The binuclear μ-phenyl­vinyl­idene complex (η⁵-C₅H₅)(CO)(μ-CO)MnPt(μ-C=CHPh)(η²-Ph₂PCH₂PPh₂)·Et₂O

The title compound, [bis­(di­phenyl­phosphino)­methane-2κ²P,P′]-μ-carbonyl-1:2κC-carbonyl-1κC-[1(η⁵)-cyclo­penta­di­enyl](μ-phenyl­vinyl­idene-1:2κ²C)­manganeseplatinum­(Mn—Pt) diethyl ether solvate, (η⁵-C₅H₅)(CO)(μ-CO)MnPt(μ-C=CHPh)(η²-Ph₂PCH₂PPh₂)·Et₂O or [MnPt(C₅H₅)(C₈H₆)(C₂₅H₂₂P₂)(CO)₂]·C₄H₁₀O, represents the first example of a structurally characterized μ-vinyl­idene Mn—Pt complex [Mn—Pt 2.6068 (10) Å]. Two metal atoms are bridged by a μ-phenyl­vinyl­idene ligand [Mn—C 1.924 (7), Pt—C 1.991 (6) and C=C 1.363 (9) Å] and an asymmetrical μ-carbonyl ligand [Mn—C 1.826 (7), Pt—C 2.212 (7), C—O 1.189 (8) Å, Mn—C—O 153.4 (6) and Pt—C—O 126.7 (5)°].

Key indicators

• Single-crystal X-ray study
• T = 110 K
• Mean [sigma](C-C) = 0.010 Å
• Disorder in solvent or counterion
• R factor = 0.054
• wR factor = 0.129
• Data-to-parameter ratio = 21.0

checkCIF results

No syntax errors found

ADDSYM reports no extra symmetry


 Alert Level C:



PLAT_202  Alert C Isotropic non-H Atoms in Anion/Solvent       =          5

PLAT_302  Alert C Anion/Solvent Disorder .......................      50.00 Perc.

PLAT_320  Alert C Check Hybridisation of  C1     in main residue          ?

PLAT_320  Alert C Check Hybridisation of  C3     in main residue          ?

General Notes



ABSTM_02  When printed, the submitted absorption T values will be replaced
          by the scaled T values. Since the ratio of scaled T's is
          identical to the ratio of reported T values, the scaling does
          not imply a change to the absorption corrections used in the
          study.
          Ratio of Tmax expected/reported      0.651
          Tmax scaled      0.452 Tmin scaled      0.289


 0 Alert Level A = Potentially serious problem

 0 Alert Level B = Potential problem

 4 Alert Level C = Please check

---

S1. Comment

No comment

S2. Experimental

The title compound was prepared according to a known procedure (Antonova et al., 1991). Suitable single crystals were obtained by isothermic evaporation of a solution in benzene–ether (2:1) at 258 K.

S3. Refinement

The solvate diethyl ether molecule is disordered over two positions with occupancies of 0.6 and 0.4. A l l atoms of the solvate molecules were refined isotropically and the C—O and C—C distances were restrained by the DFIX instruction to values of 1.426 and 1.530 Å, respectively (Allen et al., 1987). H atoms were placed in calculated positions with U_iso constrained to be 1.2 times U_eq of the carrier atom. The highest peak in the final difference map is 0.91 Å from the Mn atom.

Computing details

Data collection: SMART (Bruker, 1998); cell refinement: SAINT-Plus (Bruker, 1998); data reduction: SAINT-Plus; program(s) used to solve structure: SHELXTL (Sheldrick, 1998); program(s) used to refine structure: SHELXTL; molecular graphics: SHELXTL; software used to prepare material for publication: SHELXTL.

Figures

Fig. 1. A view of the title compound showing the atom labeling and displacement ellipsoids at the 50% probability level. The H atoms of the phenyl groups and cyclopentadienyl ligand have been omitted for clarity.

[Bis(diphenylphosphino)methane-2κ²P,P']-µ-carbonyl-1:2κC-carbonyl-1κC- [1(η⁵)-cyclopentadienyl](µ-phenylvinylidene-1:2κ²C)manganeseplatinum- (Mn—Pt) diethyl ether solvate

Crystal data

[MnPt(C5H5)(C8H6)(C25H22P2)(CO)2]·C4H10O	Dx = 1.565 Mg m^−3
Mr = 931.75	Mo Kα radiation, λ = 0.71073 Å
Orthorhombic, Pbca	Cell parameters from 932 reflections
a = 18.3417 (18) Å	θ = 2–24°
b = 18.3164 (18) Å	µ = 3.97 mm^−1
c = 23.547 (2) Å	T = 110 K
V = 7910.7 (14) Å^3	Prism, orange
Z = 8	0.4 × 0.2 × 0.2 mm
F(000) = 3712

Data collection

CCD area detector diffractometer	9557 independent reflections
Radiation source: fine-focus sealed tube	5404 reflections with I > 2σ(I)
Graphite monochromator	Rint = 0.070
ϕ and ω scans	θmax = 28.1°, θmin = 1.7°
Absorption correction: multi-scan (SADABS; Sheldrick, 1998)	h = −24→23
Tmin = 0.443, Tmax = 0.694	k = −24→11
55551 measured reflections	l = −31→31

Refinement

Refinement on F^2	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F^2 > 2σ(F^2)] = 0.054	Hydrogen site location: inferred from neighbouring sites
wR(F^2) = 0.129	H-atom parameters constrained
S = 0.97	w = 1/[σ^2(Fo^2) + (0.06P)^2] where P = (Fo^2 + 2Fc^2)/3
9557 reflections	(Δ/σ)max = 0.001
455 parameters	Δρmax = 1.91 e Å^−3
8 restraints	Δρmin = −1.67 e Å^−3

Special details

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F² against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F², conventional R-factors R are based on F, with F set to zero for negative F². The threshold expression of F² > σ(F²) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F² are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Ų)

	x	y	z	Uiso*/Ueq	Occ. (<1)
Pt1	0.044444 (12)	0.367216 (14)	−0.326505 (10)	0.02265 (9)
Mn1	−0.01953 (5)	0.38471 (6)	−0.42442 (4)	0.0274 (2)
P1	0.16410 (9)	0.37428 (10)	−0.29358 (7)	0.0242 (4)
P2	0.04716 (9)	0.31278 (9)	−0.23948 (7)	0.0233 (4)
O3	0.1075 (2)	0.4804 (3)	−0.4095 (2)	0.0408 (13)
O4	−0.1138 (3)	0.5129 (3)	−0.4137 (2)	0.0384 (12)
C1	−0.0544 (3)	0.3415 (4)	−0.3551 (3)	0.0261 (15)
C2	−0.1100 (3)	0.3015 (3)	−0.3324 (3)	0.0248 (14)
H2A	−0.1034	0.2841	−0.2948	0.030*
C3	0.0602 (4)	0.4371 (4)	−0.4022 (3)	0.0329 (17)
C4	−0.0762 (4)	0.4626 (4)	−0.4161 (3)	0.0308 (16)
C5	−0.1790 (3)	0.2829 (4)	−0.3605 (3)	0.0253 (15)
C6	−0.2163 (3)	0.3290 (4)	−0.3968 (3)	0.0307 (16)
H6A	−0.1977	0.3768	−0.4029	0.037*
C7	−0.2799 (4)	0.3084 (4)	−0.4246 (3)	0.0382 (18)
H7A	−0.3030	0.3413	−0.4501	0.046*
C8	−0.3098 (4)	0.2393 (4)	−0.4153 (3)	0.0373 (19)
H8A	−0.3536	0.2248	−0.4337	0.045*
C9	−0.2739 (4)	0.1923 (4)	−0.3784 (3)	0.0355 (17)
H9A	−0.2933	0.1449	−0.3719	0.043*
C10	−0.2107 (3)	0.2130 (4)	−0.3508 (3)	0.0308 (16)
H10A	−0.1881	0.1802	−0.3250	0.037*
C11	−0.0239 (4)	0.3875 (4)	−0.5146 (3)	0.0408 (19)
H11A	−0.0310	0.4325	−0.5380	0.049*
C12	−0.0801 (4)	0.3434 (5)	−0.4936 (3)	0.047 (2)
H12A	−0.1336	0.3500	−0.5003	0.057*
C13	−0.0467 (4)	0.2844 (4)	−0.4656 (3)	0.0407 (19)
H13A	−0.0729	0.2425	−0.4475	0.049*
C14	0.0297 (4)	0.2925 (4)	−0.4686 (3)	0.042 (2)
H14A	0.0673	0.2582	−0.4533	0.050*
C15	0.0425 (4)	0.3591 (4)	−0.4991 (3)	0.0365 (17)
H15A	0.0913	0.3797	−0.5092	0.044*
C16	0.1459 (3)	0.3207 (4)	−0.2284 (3)	0.0302 (16)
H16A	0.1708	0.2727	−0.2286	0.036*
H16B	0.1583	0.3478	−0.1933	0.036*
C17	0.2152 (3)	0.4545 (4)	−0.2706 (3)	0.0267 (15)
C18	0.2718 (4)	0.4482 (4)	−0.2319 (3)	0.0342 (17)
H18A	0.2810	0.4025	−0.2142	0.041*
C19	0.3151 (4)	0.5077 (4)	−0.2188 (3)	0.0384 (18)
H19A	0.3544	0.5027	−0.1928	0.046*
C20	0.3005 (4)	0.5750 (4)	−0.2441 (3)	0.043 (2)
H20A	0.3302	0.6161	−0.2358	0.052*
C21	0.2445 (4)	0.5814 (4)	−0.2801 (4)	0.045 (2)
H21A	0.2339	0.6278	−0.2962	0.054*
C22	0.2008 (4)	0.5213 (4)	−0.2948 (3)	0.0401 (19)
H22A	0.1620	0.5267	−0.3211	0.048*
C23	0.2321 (3)	0.3227 (3)	−0.3333 (3)	0.0256 (15)
C24	0.2859 (3)	0.2822 (4)	−0.3060 (3)	0.0324 (17)
H24A	0.2862	0.2785	−0.2658	0.039*
C25	0.3386 (4)	0.2477 (4)	−0.3377 (3)	0.0365 (18)
H25A	0.3745	0.2191	−0.3190	0.044*
C26	0.3404 (4)	0.2536 (4)	−0.3953 (4)	0.044 (2)
H26A	0.3777	0.2300	−0.4164	0.053*
C27	0.2872 (4)	0.2945 (5)	−0.4230 (3)	0.049 (2)
H27A	0.2881	0.2984	−0.4632	0.058*
C28	0.2331 (4)	0.3293 (4)	−0.3923 (3)	0.0370 (18)
H28A	0.1970	0.3574	−0.4112	0.044*
C29	0.0043 (3)	0.3587 (3)	−0.1806 (3)	0.0270 (15)
C30	−0.0548 (3)	0.3999 (3)	−0.1862 (3)	0.0342 (14)
H30A	−0.0725	0.4031	−0.2241	0.041*
C31	−0.0941 (4)	0.4375 (4)	−0.1487 (4)	0.045 (2)
H31A	−0.1369	0.4638	−0.1586	0.054*
C32	−0.0670 (4)	0.4349 (5)	−0.0937 (3)	0.048 (2)
H32A	−0.0911	0.4604	−0.0640	0.057*
C33	−0.0026 (5)	0.3936 (5)	−0.0821 (3)	0.047 (2)
H33A	0.0167	0.3914	−0.0446	0.056*
C34	0.0311 (4)	0.3571 (5)	−0.1259 (3)	0.047 (2)
H34A	0.0741	0.3299	−0.1183	0.056*
C35	0.0256 (3)	0.2158 (4)	−0.2325 (3)	0.0289 (16)
C36	0.0183 (4)	0.1813 (4)	−0.1802 (3)	0.0321 (16)
H36A	0.0238	0.2082	−0.1460	0.039*
C37	0.0028 (4)	0.1072 (4)	−0.1783 (4)	0.046 (2)
H37A	−0.0017	0.0835	−0.1426	0.055*
C38	−0.0061 (4)	0.0676 (4)	−0.2273 (4)	0.043 (2)
H38A	−0.0169	0.0170	−0.2252	0.052*
C39	0.0006 (4)	0.1006 (4)	−0.2791 (4)	0.048 (2)
H39A	−0.0055	0.0731	−0.3129	0.057*
C40	0.0165 (4)	0.1757 (4)	−0.2819 (3)	0.0322 (16)
H40A	0.0210	0.1990	−0.3178	0.039*
O1S	−0.3286 (6)	0.4488 (6)	−0.5138 (5)	0.059 (3)*	0.60
C1S	−0.2886 (14)	0.4251 (18)	−0.5619 (12)	0.096 (12)*	0.60
H1SA	−0.2425	0.4009	−0.5509	0.115*	0.60
H1SB	−0.2779	0.4660	−0.5881	0.115*	0.60
C2S	−0.3444 (10)	0.3697 (9)	−0.5883 (7)	0.078 (5)*	0.60
H2SA	−0.3224	0.3460	−0.6215	0.117*	0.60
H2SB	−0.3886	0.3958	−0.6000	0.117*	0.60
H2SC	−0.3570	0.3325	−0.5600	0.117*	0.60
C3S	−0.2884 (10)	0.5037 (10)	−0.4830 (8)	0.079 (5)*	0.60
H3SA	−0.2809	0.5471	−0.5074	0.095*	0.60
H3SB	−0.2400	0.4844	−0.4721	0.095*	0.60
C4S	−0.3317 (16)	0.5252 (18)	−0.4294 (11)	0.145 (12)*	0.60
H4SA	−0.3038	0.5610	−0.4074	0.218*	0.60
H4SB	−0.3404	0.4817	−0.4061	0.218*	0.60
H4SC	−0.3785	0.5466	−0.4406	0.218*	0.60
O1S'	−0.3303 (8)	0.4741 (9)	−0.4902 (7)	0.060 (5)*	0.40
C1S'	−0.2659 (12)	0.4717 (14)	−0.5268 (10)	0.074 (7)*	0.40
H1SC	−0.2213	0.4571	−0.5060	0.089*	0.40
H1SD	−0.2575	0.5183	−0.5471	0.089*	0.40
C2S'	−0.295 (2)	0.411 (2)	−0.5662 (17)	0.083 (16)*	0.40
H2SD	−0.2584	0.3998	−0.5954	0.124*	0.40
H2SE	−0.3401	0.4270	−0.5844	0.124*	0.40
H2SF	−0.3045	0.3666	−0.5438	0.124*	0.40
C3S'	−0.3145 (13)	0.5298 (13)	−0.4506 (11)	0.054 (6)*	0.40
H3SC	−0.3067	0.5764	−0.4710	0.065*	0.40
H3SD	−0.2690	0.5177	−0.4301	0.065*	0.40
C4S'	−0.3766 (18)	0.539 (2)	−0.4082 (14)	0.139 (15)*	0.40
H4SD	−0.3644	0.5774	−0.3811	0.208*	0.40
H4SE	−0.3839	0.4927	−0.3877	0.208*	0.40
H4SF	−0.4214	0.5516	−0.4285	0.208*	0.40

Atomic displacement parameters (Ų)

	U^11	U^22	U^33	U^12	U^13	U^23
Pt1	0.01812 (13)	0.02450 (14)	0.02534 (14)	0.00018 (11)	−0.00125 (10)	0.00279 (12)
Mn1	0.0235 (5)	0.0341 (6)	0.0246 (5)	0.0009 (4)	−0.0011 (4)	0.0022 (5)
P1	0.0174 (8)	0.0285 (10)	0.0266 (9)	0.0010 (7)	0.0012 (7)	0.0018 (8)
P2	0.0188 (8)	0.0232 (9)	0.0278 (9)	0.0009 (7)	−0.0006 (7)	0.0021 (7)
O3	0.030 (3)	0.043 (3)	0.050 (3)	−0.008 (2)	−0.005 (2)	0.018 (3)
O4	0.034 (3)	0.033 (3)	0.049 (3)	0.006 (2)	−0.003 (2)	0.002 (3)
C1	0.025 (4)	0.026 (3)	0.027 (4)	−0.001 (3)	0.000 (3)	0.001 (3)
C2	0.027 (3)	0.022 (3)	0.026 (3)	0.001 (3)	0.000 (3)	0.001 (3)
C3	0.040 (4)	0.027 (4)	0.032 (4)	0.006 (3)	0.000 (3)	0.005 (3)
C4	0.024 (4)	0.040 (4)	0.028 (4)	−0.007 (3)	−0.004 (3)	0.004 (3)
C5	0.025 (4)	0.028 (4)	0.023 (3)	−0.002 (3)	0.005 (3)	−0.003 (3)
C6	0.026 (4)	0.032 (4)	0.034 (4)	−0.003 (3)	0.002 (3)	0.003 (3)
C7	0.029 (4)	0.050 (5)	0.036 (4)	0.004 (4)	−0.002 (3)	0.012 (4)
C8	0.023 (4)	0.048 (5)	0.041 (4)	−0.007 (3)	−0.006 (3)	−0.013 (4)
C9	0.035 (4)	0.031 (4)	0.040 (4)	−0.004 (3)	0.008 (3)	−0.007 (4)
C10	0.024 (4)	0.033 (4)	0.036 (4)	0.000 (3)	0.002 (3)	−0.001 (3)
C11	0.061 (5)	0.043 (5)	0.018 (3)	0.013 (4)	0.004 (3)	0.002 (3)
C12	0.039 (5)	0.070 (6)	0.032 (4)	−0.002 (4)	−0.003 (4)	−0.021 (4)
C13	0.056 (5)	0.035 (4)	0.031 (4)	−0.011 (4)	0.007 (4)	−0.011 (3)
C14	0.054 (5)	0.038 (4)	0.033 (4)	0.013 (4)	0.002 (4)	−0.001 (4)
C15	0.033 (4)	0.045 (5)	0.032 (4)	0.002 (4)	0.011 (3)	−0.003 (4)
C16	0.020 (3)	0.032 (4)	0.039 (4)	0.004 (3)	−0.003 (3)	0.007 (3)
C17	0.021 (3)	0.025 (4)	0.035 (4)	0.002 (3)	0.002 (3)	−0.004 (3)
C18	0.032 (4)	0.032 (4)	0.039 (4)	−0.001 (3)	−0.005 (3)	0.007 (3)
C19	0.036 (4)	0.038 (4)	0.041 (4)	−0.010 (4)	−0.011 (3)	0.003 (4)
C20	0.039 (5)	0.032 (4)	0.058 (5)	0.001 (4)	0.010 (4)	−0.006 (4)
C21	0.048 (5)	0.028 (4)	0.058 (5)	0.002 (4)	−0.010 (4)	0.006 (4)
C22	0.032 (4)	0.036 (4)	0.053 (5)	0.001 (3)	−0.008 (4)	0.001 (4)
C23	0.023 (3)	0.011 (3)	0.043 (4)	0.003 (2)	0.003 (3)	−0.008 (3)
C24	0.023 (4)	0.033 (4)	0.041 (4)	−0.002 (3)	−0.004 (3)	−0.009 (3)
C25	0.021 (4)	0.033 (4)	0.055 (5)	0.001 (3)	0.001 (3)	−0.009 (4)
C26	0.036 (4)	0.041 (5)	0.056 (5)	0.000 (4)	0.005 (4)	−0.015 (4)
C27	0.051 (5)	0.058 (6)	0.037 (5)	−0.001 (4)	0.009 (4)	−0.011 (4)
C28	0.037 (4)	0.038 (4)	0.036 (4)	0.001 (3)	0.004 (4)	−0.001 (4)
C29	0.017 (3)	0.025 (4)	0.039 (4)	0.000 (3)	0.001 (3)	0.001 (3)
C30	0.027 (3)	0.032 (3)	0.042 (4)	0.003 (2)	0.016 (3)	0.003 (3)
C31	0.027 (4)	0.039 (5)	0.069 (6)	0.011 (3)	0.004 (4)	0.008 (4)
C32	0.056 (5)	0.052 (5)	0.035 (4)	0.017 (4)	0.012 (4)	−0.005 (4)
C33	0.065 (6)	0.055 (5)	0.021 (4)	−0.004 (4)	0.009 (4)	−0.012 (4)
C34	0.048 (5)	0.053 (6)	0.040 (5)	0.016 (4)	0.001 (4)	0.006 (4)
C35	0.023 (3)	0.021 (3)	0.043 (4)	0.001 (3)	−0.001 (3)	0.003 (3)
C36	0.026 (3)	0.033 (4)	0.037 (4)	0.009 (3)	0.003 (3)	0.008 (3)
C37	0.026 (4)	0.034 (4)	0.077 (6)	0.002 (3)	0.012 (4)	0.026 (5)
C38	0.038 (4)	0.016 (4)	0.076 (6)	0.002 (3)	0.000 (4)	0.003 (4)
C39	0.047 (5)	0.025 (4)	0.072 (6)	−0.004 (4)	−0.011 (4)	0.003 (4)
C40	0.032 (4)	0.029 (4)	0.035 (4)	0.002 (3)	−0.008 (3)	−0.001 (3)

Geometric parameters (Å, º)

Pt1—Mn1	2.6068 (10)	C14—C15	1.435 (10)
Pt1—P1	2.3312 (16)	C17—C22	1.374 (9)
Pt1—P2	2.2796 (17)	C17—C18	1.386 (9)
Pt1—C1	1.991 (6)	C18—C19	1.382 (9)
Pt1—C3	2.212 (7)	C19—C20	1.395 (10)
Mn1—C1	1.924 (7)	C20—C21	1.337 (10)
Mn1—C3	1.826 (7)	C21—C22	1.404 (10)
Mn1—C4	1.775 (8)	C23—C24	1.392 (9)
Mn1—C11	2.126 (7)	C23—C28	1.395 (9)
Mn1—C12	2.112 (7)	C24—C25	1.376 (9)
Mn1—C13	2.137 (7)	C25—C26	1.359 (10)
Mn1—C14	2.178 (7)	C26—C27	1.391 (11)
Mn1—C15	2.146 (7)	C27—C28	1.384 (10)
P2—C29	1.801 (7)	C29—C30	1.329 (8)
P2—C35	1.827 (7)	C29—C34	1.379 (10)
P2—C16	1.835 (6)	C30—C31	1.333 (9)
P1—C23	1.822 (6)	C31—C32	1.386 (11)
P1—C17	1.825 (7)	C32—C33	1.429 (11)
P1—C16	1.852 (7)	C33—C34	1.378 (10)
O3—C3	1.189 (8)	C35—C40	1.386 (9)
O4—C4	1.153 (8)	C35—C36	1.391 (9)
C1—C2	1.363 (9)	C36—C37	1.386 (11)
C2—C5	1.469 (9)	C37—C38	1.372 (11)
C5—C6	1.383 (9)	C38—C39	1.366 (11)
C5—C10	1.424 (9)	C39—C40	1.408 (10)
C6—C7	1.390 (9)	O1S—C1S	1.418 (18)
C7—C8	1.397 (10)	O1S—C3S	1.442 (14)
C8—C9	1.388 (10)	C1S—C2S	1.570 (17)
C9—C10	1.382 (9)	C3S—C4S	1.543 (17)
C11—C15	1.373 (10)	O1S'—C3S'	1.412 (17)
C11—C12	1.401 (11)	O1S'—C1S'	1.464 (17)
C12—C13	1.407 (11)	C1S'—C2S'	1.548 (19)
C13—C14	1.410 (10)	C3S'—C4S'	1.524 (19)
C1—Pt1—C3	89.1 (3)	Mn1—C3—Pt1	79.8 (3)
C1—Pt1—P2	102.7 (2)	O4—C4—Mn1	176.3 (6)
C3—Pt1—P2	166.9 (2)	C6—C5—C10	116.6 (6)
C1—Pt1—P1	169.4 (2)	C6—C5—C2	124.2 (6)
C3—Pt1—P1	96.47 (19)	C10—C5—C2	119.3 (6)
P2—Pt1—P1	72.83 (6)	C5—C6—C7	122.6 (7)
C1—Pt1—Mn1	47.17 (19)	C6—C7—C8	120.1 (7)
C3—Pt1—Mn1	43.57 (19)	C9—C8—C7	118.2 (6)
P2—Pt1—Mn1	149.17 (5)	C10—C9—C8	121.5 (7)
P1—Pt1—Mn1	135.32 (5)	C9—C10—C5	120.9 (7)
C4—Mn1—C3	90.8 (3)	C15—C11—C12	109.9 (7)
C4—Mn1—C1	92.4 (3)	C15—C11—Mn1	72.0 (4)
C3—Mn1—C1	103.8 (3)	C12—C11—Mn1	70.1 (4)
C4—Mn1—C12	93.7 (3)	C11—C12—C13	106.7 (7)
C3—Mn1—C12	146.2 (3)	C11—C12—Mn1	71.3 (4)
C1—Mn1—C12	109.4 (3)	C13—C12—Mn1	71.6 (4)
C4—Mn1—C11	94.0 (3)	C12—C13—C14	109.1 (7)
C3—Mn1—C11	107.7 (3)	C12—C13—Mn1	69.7 (4)
C1—Mn1—C11	147.7 (3)	C14—C13—Mn1	72.5 (4)
C12—Mn1—C11	38.6 (3)	C13—C14—C15	106.1 (7)
C4—Mn1—C13	127.2 (3)	C13—C14—Mn1	69.3 (4)
C3—Mn1—C13	140.3 (3)	C15—C14—Mn1	69.4 (4)
C1—Mn1—C13	87.3 (3)	C11—C15—C14	108.0 (7)
C12—Mn1—C13	38.7 (3)	C11—C15—Mn1	70.5 (4)
C11—Mn1—C13	63.8 (3)	C14—C15—Mn1	71.8 (4)
C4—Mn1—C15	125.2 (3)	P2—C16—P1	95.9 (3)
C3—Mn1—C15	85.7 (3)	C22—C17—C18	119.3 (6)
C1—Mn1—C15	141.4 (3)	C22—C17—P1	119.7 (5)
C12—Mn1—C15	64.5 (3)	C18—C17—P1	120.8 (5)
C11—Mn1—C15	37.5 (3)	C19—C18—C17	120.8 (7)
C13—Mn1—C15	64.2 (3)	C18—C19—C20	119.4 (7)
C4—Mn1—C14	156.6 (3)	C21—C20—C19	119.7 (7)
C3—Mn1—C14	102.3 (3)	C20—C21—C22	121.7 (7)
C1—Mn1—C14	102.9 (3)	C17—C22—C21	119.1 (7)
C12—Mn1—C14	64.7 (3)	C24—C23—C28	119.8 (6)
C11—Mn1—C14	63.7 (3)	C24—C23—P1	121.6 (5)
C13—Mn1—C14	38.1 (3)	C28—C23—P1	118.4 (5)
C15—Mn1—C14	38.8 (3)	C25—C24—C23	119.5 (7)
C4—Mn1—Pt1	105.3 (2)	C26—C25—C24	121.4 (7)
C3—Mn1—Pt1	56.6 (2)	C25—C26—C27	119.6 (7)
C1—Mn1—Pt1	49.35 (19)	C28—C27—C26	120.3 (8)
C12—Mn1—Pt1	151.0 (3)	C27—C28—C23	119.4 (7)
C11—Mn1—Pt1	154.6 (2)	C30—C29—C34	113.3 (6)
C13—Mn1—Pt1	113.6 (2)	C30—C29—P2	123.1 (5)
C15—Mn1—Pt1	117.3 (2)	C34—C29—P2	123.6 (5)
C14—Mn1—Pt1	98.1 (2)	C29—C30—C31	132.0 (7)
C29—P2—C35	106.9 (3)	C30—C31—C32	114.0 (7)
C29—P2—C16	106.5 (3)	C31—C32—C33	119.6 (7)
C35—P2—C16	106.1 (3)	C34—C33—C32	118.9 (7)
C29—P2—Pt1	118.6 (2)	C33—C34—C29	122.0 (7)
C35—P2—Pt1	120.1 (2)	C40—C35—C36	119.4 (6)
C16—P2—Pt1	96.6 (2)	C40—C35—P2	117.8 (5)
C23—P1—C17	102.6 (3)	C36—C35—P2	122.9 (5)
C23—P1—C16	105.9 (3)	C37—C36—C35	119.6 (7)
C17—P1—C16	105.9 (3)	C38—C37—C36	121.0 (7)
C23—P1—Pt1	116.4 (2)	C39—C38—C37	120.4 (7)
C17—P1—Pt1	128.8 (2)	C38—C39—C40	119.6 (8)
C16—P1—Pt1	94.4 (2)	C35—C40—C39	120.2 (7)
C2—C1—Mn1	143.2 (5)	C1S—O1S—C3S	110.5 (13)
C2—C1—Pt1	132.5 (5)	O1S—C1S—C2S	100.3 (15)
Mn1—C1—Pt1	83.5 (2)	O1S—C3S—C4S	109.0 (17)
C1—C2—C5	126.5 (6)	C3S'—O1S'—C1S'	104.1 (17)
O3—C3—Mn1	153.4 (6)	O1S'—C1S'—C2S'	96 (2)
O3—C3—Pt1	126.7 (5)	O1S'—C3S'—C4S'	111 (2)