230.98
C10—C111.34 (2)C24—H24a0.96
C11—C121.39 (1)C24—H24b0.96
C13—C141.54 (1)C24—H24c0.96
C15—C161.547 (9)C25—H25a0.96
C17—C191.46 (1)C25—H25b0.96
C17—C181.49 (1)C25—H25c0.96
C20—C221.51 (1)C26—H260.98
C20—C211.51 (1)C27—H27a0.96
C23—C251.49 (1)C27—H27b0.96
C23—C241.50 (1)C27—H27c0.96
C26—C281.50 (1)C28—H28a0.96
C26—C271.50 (1)C28—H28b0.96
N1—H1n10.90C28—H28c0.96
C1—Sn1—C7103.8 (3)C5—C4—H4119.9
C1—Sn1—O1164.4 (2)C4—C5—H5120.3
C1—Sn1—O395.5 (2)C6—C5—H5120.3
C1—Sn1—O587.6 (2)C1—C6—H6118.8
C1—Sn1—O7101.8 (2)C5—C6—H6118.8
C7—Sn1—O190.9 (2)C7—C8—H8118.3
C7—Sn1—O3101.3 (3)C9—C8—H8118.3
C7—Sn1—O5166.2 (2)C10—C9—H9120.1
C7—Sn1—O793.8 (2)C8—C9—H9120.1
O1—Sn1—O376.0 (2)C9—C10—H10120.5
O1—Sn1—O578.8 (2)C11—C10—H10120.5
O1—Sn1—O782.3 (2)C10—C11—H11119.7
O3—Sn1—O7153.6 (2)C12—C11—H11119.7
O3—Sn1—O585.2 (2)C7—C12—H12119.0
O7—Sn1—O576.0 (2)C11—C12—H12119.0
C13—O1—Sn1116.2 (4)C19—C17—H17108.7
C14—O3—Sn1116.5 (4)C18—C17—H17108.7
C15—O5—Sn1114.7 (4)N1—C17—H17108.7
C16—O7—Sn1116.6 (4)C17—C18—H18a109.5
C17—N1—C20117.4 (6)C17—C18—H18b109.5
C26—N2—C23118.8 (6)H18a—C18—H18b109.5
C6—C1—C2115.8 (7)C17—C18—H18c109.5
C6—C1—Sn1123.8 (6)H18a—C18—H18c109.5
C2—C1—Sn1120.4 (6)H18b—C18—H18c109.5
C1—C2—C3122.5 (8)C17—C19—H19a109.5
C4—C3—C2119.6 (9)C17—C19—H19b109.5
C3—C4—C5120.2 (9)H19a—C19—H19b109.5
C4—C5—C6119.4 (9)C17—C19—H19c109.5
C1—C6—C5122.4 (9)H19a—C19—H19c109.5
C12—C7—C8115.3 (8)H19b—C19—H19c109.5
C12—C7—Sn1124.2 (6)N1—C20—H20108.1
C8—C7—Sn1120.5 (7)C22—C20—H20108.1
C7—C8—C9123 (1)C21—C20—H20108.1
C10—C9—C8120 (1)C20—C21—H21a109.5
C9—C10—C11119 (1)C20—C21—H21b109.5
C10—C11—C12121 (1)H21a—C21—H21b109.5
C7—C12—C11122 (1)C20—C21—H21c109.5
O2—C13—O1125.9 (7)H21a—C21—H21c109.5
O2—C13—C14119.4 (7)H21b—C21—H21c109.5
O1—C13—C14114.7 (6)C20—C22—H22a109.5
O4—C14—O3125.1 (7)C20—C22—H22b109.5
O4—C14—C13118.3 (6)H22a—C22—H22b109.5
O3—C14—C13116.6 (6)C20—C22—H22c109.5
O6—C15—O5125.7 (6)H22a—C22—H22c109.5
O6—C15—C16118.2 (6)H22b—C22—H22c109.5
O5—C15—C16116.1 (5)C25—C23—H23108.1
O8—C16—O7126.7 (6)C24—C23—H23108.1
O8—C16—C15118.1 (6)N2—C23—H23108.1
O7—C16—C15115.2 (5)C23—C24—H24a109.5
C19—C17—C18111 (1)C23—C24—H24b109.5
C19—C17—N1111.5 (8)H24a—C24—H24b109.5
C18—C17—N1107.9 (8)C23—C24—H24c109.5
N1—C20—C22111.8 (7)H24a—C24—H24c109.5
N1—C20—C21108.2 (7)H24b—C24—H24c109.5
C22—C20—C21112.4 (8)C23—C25—H25a109.5
C25—C23—C24114.2 (8)C23—C25—H25b109.5
C25—C23—N2107.4 (6)H25a—C25—H25b109.5
C24—C23—N2110.9 (6)C23—C25—H25c109.5
N2—C26—C28111.5 (7)H25a—C25—H25c109.5
N2—C26—C27108.8 (6)H25b—C25—H25c109.5
C28—C26—C27112.0 (7)N2—C26—H26108.1
C17—N1—H1n1108.0C28—C26—H26108.1
C20—N1—H1n1108.0C27—C26—H26108.1
C17—N1—H1n2108.0C26—C27—H27a109.5
C20—N1—H1n2108.0C26—C27—H27b109.5
H1n1—N1—H1n2107.2H27a—C27—H27b109.5
C26—N2—H2n1107.6C26—C27—H27c109.5
C23—N2—H2n1107.6H27a—C27—H27c109.5
C26—N2—H2n2107.6H27b—C27—H27c109.5
C23—N2—H2n2107.6C26—C28—H28a109.5
H2n1—N2—H2n2107.1C26—C28—H28b109.5
C1—C2—H2118.7H28a—C28—H28b109.5
C3—C2—H2118.7C26—C28—H28c109.5
C4—C3—H3120.2H28a—C28—H28c109.5
C2—C3—H3120.2H28b—C28—H28c109.5
C3—C4—H4119.9
O7—Sn1—O1—C13163.1 (5)C1—Sn1—C7—C12113.3 (7)
O3—Sn1—O1—C131.8 (5)O1—Sn1—C7—C1272.2 (7)
C1—Sn1—O1—C1357 (1)O5—Sn1—C7—C1231 (2)
C7—Sn1—O1—C13103.2 (5)O7—Sn1—C7—C8166.4 (8)
O5—Sn1—O1—C1386.0 (5)O3—Sn1—C7—C835.3 (8)
O7—Sn1—O3—C1435.0 (8)C1—Sn1—C7—C863.2 (9)
C1—Sn1—O3—C14166.1 (5)O1—Sn1—C7—C8111.3 (8)
C7—Sn1—O3—C1488.6 (6)O5—Sn1—C7—C8152 (1)
O1—Sn1—O3—C140.5 (5)C12—C7—C8—C90.9 (17)
O5—Sn1—O3—C1479.1 (5)Sn1—C7—C8—C9178 (1)
O7—Sn1—O5—C150.0 (4)C7—C8—C9—C101 (2)
O3—Sn1—O5—C15161.5 (5)C8—C9—C10—C110 (2)
C1—Sn1—O5—C15102.8 (5)C9—C10—C11—C121 (2)
C7—Sn1—O5—C1543 (1)C8—C7—C12—C111 (2)
O1—Sn1—O5—C1584.8 (5)Sn1—C7—C12—C11176.2 (8)
O3—Sn1—O7—C1637.8 (7)C10—C11—C12—C72 (2)
C1—Sn1—O7—C1692.2 (5)Sn1—O1—C13—O2179.2 (7)
C7—Sn1—O7—C16162.9 (5)Sn1—O1—C13—C142.6 (8)
O1—Sn1—O7—C1672.5 (4)Sn1—O3—C14—O4178.6 (7)
O5—Sn1—O7—C167.8 (4)Sn1—O3—C14—C130.6 (8)
O7—Sn1—C1—C690.0 (7)O2—C13—C14—O41.4 (12)
O3—Sn1—C1—C670.0 (7)O1—C13—C14—O4179.7 (7)
C7—Sn1—C1—C6173.1 (7)O2—C13—C14—O3179.5 (7)
O1—Sn1—C1—C614 (1)O1—C13—C14—O32 (1)
O5—Sn1—C1—C614.9 (7)Sn1—O5—C15—O6173.1 (6)
O7—Sn1—C1—C287.8 (6)Sn1—O5—C15—C166.4 (7)
O3—Sn1—C1—C2112.2 (6)Sn1—O7—C16—O8167.4 (6)
C7—Sn1—C1—C29.1 (7)Sn1—O7—C16—C1513.2 (7)
O1—Sn1—C1—C2168.3 (7)O6—C15—C16—O813.2 (9)
O5—Sn1—C1—C2162.9 (6)O5—C15—C16—O8167.2 (6)
C6—C1—C2—C31.2 (13)O6—C15—C16—O7166.2 (6)
Sn1—C1—C2—C3176.8 (7)O5—C15—C16—O713.3 (8)
C1—C2—C3—C41 (2)C20—N1—C17—C1965 (1)
C2—C3—C4—C52 (2)C20—N1—C17—C18172.3 (9)
C3—C4—C5—C62 (2)C17—N1—C20—C2263.8 (9)
C2—C1—C6—C52 (1)C17—N1—C20—C21171.9 (7)
Sn1—C1—C6—C5176.0 (8)C26—N2—C23—C25180.0 (6)
C4—C5—C6—C13 (2)C26—N2—C23—C2454.7 (9)
O7—Sn1—C7—C1210.2 (8)C23—N2—C26—C2853.7 (9)
O3—Sn1—C7—C12148.1 (7)C23—N2—C26—C27177.8 (6)
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
N1—H1n2···O20.902.032.878 (8)157
N1—H1n2···O40.902.393.026 (8)128
N1—H1n1···O4i0.901.962.856 (8)178
N2—H2n2···O60.902.342.938 (7)124
N2—H2n1···O6ii0.901.912.812 (7)178
N2—H2n2···O80.902.072.931 (7)160
Symmetry codes: (i) x+1, y+1, z; (ii) x+1, y+1, z+1.
 

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