Chloro-cis-di­hydro-mer-tris­(tri­phenyl­phosphine)­rhodium(III) di­chloro­methane hemisolvate

Clegg, W.; Elsegood, M.R.J.; Norman, N.C.; Pickett, N.L.

doi:10.1107/S1600536802012266

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Chloro-cis-dihydro-mer-tris(triphenylphosphine)rhodium(III) dichloromethane hemisolvate

W. Clegg, M. R. J. Elsegood, N. C. Norman and N. L. Pickett

The title complex, [RhClH₂(C₁₈H₁₅P)₃]·0.5CH₂Cl₂, has distorted octahedral coordination of Rh as a consequence of the bulk of the phosphine ligands and the relatively small size of hydride ligands; the latter were not directly located in the crystallographic analysis. The dichloromethane solvent molecule is disordered.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536802012266/bt6164sup1.cif Contains datablocks I, global
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536802012266/bt6164Isup2.hkl Contains datablock I

CCDC reference: 193703

checkCIF report

Key indicators

Single-crystal X-ray study
T = 298 K
Mean (C-C) = 0.008 Å
H-atom completeness 96%
Disorder in solvent or counterion
R factor = 0.038
wR factor = 0.109
Data-to-parameter ratio = 10.9

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


 Alert Level A:



THETM_01  Alert A The value of sine(theta_max)/wavelength is less than 0.550
          Calculated sin(theta_max)/wavelength =    0.5393

Author response: Data above \q=22.5\% were weak and the data collection was limited to this maximum value.


 Alert Level C:



PLAT_302  Alert C Anion/Solvent Disorder .......................      25.00 Perc.

General Notes



FORMU_01  There is a discrepancy between the atom counts in the
          _chemical_formula_sum and the formula from the _atom_site* data.
          Atom count from _chemical_formula_sum:C54.5 H48 Cl2 P3 Rh1
          Atom count from the _atom_site data:  C54.5 H46 Cl2 P3 Rh1

CELLZ_01
         From the CIF: _cell_formula_units_Z    2
         From the CIF: _chemical_formula_sum  C54.50 H48 Cl2 P3 Rh
         TEST: Compare cell contents of formula and atom_site data

         atom    Z*formula  cif sites diff
         C        109.00    109.00    0.00
         H         96.00     92.00    4.00
         Cl         4.00      4.00    0.00
         P          6.00      6.00    0.00
         Rh         2.00      2.00    0.00
          Difference between formula and atom_site contents detected.
          WARNING: H atoms missing from atom site list. Is this intentional?


 1 Alert Level A = Potentially serious problem

 0 Alert Level B = Potential problem

 1 Alert Level C = Please check

Computing details top

Data collection: DIF4 (Stoe & Cie, 1988); cell refinement: DIF4; data reduction: local programs; program(s) used to solve structure: SHELXTL (Sheldrick, 1997); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL and local programs.

Chloro-cis-dihydro-mer-tris(triphenylphosphine)rhodium(III) dichloromethane hemisolvate top

Crystal data top

[RhClH₂(C₁₈H₁₅P)₃]·0.5CH₂Cl₂	Z = 2
M_r = 969.6	F(000) = 998
Triclinic, P1	D_x = 1.409 Mg m⁻³
a = 9.390 (5) Å	Mo Kα radiation, λ = 0.71073 Å
b = 12.581 (6) Å	Cell parameters from 31 reflections
c = 20.096 (10) Å	θ = 10.2–12.5°
α = 83.30 (5)°	µ = 0.63 mm⁻¹
β = 83.42 (4)°	T = 298 K
γ = 76.64 (4)°	Block, yellow
V = 2285 (2) Å³	0.23 × 0.20 × 0.13 mm

Data collection top

Stoe–Siemens diffractometer	4522 reflections with I > 2σ(I)
Radiation source: fine-focus sealed tube	R_int = 0.057
Graphite monochromator	θ_max = 22.5°, θ_min = 2.5°
ω/θ scans	h = −9→10
Absorption correction: ψ scan (XPREP in SHELXTL; Sheldrick, 1997)	k = −13→13
T_min = 0.86, T_max = 0.96	l = −11→21
6142 measured reflections	5 standard reflections every 60 min
5972 independent reflections	intensity decay: 1%

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.039	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.109	H-atom parameters constrained
S = 1.06	w = 1/[σ²(F_o²) + (0.0655P)² + 1.2789P] where P = (F_o² + 2F_c²)/3
5972 reflections	(Δ/σ)_max < 0.001
550 parameters	Δρ_max = 1.50 e Å⁻³
0 restraints	Δρ_min = −0.68 e Å⁻³

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq	Occ. (<1)
Rh	0.03045 (4)	0.33940 (3)	0.208811 (18)	0.02477 (13)
Cl1	−0.23926 (12)	0.40140 (9)	0.22842 (6)	0.0358 (3)
P1	0.02353 (12)	0.52628 (9)	0.20231 (6)	0.0260 (3)
C1	0.1955 (5)	0.5751 (4)	0.1838 (2)	0.0301 (11)
C2	0.2093 (6)	0.6763 (4)	0.2000 (3)	0.0430 (13)
H2	0.1295	0.7223	0.2214	0.052*
C3	0.3409 (6)	0.7090 (5)	0.1846 (3)	0.0527 (15)
H3	0.3488	0.7768	0.1961	0.063*
C4	0.4587 (6)	0.6440 (5)	0.1530 (3)	0.0521 (15)
H4	0.5465	0.6670	0.1428	0.063*
C5	0.4474 (5)	0.5437 (4)	0.1360 (3)	0.0437 (13)
H5	0.5281	0.4987	0.1146	0.052*
C6	0.3163 (5)	0.5095 (4)	0.1506 (2)	0.0350 (11)
H6	0.3090	0.4422	0.1381	0.042*
C7	−0.0853 (5)	0.6091 (4)	0.1353 (2)	0.0333 (11)
C8	−0.1194 (6)	0.7228 (4)	0.1332 (3)	0.0490 (14)
H8	−0.0901	0.7563	0.1666	0.059*
C9	−0.1957 (6)	0.7876 (5)	0.0827 (3)	0.0593 (17)
H9	−0.2191	0.8635	0.0830	0.071*
C10	−0.2367 (6)	0.7398 (5)	0.0325 (3)	0.0553 (16)
H10	−0.2860	0.7830	−0.0022	0.066*
C11	−0.2045 (6)	0.6277 (5)	0.0338 (3)	0.0529 (15)
H11	−0.2334	0.5949	0.0000	0.063*
C12	−0.1292 (5)	0.5625 (4)	0.0850 (3)	0.0419 (13)
H12	−0.1083	0.4865	0.0851	0.050*
C13	−0.0665 (5)	0.5927 (3)	0.2774 (2)	0.0301 (11)
C14	−0.2183 (6)	0.6260 (4)	0.2859 (3)	0.0402 (12)
H14	−0.2742	0.6222	0.2513	0.048*
C15	−0.2878 (7)	0.6653 (4)	0.3461 (3)	0.0549 (16)
H15	−0.3897	0.6872	0.3516	0.066*
C16	−0.2055 (8)	0.6718 (4)	0.3973 (3)	0.0587 (17)
H16	−0.2521	0.6989	0.4372	0.070*
C17	−0.0557 (7)	0.6386 (4)	0.3899 (3)	0.0545 (16)
H17	−0.0007	0.6428	0.4247	0.065*
C18	0.0143 (6)	0.5988 (4)	0.3303 (2)	0.0397 (12)
H18	0.1162	0.5759	0.3257	0.048*
P2	0.11455 (13)	0.27236 (9)	0.31971 (6)	0.0295 (3)
C19	0.2290 (5)	0.3533 (4)	0.3514 (2)	0.0322 (11)
C20	0.2065 (6)	0.3843 (4)	0.4163 (3)	0.0443 (13)
H20	0.1359	0.3596	0.4466	0.053*
C21	0.2879 (6)	0.4519 (5)	0.4368 (3)	0.0515 (15)
H21	0.2708	0.4723	0.4805	0.062*
C22	0.3925 (6)	0.4884 (5)	0.3935 (3)	0.0522 (15)
H22	0.4449	0.5349	0.4073	0.063*
C23	0.4208 (6)	0.4562 (4)	0.3288 (3)	0.0469 (14)
H23	0.4951	0.4784	0.2997	0.056*
C24	0.3375 (5)	0.3907 (4)	0.3077 (3)	0.0375 (12)
H24	0.3541	0.3713	0.2637	0.045*
C25	0.2412 (5)	0.1355 (4)	0.3161 (2)	0.0336 (11)
C26	0.3883 (5)	0.1266 (4)	0.2932 (3)	0.0414 (12)
H26	0.4266	0.1893	0.2854	0.050*
C27	0.4791 (6)	0.0251 (5)	0.2817 (3)	0.0516 (14)
H27	0.5771	0.0201	0.2657	0.062*
C28	0.4228 (6)	−0.0688 (5)	0.2943 (3)	0.0555 (15)
H28	0.4828	−0.1370	0.2866	0.067*
C29	0.2786 (7)	−0.0605 (4)	0.3181 (3)	0.0524 (15)
H29	0.2410	−0.1235	0.3269	0.063*
C30	0.1883 (6)	0.0404 (4)	0.3291 (3)	0.0407 (12)
H30	0.0906	0.0446	0.3454	0.049*
C31	−0.0131 (5)	0.2546 (4)	0.3951 (2)	0.0350 (11)
C32	0.0250 (6)	0.1771 (4)	0.4493 (2)	0.0427 (13)
H32	0.1181	0.1310	0.4484	0.051*
C33	−0.0759 (7)	0.1688 (5)	0.5047 (3)	0.0536 (15)
H33	−0.0507	0.1169	0.5407	0.064*
C34	−0.2121 (7)	0.2367 (5)	0.5061 (3)	0.0583 (16)
H34	−0.2801	0.2303	0.5430	0.070*
C35	−0.2494 (6)	0.3143 (5)	0.4536 (3)	0.0516 (14)
H35	−0.3420	0.3611	0.4555	0.062*
C36	−0.1508 (6)	0.3237 (4)	0.3977 (3)	0.0419 (12)
H36	−0.1771	0.3763	0.3622	0.050*
P3	−0.02009 (12)	0.18302 (9)	0.17498 (6)	0.0257 (3)
C37	−0.1670 (5)	0.2217 (3)	0.1178 (2)	0.0283 (10)
C38	−0.3074 (5)	0.2061 (4)	0.1358 (3)	0.0384 (12)
H38	−0.3285	0.1695	0.1774	0.046*
C39	−0.4172 (6)	0.2438 (4)	0.0931 (3)	0.0470 (14)
H39	−0.5112	0.2323	0.1059	0.056*
C40	−0.3870 (6)	0.2985 (4)	0.0315 (3)	0.0479 (14)
H40	−0.4611	0.3251	0.0030	0.057*
C41	−0.2487 (6)	0.3136 (4)	0.0124 (3)	0.0425 (13)
H41	−0.2283	0.3496	−0.0295	0.051*
C42	−0.1386 (5)	0.2759 (4)	0.0548 (2)	0.0350 (11)
H42	−0.0445	0.2866	0.0413	0.042*
C43	0.1253 (5)	0.0912 (3)	0.1268 (2)	0.0286 (10)
C44	0.0939 (6)	0.0276 (4)	0.0808 (3)	0.0435 (13)
H44	−0.0030	0.0330	0.0725	0.052*
C45	0.2066 (6)	−0.0439 (4)	0.0473 (3)	0.0517 (15)
H45	0.1847	−0.0861	0.0164	0.062*
C46	0.3508 (6)	−0.0528 (4)	0.0592 (3)	0.0530 (15)
H46	0.4262	−0.1005	0.0364	0.064*
C47	0.3815 (6)	0.0095 (4)	0.1051 (3)	0.0491 (14)
H47	0.4783	0.0034	0.1139	0.059*
C48	0.2695 (5)	0.0811 (4)	0.1385 (2)	0.0377 (12)
H48	0.2920	0.1231	0.1692	0.045*
C49	−0.0910 (5)	0.0887 (4)	0.2405 (2)	0.0294 (11)
C50	−0.0549 (6)	−0.0247 (4)	0.2402 (3)	0.0411 (12)
H50	0.0009	−0.0564	0.2034	0.049*
C51	−0.1014 (6)	−0.0911 (4)	0.2945 (3)	0.0465 (14)
H51	−0.0769	−0.1670	0.2937	0.056*
C52	−0.1835 (6)	−0.0454 (4)	0.3492 (3)	0.0468 (13)
H52	−0.2115	−0.0902	0.3861	0.056*
C53	−0.2244 (6)	0.0672 (4)	0.3493 (3)	0.0443 (13)
H53	−0.2835	0.0983	0.3856	0.053*
C54	−0.1777 (5)	0.1334 (4)	0.2958 (2)	0.0325 (11)
H54	−0.2045	0.2092	0.2966	0.039*
Cl2	−0.4465 (3)	0.8810 (2)	0.51302 (16)	0.1350 (10)
C55	−0.5518 (16)	0.9783 (16)	0.4738 (6)	0.091 (6)	0.50
H55A	−0.6513	0.9679	0.4847	0.109*	0.50
H55B	−0.5276	0.9706	0.4261	0.109*	0.50

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
Rh	0.0314 (2)	0.0212 (2)	0.0215 (2)	−0.00593 (14)	−0.00265 (14)	−0.00038 (14)
Cl1	0.0324 (6)	0.0329 (6)	0.0402 (7)	−0.0040 (5)	−0.0023 (5)	−0.0031 (5)
P1	0.0340 (6)	0.0211 (6)	0.0221 (6)	−0.0057 (5)	−0.0020 (5)	0.0007 (5)
C1	0.038 (3)	0.029 (3)	0.023 (3)	−0.011 (2)	−0.004 (2)	0.005 (2)
C2	0.050 (3)	0.036 (3)	0.042 (3)	−0.011 (2)	0.006 (2)	−0.007 (2)
C3	0.063 (4)	0.049 (3)	0.056 (4)	−0.033 (3)	−0.001 (3)	−0.008 (3)
C4	0.043 (3)	0.069 (4)	0.048 (4)	−0.029 (3)	−0.004 (3)	0.011 (3)
C5	0.034 (3)	0.051 (3)	0.042 (3)	−0.008 (2)	0.002 (2)	0.006 (3)
C6	0.042 (3)	0.034 (3)	0.027 (3)	−0.005 (2)	−0.006 (2)	0.001 (2)
C7	0.033 (3)	0.037 (3)	0.028 (3)	−0.007 (2)	−0.004 (2)	0.006 (2)
C8	0.063 (4)	0.033 (3)	0.050 (3)	−0.007 (3)	−0.017 (3)	0.006 (3)
C9	0.059 (4)	0.040 (3)	0.069 (4)	−0.003 (3)	−0.011 (3)	0.019 (3)
C10	0.043 (3)	0.070 (4)	0.044 (4)	−0.008 (3)	−0.009 (3)	0.028 (3)
C11	0.049 (3)	0.069 (4)	0.038 (3)	−0.008 (3)	−0.017 (3)	0.007 (3)
C12	0.042 (3)	0.039 (3)	0.041 (3)	−0.001 (2)	−0.007 (2)	0.000 (3)
C13	0.039 (3)	0.021 (2)	0.028 (3)	−0.005 (2)	0.002 (2)	−0.001 (2)
C14	0.052 (3)	0.026 (3)	0.040 (3)	−0.007 (2)	−0.001 (3)	0.003 (2)
C15	0.063 (4)	0.035 (3)	0.053 (4)	−0.002 (3)	0.026 (3)	0.002 (3)
C16	0.096 (5)	0.031 (3)	0.035 (3)	0.000 (3)	0.020 (3)	0.000 (3)
C17	0.095 (5)	0.037 (3)	0.026 (3)	−0.006 (3)	−0.002 (3)	0.000 (2)
C18	0.058 (3)	0.025 (3)	0.031 (3)	0.000 (2)	−0.002 (2)	−0.002 (2)
P2	0.0371 (7)	0.0270 (6)	0.0238 (7)	−0.0071 (5)	−0.0048 (5)	0.0014 (5)
C19	0.041 (3)	0.026 (2)	0.030 (3)	−0.007 (2)	−0.012 (2)	0.004 (2)
C20	0.064 (3)	0.045 (3)	0.028 (3)	−0.022 (3)	−0.004 (3)	0.002 (2)
C21	0.078 (4)	0.054 (4)	0.032 (3)	−0.030 (3)	−0.013 (3)	−0.003 (3)
C22	0.061 (4)	0.050 (3)	0.053 (4)	−0.023 (3)	−0.023 (3)	0.003 (3)
C23	0.040 (3)	0.043 (3)	0.058 (4)	−0.014 (2)	−0.004 (3)	0.001 (3)
C24	0.043 (3)	0.030 (3)	0.039 (3)	−0.005 (2)	−0.004 (2)	−0.003 (2)
C25	0.043 (3)	0.033 (3)	0.025 (3)	−0.007 (2)	−0.013 (2)	−0.001 (2)
C26	0.041 (3)	0.038 (3)	0.045 (3)	−0.004 (2)	−0.013 (2)	−0.003 (2)
C27	0.046 (3)	0.052 (4)	0.053 (4)	0.002 (3)	−0.016 (3)	−0.007 (3)
C28	0.061 (4)	0.038 (3)	0.062 (4)	0.011 (3)	−0.024 (3)	−0.007 (3)
C29	0.069 (4)	0.030 (3)	0.060 (4)	−0.007 (3)	−0.022 (3)	0.001 (3)
C30	0.052 (3)	0.037 (3)	0.033 (3)	−0.010 (2)	−0.012 (2)	0.006 (2)
C31	0.049 (3)	0.038 (3)	0.022 (3)	−0.018 (2)	−0.005 (2)	0.002 (2)
C32	0.055 (3)	0.046 (3)	0.027 (3)	−0.013 (3)	−0.007 (2)	0.004 (2)
C33	0.076 (4)	0.059 (4)	0.028 (3)	−0.026 (3)	−0.004 (3)	0.008 (3)
C34	0.064 (4)	0.078 (4)	0.033 (3)	−0.024 (3)	0.008 (3)	−0.004 (3)
C35	0.047 (3)	0.064 (4)	0.040 (3)	−0.001 (3)	0.001 (3)	−0.014 (3)
C36	0.051 (3)	0.042 (3)	0.029 (3)	−0.004 (2)	−0.005 (2)	−0.001 (2)
P3	0.0327 (6)	0.0231 (6)	0.0217 (6)	−0.0071 (5)	−0.0038 (5)	−0.0008 (5)
C37	0.033 (3)	0.024 (2)	0.029 (3)	−0.0056 (19)	−0.009 (2)	−0.003 (2)
C38	0.040 (3)	0.046 (3)	0.031 (3)	−0.013 (2)	−0.001 (2)	−0.003 (2)
C39	0.038 (3)	0.049 (3)	0.057 (4)	−0.010 (2)	−0.014 (3)	−0.008 (3)
C40	0.047 (3)	0.051 (3)	0.047 (4)	−0.003 (3)	−0.022 (3)	−0.007 (3)
C41	0.055 (3)	0.042 (3)	0.029 (3)	−0.003 (2)	−0.013 (3)	−0.003 (2)
C42	0.037 (3)	0.039 (3)	0.030 (3)	−0.011 (2)	−0.001 (2)	−0.001 (2)
C43	0.039 (3)	0.023 (2)	0.023 (2)	−0.006 (2)	−0.003 (2)	0.000 (2)
C44	0.048 (3)	0.037 (3)	0.047 (3)	−0.007 (2)	−0.010 (3)	−0.014 (3)
C45	0.067 (4)	0.042 (3)	0.045 (3)	0.001 (3)	−0.010 (3)	−0.020 (3)
C46	0.063 (4)	0.043 (3)	0.043 (3)	0.006 (3)	0.009 (3)	−0.013 (3)
C47	0.039 (3)	0.049 (3)	0.056 (4)	0.001 (3)	−0.002 (3)	−0.012 (3)
C48	0.046 (3)	0.036 (3)	0.033 (3)	−0.010 (2)	−0.003 (2)	−0.009 (2)
C49	0.035 (3)	0.027 (3)	0.029 (3)	−0.010 (2)	−0.009 (2)	0.001 (2)
C50	0.055 (3)	0.031 (3)	0.036 (3)	−0.012 (2)	0.005 (2)	−0.003 (2)
C51	0.062 (3)	0.026 (3)	0.052 (4)	−0.013 (2)	−0.003 (3)	0.003 (3)
C52	0.065 (4)	0.038 (3)	0.038 (3)	−0.020 (3)	−0.003 (3)	0.008 (3)
C53	0.055 (3)	0.046 (3)	0.034 (3)	−0.018 (3)	0.005 (2)	−0.003 (3)
C54	0.042 (3)	0.027 (3)	0.032 (3)	−0.012 (2)	−0.007 (2)	−0.004 (2)
Cl2	0.1111 (19)	0.143 (2)	0.133 (2)	−0.0030 (17)	0.0253 (17)	−0.024 (2)
C55	0.073 (9)	0.193 (19)	0.026 (7)	−0.064 (11)	−0.011 (6)	−0.019 (9)

Geometric parameters (Å, º) top

Rh—Cl1	2.4714 (18)	C27—C28	1.388 (8)
Rh—P1	2.3256 (16)	C28—H28	0.930
Rh—P2	2.4411 (18)	C28—C29	1.368 (8)
Rh—P3	2.3186 (16)	C29—H29	0.930
P1—C1	1.841 (4)	C29—C30	1.380 (7)
P1—C7	1.854 (5)	C30—H30	0.930
P1—C13	1.834 (5)	C31—C32	1.395 (7)
C1—C2	1.387 (7)	C31—C36	1.381 (7)
C1—C6	1.392 (7)	C32—H32	0.930
C2—H2	0.930	C32—C33	1.386 (7)
C2—C3	1.382 (7)	C33—H33	0.930
C3—H3	0.930	C33—C34	1.364 (8)
C3—C4	1.356 (8)	C34—H34	0.930
C4—H4	0.930	C34—C35	1.370 (8)
C4—C5	1.374 (8)	C35—H35	0.930
C5—H5	0.930	C35—C36	1.383 (7)
C5—C6	1.385 (7)	C36—H36	0.930
C6—H6	0.930	P3—C37	1.839 (4)
C7—C8	1.389 (7)	P3—C43	1.833 (5)
C7—C12	1.373 (7)	P3—C49	1.840 (5)
C8—H8	0.930	C37—C38	1.379 (6)
C8—C9	1.381 (8)	C37—C42	1.395 (7)
C9—H9	0.930	C38—H38	0.930
C9—C10	1.366 (9)	C38—C39	1.380 (7)
C10—H10	0.930	C39—H39	0.930
C10—C11	1.370 (8)	C39—C40	1.377 (8)
C11—H11	0.930	C40—H40	0.930
C11—C12	1.391 (7)	C40—C41	1.362 (7)
C12—H12	0.930	C41—H41	0.930
C13—C14	1.386 (7)	C41—C42	1.379 (7)
C13—C18	1.396 (7)	C42—H42	0.930
C14—H14	0.930	C43—C44	1.388 (7)
C14—C15	1.393 (8)	C43—C48	1.375 (6)
C15—H15	0.930	C44—H44	0.930
C15—C16	1.376 (9)	C44—C45	1.386 (7)
C16—H16	0.930	C45—H45	0.930
C16—C17	1.368 (9)	C45—C46	1.379 (8)
C17—H17	0.930	C46—H46	0.930
C17—C18	1.386 (7)	C46—C47	1.373 (8)
C18—H18	0.930	C47—H47	0.930
P2—C19	1.847 (5)	C47—C48	1.381 (7)
P2—C25	1.857 (5)	C48—H48	0.930
P2—C31	1.847 (5)	C49—C50	1.389 (7)
C19—C20	1.384 (7)	C49—C54	1.393 (7)
C19—C24	1.396 (7)	C50—H50	0.930
C20—H20	0.930	C50—C51	1.387 (7)
C20—C21	1.389 (7)	C51—H51	0.930
C21—H21	0.930	C51—C52	1.372 (8)
C21—C22	1.361 (8)	C52—H52	0.930
C22—H22	0.930	C52—C53	1.380 (7)
C22—C23	1.385 (8)	C53—H53	0.930
C23—H23	0.930	C53—C54	1.377 (7)
C23—C24	1.388 (7)	C54—H54	0.930
C24—H24	0.930	Cl2—C55	1.578 (18)
C25—C26	1.389 (7)	Cl2—C55ⁱ	1.816 (18)
C25—C30	1.385 (7)	C55—Cl2ⁱ	1.816 (18)
C26—H26	0.930	C55—H55A	0.970
C26—C27	1.389 (7)	C55—H55B	0.970
C27—H27	0.930

Cl1—Rh—P1	83.10 (6)	C26—C27—C28	119.7 (5)
Cl1—Rh—P2	105.29 (6)	H27—C27—C28	120.1
Cl1—Rh—P3	85.11 (6)	C27—C28—H28	120.2
P1—Rh—P2	103.12 (6)	C27—C28—C29	119.6 (5)
P1—Rh—P3	154.79 (5)	H28—C28—C29	120.2
P2—Rh—P3	101.46 (6)	C28—C29—H29	119.7
Rh—P1—C1	119.74 (16)	C28—C29—C30	120.6 (5)
Rh—P1—C7	114.11 (16)	H29—C29—C30	119.7
Rh—P1—C13	114.25 (15)	C25—C30—C29	120.9 (5)
C1—P1—C7	100.3 (2)	C25—C30—H30	119.5
C1—P1—C13	104.3 (2)	C29—C30—H30	119.5
C7—P1—C13	101.7 (2)	P2—C31—C32	123.0 (4)
P1—C1—C2	122.9 (4)	P2—C31—C36	117.6 (4)
P1—C1—C6	119.0 (4)	C32—C31—C36	119.3 (5)
C2—C1—C6	118.1 (4)	C31—C32—H32	120.0
C1—C2—H2	119.8	C31—C32—C33	120.0 (5)
C1—C2—C3	120.4 (5)	H32—C32—C33	120.0
H2—C2—C3	119.8	C32—C33—H33	120.0
C2—C3—H3	119.5	C32—C33—C34	119.9 (5)
C2—C3—C4	121.1 (5)	H33—C33—C34	120.0
H3—C3—C4	119.5	C33—C34—H34	119.8
C3—C4—H4	120.2	C33—C34—C35	120.4 (5)
C3—C4—C5	119.6 (5)	H34—C34—C35	119.8
H4—C4—C5	120.2	C34—C35—H35	119.7
C4—C5—H5	119.9	C34—C35—C36	120.6 (5)
C4—C5—C6	120.3 (5)	H35—C35—C36	119.7
H5—C5—C6	119.9	C31—C36—C35	119.7 (5)
C1—C6—C5	120.5 (5)	C31—C36—H36	120.2
C1—C6—H6	119.8	C35—C36—H36	120.2
C5—C6—H6	119.8	Rh—P3—C37	109.83 (15)
P1—C7—C8	120.0 (4)	Rh—P3—C43	118.80 (15)
P1—C7—C12	122.4 (4)	Rh—P3—C49	117.37 (15)
C8—C7—C12	117.6 (5)	C37—P3—C43	102.7 (2)
C7—C8—H8	119.1	C37—P3—C49	102.9 (2)
C7—C8—C9	121.7 (6)	C43—P3—C49	103.2 (2)
H8—C8—C9	119.1	P3—C37—C38	123.2 (4)
C8—C9—H9	120.1	P3—C37—C42	118.7 (3)
C8—C9—C10	119.9 (5)	C38—C37—C42	118.0 (4)
H9—C9—C10	120.1	C37—C38—H38	119.4
C9—C10—H10	120.4	C37—C38—C39	121.2 (5)
C9—C10—C11	119.3 (5)	H38—C38—C39	119.4
H10—C10—C11	120.4	C38—C39—H39	120.1
C10—C11—H11	119.6	C38—C39—C40	119.7 (5)
C10—C11—C12	120.9 (6)	H39—C39—C40	120.1
H11—C11—C12	119.6	C39—C40—H40	120.0
C7—C12—C11	120.6 (5)	C39—C40—C41	120.1 (5)
C7—C12—H12	119.7	H40—C40—C41	120.0
C11—C12—H12	119.7	C40—C41—H41	119.8
P1—C13—C14	120.4 (4)	C40—C41—C42	120.3 (5)
P1—C13—C18	120.7 (4)	H41—C41—C42	119.8
C14—C13—C18	118.5 (4)	C37—C42—C41	120.7 (4)
C13—C14—H14	119.8	C37—C42—H42	119.7
C13—C14—C15	120.4 (5)	C41—C42—H42	119.7
H14—C14—C15	119.8	P3—C43—C44	121.9 (4)
C14—C15—H15	120.0	P3—C43—C48	119.4 (3)
C14—C15—C16	120.0 (6)	C44—C43—C48	118.6 (4)
H15—C15—C16	120.0	C43—C44—H44	119.9
C15—C16—H16	119.8	C43—C44—C45	120.2 (5)
C15—C16—C17	120.3 (5)	H44—C44—C45	119.9
H16—C16—C17	119.8	C44—C45—H45	119.7
C16—C17—H17	120.0	C44—C45—C46	120.5 (5)
C16—C17—C18	120.1 (6)	H45—C45—C46	119.7
H17—C17—C18	120.0	C45—C46—H46	120.4
C13—C18—C17	120.6 (5)	C45—C46—C47	119.2 (5)
C13—C18—H18	119.7	H46—C46—C47	120.4
C17—C18—H18	119.7	C46—C47—H47	119.8
Rh—P2—C19	115.20 (15)	C46—C47—C48	120.4 (5)
Rh—P2—C25	109.88 (16)	H47—C47—C48	119.8
Rh—P2—C31	122.70 (16)	C43—C48—C47	121.1 (5)
C19—P2—C25	102.3 (2)	C43—C48—H48	119.5
C19—P2—C31	100.6 (2)	C47—C48—H48	119.5
C25—P2—C31	103.8 (2)	P3—C49—C50	123.8 (4)
P2—C19—C20	122.6 (4)	P3—C49—C54	117.9 (3)
P2—C19—C24	119.4 (4)	C50—C49—C54	118.2 (4)
C20—C19—C24	117.9 (4)	C49—C50—H50	119.7
C19—C20—H20	119.5	C49—C50—C51	120.6 (5)
C19—C20—C21	120.9 (5)	H50—C50—C51	119.7
H20—C20—C21	119.5	C50—C51—H51	119.9
C20—C21—H21	119.7	C50—C51—C52	120.3 (5)
C20—C21—C22	120.6 (5)	H51—C51—C52	119.9
H21—C21—C22	119.7	C51—C52—H52	120.0
C21—C22—H22	120.0	C51—C52—C53	120.0 (5)
C21—C22—C23	120.0 (5)	H52—C52—C53	120.0
H22—C22—C23	120.0	C52—C53—H53	120.0
C22—C23—H23	120.2	C52—C53—C54	119.9 (5)
C22—C23—C24	119.6 (5)	H53—C53—C54	120.0
H23—C23—C24	120.2	C49—C54—C53	121.1 (4)
C19—C24—C23	121.1 (5)	C49—C54—H54	119.5
C19—C24—H24	119.5	C53—C54—H54	119.5
C23—C24—H24	119.5	C55—Cl2—C55ⁱ	60.5 (7)
P2—C25—C26	120.5 (4)	Cl2—C55—Cl2ⁱ	119.5 (7)
P2—C25—C30	120.8 (4)	Cl2—C55—H55A	107.4
C26—C25—C30	118.3 (5)	Cl2ⁱ—C55—H55A	107.4
C25—C26—H26	119.6	Cl2—C55—H55B	107.4
C25—C26—C27	120.7 (5)	Cl2ⁱ—C55—H55B	107.4
H26—C26—C27	119.6	H55A—C55—H55B	107.0
C26—C27—H27	120.1

Symmetry code: (i) −x−1, −y+2, −z+1.

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