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The Ce atom in the title compound, Na4[Ce2(C2O4)5]·2H2O, is chelated by five oxalate groups in a bicapped square-anti­prismatic geometry; one oxalate ligand is located on a centre of inversion. All oxalate groups function in a μ2-bridging mode, resulting in a three-dimensional network architecture.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536806054560/bt2223sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536806054560/bt2223Isup2.hkl
Contains datablock I

CCDC reference: 636160

Key indicators

  • Single-crystal X-ray study
  • T = 293 K
  • Mean [sigma](C-C) = 0.006 Å
  • R factor = 0.026
  • wR factor = 0.083
  • Data-to-parameter ratio = 13.2

checkCIF/PLATON results

No syntax errors found



Alert level B PLAT731_ALERT_1_B Bond Calc 0.85(6), Rep 0.850(10) ...... 6.00 su-Ra O1W -H1 1.555 1.555 PLAT731_ALERT_1_B Bond Calc 0.85(6), Rep 0.850(10) ...... 6.00 su-Ra O1W -H2 1.555 1.555 PLAT735_ALERT_1_B D-H Calc 0.85(6), Rep 0.850(10) ...... 6.00 su-Ra O1W -H1 1.555 1.555 PLAT735_ALERT_1_B D-H Calc 0.85(6), Rep 0.850(10) ...... 6.00 su-Ra O1W -H2 1.555 1.555
Alert level C PLAT029_ALERT_3_C _diffrn_measured_fraction_theta_full Low ....... 0.97 PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings Differ .... ? PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ? PLAT045_ALERT_1_C Calculated and Reported Z Differ by ............ 2.00 Ratio PLAT152_ALERT_1_C Supplied and Calc Volume s.u. Inconsistent ..... ? PLAT180_ALERT_3_C Check Cell Rounding: # of Values Ending with 0 = 3 PLAT213_ALERT_2_C Atom C3 has ADP max/min Ratio ............. 3.10 oblat PLAT369_ALERT_2_C Long C(sp2)-C(sp2) Bond C1 - C1_e ... 1.53 Ang. PLAT369_ALERT_2_C Long C(sp2)-C(sp2) Bond C2 - C3 ... 1.55 Ang. PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 77 O10 -NA1 -O7 -C4 -78.50 1.00 1.655 1.555 1.555 1.555 PLAT710_ALERT_4_C Delete 1-2-3 or 2-3-4 Linear Torsion Angle ... # 82 O10 -NA1 -O7 -CE1 97.20 0.80 1.655 1.555 1.555 1.555 PLAT732_ALERT_1_C Angle Calc 109(7), Rep 109.4(18) ...... 3.89 su-Ra H1 -O1W -H2 1.555 1.555 1.555 PLAT736_ALERT_1_C H...A Calc 2.01(6), Rep 2.02(2) ...... 3.00 su-Ra H1 -O3 1.555 3.665
Alert level G PLAT199_ALERT_1_G Check the Reported _cell_measurement_temperature 293 K PLAT200_ALERT_1_G Check the Reported _diffrn_ambient_temperature . 293 K
0 ALERT level A = In general: serious problem 4 ALERT level B = Potentially serious problem 13 ALERT level C = Check and explain 2 ALERT level G = General alerts; check 12 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 3 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 2 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 2003); cell refinement: SAINT (Bruker, 2003); data reduction: SAINT; program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: X-SEED (Barbour, 2001); software used to prepare material for publication: publCIF (Westrip, 2006).

Diaquatetrasodium(I) pentaoxalatodicerate(III) top
Crystal data top
[Na4(H2O)2][Ce2(C2O4)5]F(000) = 800
Mr = 848.33Dx = 2.634 Mg m3
Monoclinic, P21/nMo Kα radiation, λ = 0.71073 Å
Hall symbol: -P 2ynCell parameters from 3229 reflections
a = 7.8378 (6) Åθ = 2.5–28.4°
b = 11.647 (1) ŵ = 4.39 mm1
c = 11.938 (1) ÅT = 293 K
β = 101.030 (1)°Block, colourless
V = 1069.7 (2) Å30.14 × 0.06 × 0.05 mm
Z = 2
Data collection top
Bruker APEX area-detector
diffractometer
2369 independent reflections
Radiation source: fine-focus sealed tube2131 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.030
φ and ω scansθmax = 27.5°, θmin = 2.9°
Absorption correction: multi-scan
(SADABS; Sheldrick, 1996)
h = 810
Tmin = 0.578, Tmax = 0.810k = 1415
6885 measured reflectionsl = 1511
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.026Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.083All H-atom parameters refined
S = 1.08 w = 1/[σ2(Fo2) + (0.05P)2]
where P = (Fo2 + 2Fc2)/3
2369 reflections(Δ/σ)max = 0.001
180 parametersΔρmax = 0.89 e Å3
3 restraintsΔρmin = 0.71 e Å3
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Ce10.62360 (3)0.314478 (18)0.326801 (18)0.01004 (11)
Na10.8585 (2)0.29535 (17)0.07326 (16)0.0241 (4)
Na20.8855 (2)0.68800 (16)0.66598 (15)0.0207 (5)
O10.7047 (4)0.4783 (3)0.4669 (3)0.0242 (7)
O20.6146 (4)0.6175 (2)0.5689 (3)0.0158 (6)
O30.5317 (4)0.5063 (3)0.2363 (3)0.0231 (7)
O40.6375 (4)0.6850 (2)0.2482 (3)0.0177 (7)
O50.8592 (4)0.4268 (2)0.2458 (3)0.0163 (6)
O60.9360 (4)0.6014 (3)0.1978 (3)0.0235 (7)
O70.5847 (4)0.2815 (3)0.1135 (3)0.0224 (7)
O80.4204 (4)0.2178 (3)0.0465 (3)0.0210 (7)
O90.3026 (4)0.2976 (3)0.2079 (3)0.0199 (7)
O100.1362 (4)0.2762 (3)0.0343 (3)0.0224 (7)
O1w0.7657 (5)0.3901 (3)0.0993 (3)0.0350 (9)
H10.675 (6)0.427 (7)0.130 (6)0.10 (3)*
H20.849 (6)0.409 (8)0.132 (6)0.11 (4)*
C10.5909 (5)0.5269 (3)0.5100 (4)0.0152 (9)
C20.6512 (5)0.5786 (4)0.2385 (4)0.0153 (9)
C30.8321 (5)0.5316 (3)0.2274 (3)0.0108 (8)
C40.4405 (6)0.2563 (4)0.0520 (3)0.0144 (8)
C50.2791 (5)0.2784 (4)0.1027 (4)0.0142 (8)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Ce10.01104 (16)0.00935 (15)0.00976 (16)0.00020 (7)0.00207 (10)0.00104 (8)
Na10.0136 (9)0.0375 (11)0.0226 (11)0.0014 (7)0.0074 (8)0.0012 (8)
Na20.0094 (10)0.0334 (12)0.0203 (11)0.0007 (6)0.0053 (8)0.0018 (7)
O10.0222 (17)0.0250 (17)0.0262 (18)0.0028 (13)0.0070 (14)0.0127 (14)
O20.0098 (14)0.0168 (15)0.0208 (16)0.0016 (11)0.0030 (12)0.0078 (12)
O30.0179 (16)0.0141 (15)0.036 (2)0.0011 (12)0.0024 (14)0.0078 (14)
O40.0168 (17)0.0118 (15)0.0248 (18)0.0017 (11)0.0048 (13)0.0028 (12)
O50.0162 (15)0.0114 (14)0.0223 (17)0.0009 (11)0.0061 (13)0.0027 (12)
O60.0235 (17)0.0140 (15)0.036 (2)0.0012 (13)0.0134 (15)0.0061 (14)
O70.0170 (17)0.0359 (18)0.0137 (16)0.0028 (14)0.0009 (13)0.0048 (14)
O80.0106 (16)0.0383 (18)0.0152 (16)0.0047 (14)0.0055 (13)0.0073 (14)
O90.0115 (16)0.0334 (18)0.0152 (17)0.0003 (13)0.0038 (13)0.0034 (13)
O100.0150 (17)0.0316 (18)0.0209 (18)0.0033 (14)0.0038 (13)0.0053 (15)
O1w0.027 (2)0.042 (2)0.037 (2)0.0078 (17)0.0095 (18)0.0157 (18)
C10.019 (2)0.014 (2)0.011 (2)0.0011 (16)0.0005 (17)0.0010 (16)
C20.018 (2)0.015 (2)0.012 (2)0.0029 (16)0.0023 (17)0.0034 (16)
C30.0021 (18)0.0137 (19)0.017 (2)0.0009 (14)0.0022 (15)0.0006 (16)
C40.013 (2)0.021 (2)0.010 (2)0.0031 (16)0.0039 (16)0.0006 (17)
C50.011 (2)0.017 (2)0.015 (2)0.0029 (16)0.0031 (17)0.0025 (17)
Geometric parameters (Å, º) top
Ce1—O12.537 (3)Na2—O5vi2.469 (3)
Ce1—O2i2.560 (3)Na2—O4vii2.512 (3)
Ce1—O32.526 (3)Na2—O1wv2.687 (5)
Ce1—O4ii2.688 (3)O1—C11.247 (5)
Ce1—O52.596 (3)O2—C11.261 (5)
Ce1—O6ii2.532 (3)O3—C21.256 (5)
Ce1—O72.535 (3)O4—C21.250 (5)
Ce1—O8iii2.548 (3)O5—C31.251 (5)
Ce1—O92.649 (3)O6—C31.249 (5)
Ce1—O10iii2.677 (3)O7—C41.259 (5)
Na1—O72.293 (4)O8—C41.240 (5)
Na1—O10iv2.322 (4)O9—C51.254 (5)
Na1—O1w2.327 (4)O10—C51.254 (5)
Na1—O4ii2.484 (4)O1w—H10.85 (1)
Na1—O52.566 (4)O1w—H20.85 (1)
Na1—O2ii2.712 (4)C1—C1i1.534 (8)
Na2—O8v2.302 (4)C2—C31.550 (6)
Na2—O9i2.306 (4)C4—C51.525 (6)
Na2—O22.363 (3)
O3—Ce1—O6ii141.83 (11)O2—Na2—O5vi126.86 (12)
O3—Ce1—O774.63 (11)O8v—Na2—O4vii65.80 (12)
O6ii—Ce1—O775.57 (11)O9i—Na2—O4vii104.79 (13)
O3—Ce1—O168.39 (11)O2—Na2—O4vii164.10 (13)
O6ii—Ce1—O1146.21 (11)O5vi—Na2—O4vii68.89 (11)
O7—Ce1—O1138.00 (11)O8v—Na2—O1wv89.47 (13)
O3—Ce1—O8iii122.51 (11)O9i—Na2—O1wv80.14 (13)
O6ii—Ce1—O8iii92.97 (11)O2—Na2—O1wv81.66 (12)
O7—Ce1—O8iii119.64 (10)O5vi—Na2—O1wv151.24 (13)
O1—Ce1—O8iii68.55 (11)O4vii—Na2—O1wv82.48 (12)
O3—Ce1—O2i76.07 (10)C1—O1—Ce1120.3 (3)
O6ii—Ce1—O2i102.96 (10)C1—O2—Na2125.9 (3)
O7—Ce1—O2i125.22 (10)C1—O2—Ce1i119.1 (3)
O1—Ce1—O2i63.93 (10)Na2—O2—Ce1i108.93 (11)
O8iii—Ce1—O2i115.14 (10)C1—O2—Na1v108.1 (3)
O3—Ce1—O563.88 (10)Na2—O2—Na1v82.60 (10)
O6ii—Ce1—O5125.41 (9)Ce1i—O2—Na1v102.66 (11)
O7—Ce1—O570.10 (10)C2—O3—Ce1115.7 (3)
O1—Ce1—O576.13 (10)C2—O4—Na1v127.2 (3)
O8iii—Ce1—O570.24 (10)C2—O4—Na2viii128.5 (3)
O2i—Ce1—O5131.45 (9)Na1v—O4—Na2viii84.84 (11)
O3—Ce1—O970.89 (10)C2—O4—Ce1v116.6 (3)
O6ii—Ce1—O974.32 (10)Na1v—O4—Ce1v95.76 (11)
O7—Ce1—O962.05 (10)Na2viii—O4—Ce1v94.88 (10)
O1—Ce1—O9120.10 (10)C3—O5—Na2vi134.4 (3)
O8iii—Ce1—O9166.58 (11)C3—O5—Na1117.8 (3)
O2i—Ce1—O964.99 (10)Na2vi—O5—Na184.04 (11)
O5—Ce1—O9120.54 (10)C3—O5—Ce1116.6 (3)
O3—Ce1—O10iii134.57 (11)Na2vi—O5—Ce198.29 (11)
O6ii—Ce1—O10iii72.18 (11)Na1—O5—Ce196.08 (10)
O7—Ce1—O10iii147.72 (11)C3—O6—Ce1v123.7 (3)
O1—Ce1—O10iii74.13 (11)C4—O7—Na1131.8 (3)
O8iii—Ce1—O10iii61.62 (10)C4—O7—Ce1122.9 (3)
O2i—Ce1—O10iii64.76 (10)Na1—O7—Ce1105.20 (12)
O5—Ce1—O10iii129.83 (9)C4—O8—Na2ii131.5 (3)
O9—Ce1—O10iii109.24 (10)C4—O8—Ce1ix123.5 (3)
O3—Ce1—O4ii120.92 (10)Na2ii—O8—Ce1ix104.26 (13)
O6ii—Ce1—O4ii62.36 (9)C5—O9—Na2i132.6 (3)
O7—Ce1—O4ii62.47 (10)C5—O9—Ce1119.5 (3)
O1—Ce1—O4ii122.63 (10)Na2i—O9—Ce1107.77 (13)
O8iii—Ce1—O4ii60.01 (11)C5—O10—Na1x128.5 (3)
O2i—Ce1—O4ii162.77 (10)C5—O10—Ce1ix118.8 (3)
O5—Ce1—O4ii64.44 (9)Na1x—O10—Ce1ix110.69 (13)
O9—Ce1—O4ii115.50 (10)Na1—O1w—Na2ii83.83 (13)
O10iii—Ce1—O4ii100.48 (10)Na1—O1w—H1135 (5)
O7—Na1—O10iv170.43 (16)Na2ii—O1w—H191 (6)
O7—Na1—O1w94.14 (15)Na1—O1w—H2113 (5)
O10iv—Na1—O1w90.83 (15)Na2ii—O1w—H2115 (7)
O7—Na1—O4ii69.03 (12)H1—O1w—H2109.4 (18)
O10iv—Na1—O4ii105.32 (13)O1—C1—O2124.7 (4)
O1w—Na1—O4ii162.77 (15)O1—C1—C1i117.8 (5)
O7—Na1—O574.46 (12)O2—C1—C1i117.5 (5)
O10iv—Na1—O5111.12 (13)O4—C2—O3126.1 (4)
O1w—Na1—O5112.32 (15)O4—C2—C3117.0 (4)
O4ii—Na1—O567.81 (11)O3—C2—C3116.9 (4)
O7—Na1—O2ii105.38 (13)O6—C3—O5126.0 (4)
O10iv—Na1—O2ii67.24 (11)O6—C3—C2116.8 (4)
O1w—Na1—O2ii81.76 (13)O5—C3—C2117.2 (4)
O4ii—Na1—O2ii98.75 (11)O8—C4—O7125.1 (4)
O5—Na1—O2ii165.92 (12)O8—C4—C5118.2 (4)
O8v—Na2—O9i167.01 (16)O7—C4—C5116.7 (4)
O8v—Na2—O2112.76 (13)O10—C5—O9126.7 (4)
O9i—Na2—O273.65 (12)O10—C5—C4116.3 (4)
O8v—Na2—O5vi76.60 (12)O9—C5—C4117.0 (4)
O9i—Na2—O5vi109.16 (13)
O3—Ce1—O1—C175.1 (3)O6ii—Ce1—O7—C469.4 (3)
O6ii—Ce1—O1—C183.1 (4)O1—Ce1—O7—C4115.3 (3)
O7—Ce1—O1—C1105.1 (3)O8iii—Ce1—O7—C4154.6 (3)
O8iii—Ce1—O1—C1144.0 (3)O2i—Ce1—O7—C426.4 (4)
O2i—Ce1—O1—C19.5 (3)O5—Ce1—O7—C4153.7 (4)
O5—Ce1—O1—C1142.1 (3)O9—Ce1—O7—C410.2 (3)
O9—Ce1—O1—C124.6 (4)O10iii—Ce1—O7—C471.6 (4)
O10iii—Ce1—O1—C178.8 (3)O4ii—Ce1—O7—C4135.5 (4)
O4ii—Ce1—O1—C1171.2 (3)O3—Ce1—O7—Na197.36 (15)
O8v—Na2—O2—C157.4 (4)O6ii—Ce1—O7—Na1106.77 (15)
O9i—Na2—O2—C1134.6 (4)O1—Ce1—O7—Na168.5 (2)
O5vi—Na2—O2—C132.6 (4)O8iii—Ce1—O7—Na121.64 (19)
O4vii—Na2—O2—C1138.8 (5)O2i—Ce1—O7—Na1157.39 (12)
O1wv—Na2—O2—C1143.3 (4)O5—Ce1—O7—Na130.07 (12)
O8v—Na2—O2—Ce1i150.49 (13)O9—Ce1—O7—Na1173.57 (19)
O9i—Na2—O2—Ce1i17.51 (12)O10iii—Ce1—O7—Na1104.56 (19)
O5vi—Na2—O2—Ce1i119.49 (14)O4ii—Ce1—O7—Na140.73 (12)
O4vii—Na2—O2—Ce1i69.1 (5)O3—Ce1—O9—C584.1 (3)
O1wv—Na2—O2—Ce1i64.60 (13)O6ii—Ce1—O9—C580.0 (3)
O8v—Na2—O2—Na1v49.59 (14)O7—Ce1—O9—C51.7 (3)
O9i—Na2—O2—Na1v118.40 (12)O1—Ce1—O9—C5133.4 (3)
O5vi—Na2—O2—Na1v139.61 (14)O8iii—Ce1—O9—C599.1 (5)
O4vii—Na2—O2—Na1v31.8 (5)O2i—Ce1—O9—C5167.2 (3)
O1wv—Na2—O2—Na1v36.30 (11)O5—Ce1—O9—C542.2 (3)
Na1vi—Na2—O2—Na1v151.77 (14)O10iii—Ce1—O9—C5144.2 (3)
O7—Ce1—O3—C2102.2 (3)O4ii—Ce1—O9—C531.9 (3)
O1—Ce1—O3—C257.5 (3)O3—Ce1—O9—Na2i99.53 (15)
O8iii—Ce1—O3—C213.4 (4)O6ii—Ce1—O9—Na2i96.44 (14)
O2i—Ce1—O3—C2124.6 (3)O7—Ce1—O9—Na2i178.15 (18)
O5—Ce1—O3—C227.2 (3)O1—Ce1—O9—Na2i50.19 (17)
O9—Ce1—O3—C2167.4 (3)O8iii—Ce1—O9—Na2i77.3 (4)
O10iii—Ce1—O3—C294.0 (3)O2i—Ce1—O9—Na2i16.40 (12)
O4ii—Ce1—O3—C258.5 (3)O5—Ce1—O9—Na2i141.35 (12)
O7—Na1—O5—C396.5 (3)O10iii—Ce1—O9—Na2i32.20 (16)
O10iv—Na1—O5—C391.7 (3)O4ii—Ce1—O9—Na2i144.54 (12)
O1w—Na1—O5—C38.4 (3)O10iv—Na1—O1w—Na2ii103.69 (13)
O4ii—Na1—O5—C3169.8 (3)O4ii—Na1—O1w—Na2ii56.1 (6)
O2ii—Na1—O5—C3172.2 (4)O5—Na1—O1w—Na2ii143.01 (12)
Na2ii—Na1—O5—C364.6 (3)O2ii—Na1—O1w—Na2ii36.84 (10)
Na2vi—Na1—O5—C3137.8 (3)Ce1—O1—C1—O2170.8 (3)
O10iv—Na1—O5—Na2vi46.10 (14)Ce1—O1—C1—C1i9.1 (6)
O1w—Na1—O5—Na2vi146.19 (14)Na2—O2—C1—O121.5 (6)
O4ii—Na1—O5—Na2vi52.43 (11)Ce1i—O2—C1—O1171.0 (3)
O2ii—Na1—O5—Na2vi34.4 (5)Na1v—O2—C1—O172.5 (4)
O7—Na1—O5—Ce127.97 (11)Na2—O2—C1—C1i158.6 (3)
O10iv—Na1—O5—Ce1143.84 (12)Ce1i—O2—C1—C1i9.0 (6)
O1w—Na1—O5—Ce1116.07 (14)Na1v—O2—C1—C1i107.4 (4)
O4ii—Na1—O5—Ce145.31 (11)Na1v—O4—C2—O380.6 (5)
O2ii—Na1—O5—Ce163.3 (5)Na2viii—O4—C2—O336.6 (6)
O3—Ce1—O5—C317.4 (3)Ce1v—O4—C2—O3157.9 (3)
O6ii—Ce1—O5—C3154.0 (3)Na1v—O4—C2—C399.8 (4)
O7—Ce1—O5—C399.6 (3)Na2viii—O4—C2—C3142.9 (3)
O1—Ce1—O5—C355.0 (3)Ce1v—O4—C2—C321.6 (5)
O8iii—Ce1—O5—C3126.9 (3)Ce1—O3—C2—O4146.0 (4)
O2i—Ce1—O5—C320.3 (3)Ce1—O3—C2—C334.5 (5)
O9—Ce1—O5—C362.0 (3)Ce1v—O6—C3—O5176.4 (3)
O10iii—Ce1—O5—C3110.1 (3)Ce1v—O6—C3—C25.6 (5)
O4ii—Ce1—O5—C3167.8 (3)Na2vi—O5—C3—O637.8 (7)
O3—Ce1—O5—Na2vi167.25 (15)Na1—O5—C3—O672.8 (5)
O6ii—Ce1—O5—Na2vi56.22 (16)Ce1—O5—C3—O6173.6 (3)
O7—Ce1—O5—Na2vi110.59 (13)Na2vi—O5—C3—C2144.2 (3)
O1—Ce1—O5—Na2vi94.80 (12)Na1—O5—C3—C2105.1 (4)
O8iii—Ce1—O5—Na2vi22.95 (11)Ce1—O5—C3—C28.4 (5)
O2i—Ce1—O5—Na2vi129.50 (11)O4—C2—C3—O619.0 (6)
O9—Ce1—O5—Na2vi148.19 (10)O3—C2—C3—O6160.6 (4)
O10iii—Ce1—O5—Na2vi39.75 (17)O4—C2—C3—O5162.9 (4)
O4ii—Ce1—O5—Na2vi42.41 (11)O3—C2—C3—O517.6 (6)
O3—Ce1—O5—Na1107.92 (13)Na2ii—O8—C4—O75.5 (7)
O6ii—Ce1—O5—Na128.61 (16)Ce1ix—O8—C4—O7174.2 (3)
O7—Ce1—O5—Na125.76 (11)Na2ii—O8—C4—C5172.8 (3)
O1—Ce1—O5—Na1179.63 (13)Ce1ix—O8—C4—C54.0 (6)
O8iii—Ce1—O5—Na1107.78 (13)Na1—O7—C4—O810.0 (7)
O2i—Ce1—O5—Na1145.67 (11)Ce1—O7—C4—O8165.1 (3)
O9—Ce1—O5—Na163.36 (13)Na1—O7—C4—C5168.3 (3)
O10iii—Ce1—O5—Na1124.58 (13)Ce1—O7—C4—C516.6 (5)
O4ii—Ce1—O5—Na142.42 (11)Na1x—O10—C5—O93.9 (7)
O10iv—Na1—O7—C478.5 (10)Ce1ix—O10—C5—O9165.9 (3)
O1w—Na1—O7—C442.6 (4)Na1x—O10—C5—C4176.5 (3)
O4ii—Na1—O7—C4133.6 (4)Ce1ix—O10—C5—C414.6 (5)
O5—Na1—O7—C4154.6 (4)Na2i—O9—C5—O1010.0 (7)
O2ii—Na1—O7—C440.0 (4)Ce1—O9—C5—O10174.7 (4)
O10iv—Na1—O7—Ce197.2 (8)Na2i—O9—C5—C4170.4 (3)
O1w—Na1—O7—Ce1141.69 (15)Ce1—O9—C5—C44.9 (5)
O4ii—Na1—O7—Ce142.09 (12)O8—C4—C5—O1012.7 (6)
O5—Na1—O7—Ce129.66 (12)O7—C4—C5—O10165.7 (4)
O2ii—Na1—O7—Ce1135.73 (12)O8—C4—C5—O9167.7 (4)
O3—Ce1—O7—C486.4 (4)O7—C4—C5—O913.9 (6)
Symmetry codes: (i) x+1, y+1, z+1; (ii) x+3/2, y1/2, z+1/2; (iii) x+1/2, y+1/2, z+1/2; (iv) x+1, y, z; (v) x+3/2, y+1/2, z+1/2; (vi) x+2, y+1, z+1; (vii) x+1/2, y+3/2, z+1/2; (viii) x1/2, y+3/2, z1/2; (ix) x1/2, y+1/2, z1/2; (x) x1, y, z.
Hydrogen-bond geometry (Å, º) top
D—H···AD—HH···AD···AD—H···A
O1w—H1···O3xi0.85 (1)2.02 (2)2.848 (5)166 (8)
O1w—H2···O6xii0.85 (1)1.99 (3)2.813 (5)161 (8)
Symmetry codes: (xi) x+1, y+1, z; (xii) x+2, y+1, z.
 

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