Tetra­sodium(I) penta­oxalatodilanthanate(III) dihydrate

Lu, H.; Fu, Y.-L.; Yang, J.-Y.; Ng, S.W.

doi:10.1107/S1600536806054559

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Tetrasodium(I) pentaoxalatodilanthanate(III) dihydrate

H. Lu, Y.-L. Fu, J.-Y. Yang and S. W. Ng

The La atom in the title compound, Na₄[La₂(C₂O₄)₅]·2H₂O, is chelated by five oxalate groups in a bicapped square-antiprismatic geometry; one oxalate ligand is located on a centre of inversion. All oxalate groups function in a μ₂-bridging mode, resulting in a three-dimensional network architecture. The Na⁺ cations are octahedrally coordinated by oxalate O atoms and water molecules, the latter bridging pairs of cations.

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Supporting information

	Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806054559/bt2225sup1.cif Contains datablocks global, I
	Structure factor file (CIF format) https://doi.org/10.1107/S1600536806054559/bt2225Isup2.hkl Contains datablock I

CCDC reference: 636161

checkCIF report

Key indicators

Single-crystal X-ray study
T = 293 K
Mean (C-C) = 0.007 Å
R factor = 0.025
wR factor = 0.080
Data-to-parameter ratio = 13.3

checkCIF/PLATON results

No syntax errors found



Alert level B
PLAT369_ALERT_2_B Long   C(sp2)-C(sp2) Bond  C1     -   C1_e   ...       1.57 Ang.
PLAT731_ALERT_1_B Bond    Calc     0.85(5), Rep   0.850(10) ......       5.00 su-Ra
              O1W  -H1      1.555   1.555
PLAT731_ALERT_1_B Bond    Calc     0.85(6), Rep   0.850(10) ......       6.00 su-Ra
              O1W  -H2      1.555   1.555
PLAT735_ALERT_1_B D-H     Calc     0.85(5), Rep   0.850(10) ......       5.00 su-Ra
              O1W  -H1      1.555   1.555
PLAT735_ALERT_1_B D-H     Calc     0.85(6), Rep   0.850(10) ......       6.00 su-Ra
              O1W  -H2      1.555   1.555

Alert level C
PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low .......       0.97
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings    Differ ....          ?
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ ....          ?
PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............       2.00 Ratio
PLAT062_ALERT_4_C Rescale T(min) & T(max) by .....................       0.95
PLAT180_ALERT_3_C Check Cell Rounding: # of Values Ending with 0 =          3
PLAT369_ALERT_2_C Long   C(sp2)-C(sp2) Bond  C2     -   C3     ...       1.56 Ang.
PLAT369_ALERT_2_C Long   C(sp2)-C(sp2) Bond  C4     -   C5     ...       1.53 Ang.
PLAT732_ALERT_1_C Angle   Calc      110(6), Rep      109(2) ......       3.00 su-Ra
              H1   -O1W  -H2      1.555   1.555   1.555
PLAT736_ALERT_1_C H...A   Calc     1.98(5), Rep     1.97(2) ......       2.50 su-Ra
              H2   -O6      1.555   3.765

Alert level G
ABSTM02_ALERT_3_G  When printed, the submitted absorption T values will be
            replaced by the scaled T values. Since the ratio of scaled T's
            is identical to the ratio of reported T values, the scaling
            does not imply a change to the absorption corrections used in
            the study.
            Ratio of Tmax expected/reported      0.950
            Tmax scaled      0.588 Tmin scaled      0.430
PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature        293 K
PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature .        293 K

   0 ALERT level A = In general: serious problem
   5 ALERT level B = Potentially serious problem
  10 ALERT level C = Check and explain
   3 ALERT level G = General alerts; check

  11 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
   3 ALERT type 2 Indicator that the structure model may be wrong or deficient
   3 ALERT type 3 Indicator that the structure quality may be low
   1 ALERT type 4 Improvement, methodology, query or suggestion
   0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 2003); cell refinement: SAINT (Bruker, 2003); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2006).

Diaquatetrasodium(I) pentaoxalatodilanthanate(III) top

Crystal data top

[Na₄(H₂O)₂][La₂(C₂O₄)₅]	F(000) = 796
M_r = 845.91	D_x = 2.598 Mg m⁻³
Monoclinic, P2₁/n	Mo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2yn	Cell parameters from 4009 reflections
a = 7.8410 (4) Å	θ = 2.5–28.4°
b = 11.6990 (7) Å	µ = 4.09 mm⁻¹
c = 12.0084 (7) Å	T = 293 K
β = 100.943 (1)°	Block, colourless
V = 1081.5 (1) Å³	0.23 × 0.16 × 0.13 mm
Z = 2

Data collection top

Bruker APEX area-detector diffractometer	2400 independent reflections
Radiation source: fine-focus sealed tube	2277 reflections with I > 2σ(I)
Graphite monochromator	R_int = 0.020
φ and ω scans	θ_max = 27.5°, θ_min = 2.5°
Absorption correction: multi-scan (SADABS; Sheldrick, 1996)	h = −8→10
T_min = 0.453, T_max = 0.619	k = −13→15
5919 measured reflections	l = −15→13

Refinement top

Refinement on F²	Primary atom site location: structure-invariant direct methods
Least-squares matrix: full	Secondary atom site location: difference Fourier map
R[F² > 2σ(F²)] = 0.025	Hydrogen site location: inferred from neighbouring sites
wR(F²) = 0.080	All H-atom parameters refined
S = 1.23	w = 1/[σ²(F_o²) + (0.0274P)² + 5.3936P] where P = (F_o² + 2F_c²)/3
2400 reflections	(Δ/σ)_max = 0.001
180 parameters	Δρ_max = 0.76 e Å⁻³
3 restraints	Δρ_min = −0.77 e Å⁻³

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å²) top

	x	y	z	U_iso*/U_eq
La1	0.62107 (3)	0.31399 (2)	0.32586 (2)	0.0106 (1)
Na1	0.8572 (3)	0.2940 (2)	0.0732 (2)	0.0251 (5)
Na2	0.8874 (2)	0.6879 (2)	0.6665 (2)	0.0221 (5)
O1	0.7053 (5)	0.4773 (3)	0.4665 (3)	0.0248 (8)
O2	0.6152 (4)	0.6156 (3)	0.5690 (3)	0.0192 (7)
O3	0.5319 (5)	0.5064 (3)	0.2351 (3)	0.0249 (8)
O4	0.6390 (5)	0.6846 (3)	0.2494 (3)	0.0202 (7)
O5	0.8582 (5)	0.4261 (3)	0.2457 (3)	0.0189 (7)
O6	0.9374 (5)	0.6001 (3)	0.1986 (3)	0.0242 (8)
O7	0.5832 (5)	0.2823 (4)	0.1122 (3)	0.0242 (8)
O8	0.4189 (5)	0.2199 (4)	−0.0473 (3)	0.0241 (8)
O9	0.2985 (5)	0.2969 (3)	0.2059 (3)	0.0218 (8)
O10	0.1324 (5)	0.2764 (4)	0.0334 (3)	0.0242 (8)
O1w	0.7659 (6)	0.3873 (4)	−0.0995 (4)	0.036 (1)
H1	0.681 (5)	0.431 (5)	−0.125 (5)	0.04 (2)*
H2	0.848 (6)	0.399 (6)	−0.135 (6)	0.06 (3)*
C1	0.5940 (5)	0.5262 (4)	0.5106 (4)	0.0138 (9)
C2	0.6515 (6)	0.5782 (4)	0.2394 (4)	0.0162 (9)
C3	0.8327 (6)	0.5310 (4)	0.2273 (4)	0.0150 (9)
C4	0.4387 (6)	0.2578 (4)	0.0506 (4)	0.0148 (9)
C5	0.2780 (6)	0.2784 (4)	0.1024 (4)	0.0145 (9)

Atomic displacement parameters (Å²) top

	U¹¹	U²²	U³³	U¹²	U¹³	U²³
La1	0.0114 (2)	0.0104 (1)	0.0103 (2)	0.0001 (1)	0.0030 (1)	−0.0010 (1)
Na1	0.012 (1)	0.041 (1)	0.023 (1)	0.004 (1)	0.005 (1)	0.002 (1)
Na2	0.011 (1)	0.036 (1)	0.019 (1)	−0.004 (1)	0.004 (1)	0.002 (1)
O1	0.018 (2)	0.026 (2)	0.033 (2)	−0.004 (2)	0.010 (2)	−0.016 (2)
O2	0.017 (2)	0.019 (2)	0.021 (2)	−0.003 (1)	0.003 (1)	−0.009 (1)
O3	0.023 (2)	0.013 (2)	0.041 (2)	−0.001 (1)	0.009 (2)	0.006 (2)
O4	0.026 (2)	0.010 (2)	0.027 (2)	0.001 (1)	0.011 (2)	0.000 (1)
O5	0.025 (2)	0.010 (2)	0.023 (2)	0.004 (1)	0.008 (1)	0.001 (1)
O6	0.016 (2)	0.019 (2)	0.040 (2)	0.000 (1)	0.012 (2)	0.005 (2)
O7	0.019 (2)	0.038 (2)	0.016 (2)	−0.005 (2)	0.005 (1)	−0.005 (2)
O8	0.020 (2)	0.039 (2)	0.014 (2)	−0.001 (2)	0.006 (1)	−0.007 (2)
O9	0.017 (2)	0.034 (2)	0.016 (2)	−0.002 (2)	0.008 (1)	−0.007 (2)
O10	0.016 (2)	0.038 (2)	0.019 (2)	0.001 (2)	0.004 (1)	−0.006 (2)
O1w	0.026 (2)	0.045 (3)	0.038 (2)	0.013 (2)	0.011 (2)	0.017 (2)
C1	0.009 (2)	0.018 (2)	0.014 (2)	−0.002 (2)	−0.001 (2)	0.000 (2)
C2	0.021 (2)	0.015 (2)	0.013 (2)	0.000 (2)	0.005 (2)	0.004 (2)
C3	0.011 (2)	0.017 (2)	0.016 (2)	0.004 (2)	0.000 (2)	−0.003 (2)
C4	0.0051 (19)	0.026 (2)	0.013 (2)	0.000 (2)	0.000 (2)	0.001 (2)
C5	0.009 (2)	0.018 (2)	0.015 (2)	0.000 (2)	0.000 (2)	−0.001 (2)

Geometric parameters (Å, º) top

La1—O1	2.553 (4)	Na2—O8^vii	2.306 (4)
La1—O2ⁱ	2.568 (3)	Na2—O9ⁱ	2.314 (4)
La1—O3	2.541 (4)	Na2—O1w^vii	2.677 (5)
La1—O4ⁱⁱ	2.701 (4)	O1—C1	1.243 (6)
La1—O5	2.605 (3)	O2—C1	1.253 (6)
La1—O6ⁱⁱ	2.551 (4)	O3—C2	1.253 (6)
La1—O7	2.553 (4)	O4—C2	1.255 (6)
La1—O8ⁱⁱⁱ	2.565 (4)	O5—C3	1.256 (6)
La1—O9	2.670 (4)	O6—C3	1.247 (6)
La1—O10ⁱⁱⁱ	2.693 (4)	O7—C4	1.263 (6)
Na1—O2ⁱⁱ	2.731 (4)	O8—C4	1.239 (6)
Na1—O4ⁱⁱ	2.481 (4)	O9—C5	1.241 (6)
Na1—O5	2.583 (4)	O10—C5	1.277 (6)
Na1—O7	2.288 (4)	C1—C1ⁱ	1.572 (8)
Na1—O10^iv	2.306 (4)	C2—C3	1.557 (6)
Na1—O1w	2.332 (5)	C4—C5	1.526 (6)
Na2—O2	2.385 (4)	O1w—H1	0.85 (1)
Na2—O4^v	2.522 (4)	O1w—H2	0.85 (1)
Na2—O5^vi	2.465 (4)

O1—La1—O2ⁱ	63.6 (1)	O2—Na2—O5^vi	126.5 (2)
O1—La1—O3	68.7 (1)	O8^vii—Na2—O4^v	65.9 (1)
O1—La1—O4ⁱⁱ	122.1 (1)	O9ⁱ—Na2—O4^v	103.7 (1)
O1—La1—O5	75.8 (1)	O2—Na2—O4^v	164.4 (2)
O1—La1—O6ⁱⁱ	146.0 (1)	O5^vi—Na2—O4^v	69.0 (1)
O1—La1—O7	137.7 (1)	O8^vii—Na2—O1w^vii	89.0 (2)
O1—La1—O8ⁱⁱⁱ	68.3 (1)	O9ⁱ—Na2—O1w^vii	80.2 (2)
O1—La1—O9	120.8 (1)	O2—Na2—O1w^vii	81.5 (1)
O1—La1—O10ⁱⁱⁱ	73.9 (1)	O5^vi—Na2—O1w^vii	151.8 (2)
O2ⁱ—La1—O3	76.2 (1)	O4^v—Na2—O1w^vii	82.9 (1)
O2ⁱ—La1—O4ⁱⁱ	163.3 (1)	C1—O1—La1	120.8 (3)
O2ⁱ—La1—O5	130.7 (1)	C1—O2—Na2	125.6 (3)
O2ⁱ—La1—O6ⁱⁱ	103.9 (1)	C1—O2—La1ⁱ	120.7 (3)
O2ⁱ—La1—O7	125.7 (1)	Na2—O2—La1ⁱ	107.9 (1)
O2ⁱ—La1—O8ⁱⁱⁱ	114.7 (1)	C1—O2—Na1^vii	107.8 (3)
O2ⁱ—La1—O9	65.9 (1)	Na2—O2—Na1^vii	82.3 (1)
O2ⁱ—La1—O10ⁱⁱⁱ	64.6 (1)	La1ⁱ—O2—Na1^vii	102.3 (1)
O3—La1—O4ⁱⁱ	120.4 (1)	C2—O3—La1	115.7 (3)
O3—La1—O5	63.4 (1)	C2—O4—Na1^vii	127.2 (3)
O3—La1—O6ⁱⁱ	142.3 (1)	C2—O4—Na2^viii	128.2 (3)
O3—La1—O7	74.2 (1)	Na1^vii—O4—Na2^viii	85.1 (1)
O3—La1—O8ⁱⁱⁱ	122.5 (1)	C2—O4—La1^vii	116.9 (3)
O3—La1—O9	71.3 (1)	Na1^vii—O4—La1^vii	95.9 (1)
O3—La1—O10ⁱⁱⁱ	134.7 (1)	Na2^viii—O4—La1^vii	94.5 (1)
O4ⁱⁱ—La1—O5	64.4 (1)	C3—O5—Na2^vi	133.9 (3)
O4ⁱⁱ—La1—O6ⁱⁱ	62.2 (1)	C3—O5—Na1	117.9 (3)
O4ⁱⁱ—La1—O7	62.5 (1)	Na2^vi—O5—Na1	84.2 (1)
O4ⁱⁱ—La1—O8ⁱⁱⁱ	59.9 (1)	C3—O5—La1	117.1 (3)
O4ⁱⁱ—La1—O9	115.2 (1)	Na2^vi—O5—La1	98.4 (1)
O4ⁱⁱ—La1—O10ⁱⁱⁱ	100.8 (1)	Na1—O5—La1	95.8 (1)
O5—La1—O6ⁱⁱ	125.2 (1)	C3—O6—La1^vii	123.7 (3)
O5—La1—O7	69.9 (1)	C4—O7—Na1	131.8 (3)
O5—La1—O8ⁱⁱⁱ	70.4 (1)	C4—O7—La1	122.8 (3)
O5—La1—O9	120.5 (1)	Na1—O7—La1	105.23 (14)
O5—La1—O10ⁱⁱⁱ	129.8 (1)	C4—O8—Na2ⁱⁱ	132.0 (3)
O6ⁱⁱ—La1—O7	76.0 (1)	C4—O8—La1^ix	123.7 (3)
O6ⁱⁱ—La1—O8ⁱⁱⁱ	92.3 (1)	Na2ⁱⁱ—O8—La1^ix	103.84 (14)
O6ⁱⁱ—La1—O9	74.6 (1)	C5—O9—Na2ⁱ	134.3 (3)
O6ⁱⁱ—La1—O10ⁱⁱⁱ	72.2 (1)	C5—O9—La1	118.8 (3)
O7—La1—O8ⁱⁱⁱ	119.6 (1)	Na2ⁱ—O9—La1	106.73 (14)
O7—La1—O9	61.9 (1)	C5—O10—Na1^x	128.3 (3)
O7—La1—O10ⁱⁱⁱ	148.2 (1)	C5—O10—La1^ix	118.4 (3)
O8ⁱⁱⁱ—La1—O9	166.2 (1)	Na1^x—O10—La1^ix	111.03 (15)
O8ⁱⁱⁱ—La1—O10ⁱⁱⁱ	61.6 (1)	Na1—O1w—Na2ⁱⁱ	84.47 (16)
O9—La1—O10ⁱⁱⁱ	109.4 (1)	Na1—O1w—H1	134 (4)
O7—Na1—O10^iv	171.5 (2)	Na2ⁱⁱ—O1w—H1	98 (5)
O7—Na1—O1w	93.9 (2)	Na1—O1w—H2	113 (4)
O10^iv—Na1—O1w	89.9 (2)	Na2ⁱⁱ—O1w—H2	109 (6)
O7—Na1—O4ⁱⁱ	69.6 (1)	H1—O1w—H2	109 (2)
O10^iv—Na1—O4ⁱⁱ	105.8 (2)	O1—C1—O2	126.4 (4)
O1w—Na1—O4ⁱⁱ	163.1 (2)	O1—C1—C1ⁱ	117.7 (5)
O7—Na1—O5	74.4 (1)	O2—C1—C1ⁱ	115.9 (5)
O10^iv—Na1—O5	111.0 (2)	O3—C2—O4	126.7 (5)
O1w—Na1—O5	112.7 (2)	O3—C2—C3	116.5 (4)
O4ⁱⁱ—Na1—O5	67.8 (1)	O4—C2—C3	116.8 (4)
O7—Na1—O2ⁱⁱ	105.7 (1)	O6—C3—O5	126.2 (4)
O10^iv—Na1—O2ⁱⁱ	67.3 (1)	O6—C3—C2	117.1 (4)
O1w—Na1—O2ⁱⁱ	81.3 (2)	O5—C3—C2	116.6 (4)
O4ⁱⁱ—Na1—O2ⁱⁱ	98.8 (1)	O8—C4—O7	125.0 (4)
O5—Na1—O2ⁱⁱ	166.0 (1)	O8—C4—C5	118.6 (4)
O8^vii—Na2—O9ⁱ	166.0 (2)	O7—C4—C5	116.3 (4)
O8^vii—Na2—O2	112.7 (2)	O9—C5—O10	125.6 (4)
O9ⁱ—Na2—O2	74.6 (1)	O9—C5—C4	118.4 (4)
O8^vii—Na2—O5^vi	77.2 (1)	O10—C5—C4	116.0 (4)
O9ⁱ—Na2—O5^vi	108.6 (1)

O3—La1—O1—C1	75.8 (4)	O8ⁱⁱⁱ—La1—O7—C4	154.5 (4)
O6ⁱⁱ—La1—O1—C1	−84.1 (4)	O2ⁱ—La1—O7—C4	−27.4 (5)
O7—La1—O1—C1	106.0 (4)	O5—La1—O7—C4	−153.7 (4)
O8ⁱⁱⁱ—La1—O1—C1	−143.4 (4)	O9—La1—O7—C4	−9.9 (4)
O2ⁱ—La1—O1—C1	−8.9 (4)	O10ⁱⁱⁱ—La1—O7—C4	71.7 (5)
O5—La1—O1—C1	142.4 (4)	O4ⁱⁱ—La1—O7—C4	135.5 (4)
O9—La1—O1—C1	25.2 (4)	O3—La1—O7—Na1	97.6 (2)
O10ⁱⁱⁱ—La1—O1—C1	−78.1 (4)	O6ⁱⁱ—La1—O7—Na1	−105.7 (2)
O4ⁱⁱ—La1—O1—C1	−170.9 (3)	O1—La1—O7—Na1	68.5 (2)
O8^vii—Na2—O2—C1	57.5 (4)	O8ⁱⁱⁱ—La1—O7—Na1	−21.1 (2)
O9ⁱ—Na2—O2—C1	−135.1 (4)	O2ⁱ—La1—O7—Na1	157.0 (1)
O5^vi—Na2—O2—C1	−33.2 (4)	O5—La1—O7—Na1	30.7 (1)
O4^v—Na2—O2—C1	138.9 (5)	O9—La1—O7—Na1	174.5 (2)
O1w^vii—Na2—O2—C1	142.8 (4)	O10ⁱⁱⁱ—La1—O7—Na1	−103.9 (2)
O8^vii—Na2—O2—La1ⁱ	−149.45 (15)	O4ⁱⁱ—La1—O7—Na1	−40.1 (1)
O9ⁱ—Na2—O2—La1ⁱ	17.96 (15)	O3—La1—O9—C5	83.6 (4)
O5^vi—Na2—O2—La1ⁱ	119.92 (16)	O6ⁱⁱ—La1—O9—C5	−80.2 (4)
O4^v—Na2—O2—La1ⁱ	−68.0 (6)	O1—La1—O9—C5	133.1 (4)
O1w^vii—Na2—O2—La1ⁱ	−64.09 (15)	O7—La1—O9—C5	1.9 (3)
O8^vii—Na2—O2—Na1^vii	−48.98 (17)	O8ⁱⁱⁱ—La1—O9—C5	−97.9 (5)
O9ⁱ—Na2—O2—Na1^vii	118.43 (14)	O2ⁱ—La1—O9—C5	166.4 (4)
O5^vi—Na2—O2—Na1^vii	−139.61 (15)	O5—La1—O9—C5	42.0 (4)
O4^v—Na2—O2—Na1^vii	32.5 (6)	O10ⁱⁱⁱ—La1—O9—C5	−144.5 (4)
O1w^vii—Na2—O2—Na1^vii	36.38 (12)	O4ⁱⁱ—La1—O9—C5	−31.9 (4)
O6ⁱⁱ—La1—O3—C2	−142.3 (3)	O3—La1—O9—Na2ⁱ	−99.6 (2)
O1—La1—O3—C2	56.0 (3)	O6ⁱⁱ—La1—O9—Na2ⁱ	96.6 (2)
O7—La1—O3—C2	−103.4 (4)	O1—La1—O9—Na2ⁱ	−50.2 (2)
O8ⁱⁱⁱ—La1—O3—C2	11.9 (4)	O7—La1—O9—Na2ⁱ	178.7 (2)
O2ⁱ—La1—O3—C2	122.7 (4)	O8ⁱⁱⁱ—La1—O9—Na2ⁱ	78.8 (5)
O5—La1—O3—C2	−28.3 (3)	O2ⁱ—La1—O9—Na2ⁱ	−16.8 (2)
O9—La1—O3—C2	−168.5 (4)	O5—La1—O9—Na2ⁱ	−141.3 (1)
O10ⁱⁱⁱ—La1—O3—C2	92.4 (4)	O10ⁱⁱⁱ—La1—O9—Na2ⁱ	32.3 (2)
O4ⁱⁱ—La1—O3—C2	−59.6 (4)	O4ⁱⁱ—La1—O9—Na2ⁱ	144.8 (1)
O7—Na1—O5—C3	−96.4 (4)	O7—Na1—O1w—Na2ⁱⁱ	−68.2 (2)
O10^iv—Na1—O5—C3	90.5 (4)	O10^iv—Na1—O1w—Na2ⁱⁱ	104.2 (2)
O1w—Na1—O5—C3	−8.7 (4)	O4ⁱⁱ—Na1—O1w—Na2ⁱⁱ	−54.6 (6)
O4ⁱⁱ—Na1—O5—C3	−170.4 (4)	O5—Na1—O1w—Na2ⁱⁱ	−142.9 (1)
O2ⁱⁱ—Na1—O5—C3	170.9 (5)	O2ⁱⁱ—Na1—O1w—Na2ⁱⁱ	37.2 (1)
O7—Na1—O5—Na2^vi	126.3 (2)	La1—O1—C1—O2	−170.4 (4)
O10^iv—Na1—O5—Na2^vi	−46.7 (2)	La1—O1—C1—C1ⁱ	7.8 (7)
O1w—Na1—O5—Na2^vi	−145.9 (2)	Na2—O2—C1—O1	−21.7 (7)
O4ⁱⁱ—Na1—O5—Na2^vi	52.4 (1)	La1ⁱ—O2—C1—O1	−171.6 (4)
O2ⁱⁱ—Na1—O5—Na2^vi	33.7 (6)	Na1^vii—O2—C1—O1	71.6 (5)
O7—Na1—O5—La1	28.5 (1)	Na2—O2—C1—C1ⁱ	160.1 (4)
O10^iv—Na1—O5—La1	−144.6 (1)	La1ⁱ—O2—C1—C1ⁱ	10.1 (7)
O1w—Na1—O5—La1	116.2 (2)	Na1^vii—O2—C1—C1ⁱ	−106.7 (5)
O4ⁱⁱ—Na1—O5—La1	−45.5 (1)	La1—O3—C2—O4	−145.9 (4)
O2ⁱⁱ—Na1—O5—La1	−64.2 (6)	La1—O3—C2—C3	36.3 (5)
O3—La1—O5—C3	17.6 (3)	Na1^vii—O4—C2—O3	81.7 (6)
O6ⁱⁱ—La1—O5—C3	154.4 (3)	Na2^viii—O4—C2—O3	−35.7 (7)
O1—La1—O5—C3	−55.4 (3)	La1^vii—O4—C2—O3	−156.4 (4)
O7—La1—O5—C3	99.5 (3)	Na1^vii—O4—C2—C3	−100.5 (4)
O8ⁱⁱⁱ—La1—O5—C3	−127.1 (4)	Na2^viii—O4—C2—C3	142.1 (3)
O2ⁱ—La1—O5—C3	−20.9 (4)	La1^vii—O4—C2—C3	21.4 (5)
O9—La1—O5—C3	62.3 (4)	La1^vii—O6—C3—O5	−176.4 (4)
O10ⁱⁱⁱ—La1—O5—C3	−109.7 (3)	La1^vii—O6—C3—C2	4.8 (6)
O4ⁱⁱ—La1—O5—C3	167.7 (4)	Na2^vi—O5—C3—O6	37.3 (7)
O3—La1—O5—Na2^vi	167.2 (2)	Na1—O5—C3—O6	−73.1 (6)
O6ⁱⁱ—La1—O5—Na2^vi	−55.9 (2)	La1—O5—C3—O6	173.4 (4)
O1—La1—O5—Na2^vi	94.3 (1)	Na2^vi—O5—C3—C2	−143.8 (3)
O7—La1—O5—Na2^vi	−110.9 (2)	Na1—O5—C3—C2	105.8 (4)
O8ⁱⁱⁱ—La1—O5—Na2^vi	22.5 (1)	La1—O5—C3—C2	−7.8 (5)
O2ⁱ—La1—O5—Na2^vi	128.7 (1)	O3—C2—C3—O6	159.7 (5)
O9—La1—O5—Na2^vi	−148.1 (1)	O4—C2—C3—O6	−18.3 (7)
O10ⁱⁱⁱ—La1—O5—Na2^vi	39.9 (2)	O3—C2—C3—O5	−19.2 (6)
O4ⁱⁱ—La1—O5—Na2^vi	−42.7 (1)	O4—C2—C3—O5	162.7 (4)
O3—La1—O5—Na1	−107.9 (2)	Na2ⁱⁱ—O8—C4—O7	−4.7 (8)
O6ⁱⁱ—La1—O5—Na1	29.0 (2)	La1^ix—O8—C4—O7	−175.1 (4)
O1—La1—O5—Na1	179.2 (2)	Na2ⁱⁱ—O8—C4—C5	174.6 (3)
O7—La1—O5—Na1	−26.0 (1)	La1^ix—O8—C4—C5	4.2 (6)
O8ⁱⁱⁱ—La1—O5—Na1	107.5 (1)	Na1—O7—C4—O8	9.3 (8)
O2ⁱ—La1—O5—Na1	−146.3 (1)	La1—O7—C4—O8	−165.0 (4)
O9—La1—O5—Na1	−63.2 (2)	Na1—O7—C4—C5	−170.0 (3)
O10ⁱⁱⁱ—La1—O5—Na1	124.8 (1)	La1—O7—C4—C5	15.7 (6)
O4ⁱⁱ—La1—O5—Na1	42.3 (1)	Na2ⁱ—O9—C5—O10	9.7 (8)
O1w—Na1—O7—C4	42.4 (5)	La1—O9—C5—O10	−174.7 (4)
O4ⁱⁱ—Na1—O7—C4	−133.5 (5)	Na2ⁱ—O9—C5—C4	−171.3 (3)
O5—Na1—O7—C4	154.9 (5)	La1—O9—C5—C4	4.3 (6)
O2ⁱⁱ—Na1—O7—C4	−39.7 (5)	Na1^x—O10—C5—O9	−4.3 (8)
O1w—Na1—O7—La1	−142.6 (2)	La1^ix—O10—C5—O9	−165.7 (4)
O4ⁱⁱ—Na1—O7—La1	41.6 (1)	Na1^x—O10—C5—C4	176.7 (3)
O5—Na1—O7—La1	−30.1 (1)	La1^ix—O10—C5—C4	15.2 (6)
O2ⁱⁱ—Na1—O7—La1	135.3 (1)	O8—C4—C5—O9	167.6 (5)
O3—La1—O7—C4	−86.8 (4)	O7—C4—C5—O9	−13.1 (7)
O6ⁱⁱ—La1—O7—C4	69.9 (4)	O8—C4—C5—O10	−13.3 (7)
O1—La1—O7—C4	−115.9 (4)	O7—C4—C5—O10	166.0 (5)

Symmetry codes: (i) −x+1, −y+1, −z+1; (ii) −x+3/2, y−1/2, −z+1/2; (iii) x+1/2, −y+1/2, z+1/2; (iv) x+1, y, z; (v) x+1/2, −y+3/2, z+1/2; (vi) −x+2, −y+1, −z+1; (vii) −x+3/2, y+1/2, −z+1/2; (viii) x−1/2, −y+3/2, z−1/2; (ix) x−1/2, −y+1/2, z−1/2; (x) x−1, y, z.

Hydrogen-bond geometry (Å, º) top

D—H···A	D—H	H···A	D···A	D—H···A
O1w—H1···O3^xi	0.85 (1)	2.06 (3)	2.865 (6)	159 (7)
O1w—H2···O6^xii	0.85 (1)	1.97 (2)	2.811 (5)	168 (6)

Symmetry codes: (xi) −x+1, −y+1, −z; (xii) −x+2, −y+1, −z.

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