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In order to gain a deeper understanding into the bonding situation in rhodium complexes containing rhodium–carbon interactions, the experimental charge-density analysis for [Rh(C7H8)(PPh3)Cl] (1) is reported. Accurate, high-resolution (sin θ/λ = 1.08 Å−1), single-crystal data were obtained at 100 K. The results from the investigation were interesting in relation to the interactions between the rhodium metal centre and the norbornadiene fragment and illustrate the importance of such analyses in studying bonding in organometallic complexes.
Supporting information
CCDC reference: 705576
Data collection: Collect (Nonius BV, 1997-2000); cell refinement: HKL SCALEPACK (Otwinowski & Minor 1997); data reduction: HKL DENZO and SCALEPACK (Otwinowski & Minor 1997); program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: Volkov et al., (2006); molecular graphics: Volkov et al., (2006); software used to prepare material for publication: Volkov et al., (2006).
Crystal data top
C25H23ClPRh | V = 1026.01 (2) Å3 |
Mr = 492.76 | Z = 2 |
Triclinic, P1 | F(000) = 500 |
Hall symbol: -P 1 | Dx = 1.595 Mg m−3 |
a = 10.2430 (1) Å | Mo Kα radiation, λ = 0.71073 Å |
b = 10.4042 (1) Å | µ = 1.05 mm−1 |
c = 11.4078 (1) Å | T = 100 K |
α = 99.213 (1)° | Block, orange |
β = 103.131 (1)° | × × mm |
γ = 115.080 (1)° | |
Data collection top
Nonius Kappa CCD diffractometer | 19920 reflections with I > 3 σ(I) |
Radiation source: fine-focus sealed tube | Rint = 0.038 |
Graphite monochromator | θmax = 50.2°, θmin = 2.3° |
CCD scans | h = −22→22 |
370693 measured reflections | k = −22→22 |
21647 independent reflections | l = −24→24 |
Refinement top
Refinement on F | 0 restraints |
Least-squares matrix: full | Only H-atom displacement parameters refined |
R[F2 > 2σ(F2)] = 0.012 | w1 = 1/[s2(Fo)] |
wR(F2) = 0.012 | (Δ/σ)max < 0.001 |
S = 1.35 | Δρmax = 0.20 e Å−3 |
19920 reflections | Δρmin = −0.21 e Å−3 |
514 parameters | |
Crystal data top
C25H23ClPRh | γ = 115.080 (1)° |
Mr = 492.76 | V = 1026.01 (2) Å3 |
Triclinic, P1 | Z = 2 |
a = 10.2430 (1) Å | Mo Kα radiation |
b = 10.4042 (1) Å | µ = 1.05 mm−1 |
c = 11.4078 (1) Å | T = 100 K |
α = 99.213 (1)° | × × mm |
β = 103.131 (1)° | |
Data collection top
Nonius Kappa CCD diffractometer | 19920 reflections with I > 3 σ(I) |
370693 measured reflections | Rint = 0.038 |
21647 independent reflections | |
Refinement top
R[F2 > 2σ(F2)] = 0.012 | 0 restraints |
wR(F2) = 0.012 | Only H-atom displacement parameters refined |
S = 1.35 | Δρmax = 0.20 e Å−3 |
19920 reflections | Δρmin = −0.21 e Å−3 |
514 parameters | |
Special details top
Geometry. Bond distances, angles etc. have been calculated using the rounded fractional coordinates. All su's are estimated from the variances of the (full) variance-covariance matrix. The cell e.s.d.'s are taken into account in the estimation of distances, angles and torsion angles |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | Occ. (<1) |
RH(1) | 0.787155 (2) | 0.772452 (2) | 0.723188 (2) | 0.009 | |
CL(1) | 0.703751 (7) | 0.524121 (7) | 0.726514 (6) | 0.014 | |
P(1) | 1.038951 (7) | 0.833909 (7) | 0.753578 (5) | 0.009 | |
C(1) | 0.57359 (3) | 0.76988 (4) | 0.73741 (3) | 0.014 | |
C(2) | 0.55919 (4) | 0.73356 (4) | 0.61128 (3) | 0.015 | |
C(3) | 0.62251 (4) | 0.88065 (4) | 0.57771 (3) | 0.016 | |
C(4) | 0.79460 (4) | 0.94849 (4) | 0.65042 (3) | 0.015 | |
C(5) | 0.80950 (4) | 0.98571 (3) | 0.77949 (3) | 0.014 | |
C(6) | 0.64693 (4) | 0.93992 (4) | 0.78397 (3) | 0.015 | |
C(7) | 0.57716 (4) | 0.97283 (4) | 0.66465 (3) | 0.017 | |
C(8) | 1.16740 (3) | 1.03313 (3) | 0.79144 (2) | 0.011 | |
C(9) | 1.18870 (3) | 1.12563 (3) | 0.90621 (2) | 0.013 | |
C(10) | 1.28192 (3) | 1.27875 (3) | 0.93910 (2) | 0.015 | |
C(11) | 1.35652 (3) | 1.34086 (3) | 0.85797 (3) | 0.017 | |
C(12) | 1.33788 (3) | 1.24985 (3) | 0.74471 (3) | 0.016 | |
C(13) | 1.24307 (3) | 1.09672 (3) | 0.71121 (2) | 0.013 | |
C(14) | 1.05684 (3) | 0.75315 (3) | 0.60731 (2) | 0.011 | |
C(15) | 0.96550 (3) | 0.75167 (3) | 0.49451 (2) | 0.016 | |
C(16) | 0.97714 (4) | 0.69701 (4) | 0.37963 (2) | 0.019 | |
C(17) | 1.07786 (4) | 0.64058 (3) | 0.37567 (3) | 0.017 | |
C(18) | 1.16620 (3) | 0.63821 (3) | 0.48670 (2) | 0.016 | |
C(19) | 1.15592 (3) | 0.69400 (3) | 0.60186 (2) | 0.014 | |
C(20) | 1.14490 (3) | 0.78763 (3) | 0.87592 (2) | 0.011 | |
C(21) | 1.30128 (3) | 0.83458 (3) | 0.89884 (2) | 0.013 | |
C(22) | 1.38014 (3) | 0.79347 (3) | 0.98835 (2) | 0.016 | |
C(23) | 1.30540 (4) | 0.70980 (3) | 1.05982 (3) | 0.018 | |
C(24) | 1.15240 (3) | 0.66861 (3) | 1.04128 (3) | 0.018 | |
C(25) | 1.07137 (3) | 0.70535 (3) | 0.94857 (2) | 0.014 | |
H(1) | 0.538368 | 0.691836 | 0.792889 | 0.037 | |
H(2) | 0.493344 | 0.623047 | 0.542096 | 0.025 | |
H(3) | 0.589356 | 0.869806 | 0.476452 | 0.026 | |
H(4) | 0.887016 | 0.999483 | 0.611813 | 0.02 | |
H(5) | 0.911195 | 1.070806 | 0.857875 | 0.024 | |
H(6) | 0.642067 | 0.991658 | 0.873724 | 0.027 | |
H(7B) | 0.631184 | 1.090811 | 0.668612 | 0.025 | |
H(7A) | 0.452523 | 0.926975 | 0.637468 | 0.024 | |
H(9) | 1.131536 | 1.074026 | 0.967816 | 0.02 | |
H(10) | 1.296051 | 1.349127 | 1.026725 | 0.023 | |
H(11) | 1.427987 | 1.459179 | 0.880588 | 0.034 | |
H(12) | 1.400042 | 1.297166 | 0.684227 | 0.027 | |
H(13) | 1.227628 | 1.02814 | 0.622107 | 0.021 | |
H(15) | 0.881561 | 0.788878 | 0.492818 | 0.029 | |
H(16) | 0.903517 | 0.691546 | 0.292418 | 0.026 | |
H(17) | 1.083195 | 0.597283 | 0.285309 | 0.029 | |
H(18) | 1.245579 | 0.596059 | 0.483222 | 0.026 | |
H(19) | 1.225312 | 0.694502 | 0.688933 | 0.033 | |
H(21) | 1.359091 | 0.902062 | 0.845263 | 0.026 | |
H(22) | 1.499848 | 0.829394 | 1.003835 | 0.019 | |
H(23) | 1.367037 | 0.679622 | 1.130575 | 0.033 | |
H(24) | 1.093755 | 0.603139 | 1.095603 | 0.032 | |
H(25) | 0.950536 | 0.665982 | 0.929523 | 0.022 | |
DUM0 | 0 | 0 | 0 | 0 | 0 |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
RH(1) | 0.008013 (7) | 0.010441 (7) | 0.010231 (6) | 0.004524 (6) | 0.003436 (5) | 0.003240 (5) |
CL(1) | 0.01341 (2) | 0.01133 (2) | 0.01681 (2) | 0.005118 (19) | 0.005363 (19) | 0.004116 (18) |
P(1) | 0.00831 (2) | 0.01039 (2) | 0.00942 (2) | 0.004648 (18) | 0.003331 (17) | 0.003571 (17) |
C(1) | 0.01169 (10) | 0.01670 (11) | 0.01700 (11) | 0.00732 (9) | 0.00685 (9) | 0.00595 (9) |
C(2) | 0.01180 (10) | 0.01664 (11) | 0.01502 (11) | 0.00714 (9) | 0.00201 (9) | 0.00216 (9) |
C(3) | 0.01654 (12) | 0.02171 (13) | 0.01417 (10) | 0.01218 (11) | 0.00473 (9) | 0.00725 (10) |
C(4) | 0.01433 (11) | 0.01683 (11) | 0.01708 (11) | 0.00906 (9) | 0.00763 (9) | 0.00846 (9) |
C(5) | 0.01207 (10) | 0.01326 (10) | 0.01579 (10) | 0.00653 (9) | 0.00394 (9) | 0.00311 (8) |
C(6) | 0.01430 (11) | 0.01710 (11) | 0.01524 (10) | 0.00972 (10) | 0.00604 (9) | 0.00388 (9) |
C(7) | 0.01634 (12) | 0.02027 (13) | 0.02076 (12) | 0.01269 (11) | 0.00607 (10) | 0.00753 (10) |
C(8) | 0.01028 (8) | 0.01086 (8) | 0.01108 (8) | 0.00462 (7) | 0.00399 (6) | 0.00371 (6) |
C(9) | 0.01256 (9) | 0.01307 (8) | 0.01154 (8) | 0.00490 (7) | 0.00398 (7) | 0.00250 (7) |
C(10) | 0.01443 (9) | 0.01288 (9) | 0.01430 (9) | 0.00486 (8) | 0.00258 (7) | 0.00110 (7) |
C(11) | 0.01543 (10) | 0.01152 (9) | 0.01769 (10) | 0.00337 (8) | 0.00313 (8) | 0.00378 (8) |
C(12) | 0.01547 (10) | 0.01331 (9) | 0.01658 (9) | 0.00362 (8) | 0.00600 (8) | 0.00621 (8) |
C(13) | 0.01376 (9) | 0.01248 (8) | 0.01322 (8) | 0.00474 (7) | 0.00616 (7) | 0.00500 (7) |
C(14) | 0.01118 (8) | 0.01242 (8) | 0.01033 (7) | 0.00627 (7) | 0.00386 (7) | 0.00322 (6) |
C(15) | 0.02070 (11) | 0.02233 (11) | 0.01075 (8) | 0.01520 (10) | 0.00463 (8) | 0.00495 (8) |
C(16) | 0.02748 (13) | 0.02632 (13) | 0.01080 (8) | 0.01838 (11) | 0.00624 (9) | 0.00573 (8) |
C(17) | 0.02089 (12) | 0.02098 (11) | 0.01265 (9) | 0.01151 (10) | 0.00756 (9) | 0.00341 (8) |
C(18) | 0.01442 (10) | 0.02081 (11) | 0.01433 (9) | 0.01002 (9) | 0.00496 (8) | 0.00080 (8) |
C(19) | 0.01257 (9) | 0.01814 (10) | 0.01237 (8) | 0.00930 (8) | 0.00323 (7) | 0.00158 (7) |
C(20) | 0.00996 (8) | 0.01226 (8) | 0.01072 (7) | 0.00534 (7) | 0.00307 (6) | 0.00459 (6) |
C(21) | 0.01011 (8) | 0.01530 (9) | 0.01288 (8) | 0.00621 (7) | 0.00298 (7) | 0.00476 (7) |
C(22) | 0.01289 (9) | 0.01745 (10) | 0.01582 (9) | 0.00848 (8) | 0.00139 (7) | 0.00479 (8) |
C(23) | 0.01759 (11) | 0.01691 (10) | 0.01667 (10) | 0.00808 (9) | 0.00010 (9) | 0.00720 (8) |
C(24) | 0.01675 (11) | 0.01733 (10) | 0.01529 (9) | 0.00500 (9) | 0.00219 (8) | 0.00927 (8) |
C(25) | 0.01232 (9) | 0.01572 (9) | 0.01273 (8) | 0.00475 (8) | 0.00376 (7) | 0.00708 (7) |
Geometric parameters (Å, º) top
RH(1)—CL(1) | 2.3625 (1) | C(10)—H(10) | 1.0800 (3) |
RH(1)—P(1) | 2.3034 (1) | C(10)—H(11) | 2.1638 (3) |
RH(1)—C(1) | 2.2193 (3) | C(11)—C(12) | 1.3948 (4) |
RH(1)—C(2) | 2.2192 (3) | C(11)—H(10) | 2.1520 (3) |
RH(1)—C(4) | 2.1087 (3) | C(11)—H(11) | 1.0800 (3) |
RH(1)—C(5) | 2.1058 (3) | C(11)—H(12) | 2.1491 (3) |
P(1)—C(8) | 1.8322 (2) | C(12)—C(13) | 1.3972 (4) |
P(1)—C(14) | 1.8287 (2) | C(12)—H(11) | 2.1361 (3) |
P(1)—C(20) | 1.8242 (2) | C(12)—H(12) | 1.0800 (3) |
C(1)—C(2) | 1.3845 (4) | C(12)—H(13) | 2.1432 (3) |
C(1)—C(3) | 2.3443 (4) | C(13)—H(12) | 2.1488 (2) |
C(1)—C(5) | 2.3748 (4) | C(13)—H(13) | 1.0800 (2) |
C(1)—C(6) | 1.5386 (4) | C(14)—C(15) | 1.4021 (3) |
C(1)—C(7) | 2.3788 (5) | C(14)—C(19) | 1.3995 (3) |
C(1)—H(1) | 1.1000 (3) | C(14)—H(15) | 2.1733 (2) |
C(1)—H(2) | 2.2332 (3) | C(14)—H(19) | 2.1358 (2) |
C(1)—H(6) | 2.2843 (3) | C(15)—C(16) | 1.3947 (4) |
C(2)—C(3) | 1.5390 (5) | C(15)—H(15) | 1.0800 (3) |
C(2)—C(4) | 2.3736 (5) | C(15)—H(16) | 2.1554 (2) |
C(2)—C(6) | 2.3459 (4) | C(16)—C(17) | 1.3918 (4) |
C(2)—C(7) | 2.3827 (5) | C(16)—H(15) | 2.1241 (3) |
C(2)—H(1) | 2.2218 (3) | C(16)—H(16) | 1.0800 (3) |
C(2)—H(2) | 1.1000 (3) | C(16)—H(17) | 2.1315 (3) |
C(2)—H(3) | 2.2391 (3) | C(17)—C(18) | 1.3899 (4) |
C(3)—C(4) | 1.5449 (5) | C(17)—H(16) | 2.1367 (3) |
C(3)—C(5) | 2.3617 (5) | C(17)—H(17) | 1.0800 (3) |
C(3)—C(6) | 2.2619 (4) | C(17)—H(18) | 2.1378 (3) |
C(3)—C(7) | 1.5497 (4) | C(18)—C(19) | 1.3944 (3) |
C(3)—H(2) | 2.3452 (4) | C(18)—H(17) | 2.1621 (3) |
C(3)—H(3) | 1.1000 (3) | C(18)—H(18) | 1.0800 (3) |
C(3)—H(4) | 2.3554 (3) | C(18)—H(19) | 2.1596 (3) |
C(3)—H(7B) | 2.2207 (3) | C(19)—H(18) | 2.1517 (2) |
C(3)—H(7A) | 2.2078 (3) | C(19)—H(19) | 1.0800 (3) |
C(4)—C(5) | 1.4164 (4) | C(20)—C(21) | 1.4065 (3) |
C(4)—C(6) | 2.3650 (4) | C(20)—C(25) | 1.3968 (3) |
C(4)—C(7) | 2.3834 (4) | C(20)—H(21) | 2.1496 (2) |
C(4)—H(3) | 2.2702 (3) | C(20)—H(25) | 2.1458 (2) |
C(4)—H(4) | 1.1000 (3) | C(21)—C(22) | 1.3915 (4) |
C(4)—H(5) | 2.2604 (3) | C(21)—H(19) | 2.3533 (2) |
C(5)—C(6) | 1.5416 (4) | C(21)—H(21) | 1.0800 (2) |
C(5)—C(7) | 2.3780 (4) | C(21)—H(22) | 2.1404 (2) |
C(5)—H(4) | 2.2341 (3) | C(22)—C(23) | 1.3980 (4) |
C(5)—H(5) | 1.1000 (3) | C(22)—H(21) | 2.1505 (3) |
C(5)—H(6) | 2.2377 (3) | C(22)—H(22) | 1.0800 (3) |
C(6)—C(7) | 1.5478 (5) | C(22)—H(23) | 2.1524 (3) |
C(6)—H(1) | 2.3688 (3) | C(23)—C(24) | 1.3911 (4) |
C(6)—H(5) | 2.3158 (3) | C(23)—H(22) | 2.1575 (3) |
C(6)—H(6) | 1.1000 (3) | C(23)—H(23) | 1.0800 (3) |
C(6)—H(7B) | 2.2366 (3) | C(23)—H(24) | 2.1460 (3) |
C(6)—H(7A) | 2.2282 (3) | C(24)—C(25) | 1.3976 (4) |
C(7)—H(3) | 2.2961 (3) | C(24)—H(23) | 2.1484 (3) |
C(7)—H(6) | 2.2779 (3) | C(24)—H(24) | 1.0800 (3) |
C(7)—H(7B) | 1.1000 (4) | C(24)—H(25) | 2.1552 (3) |
C(7)—H(7A) | 1.1000 (3) | C(25)—H(24) | 2.1448 (2) |
C(8)—C(9) | 1.4059 (3) | C(25)—H(25) | 1.0800 (3) |
C(8)—C(13) | 1.3991 (3) | H(2)—H(18)i | 2.3520 |
C(8)—H(9) | 2.1351 (2) | H(3)—H(12)ii | 2.3707 |
C(8)—H(13) | 2.1567 (2) | H(3)—H(13)ii | 2.3576 |
C(9)—C(10) | 1.3952 (4) | H(4)—H(15) | 2.3572 |
C(9)—H(9) | 1.0800 (2) | H(5)—H(9) | 2.3031 |
C(9)—H(10) | 2.1513 (2) | H(7B)—H(7A) | 1.8019 |
C(10)—C(11) | 1.3972 (4) | H(17)—H(24)iii | 2.2004 |
C(10)—H(9) | 2.1652 (3) | H(19)—H(21) | 2.2067 |
| | | |
CL(1)—RH(1)—P(1) | 96.346 (2) | C(5)—C(7)—C(6) | 39.576 (16) |
CL(1)—RH(1)—C(1) | 93.758 (8) | C(5)—C(7)—H(3) | 91.996 (13) |
CL(1)—RH(1)—C(2) | 95.090 (9) | C(5)—C(7)—H(6) | 57.403 (11) |
CL(1)—RH(1)—C(4) | 157.369 (9) | C(5)—C(7)—H(7B) | 93.87 (2) |
CL(1)—RH(1)—C(5) | 154.088 (9) | C(5)—C(7)—H(7A) | 151.57 (3) |
P(1)—RH(1)—C(1) | 164.189 (9) | C(6)—C(7)—H(3) | 118.53 (2) |
P(1)—RH(1)—C(2) | 153.217 (9) | C(6)—C(7)—H(6) | 25.313 (12) |
P(1)—RH(1)—C(4) | 95.663 (9) | C(6)—C(7)—H(7B) | 114.22 (3) |
P(1)—RH(1)—C(5) | 99.964 (8) | C(6)—C(7)—H(7A) | 113.53 (3) |
C(1)—RH(1)—C(2) | 36.352 (11) | H(3)—C(7)—H(6) | 143.836 (15) |
C(1)—RH(1)—C(4) | 79.135 (12) | H(3)—C(7)—H(7B) | 100.47 (2) |
C(1)—RH(1)—C(5) | 66.548 (12) | H(3)—C(7)—H(7A) | 98.38 (2) |
C(2)—RH(1)—C(4) | 66.464 (13) | H(6)—C(7)—H(7B) | 100.40 (2) |
C(2)—RH(1)—C(5) | 79.078 (12) | H(6)—C(7)—H(7A) | 101.76 (2) |
C(4)—RH(1)—C(5) | 39.276 (12) | H(7B)—C(7)—H(7A) | 109.98 (3) |
RH(1)—P(1)—C(8) | 114.197 (8) | P(1)—C(8)—C(9) | 117.895 (18) |
RH(1)—P(1)—C(14) | 109.506 (8) | P(1)—C(8)—C(13) | 123.135 (18) |
RH(1)—P(1)—C(20) | 121.381 (8) | P(1)—C(8)—H(9) | 91.327 (10) |
C(8)—P(1)—C(14) | 104.183 (11) | P(1)—C(8)—H(13) | 97.534 (10) |
C(8)—P(1)—C(20) | 100.444 (11) | C(9)—C(8)—C(13) | 118.97 (2) |
C(14)—P(1)—C(20) | 105.455 (11) | C(9)—C(8)—H(9) | 26.584 (11) |
RH(1)—C(1)—C(2) | 71.819 (17) | C(9)—C(8)—H(13) | 144.565 (18) |
RH(1)—C(1)—C(3) | 75.419 (12) | C(13)—C(8)—H(9) | 145.537 (19) |
RH(1)—C(1)—C(5) | 54.435 (10) | C(13)—C(8)—H(13) | 25.600 (11) |
RH(1)—C(1)—C(6) | 93.981 (18) | H(9)—C(8)—H(13) | 171.133 (13) |
RH(1)—C(1)—C(7) | 103.305 (14) | C(8)—C(9)—C(10) | 120.70 (2) |
RH(1)—C(1)—H(1) | 102.015 (19) | C(8)—C(9)—H(9) | 117.78 (2) |
RH(1)—C(1)—H(2) | 78.416 (10) | C(8)—C(9)—H(10) | 146.415 (19) |
RH(1)—C(1)—H(6) | 107.179 (13) | C(10)—C(9)—H(9) | 121.51 (2) |
C(2)—C(1)—C(3) | 39.009 (18) | C(10)—C(9)—H(10) | 25.719 (12) |
C(2)—C(1)—C(5) | 90.27 (2) | H(9)—C(9)—H(10) | 95.800 (14) |
C(2)—C(1)—C(6) | 106.63 (3) | C(9)—C(10)—C(11) | 119.74 (2) |
C(2)—C(1)—C(7) | 73.25 (2) | C(9)—C(10)—H(9) | 25.167 (11) |
C(2)—C(1)—H(1) | 126.44 (3) | C(9)—C(10)—H(10) | 120.18 (2) |
C(2)—C(1)—H(2) | 22.957 (15) | C(9)—C(10)—H(11) | 145.011 (19) |
C(2)—C(1)—H(6) | 130.39 (2) | C(11)—C(10)—H(9) | 144.90 (2) |
C(3)—C(1)—C(5) | 60.057 (14) | C(11)—C(10)—H(10) | 120.07 (2) |
C(3)—C(1)—C(6) | 67.620 (18) | C(11)—C(10)—H(11) | 25.273 (13) |
C(3)—C(1)—C(7) | 38.299 (12) | H(9)—C(10)—H(10) | 95.025 (17) |
C(3)—C(1)—H(1) | 165.44 (3) | H(9)—C(10)—H(11) | 170.171 (13) |
C(3)—C(1)—H(2) | 61.581 (12) | H(10)—C(10)—H(11) | 94.802 (16) |
C(3)—C(1)—H(6) | 91.665 (14) | C(10)—C(11)—C(12) | 120.01 (2) |
C(5)—C(1)—C(6) | 39.603 (15) | C(10)—C(11)—H(10) | 25.741 (12) |
C(5)—C(1)—C(7) | 60.033 (13) | C(10)—C(11)—H(11) | 121.20 (3) |
C(5)—C(1)—H(1) | 130.30 (2) | C(10)—C(11)—H(12) | 145.74 (2) |
C(5)—C(1)—H(2) | 111.083 (14) | C(12)—C(11)—H(10) | 145.75 (2) |
C(5)—C(1)—H(6) | 57.368 (10) | C(12)—C(11)—H(11) | 118.79 (3) |
C(6)—C(1)—C(7) | 39.722 (16) | C(12)—C(11)—H(12) | 25.796 (12) |
C(6)—C(1)—H(1) | 126.93 (3) | H(10)—C(11)—H(11) | 95.460 (18) |
C(6)—C(1)—H(2) | 128.96 (2) | H(10)—C(11)—H(12) | 171.410 (15) |
C(6)—C(1)—H(6) | 24.912 (12) | H(11)—C(11)—H(12) | 93.045 (18) |
C(7)—C(1)—H(1) | 152.11 (2) | C(11)—C(12)—C(13) | 120.18 (2) |
C(7)—C(1)—H(2) | 92.517 (14) | C(11)—C(12)—H(11) | 26.302 (13) |
C(7)—C(1)—H(6) | 58.441 (11) | C(11)—C(12)—H(12) | 120.01 (2) |
H(1)—C(1)—H(2) | 103.87 (2) | C(11)—C(12)—H(13) | 146.25 (2) |
H(1)—C(1)—H(6) | 102.72 (2) | C(13)—C(12)—H(11) | 146.47 (2) |
H(2)—C(1)—H(6) | 150.947 (16) | C(13)—C(12)—H(12) | 119.77 (2) |
RH(1)—C(2)—C(1) | 71.829 (18) | C(13)—C(12)—H(13) | 26.084 (11) |
RH(1)—C(2)—C(3) | 94.267 (19) | H(11)—C(12)—H(12) | 93.758 (16) |
RH(1)—C(2)—C(4) | 54.536 (10) | H(11)—C(12)—H(13) | 172.420 (14) |
RH(1)—C(2)—C(6) | 75.191 (12) | H(12)—C(12)—H(13) | 93.734 (17) |
RH(1)—C(2)—C(7) | 103.183 (15) | C(8)—C(13)—C(12) | 120.39 (2) |
RH(1)—C(2)—H(1) | 74.054 (10) | C(8)—C(13)—H(12) | 146.203 (19) |
RH(1)—C(2)—H(2) | 111.47 (2) | C(8)—C(13)—H(13) | 120.36 (2) |
RH(1)—C(2)—H(3) | 108.641 (14) | C(12)—C(13)—H(12) | 25.867 (12) |
C(1)—C(2)—C(3) | 106.50 (3) | C(12)—C(13)—H(13) | 119.25 (2) |
C(1)—C(2)—C(4) | 90.49 (2) | H(12)—C(13)—H(13) | 93.427 (14) |
C(1)—C(2)—C(6) | 38.935 (18) | P(1)—C(14)—C(15) | 117.357 (18) |
C(1)—C(2)—C(7) | 72.94 (2) | P(1)—C(14)—C(19) | 123.988 (18) |
C(1)—C(2)—H(1) | 23.472 (15) | P(1)—C(14)—H(15) | 92.410 (10) |
C(1)—C(2)—H(2) | 127.64 (3) | P(1)—C(14)—H(19) | 97.574 (10) |
C(1)—C(2)—H(3) | 131.47 (2) | C(15)—C(14)—C(19) | 118.65 (2) |
C(3)—C(2)—C(4) | 39.767 (16) | C(15)—C(14)—H(15) | 25.015 (11) |
C(3)—C(2)—C(6) | 67.566 (18) | C(15)—C(14)—H(19) | 145.068 (18) |
C(3)—C(2)—C(7) | 39.682 (16) | C(19)—C(14)—H(15) | 143.569 (18) |
C(3)—C(2)—H(1) | 129.97 (2) | C(19)—C(14)—H(19) | 26.415 (11) |
C(3)—C(2)—H(2) | 124.57 (3) | H(15)—C(14)—H(19) | 169.814 (12) |
C(3)—C(2)—H(3) | 26.421 (13) | C(14)—C(15)—C(16) | 120.58 (2) |
C(4)—C(2)—C(6) | 60.143 (13) | C(14)—C(15)—H(15) | 121.69 (2) |
C(4)—C(2)—C(7) | 60.145 (14) | C(14)—C(15)—H(16) | 146.080 (19) |
C(4)—C(2)—H(1) | 109.244 (15) | C(16)—C(15)—H(15) | 117.70 (2) |
C(4)—C(2)—H(2) | 135.74 (2) | C(16)—C(15)—H(16) | 25.544 (13) |
C(4)—C(2)—H(3) | 58.878 (11) | H(15)—C(15)—H(16) | 92.161 (15) |
C(6)—C(2)—C(7) | 38.203 (12) | C(15)—C(16)—C(17) | 120.17 (3) |
C(6)—C(2)—H(1) | 62.406 (11) | C(15)—C(16)—H(15) | 26.753 (12) |
C(6)—C(2)—H(2) | 164.02 (3) | C(15)—C(16)—H(16) | 120.62 (3) |
C(6)—C(2)—H(3) | 92.977 (14) | C(15)—C(16)—H(17) | 146.57 (2) |
C(7)—C(2)—H(1) | 94.771 (14) | C(17)—C(16)—H(15) | 146.86 (2) |
C(7)—C(2)—H(2) | 143.71 (2) | C(17)—C(16)—H(16) | 119.10 (2) |
C(7)—C(2)—H(3) | 59.482 (12) | C(17)—C(16)—H(17) | 26.408 (12) |
H(1)—C(2)—H(2) | 104.56 (2) | H(15)—C(16)—H(16) | 93.867 (18) |
H(1)—C(2)—H(3) | 154.227 (16) | H(15)—C(16)—H(17) | 173.023 (15) |
H(2)—C(2)—H(3) | 98.23 (2) | H(16)—C(16)—H(17) | 92.719 (16) |
C(1)—C(3)—C(2) | 34.491 (15) | C(16)—C(17)—C(18) | 119.69 (2) |
C(1)—C(3)—C(4) | 87.826 (19) | C(16)—C(17)—H(16) | 26.209 (13) |
C(1)—C(3)—C(5) | 60.613 (13) | C(16)—C(17)—H(17) | 118.62 (3) |
C(1)—C(3)—C(6) | 38.975 (12) | C(16)—C(17)—H(18) | 145.81 (2) |
C(1)—C(3)—C(7) | 72.054 (19) | C(18)—C(17)—H(16) | 145.80 (2) |
C(1)—C(3)—H(2) | 56.877 (11) | C(18)—C(17)—H(17) | 121.67 (3) |
C(1)—C(3)—H(3) | 147.10 (3) | C(18)—C(17)—H(18) | 26.122 (12) |
C(1)—C(3)—H(4) | 109.614 (14) | H(16)—C(17)—H(17) | 92.438 (18) |
C(1)—C(3)—H(7B) | 95.873 (14) | H(16)—C(17)—H(18) | 171.848 (14) |
C(1)—C(3)—H(7A) | 72.061 (12) | H(17)—C(17)—H(18) | 95.572 (18) |
C(2)—C(3)—C(4) | 100.65 (2) | C(17)—C(18)—C(19) | 120.32 (2) |
C(2)—C(3)—C(5) | 87.178 (19) | C(17)—C(18)—H(17) | 25.158 (12) |
C(2)—C(3)—C(6) | 73.465 (19) | C(17)—C(18)—H(18) | 119.36 (2) |
C(2)—C(3)—C(7) | 100.96 (3) | C(17)—C(18)—H(19) | 145.68 (2) |
C(2)—C(3)—H(2) | 22.719 (13) | C(19)—C(18)—H(17) | 145.47 (2) |
C(2)—C(3)—H(3) | 115.08 (3) | C(19)—C(18)—H(18) | 120.29 (3) |
C(2)—C(3)—H(4) | 115.52 (2) | C(19)—C(18)—H(19) | 25.368 (12) |
C(2)—C(3)—H(7B) | 127.55 (2) | H(17)—C(18)—H(18) | 94.225 (15) |
C(2)—C(3)—H(7A) | 89.239 (19) | H(17)—C(18)—H(19) | 170.833 (14) |
C(4)—C(3)—C(5) | 35.264 (15) | H(18)—C(18)—H(19) | 94.927 (17) |
C(4)—C(3)—C(6) | 74.140 (18) | C(14)—C(19)—C(18) | 120.56 (2) |
C(4)—C(3)—C(7) | 100.74 (3) | C(14)—C(19)—H(18) | 146.218 (19) |
C(4)—C(3)—H(2) | 111.85 (2) | C(14)—C(19)—H(19) | 118.38 (2) |
C(4)—C(3)—H(3) | 117.26 (3) | C(18)—C(19)—H(18) | 25.684 (13) |
C(4)—C(3)—H(4) | 22.484 (13) | C(18)—C(19)—H(19) | 121.05 (2) |
C(4)—C(3)—H(7B) | 89.00 (2) | H(18)—C(19)—H(19) | 95.369 (15) |
C(4)—C(3)—H(7A) | 127.76 (2) | P(1)—C(20)—C(21) | 120.675 (18) |
C(5)—C(3)—C(6) | 38.877 (12) | P(1)—C(20)—C(25) | 120.184 (19) |
C(5)—C(3)—C(7) | 71.484 (19) | P(1)—C(20)—H(21) | 94.642 (10) |
C(5)—C(3)—H(2) | 107.684 (14) | P(1)—C(20)—H(25) | 94.226 (10) |
C(5)—C(3)—H(3) | 150.44 (3) | C(21)—C(20)—C(25) | 119.14 (2) |
C(5)—C(3)—H(4) | 56.537 (11) | C(21)—C(20)—H(21) | 26.050 (11) |
C(5)—C(3)—H(7B) | 71.713 (12) | C(21)—C(20)—H(25) | 145.093 (18) |
C(5)—C(3)—H(7A) | 95.576 (14) | C(25)—C(20)—H(21) | 145.153 (19) |
C(6)—C(3)—C(7) | 43.059 (16) | C(25)—C(20)—H(25) | 25.974 (12) |
C(6)—C(3)—H(2) | 95.728 (15) | H(21)—C(20)—H(25) | 171.127 (12) |
C(6)—C(3)—H(3) | 162.13 (3) | C(20)—C(21)—C(22) | 120.50 (2) |
C(6)—C(3)—H(4) | 94.937 (15) | C(20)—C(21)—H(19) | 85.357 (14) |
C(6)—C(3)—H(7B) | 59.852 (11) | C(20)—C(21)—H(21) | 119.07 (2) |
C(6)—C(3)—H(7A) | 59.789 (11) | C(20)—C(21)—H(22) | 146.558 (19) |
C(7)—C(3)—H(2) | 116.22 (2) | C(22)—C(21)—H(19) | 115.279 (18) |
C(7)—C(3)—H(3) | 119.15 (3) | C(22)—C(21)—H(21) | 120.43 (2) |
C(7)—C(3)—H(4) | 112.05 (2) | C(22)—C(21)—H(22) | 26.059 (13) |
C(7)—C(3)—H(7B) | 27.175 (15) | H(19)—C(21)—H(21) | 68.839 (12) |
C(7)—C(3)—H(7A) | 27.569 (15) | H(19)—C(21)—H(22) | 108.001 (10) |
H(2)—C(3)—H(3) | 92.43 (2) | H(21)—C(21)—H(22) | 94.367 (15) |
H(2)—C(3)—H(4) | 118.912 (13) | C(21)—C(22)—C(23) | 119.98 (2) |
H(2)—C(3)—H(7B) | 143.104 (16) | C(21)—C(22)—H(21) | 25.661 (12) |
H(2)—C(3)—H(7A) | 96.708 (13) | C(21)—C(22)—H(22) | 119.47 (3) |
H(3)—C(3)—H(4) | 94.98 (2) | C(21)—C(22)—H(23) | 145.71 (2) |
H(3)—C(3)—H(7B) | 104.93 (2) | C(23)—C(22)—H(21) | 145.62 (2) |
H(3)—C(3)—H(7A) | 103.51 (2) | C(23)—C(22)—H(22) | 120.53 (2) |
H(4)—C(3)—H(7B) | 92.168 (13) | C(23)—C(22)—H(23) | 25.742 (13) |
H(4)—C(3)—H(7A) | 139.059 (17) | H(21)—C(22)—H(22) | 93.809 (17) |
H(7B)—C(3)—H(7A) | 48.019 (7) | H(21)—C(22)—H(23) | 171.262 (14) |
RH(1)—C(4)—C(2) | 59.000 (11) | H(22)—C(22)—H(23) | 94.787 (16) |
RH(1)—C(4)—C(3) | 98.54 (2) | C(22)—C(23)—C(24) | 119.68 (2) |
RH(1)—C(4)—C(5) | 70.250 (17) | C(22)—C(23)—H(22) | 25.544 (12) |
RH(1)—C(4)—C(6) | 76.828 (12) | C(22)—C(23)—H(23) | 120.05 (3) |
RH(1)—C(4)—C(7) | 106.690 (15) | C(22)—C(23)—H(24) | 145.51 (2) |
RH(1)—C(4)—H(3) | 111.537 (14) | C(24)—C(23)—H(22) | 145.20 (2) |
RH(1)—C(4)—H(4) | 116.73 (2) | C(24)—C(23)—H(23) | 120.26 (3) |
RH(1)—C(4)—H(5) | 79.709 (10) | C(24)—C(23)—H(24) | 25.831 (12) |
C(2)—C(4)—C(3) | 39.583 (16) | H(22)—C(23)—H(23) | 94.51 (2) |
C(2)—C(4)—C(5) | 89.56 (2) | H(22)—C(23)—H(24) | 171.013 (14) |
C(2)—C(4)—C(6) | 59.348 (13) | H(23)—C(23)—H(24) | 94.441 (19) |
C(2)—C(4)—C(7) | 60.116 (14) | C(23)—C(24)—C(25) | 120.54 (2) |
C(2)—C(4)—H(3) | 57.602 (11) | C(23)—C(24)—H(23) | 25.735 (13) |
C(2)—C(4)—H(4) | 143.46 (3) | C(23)—C(24)—H(24) | 120.03 (3) |
C(2)—C(4)—H(5) | 111.812 (14) | C(23)—C(24)—H(25) | 146.03 (2) |
C(3)—C(4)—C(5) | 105.71 (2) | C(25)—C(24)—H(23) | 146.26 (2) |
C(3)—C(4)—C(6) | 66.928 (18) | C(25)—C(24)—H(24) | 119.37 (3) |
C(3)—C(4)—C(7) | 39.704 (16) | C(25)—C(24)—H(25) | 25.625 (12) |
C(3)—C(4)—H(3) | 25.514 (13) | H(23)—C(24)—H(24) | 94.306 (17) |
C(3)—C(4)—H(4) | 125.03 (3) | H(23)—C(24)—H(25) | 171.447 (15) |
C(3)—C(4)—H(5) | 125.93 (2) | H(24)—C(24)—H(25) | 93.756 (18) |
C(5)—C(4)—C(6) | 38.778 (16) | C(20)—C(25)—C(24) | 120.07 (2) |
C(5)—C(4)—C(7) | 72.486 (19) | C(20)—C(25)—H(24) | 146.09 (2) |
C(5)—C(4)—H(3) | 130.16 (2) | C(20)—C(25)—H(25) | 119.52 (2) |
C(5)—C(4)—H(4) | 124.72 (3) | C(24)—C(25)—H(24) | 26.029 (13) |
C(5)—C(4)—H(5) | 22.738 (14) | C(24)—C(25)—H(25) | 120.34 (2) |
C(6)—C(4)—C(7) | 38.045 (12) | H(24)—C(25)—H(25) | 94.326 (15) |
C(6)—C(4)—H(3) | 91.685 (14) | C(1)—H(1)—C(2) | 30.088 (19) |
C(6)—C(4)—H(4) | 156.68 (3) | C(1)—H(1)—C(6) | 31.280 (18) |
C(6)—C(4)—H(5) | 60.038 (11) | C(2)—H(1)—C(6) | 61.367 (11) |
C(7)—C(4)—H(3) | 59.071 (11) | C(1)—H(2)—C(2) | 29.402 (19) |
C(7)—C(4)—H(4) | 136.44 (2) | C(1)—H(2)—C(3) | 61.542 (11) |
C(7)—C(4)—H(5) | 88.468 (14) | C(1)—H(2)—H(18)i | 96.512 (7) |
H(3)—C(4)—H(4) | 99.723 (19) | C(2)—H(2)—C(3) | 32.707 (19) |
H(3)—C(4)—H(5) | 147.286 (14) | C(2)—H(2)—H(18)i | 101.831 (16) |
H(4)—C(4)—H(5) | 101.99 (2) | C(3)—H(2)—H(18)i | 96.244 (8) |
RH(1)—C(5)—C(1) | 59.018 (11) | C(2)—H(3)—C(3) | 38.50 (2) |
RH(1)—C(5)—C(3) | 77.160 (13) | C(2)—H(3)—C(4) | 63.520 (11) |
RH(1)—C(5)—C(4) | 70.473 (17) | C(2)—H(3)—C(7) | 63.372 (12) |
RH(1)—C(5)—C(6) | 98.468 (19) | C(2)—H(3)—H(12)ii | 97.659 (8) |
RH(1)—C(5)—C(7) | 106.980 (15) | C(2)—H(3)—H(13)ii | 136.024 (8) |
RH(1)—C(5)—H(4) | 79.701 (10) | C(3)—H(3)—C(4) | 37.226 (19) |
RH(1)—C(5)—H(5) | 118.47 (2) | C(3)—H(3)—C(7) | 36.117 (18) |
RH(1)—C(5)—H(6) | 113.093 (14) | C(3)—H(3)—H(12)ii | 126.862 (17) |
C(1)—C(5)—C(3) | 59.330 (14) | C(3)—H(3)—H(13)ii | 121.788 (18) |
C(1)—C(5)—C(4) | 89.67 (2) | C(4)—H(3)—C(7) | 62.923 (11) |
C(1)—C(5)—C(6) | 39.511 (15) | C(4)—H(3)—H(12)ii | 108.442 (8) |
C(1)—C(5)—C(7) | 60.065 (14) | C(4)—H(3)—H(13)ii | 84.812 (8) |
C(1)—C(5)—H(4) | 112.846 (15) | C(7)—H(3)—H(12)ii | 160.956 (8) |
C(1)—C(5)—H(5) | 141.42 (2) | C(7)—H(3)—H(13)ii | 129.231 (9) |
C(1)—C(5)—H(6) | 59.281 (11) | H(12)ii—H(3)—H(13)ii | 62.7546 |
C(3)—C(5)—C(4) | 39.030 (17) | C(3)—H(4)—C(4) | 32.488 (18) |
C(3)—C(5)—C(6) | 67.062 (18) | C(3)—H(4)—C(5) | 61.876 (11) |
C(3)—C(5)—C(7) | 38.166 (12) | C(3)—H(4)—H(15) | 94.161 (8) |
C(3)—C(5)—H(4) | 61.587 (11) | C(4)—H(4)—C(5) | 31.408 (19) |
C(3)—C(5)—H(5) | 157.68 (2) | C(4)—H(4)—H(15) | 101.601 (16) |
C(3)—C(5)—H(6) | 92.384 (13) | C(5)—H(4)—H(15) | 119.083 (7) |
C(4)—C(5)—C(6) | 106.09 (3) | C(4)—H(5)—C(5) | 29.848 (18) |
C(4)—C(5)—C(7) | 72.902 (19) | C(4)—H(5)—C(6) | 62.222 (11) |
C(4)—C(5)—H(4) | 23.873 (15) | C(4)—H(5)—H(9) | 120.597 (8) |
C(4)—C(5)—H(5) | 127.41 (3) | C(5)—H(5)—C(6) | 34.546 (17) |
C(4)—C(5)—H(6) | 130.96 (2) | C(5)—H(5)—H(9) | 132.225 (15) |
C(6)—C(5)—C(7) | 39.766 (16) | C(6)—H(5)—H(9) | 145.388 (8) |
C(6)—C(5)—H(4) | 127.71 (2) | C(1)—H(6)—C(5) | 63.351 (11) |
C(6)—C(5)—H(5) | 121.59 (3) | C(1)—H(6)—C(6) | 36.099 (19) |
C(6)—C(5)—H(6) | 26.511 (13) | C(1)—H(6)—C(7) | 62.855 (12) |
C(7)—C(5)—H(4) | 90.239 (14) | C(5)—H(6)—C(6) | 38.725 (18) |
C(7)—C(5)—H(5) | 134.04 (2) | C(5)—H(6)—C(7) | 63.548 (11) |
C(7)—C(5)—H(6) | 59.049 (11) | C(6)—H(6)—C(7) | 36.985 (18) |
H(4)—C(5)—H(5) | 103.55 (2) | C(3)—H(7B)—C(6) | 60.990 (11) |
H(4)—C(5)—H(6) | 148.682 (15) | C(3)—H(7B)—C(7) | 40.047 (19) |
H(5)—C(5)—H(6) | 95.157 (18) | C(3)—H(7B)—H(7A) | 65.614 (9) |
C(1)—C(6)—C(2) | 34.437 (15) | C(6)—H(7B)—C(7) | 39.13 (2) |
C(1)—C(6)—C(3) | 73.405 (19) | C(6)—H(7B)—H(7A) | 65.955 (8) |
C(1)—C(6)—C(4) | 87.221 (18) | C(7)—H(7B)—H(7A) | 35.009 (17) |
C(1)—C(6)—C(5) | 100.89 (2) | C(3)—H(7A)—C(6) | 61.314 (11) |
C(1)—C(6)—C(7) | 100.84 (3) | C(3)—H(7A)—C(7) | 40.69 (2) |
C(1)—C(6)—H(1) | 21.790 (13) | C(3)—H(7A)—H(7B) | 66.367 (9) |
C(1)—C(6)—H(5) | 116.714 (19) | C(6)—H(7A)—C(7) | 39.56 (2) |
C(1)—C(6)—H(6) | 118.99 (3) | C(6)—H(7A)—H(7B) | 66.441 (8) |
C(1)—C(6)—H(7B) | 126.80 (2) | C(7)—H(7A)—H(7B) | 35.010 (18) |
C(1)—C(6)—H(7A) | 88.741 (19) | C(8)—H(9)—C(9) | 35.631 (14) |
C(2)—C(6)—C(3) | 38.968 (13) | C(8)—H(9)—C(10) | 68.954 (9) |
C(2)—C(6)—C(4) | 60.509 (13) | C(8)—H(9)—H(5) | 86.694 (6) |
C(2)—C(6)—C(5) | 87.689 (18) | C(9)—H(9)—C(10) | 33.324 (15) |
C(2)—C(6)—C(7) | 72.183 (19) | C(9)—H(9)—H(5) | 90.590 (13) |
C(2)—C(6)—H(1) | 56.227 (11) | C(10)—H(9)—H(5) | 94.376 (7) |
C(2)—C(6)—H(5) | 110.832 (14) | C(9)—H(10)—C(10) | 34.098 (16) |
C(2)—C(6)—H(6) | 151.13 (3) | C(9)—H(10)—C(11) | 68.283 (10) |
C(2)—C(6)—H(7B) | 95.249 (14) | C(10)—H(10)—C(11) | 34.185 (16) |
C(2)—C(6)—H(7A) | 71.507 (12) | C(10)—H(11)—C(11) | 33.527 (17) |
C(3)—C(6)—C(4) | 38.931 (12) | C(10)—H(11)—C(12) | 68.433 (10) |
C(3)—C(6)—C(5) | 74.061 (18) | C(11)—H(11)—C(12) | 34.908 (17) |
C(3)—C(6)—C(7) | 43.125 (16) | C(11)—H(12)—C(12) | 34.195 (16) |
C(3)—C(6)—H(1) | 95.194 (15) | C(11)—H(12)—C(13) | 68.543 (10) |
C(3)—C(6)—H(5) | 96.108 (14) | C(11)—H(12)—H(3)ii | 149.067 (7) |
C(3)—C(6)—H(6) | 160.76 (2) | C(12)—H(12)—C(13) | 34.364 (16) |
C(3)—C(6)—H(7B) | 59.158 (12) | C(12)—H(12)—H(3)ii | 116.929 (15) |
C(3)—C(6)—H(7A) | 58.897 (11) | C(13)—H(12)—H(3)ii | 83.321 (6) |
C(4)—C(6)—C(5) | 35.130 (15) | C(8)—H(13)—C(12) | 68.707 (9) |
C(4)—C(6)—C(7) | 71.620 (18) | C(8)—H(13)—C(13) | 34.039 (14) |
C(4)—C(6)—H(1) | 104.696 (13) | C(8)—H(13)—H(3)ii | 148.518 (6) |
C(4)—C(6)—H(5) | 57.739 (11) | C(12)—H(13)—C(13) | 34.670 (14) |
C(4)—C(6)—H(6) | 147.04 (3) | C(12)—H(13)—H(3)ii | 84.060 (7) |
C(4)—C(6)—H(7B) | 71.268 (12) | C(13)—H(13)—H(3)ii | 117.200 (13) |
C(4)—C(6)—H(7A) | 94.791 (14) | C(14)—H(15)—C(15) | 33.297 (14) |
C(5)—C(6)—C(7) | 100.66 (2) | C(14)—H(15)—C(16) | 68.827 (10) |
C(5)—C(6)—H(1) | 107.870 (18) | C(14)—H(15)—H(4) | 107.583 (6) |
C(5)—C(6)—H(5) | 23.867 (13) | C(15)—H(15)—C(16) | 35.542 (15) |
C(5)—C(6)—H(6) | 114.76 (3) | C(15)—H(15)—H(4) | 133.468 (15) |
C(5)—C(6)—H(7B) | 88.662 (18) | C(16)—H(15)—H(4) | 149.271 (9) |
C(5)—C(6)—H(7A) | 126.89 (2) | C(15)—H(16)—C(16) | 33.837 (16) |
C(7)—C(6)—H(1) | 118.40 (2) | C(15)—H(16)—C(17) | 68.484 (10) |
C(7)—C(6)—H(5) | 112.50 (2) | C(16)—H(16)—C(17) | 34.690 (16) |
C(7)—C(6)—H(6) | 117.70 (3) | C(16)—H(17)—C(17) | 34.970 (18) |
C(7)—C(6)—H(7B) | 26.651 (15) | C(16)—H(17)—C(18) | 68.133 (11) |
C(7)—C(6)—H(7A) | 26.912 (14) | C(16)—H(17)—H(24)iii | 123.868 (7) |
H(1)—C(6)—H(5) | 115.470 (13) | C(17)—H(17)—C(18) | 33.168 (18) |
H(1)—C(6)—H(6) | 97.865 (19) | C(17)—H(17)—H(24)iii | 153.937 (16) |
H(1)—C(6)—H(7B) | 145.027 (15) | C(18)—H(17)—H(24)iii | 157.927 (7) |
H(1)—C(6)—H(7A) | 99.983 (13) | C(17)—H(18)—C(18) | 34.515 (16) |
H(5)—C(6)—H(6) | 90.975 (19) | C(17)—H(18)—C(19) | 68.528 (10) |
H(5)—C(6)—H(7B) | 92.225 (12) | C(17)—H(18)—H(2)iv | 150.425 (8) |
H(5)—C(6)—H(7A) | 138.873 (15) | C(18)—H(18)—C(19) | 34.025 (16) |
H(6)—C(6)—H(7B) | 102.814 (19) | C(18)—H(18)—H(2)iv | 151.700 (15) |
H(6)—C(6)—H(7A) | 104.716 (19) | C(19)—H(18)—H(2)iv | 125.422 (7) |
H(7B)—C(6)—H(7A) | 47.604 (6) | C(14)—H(19)—C(18) | 68.781 (9) |
C(1)—C(7)—C(2) | 33.809 (11) | C(14)—H(19)—C(19) | 35.203 (14) |
C(1)—C(7)—C(3) | 69.647 (18) | C(14)—H(19)—C(21) | 98.371 (9) |
C(1)—C(7)—C(4) | 70.789 (13) | C(14)—H(19)—H(21) | 94.205 (6) |
C(1)—C(7)—C(5) | 59.902 (13) | C(18)—H(19)—C(19) | 33.582 (14) |
C(1)—C(7)—C(6) | 39.440 (16) | C(18)—H(19)—C(21) | 160.199 (10) |
C(1)—C(7)—H(3) | 90.554 (14) | C(18)—H(19)—H(21) | 135.276 (8) |
C(1)—C(7)—H(6) | 58.704 (11) | C(19)—H(19)—C(21) | 132.057 (14) |
C(1)—C(7)—H(7B) | 152.08 (3) | C(19)—H(19)—H(21) | 119.155 (14) |
C(1)—C(7)—H(7A) | 93.43 (2) | C(21)—H(19)—H(21) | 27.157 (6) |
C(2)—C(7)—C(3) | 39.355 (17) | C(20)—H(21)—C(21) | 34.883 (14) |
C(2)—C(7)—C(4) | 59.740 (13) | C(20)—H(21)—C(22) | 68.795 (10) |
C(2)—C(7)—C(5) | 70.710 (13) | C(20)—H(21)—H(19) | 74.659 (6) |
C(2)—C(7)—C(6) | 69.614 (18) | C(21)—H(21)—C(22) | 33.913 (15) |
C(2)—C(7)—H(3) | 57.147 (11) | C(21)—H(21)—H(19) | 84.004 (13) |
C(2)—C(7)—H(6) | 91.940 (14) | C(22)—H(21)—H(19) | 94.693 (7) |
C(2)—C(7)—H(7B) | 150.87 (3) | C(21)—H(22)—C(22) | 34.471 (16) |
C(2)—C(7)—H(7A) | 92.90 (2) | C(21)—H(22)—C(23) | 68.390 (10) |
C(3)—C(7)—C(4) | 39.559 (17) | C(22)—H(22)—C(23) | 33.929 (16) |
C(3)—C(7)—C(5) | 70.349 (18) | C(22)—H(23)—C(23) | 34.209 (19) |
C(3)—C(7)—C(6) | 93.82 (2) | C(22)—H(23)—C(24) | 68.210 (10) |
C(3)—C(7)—H(3) | 24.733 (13) | C(23)—H(23)—C(24) | 34.007 (19) |
C(3)—C(7)—H(6) | 119.11 (2) | C(23)—H(24)—C(24) | 34.142 (17) |
C(3)—C(7)—H(7B) | 112.78 (3) | C(23)—H(24)—C(25) | 68.716 (10) |
C(3)—C(7)—H(7A) | 111.74 (3) | C(23)—H(24)—H(17)v | 122.583 (7) |
C(4)—C(7)—C(5) | 34.612 (11) | C(24)—H(24)—C(25) | 34.601 (17) |
C(4)—C(7)—C(6) | 70.335 (17) | C(24)—H(24)—H(17)v | 145.291 (15) |
C(4)—C(7)—H(3) | 58.006 (11) | C(25)—H(24)—H(17)v | 146.610 (7) |
C(4)—C(7)—H(6) | 91.582 (14) | C(20)—H(25)—C(24) | 68.507 (9) |
C(4)—C(7)—H(7B) | 93.36 (2) | C(20)—H(25)—C(25) | 34.502 (14) |
C(4)—C(7)—H(7A) | 150.16 (3) | C(24)—H(25)—C(25) | 34.031 (15) |
Symmetry codes: (i) x−1, y, z; (ii) −x+2, −y+2, −z+1; (iii) x, y, z−1; (iv) x+1, y, z; (v) x, y, z+1. |
Experimental details
Crystal data |
Chemical formula | C25H23ClPRh |
Mr | 492.76 |
Crystal system, space group | Triclinic, P1 |
Temperature (K) | 100 |
a, b, c (Å) | 10.2430 (1), 10.4042 (1), 11.4078 (1) |
α, β, γ (°) | 99.213 (1), 103.131 (1), 115.080 (1) |
V (Å3) | 1026.01 (2) |
Z | 2 |
Radiation type | Mo Kα |
µ (mm−1) | 1.05 |
Crystal size (mm) | × × |
|
Data collection |
Diffractometer | Nonius Kappa CCD diffractometer |
Absorption correction | – |
No. of measured, independent and observed [I > 3 σ(I)] reflections | 370693, 21647, 19920 |
Rint | 0.038 |
(sin θ/λ)max (Å−1) | 1.080 |
|
Refinement |
R[F2 > 2σ(F2)], wR(F2), S | 0.012, 0.012, 1.35 |
No. of reflections | 19920 |
No. of parameters | 514 |
H-atom treatment | Only H-atom displacement parameters refined |
Δρmax, Δρmin (e Å−3) | 0.20, −0.21 |
Selected geometric parameters (Å, º) topRH(1)—CL(1) | 2.3625 (1) | C(10)—H(10) | 1.0800 (3) |
RH(1)—P(1) | 2.3034 (1) | C(10)—H(11) | 2.1638 (3) |
RH(1)—C(1) | 2.2193 (3) | C(11)—C(12) | 1.3948 (4) |
RH(1)—C(2) | 2.2192 (3) | C(11)—H(10) | 2.1520 (3) |
RH(1)—C(4) | 2.1087 (3) | C(11)—H(11) | 1.0800 (3) |
RH(1)—C(5) | 2.1058 (3) | C(11)—H(12) | 2.1491 (3) |
P(1)—C(8) | 1.8322 (2) | C(12)—C(13) | 1.3972 (4) |
P(1)—C(14) | 1.8287 (2) | C(12)—H(11) | 2.1361 (3) |
P(1)—C(20) | 1.8242 (2) | C(12)—H(12) | 1.0800 (3) |
C(1)—C(2) | 1.3845 (4) | C(12)—H(13) | 2.1432 (3) |
C(1)—C(3) | 2.3443 (4) | C(13)—H(12) | 2.1488 (2) |
C(1)—C(5) | 2.3748 (4) | C(13)—H(13) | 1.0800 (2) |
C(1)—C(6) | 1.5386 (4) | C(14)—C(15) | 1.4021 (3) |
C(1)—C(7) | 2.3788 (5) | C(14)—C(19) | 1.3995 (3) |
C(1)—H(1) | 1.1000 (3) | C(14)—H(15) | 2.1733 (2) |
C(1)—H(2) | 2.2332 (3) | C(14)—H(19) | 2.1358 (2) |
C(1)—H(6) | 2.2843 (3) | C(15)—C(16) | 1.3947 (4) |
C(2)—C(3) | 1.5390 (5) | C(15)—H(15) | 1.0800 (3) |
C(2)—C(4) | 2.3736 (5) | C(15)—H(16) | 2.1554 (2) |
C(2)—C(6) | 2.3459 (4) | C(16)—C(17) | 1.3918 (4) |
C(2)—C(7) | 2.3827 (5) | C(16)—H(15) | 2.1241 (3) |
C(2)—H(1) | 2.2218 (3) | C(16)—H(16) | 1.0800 (3) |
C(2)—H(2) | 1.1000 (3) | C(16)—H(17) | 2.1315 (3) |
C(2)—H(3) | 2.2391 (3) | C(17)—C(18) | 1.3899 (4) |
C(3)—C(4) | 1.5449 (5) | C(17)—H(16) | 2.1367 (3) |
C(3)—C(5) | 2.3617 (5) | C(17)—H(17) | 1.0800 (3) |
C(3)—C(6) | 2.2619 (4) | C(17)—H(18) | 2.1378 (3) |
C(3)—C(7) | 1.5497 (4) | C(18)—C(19) | 1.3944 (3) |
C(3)—H(2) | 2.3452 (4) | C(18)—H(17) | 2.1621 (3) |
C(3)—H(3) | 1.1000 (3) | C(18)—H(18) | 1.0800 (3) |
C(3)—H(4) | 2.3554 (3) | C(18)—H(19) | 2.1596 (3) |
C(3)—H(7B) | 2.2207 (3) | C(19)—H(18) | 2.1517 (2) |
C(3)—H(7A) | 2.2078 (3) | C(19)—H(19) | 1.0800 (3) |
C(4)—C(5) | 1.4164 (4) | C(20)—C(21) | 1.4065 (3) |
C(4)—C(6) | 2.3650 (4) | C(20)—C(25) | 1.3968 (3) |
C(4)—C(7) | 2.3834 (4) | C(20)—H(21) | 2.1496 (2) |
C(4)—H(3) | 2.2702 (3) | C(20)—H(25) | 2.1458 (2) |
C(4)—H(4) | 1.1000 (3) | C(21)—C(22) | 1.3915 (4) |
C(4)—H(5) | 2.2604 (3) | C(21)—H(19) | 2.3533 (2) |
C(5)—C(6) | 1.5416 (4) | C(21)—H(21) | 1.0800 (2) |
C(5)—C(7) | 2.3780 (4) | C(21)—H(22) | 2.1404 (2) |
C(5)—H(4) | 2.2341 (3) | C(22)—C(23) | 1.3980 (4) |
C(5)—H(5) | 1.1000 (3) | C(22)—H(21) | 2.1505 (3) |
C(5)—H(6) | 2.2377 (3) | C(22)—H(22) | 1.0800 (3) |
C(6)—C(7) | 1.5478 (5) | C(22)—H(23) | 2.1524 (3) |
C(6)—H(1) | 2.3688 (3) | C(23)—C(24) | 1.3911 (4) |
C(6)—H(5) | 2.3158 (3) | C(23)—H(22) | 2.1575 (3) |
C(6)—H(6) | 1.1000 (3) | C(23)—H(23) | 1.0800 (3) |
C(6)—H(7B) | 2.2366 (3) | C(23)—H(24) | 2.1460 (3) |
C(6)—H(7A) | 2.2282 (3) | C(24)—C(25) | 1.3976 (4) |
C(7)—H(3) | 2.2961 (3) | C(24)—H(23) | 2.1484 (3) |
C(7)—H(6) | 2.2779 (3) | C(24)—H(24) | 1.0800 (3) |
C(7)—H(7B) | 1.1000 (4) | C(24)—H(25) | 2.1552 (3) |
C(7)—H(7A) | 1.1000 (3) | C(25)—H(24) | 2.1448 (2) |
C(8)—C(9) | 1.4059 (3) | C(25)—H(25) | 1.0800 (3) |
C(8)—C(13) | 1.3991 (3) | H(2)—H(18)i | 2.3520 |
C(8)—H(9) | 2.1351 (2) | H(3)—H(12)ii | 2.3707 |
C(8)—H(13) | 2.1567 (2) | H(3)—H(13)ii | 2.3576 |
C(9)—C(10) | 1.3952 (4) | H(4)—H(15) | 2.3572 |
C(9)—H(9) | 1.0800 (2) | H(5)—H(9) | 2.3031 |
C(9)—H(10) | 2.1513 (2) | H(7B)—H(7A) | 1.8019 |
C(10)—C(11) | 1.3972 (4) | H(17)—H(24)iii | 2.2004 |
C(10)—H(9) | 2.1652 (3) | H(19)—H(21) | 2.2067 |
| | | |
CL(1)—RH(1)—P(1) | 96.346 (2) | C(5)—C(7)—C(6) | 39.576 (16) |
CL(1)—RH(1)—C(1) | 93.758 (8) | C(5)—C(7)—H(3) | 91.996 (13) |
CL(1)—RH(1)—C(2) | 95.090 (9) | C(5)—C(7)—H(6) | 57.403 (11) |
CL(1)—RH(1)—C(4) | 157.369 (9) | C(5)—C(7)—H(7B) | 93.87 (2) |
CL(1)—RH(1)—C(5) | 154.088 (9) | C(5)—C(7)—H(7A) | 151.57 (3) |
P(1)—RH(1)—C(1) | 164.189 (9) | C(6)—C(7)—H(3) | 118.53 (2) |
P(1)—RH(1)—C(2) | 153.217 (9) | C(6)—C(7)—H(6) | 25.313 (12) |
P(1)—RH(1)—C(4) | 95.663 (9) | C(6)—C(7)—H(7B) | 114.22 (3) |
P(1)—RH(1)—C(5) | 99.964 (8) | C(6)—C(7)—H(7A) | 113.53 (3) |
C(1)—RH(1)—C(2) | 36.352 (11) | H(3)—C(7)—H(6) | 143.836 (15) |
C(1)—RH(1)—C(4) | 79.135 (12) | H(3)—C(7)—H(7B) | 100.47 (2) |
C(1)—RH(1)—C(5) | 66.548 (12) | H(3)—C(7)—H(7A) | 98.38 (2) |
C(2)—RH(1)—C(4) | 66.464 (13) | H(6)—C(7)—H(7B) | 100.40 (2) |
C(2)—RH(1)—C(5) | 79.078 (12) | H(6)—C(7)—H(7A) | 101.76 (2) |
C(4)—RH(1)—C(5) | 39.276 (12) | H(7B)—C(7)—H(7A) | 109.98 (3) |
RH(1)—P(1)—C(8) | 114.197 (8) | P(1)—C(8)—C(9) | 117.895 (18) |
RH(1)—P(1)—C(14) | 109.506 (8) | P(1)—C(8)—C(13) | 123.135 (18) |
RH(1)—P(1)—C(20) | 121.381 (8) | P(1)—C(8)—H(9) | 91.327 (10) |
C(8)—P(1)—C(14) | 104.183 (11) | P(1)—C(8)—H(13) | 97.534 (10) |
C(8)—P(1)—C(20) | 100.444 (11) | C(9)—C(8)—C(13) | 118.97 (2) |
C(14)—P(1)—C(20) | 105.455 (11) | C(9)—C(8)—H(9) | 26.584 (11) |
RH(1)—C(1)—C(2) | 71.819 (17) | C(9)—C(8)—H(13) | 144.565 (18) |
RH(1)—C(1)—C(3) | 75.419 (12) | C(13)—C(8)—H(9) | 145.537 (19) |
RH(1)—C(1)—C(5) | 54.435 (10) | C(13)—C(8)—H(13) | 25.600 (11) |
RH(1)—C(1)—C(6) | 93.981 (18) | H(9)—C(8)—H(13) | 171.133 (13) |
RH(1)—C(1)—C(7) | 103.305 (14) | C(8)—C(9)—C(10) | 120.70 (2) |
RH(1)—C(1)—H(1) | 102.015 (19) | C(8)—C(9)—H(9) | 117.78 (2) |
RH(1)—C(1)—H(2) | 78.416 (10) | C(8)—C(9)—H(10) | 146.415 (19) |
RH(1)—C(1)—H(6) | 107.179 (13) | C(10)—C(9)—H(9) | 121.51 (2) |
C(2)—C(1)—C(3) | 39.009 (18) | C(10)—C(9)—H(10) | 25.719 (12) |
C(2)—C(1)—C(5) | 90.27 (2) | H(9)—C(9)—H(10) | 95.800 (14) |
C(2)—C(1)—C(6) | 106.63 (3) | C(9)—C(10)—C(11) | 119.74 (2) |
C(2)—C(1)—C(7) | 73.25 (2) | C(9)—C(10)—H(9) | 25.167 (11) |
C(2)—C(1)—H(1) | 126.44 (3) | C(9)—C(10)—H(10) | 120.18 (2) |
C(2)—C(1)—H(2) | 22.957 (15) | C(9)—C(10)—H(11) | 145.011 (19) |
C(2)—C(1)—H(6) | 130.39 (2) | C(11)—C(10)—H(9) | 144.90 (2) |
C(3)—C(1)—C(5) | 60.057 (14) | C(11)—C(10)—H(10) | 120.07 (2) |
C(3)—C(1)—C(6) | 67.620 (18) | C(11)—C(10)—H(11) | 25.273 (13) |
C(3)—C(1)—C(7) | 38.299 (12) | H(9)—C(10)—H(10) | 95.025 (17) |
C(3)—C(1)—H(1) | 165.44 (3) | H(9)—C(10)—H(11) | 170.171 (13) |
C(3)—C(1)—H(2) | 61.581 (12) | H(10)—C(10)—H(11) | 94.802 (16) |
C(3)—C(1)—H(6) | 91.665 (14) | C(10)—C(11)—C(12) | 120.01 (2) |
C(5)—C(1)—C(6) | 39.603 (15) | C(10)—C(11)—H(10) | 25.741 (12) |
C(5)—C(1)—C(7) | 60.033 (13) | C(10)—C(11)—H(11) | 121.20 (3) |
C(5)—C(1)—H(1) | 130.30 (2) | C(10)—C(11)—H(12) | 145.74 (2) |
C(5)—C(1)—H(2) | 111.083 (14) | C(12)—C(11)—H(10) | 145.75 (2) |
C(5)—C(1)—H(6) | 57.368 (10) | C(12)—C(11)—H(11) | 118.79 (3) |
C(6)—C(1)—C(7) | 39.722 (16) | C(12)—C(11)—H(12) | 25.796 (12) |
C(6)—C(1)—H(1) | 126.93 (3) | H(10)—C(11)—H(11) | 95.460 (18) |
C(6)—C(1)—H(2) | 128.96 (2) | H(10)—C(11)—H(12) | 171.410 (15) |
C(6)—C(1)—H(6) | 24.912 (12) | H(11)—C(11)—H(12) | 93.045 (18) |
C(7)—C(1)—H(1) | 152.11 (2) | C(11)—C(12)—C(13) | 120.18 (2) |
C(7)—C(1)—H(2) | 92.517 (14) | C(11)—C(12)—H(11) | 26.302 (13) |
C(7)—C(1)—H(6) | 58.441 (11) | C(11)—C(12)—H(12) | 120.01 (2) |
H(1)—C(1)—H(2) | 103.87 (2) | C(11)—C(12)—H(13) | 146.25 (2) |
H(1)—C(1)—H(6) | 102.72 (2) | C(13)—C(12)—H(11) | 146.47 (2) |
H(2)—C(1)—H(6) | 150.947 (16) | C(13)—C(12)—H(12) | 119.77 (2) |
RH(1)—C(2)—C(1) | 71.829 (18) | C(13)—C(12)—H(13) | 26.084 (11) |
RH(1)—C(2)—C(3) | 94.267 (19) | H(11)—C(12)—H(12) | 93.758 (16) |
RH(1)—C(2)—C(4) | 54.536 (10) | H(11)—C(12)—H(13) | 172.420 (14) |
RH(1)—C(2)—C(6) | 75.191 (12) | H(12)—C(12)—H(13) | 93.734 (17) |
RH(1)—C(2)—C(7) | 103.183 (15) | C(8)—C(13)—C(12) | 120.39 (2) |
RH(1)—C(2)—H(1) | 74.054 (10) | C(8)—C(13)—H(12) | 146.203 (19) |
RH(1)—C(2)—H(2) | 111.47 (2) | C(8)—C(13)—H(13) | 120.36 (2) |
RH(1)—C(2)—H(3) | 108.641 (14) | C(12)—C(13)—H(12) | 25.867 (12) |
C(1)—C(2)—C(3) | 106.50 (3) | C(12)—C(13)—H(13) | 119.25 (2) |
C(1)—C(2)—C(4) | 90.49 (2) | H(12)—C(13)—H(13) | 93.427 (14) |
C(1)—C(2)—C(6) | 38.935 (18) | P(1)—C(14)—C(15) | 117.357 (18) |
C(1)—C(2)—C(7) | 72.94 (2) | P(1)—C(14)—C(19) | 123.988 (18) |
C(1)—C(2)—H(1) | 23.472 (15) | P(1)—C(14)—H(15) | 92.410 (10) |
C(1)—C(2)—H(2) | 127.64 (3) | P(1)—C(14)—H(19) | 97.574 (10) |
C(1)—C(2)—H(3) | 131.47 (2) | C(15)—C(14)—C(19) | 118.65 (2) |
C(3)—C(2)—C(4) | 39.767 (16) | C(15)—C(14)—H(15) | 25.015 (11) |
C(3)—C(2)—C(6) | 67.566 (18) | C(15)—C(14)—H(19) | 145.068 (18) |
C(3)—C(2)—C(7) | 39.682 (16) | C(19)—C(14)—H(15) | 143.569 (18) |
C(3)—C(2)—H(1) | 129.97 (2) | C(19)—C(14)—H(19) | 26.415 (11) |
C(3)—C(2)—H(2) | 124.57 (3) | H(15)—C(14)—H(19) | 169.814 (12) |
C(3)—C(2)—H(3) | 26.421 (13) | C(14)—C(15)—C(16) | 120.58 (2) |
C(4)—C(2)—C(6) | 60.143 (13) | C(14)—C(15)—H(15) | 121.69 (2) |
C(4)—C(2)—C(7) | 60.145 (14) | C(14)—C(15)—H(16) | 146.080 (19) |
C(4)—C(2)—H(1) | 109.244 (15) | C(16)—C(15)—H(15) | 117.70 (2) |
C(4)—C(2)—H(2) | 135.74 (2) | C(16)—C(15)—H(16) | 25.544 (13) |
C(4)—C(2)—H(3) | 58.878 (11) | H(15)—C(15)—H(16) | 92.161 (15) |
C(6)—C(2)—C(7) | 38.203 (12) | C(15)—C(16)—C(17) | 120.17 (3) |
C(6)—C(2)—H(1) | 62.406 (11) | C(15)—C(16)—H(15) | 26.753 (12) |
C(6)—C(2)—H(2) | 164.02 (3) | C(15)—C(16)—H(16) | 120.62 (3) |
C(6)—C(2)—H(3) | 92.977 (14) | C(15)—C(16)—H(17) | 146.57 (2) |
C(7)—C(2)—H(1) | 94.771 (14) | C(17)—C(16)—H(15) | 146.86 (2) |
C(7)—C(2)—H(2) | 143.71 (2) | C(17)—C(16)—H(16) | 119.10 (2) |
C(7)—C(2)—H(3) | 59.482 (12) | C(17)—C(16)—H(17) | 26.408 (12) |
H(1)—C(2)—H(2) | 104.56 (2) | H(15)—C(16)—H(16) | 93.867 (18) |
H(1)—C(2)—H(3) | 154.227 (16) | H(15)—C(16)—H(17) | 173.023 (15) |
H(2)—C(2)—H(3) | 98.23 (2) | H(16)—C(16)—H(17) | 92.719 (16) |
C(1)—C(3)—C(2) | 34.491 (15) | C(16)—C(17)—C(18) | 119.69 (2) |
C(1)—C(3)—C(4) | 87.826 (19) | C(16)—C(17)—H(16) | 26.209 (13) |
C(1)—C(3)—C(5) | 60.613 (13) | C(16)—C(17)—H(17) | 118.62 (3) |
C(1)—C(3)—C(6) | 38.975 (12) | C(16)—C(17)—H(18) | 145.81 (2) |
C(1)—C(3)—C(7) | 72.054 (19) | C(18)—C(17)—H(16) | 145.80 (2) |
C(1)—C(3)—H(2) | 56.877 (11) | C(18)—C(17)—H(17) | 121.67 (3) |
C(1)—C(3)—H(3) | 147.10 (3) | C(18)—C(17)—H(18) | 26.122 (12) |
C(1)—C(3)—H(4) | 109.614 (14) | H(16)—C(17)—H(17) | 92.438 (18) |
C(1)—C(3)—H(7B) | 95.873 (14) | H(16)—C(17)—H(18) | 171.848 (14) |
C(1)—C(3)—H(7A) | 72.061 (12) | H(17)—C(17)—H(18) | 95.572 (18) |
C(2)—C(3)—C(4) | 100.65 (2) | C(17)—C(18)—C(19) | 120.32 (2) |
C(2)—C(3)—C(5) | 87.178 (19) | C(17)—C(18)—H(17) | 25.158 (12) |
C(2)—C(3)—C(6) | 73.465 (19) | C(17)—C(18)—H(18) | 119.36 (2) |
C(2)—C(3)—C(7) | 100.96 (3) | C(17)—C(18)—H(19) | 145.68 (2) |
C(2)—C(3)—H(2) | 22.719 (13) | C(19)—C(18)—H(17) | 145.47 (2) |
C(2)—C(3)—H(3) | 115.08 (3) | C(19)—C(18)—H(18) | 120.29 (3) |
C(2)—C(3)—H(4) | 115.52 (2) | C(19)—C(18)—H(19) | 25.368 (12) |
C(2)—C(3)—H(7B) | 127.55 (2) | H(17)—C(18)—H(18) | 94.225 (15) |
C(2)—C(3)—H(7A) | 89.239 (19) | H(17)—C(18)—H(19) | 170.833 (14) |
C(4)—C(3)—C(5) | 35.264 (15) | H(18)—C(18)—H(19) | 94.927 (17) |
C(4)—C(3)—C(6) | 74.140 (18) | C(14)—C(19)—C(18) | 120.56 (2) |
C(4)—C(3)—C(7) | 100.74 (3) | C(14)—C(19)—H(18) | 146.218 (19) |
C(4)—C(3)—H(2) | 111.85 (2) | C(14)—C(19)—H(19) | 118.38 (2) |
C(4)—C(3)—H(3) | 117.26 (3) | C(18)—C(19)—H(18) | 25.684 (13) |
C(4)—C(3)—H(4) | 22.484 (13) | C(18)—C(19)—H(19) | 121.05 (2) |
C(4)—C(3)—H(7B) | 89.00 (2) | H(18)—C(19)—H(19) | 95.369 (15) |
C(4)—C(3)—H(7A) | 127.76 (2) | P(1)—C(20)—C(21) | 120.675 (18) |
C(5)—C(3)—C(6) | 38.877 (12) | P(1)—C(20)—C(25) | 120.184 (19) |
C(5)—C(3)—C(7) | 71.484 (19) | P(1)—C(20)—H(21) | 94.642 (10) |
C(5)—C(3)—H(2) | 107.684 (14) | P(1)—C(20)—H(25) | 94.226 (10) |
C(5)—C(3)—H(3) | 150.44 (3) | C(21)—C(20)—C(25) | 119.14 (2) |
C(5)—C(3)—H(4) | 56.537 (11) | C(21)—C(20)—H(21) | 26.050 (11) |
C(5)—C(3)—H(7B) | 71.713 (12) | C(21)—C(20)—H(25) | 145.093 (18) |
C(5)—C(3)—H(7A) | 95.576 (14) | C(25)—C(20)—H(21) | 145.153 (19) |
C(6)—C(3)—C(7) | 43.059 (16) | C(25)—C(20)—H(25) | 25.974 (12) |
C(6)—C(3)—H(2) | 95.728 (15) | H(21)—C(20)—H(25) | 171.127 (12) |
C(6)—C(3)—H(3) | 162.13 (3) | C(20)—C(21)—C(22) | 120.50 (2) |
C(6)—C(3)—H(4) | 94.937 (15) | C(20)—C(21)—H(19) | 85.357 (14) |
C(6)—C(3)—H(7B) | 59.852 (11) | C(20)—C(21)—H(21) | 119.07 (2) |
C(6)—C(3)—H(7A) | 59.789 (11) | C(20)—C(21)—H(22) | 146.558 (19) |
C(7)—C(3)—H(2) | 116.22 (2) | C(22)—C(21)—H(19) | 115.279 (18) |
C(7)—C(3)—H(3) | 119.15 (3) | C(22)—C(21)—H(21) | 120.43 (2) |
C(7)—C(3)—H(4) | 112.05 (2) | C(22)—C(21)—H(22) | 26.059 (13) |
C(7)—C(3)—H(7B) | 27.175 (15) | H(19)—C(21)—H(21) | 68.839 (12) |
C(7)—C(3)—H(7A) | 27.569 (15) | H(19)—C(21)—H(22) | 108.001 (10) |
H(2)—C(3)—H(3) | 92.43 (2) | H(21)—C(21)—H(22) | 94.367 (15) |
H(2)—C(3)—H(4) | 118.912 (13) | C(21)—C(22)—C(23) | 119.98 (2) |
H(2)—C(3)—H(7B) | 143.104 (16) | C(21)—C(22)—H(21) | 25.661 (12) |
H(2)—C(3)—H(7A) | 96.708 (13) | C(21)—C(22)—H(22) | 119.47 (3) |
H(3)—C(3)—H(4) | 94.98 (2) | C(21)—C(22)—H(23) | 145.71 (2) |
H(3)—C(3)—H(7B) | 104.93 (2) | C(23)—C(22)—H(21) | 145.62 (2) |
H(3)—C(3)—H(7A) | 103.51 (2) | C(23)—C(22)—H(22) | 120.53 (2) |
H(4)—C(3)—H(7B) | 92.168 (13) | C(23)—C(22)—H(23) | 25.742 (13) |
H(4)—C(3)—H(7A) | 139.059 (17) | H(21)—C(22)—H(22) | 93.809 (17) |
H(7B)—C(3)—H(7A) | 48.019 (7) | H(21)—C(22)—H(23) | 171.262 (14) |
RH(1)—C(4)—C(2) | 59.000 (11) | H(22)—C(22)—H(23) | 94.787 (16) |
RH(1)—C(4)—C(3) | 98.54 (2) | C(22)—C(23)—C(24) | 119.68 (2) |
RH(1)—C(4)—C(5) | 70.250 (17) | C(22)—C(23)—H(22) | 25.544 (12) |
RH(1)—C(4)—C(6) | 76.828 (12) | C(22)—C(23)—H(23) | 120.05 (3) |
RH(1)—C(4)—C(7) | 106.690 (15) | C(22)—C(23)—H(24) | 145.51 (2) |
RH(1)—C(4)—H(3) | 111.537 (14) | C(24)—C(23)—H(22) | 145.20 (2) |
RH(1)—C(4)—H(4) | 116.73 (2) | C(24)—C(23)—H(23) | 120.26 (3) |
RH(1)—C(4)—H(5) | 79.709 (10) | C(24)—C(23)—H(24) | 25.831 (12) |
C(2)—C(4)—C(3) | 39.583 (16) | H(22)—C(23)—H(23) | 94.51 (2) |
C(2)—C(4)—C(5) | 89.56 (2) | H(22)—C(23)—H(24) | 171.013 (14) |
C(2)—C(4)—C(6) | 59.348 (13) | H(23)—C(23)—H(24) | 94.441 (19) |
C(2)—C(4)—C(7) | 60.116 (14) | C(23)—C(24)—C(25) | 120.54 (2) |
C(2)—C(4)—H(3) | 57.602 (11) | C(23)—C(24)—H(23) | 25.735 (13) |
C(2)—C(4)—H(4) | 143.46 (3) | C(23)—C(24)—H(24) | 120.03 (3) |
C(2)—C(4)—H(5) | 111.812 (14) | C(23)—C(24)—H(25) | 146.03 (2) |
C(3)—C(4)—C(5) | 105.71 (2) | C(25)—C(24)—H(23) | 146.26 (2) |
C(3)—C(4)—C(6) | 66.928 (18) | C(25)—C(24)—H(24) | 119.37 (3) |
C(3)—C(4)—C(7) | 39.704 (16) | C(25)—C(24)—H(25) | 25.625 (12) |
C(3)—C(4)—H(3) | 25.514 (13) | H(23)—C(24)—H(24) | 94.306 (17) |
C(3)—C(4)—H(4) | 125.03 (3) | H(23)—C(24)—H(25) | 171.447 (15) |
C(3)—C(4)—H(5) | 125.93 (2) | H(24)—C(24)—H(25) | 93.756 (18) |
C(5)—C(4)—C(6) | 38.778 (16) | C(20)—C(25)—C(24) | 120.07 (2) |
C(5)—C(4)—C(7) | 72.486 (19) | C(20)—C(25)—H(24) | 146.09 (2) |
C(5)—C(4)—H(3) | 130.16 (2) | C(20)—C(25)—H(25) | 119.52 (2) |
C(5)—C(4)—H(4) | 124.72 (3) | C(24)—C(25)—H(24) | 26.029 (13) |
C(5)—C(4)—H(5) | 22.738 (14) | C(24)—C(25)—H(25) | 120.34 (2) |
C(6)—C(4)—C(7) | 38.045 (12) | H(24)—C(25)—H(25) | 94.326 (15) |
C(6)—C(4)—H(3) | 91.685 (14) | C(1)—H(1)—C(2) | 30.088 (19) |
C(6)—C(4)—H(4) | 156.68 (3) | C(1)—H(1)—C(6) | 31.280 (18) |
C(6)—C(4)—H(5) | 60.038 (11) | C(2)—H(1)—C(6) | 61.367 (11) |
C(7)—C(4)—H(3) | 59.071 (11) | C(1)—H(2)—C(2) | 29.402 (19) |
C(7)—C(4)—H(4) | 136.44 (2) | C(1)—H(2)—C(3) | 61.542 (11) |
C(7)—C(4)—H(5) | 88.468 (14) | C(1)—H(2)—H(18)i | 96.512 (7) |
H(3)—C(4)—H(4) | 99.723 (19) | C(2)—H(2)—C(3) | 32.707 (19) |
H(3)—C(4)—H(5) | 147.286 (14) | C(2)—H(2)—H(18)i | 101.831 (16) |
H(4)—C(4)—H(5) | 101.99 (2) | C(3)—H(2)—H(18)i | 96.244 (8) |
RH(1)—C(5)—C(1) | 59.018 (11) | C(2)—H(3)—C(3) | 38.50 (2) |
RH(1)—C(5)—C(3) | 77.160 (13) | C(2)—H(3)—C(4) | 63.520 (11) |
RH(1)—C(5)—C(4) | 70.473 (17) | C(2)—H(3)—C(7) | 63.372 (12) |
RH(1)—C(5)—C(6) | 98.468 (19) | C(2)—H(3)—H(12)ii | 97.659 (8) |
RH(1)—C(5)—C(7) | 106.980 (15) | C(2)—H(3)—H(13)ii | 136.024 (8) |
RH(1)—C(5)—H(4) | 79.701 (10) | C(3)—H(3)—C(4) | 37.226 (19) |
RH(1)—C(5)—H(5) | 118.47 (2) | C(3)—H(3)—C(7) | 36.117 (18) |
RH(1)—C(5)—H(6) | 113.093 (14) | C(3)—H(3)—H(12)ii | 126.862 (17) |
C(1)—C(5)—C(3) | 59.330 (14) | C(3)—H(3)—H(13)ii | 121.788 (18) |
C(1)—C(5)—C(4) | 89.67 (2) | C(4)—H(3)—C(7) | 62.923 (11) |
C(1)—C(5)—C(6) | 39.511 (15) | C(4)—H(3)—H(12)ii | 108.442 (8) |
C(1)—C(5)—C(7) | 60.065 (14) | C(4)—H(3)—H(13)ii | 84.812 (8) |
C(1)—C(5)—H(4) | 112.846 (15) | C(7)—H(3)—H(12)ii | 160.956 (8) |
C(1)—C(5)—H(5) | 141.42 (2) | C(7)—H(3)—H(13)ii | 129.231 (9) |
C(1)—C(5)—H(6) | 59.281 (11) | H(12)ii—H(3)—H(13)ii | 62.7546 |
C(3)—C(5)—C(4) | 39.030 (17) | C(3)—H(4)—C(4) | 32.488 (18) |
C(3)—C(5)—C(6) | 67.062 (18) | C(3)—H(4)—C(5) | 61.876 (11) |
C(3)—C(5)—C(7) | 38.166 (12) | C(3)—H(4)—H(15) | 94.161 (8) |
C(3)—C(5)—H(4) | 61.587 (11) | C(4)—H(4)—C(5) | 31.408 (19) |
C(3)—C(5)—H(5) | 157.68 (2) | C(4)—H(4)—H(15) | 101.601 (16) |
C(3)—C(5)—H(6) | 92.384 (13) | C(5)—H(4)—H(15) | 119.083 (7) |
C(4)—C(5)—C(6) | 106.09 (3) | C(4)—H(5)—C(5) | 29.848 (18) |
C(4)—C(5)—C(7) | 72.902 (19) | C(4)—H(5)—C(6) | 62.222 (11) |
C(4)—C(5)—H(4) | 23.873 (15) | C(4)—H(5)—H(9) | 120.597 (8) |
C(4)—C(5)—H(5) | 127.41 (3) | C(5)—H(5)—C(6) | 34.546 (17) |
C(4)—C(5)—H(6) | 130.96 (2) | C(5)—H(5)—H(9) | 132.225 (15) |
C(6)—C(5)—C(7) | 39.766 (16) | C(6)—H(5)—H(9) | 145.388 (8) |
C(6)—C(5)—H(4) | 127.71 (2) | C(1)—H(6)—C(5) | 63.351 (11) |
C(6)—C(5)—H(5) | 121.59 (3) | C(1)—H(6)—C(6) | 36.099 (19) |
C(6)—C(5)—H(6) | 26.511 (13) | C(1)—H(6)—C(7) | 62.855 (12) |
C(7)—C(5)—H(4) | 90.239 (14) | C(5)—H(6)—C(6) | 38.725 (18) |
C(7)—C(5)—H(5) | 134.04 (2) | C(5)—H(6)—C(7) | 63.548 (11) |
C(7)—C(5)—H(6) | 59.049 (11) | C(6)—H(6)—C(7) | 36.985 (18) |
H(4)—C(5)—H(5) | 103.55 (2) | C(3)—H(7B)—C(6) | 60.990 (11) |
H(4)—C(5)—H(6) | 148.682 (15) | C(3)—H(7B)—C(7) | 40.047 (19) |
H(5)—C(5)—H(6) | 95.157 (18) | C(3)—H(7B)—H(7A) | 65.614 (9) |
C(1)—C(6)—C(2) | 34.437 (15) | C(6)—H(7B)—C(7) | 39.13 (2) |
C(1)—C(6)—C(3) | 73.405 (19) | C(6)—H(7B)—H(7A) | 65.955 (8) |
C(1)—C(6)—C(4) | 87.221 (18) | C(7)—H(7B)—H(7A) | 35.009 (17) |
C(1)—C(6)—C(5) | 100.89 (2) | C(3)—H(7A)—C(6) | 61.314 (11) |
C(1)—C(6)—C(7) | 100.84 (3) | C(3)—H(7A)—C(7) | 40.69 (2) |
C(1)—C(6)—H(1) | 21.790 (13) | C(3)—H(7A)—H(7B) | 66.367 (9) |
C(1)—C(6)—H(5) | 116.714 (19) | C(6)—H(7A)—C(7) | 39.56 (2) |
C(1)—C(6)—H(6) | 118.99 (3) | C(6)—H(7A)—H(7B) | 66.441 (8) |
C(1)—C(6)—H(7B) | 126.80 (2) | C(7)—H(7A)—H(7B) | 35.010 (18) |
C(1)—C(6)—H(7A) | 88.741 (19) | C(8)—H(9)—C(9) | 35.631 (14) |
C(2)—C(6)—C(3) | 38.968 (13) | C(8)—H(9)—C(10) | 68.954 (9) |
C(2)—C(6)—C(4) | 60.509 (13) | C(8)—H(9)—H(5) | 86.694 (6) |
C(2)—C(6)—C(5) | 87.689 (18) | C(9)—H(9)—C(10) | 33.324 (15) |
C(2)—C(6)—C(7) | 72.183 (19) | C(9)—H(9)—H(5) | 90.590 (13) |
C(2)—C(6)—H(1) | 56.227 (11) | C(10)—H(9)—H(5) | 94.376 (7) |
C(2)—C(6)—H(5) | 110.832 (14) | C(9)—H(10)—C(10) | 34.098 (16) |
C(2)—C(6)—H(6) | 151.13 (3) | C(9)—H(10)—C(11) | 68.283 (10) |
C(2)—C(6)—H(7B) | 95.249 (14) | C(10)—H(10)—C(11) | 34.185 (16) |
C(2)—C(6)—H(7A) | 71.507 (12) | C(10)—H(11)—C(11) | 33.527 (17) |
C(3)—C(6)—C(4) | 38.931 (12) | C(10)—H(11)—C(12) | 68.433 (10) |
C(3)—C(6)—C(5) | 74.061 (18) | C(11)—H(11)—C(12) | 34.908 (17) |
C(3)—C(6)—C(7) | 43.125 (16) | C(11)—H(12)—C(12) | 34.195 (16) |
C(3)—C(6)—H(1) | 95.194 (15) | C(11)—H(12)—C(13) | 68.543 (10) |
C(3)—C(6)—H(5) | 96.108 (14) | C(11)—H(12)—H(3)ii | 149.067 (7) |
C(3)—C(6)—H(6) | 160.76 (2) | C(12)—H(12)—C(13) | 34.364 (16) |
C(3)—C(6)—H(7B) | 59.158 (12) | C(12)—H(12)—H(3)ii | 116.929 (15) |
C(3)—C(6)—H(7A) | 58.897 (11) | C(13)—H(12)—H(3)ii | 83.321 (6) |
C(4)—C(6)—C(5) | 35.130 (15) | C(8)—H(13)—C(12) | 68.707 (9) |
C(4)—C(6)—C(7) | 71.620 (18) | C(8)—H(13)—C(13) | 34.039 (14) |
C(4)—C(6)—H(1) | 104.696 (13) | C(8)—H(13)—H(3)ii | 148.518 (6) |
C(4)—C(6)—H(5) | 57.739 (11) | C(12)—H(13)—C(13) | 34.670 (14) |
C(4)—C(6)—H(6) | 147.04 (3) | C(12)—H(13)—H(3)ii | 84.060 (7) |
C(4)—C(6)—H(7B) | 71.268 (12) | C(13)—H(13)—H(3)ii | 117.200 (13) |
C(4)—C(6)—H(7A) | 94.791 (14) | C(14)—H(15)—C(15) | 33.297 (14) |
C(5)—C(6)—C(7) | 100.66 (2) | C(14)—H(15)—C(16) | 68.827 (10) |
C(5)—C(6)—H(1) | 107.870 (18) | C(14)—H(15)—H(4) | 107.583 (6) |
C(5)—C(6)—H(5) | 23.867 (13) | C(15)—H(15)—C(16) | 35.542 (15) |
C(5)—C(6)—H(6) | 114.76 (3) | C(15)—H(15)—H(4) | 133.468 (15) |
C(5)—C(6)—H(7B) | 88.662 (18) | C(16)—H(15)—H(4) | 149.271 (9) |
C(5)—C(6)—H(7A) | 126.89 (2) | C(15)—H(16)—C(16) | 33.837 (16) |
C(7)—C(6)—H(1) | 118.40 (2) | C(15)—H(16)—C(17) | 68.484 (10) |
C(7)—C(6)—H(5) | 112.50 (2) | C(16)—H(16)—C(17) | 34.690 (16) |
C(7)—C(6)—H(6) | 117.70 (3) | C(16)—H(17)—C(17) | 34.970 (18) |
C(7)—C(6)—H(7B) | 26.651 (15) | C(16)—H(17)—C(18) | 68.133 (11) |
C(7)—C(6)—H(7A) | 26.912 (14) | C(16)—H(17)—H(24)iii | 123.868 (7) |
H(1)—C(6)—H(5) | 115.470 (13) | C(17)—H(17)—C(18) | 33.168 (18) |
H(1)—C(6)—H(6) | 97.865 (19) | C(17)—H(17)—H(24)iii | 153.937 (16) |
H(1)—C(6)—H(7B) | 145.027 (15) | C(18)—H(17)—H(24)iii | 157.927 (7) |
H(1)—C(6)—H(7A) | 99.983 (13) | C(17)—H(18)—C(18) | 34.515 (16) |
H(5)—C(6)—H(6) | 90.975 (19) | C(17)—H(18)—C(19) | 68.528 (10) |
H(5)—C(6)—H(7B) | 92.225 (12) | C(17)—H(18)—H(2)iv | 150.425 (8) |
H(5)—C(6)—H(7A) | 138.873 (15) | C(18)—H(18)—C(19) | 34.025 (16) |
H(6)—C(6)—H(7B) | 102.814 (19) | C(18)—H(18)—H(2)iv | 151.700 (15) |
H(6)—C(6)—H(7A) | 104.716 (19) | C(19)—H(18)—H(2)iv | 125.422 (7) |
H(7B)—C(6)—H(7A) | 47.604 (6) | C(14)—H(19)—C(18) | 68.781 (9) |
C(1)—C(7)—C(2) | 33.809 (11) | C(14)—H(19)—C(19) | 35.203 (14) |
C(1)—C(7)—C(3) | 69.647 (18) | C(14)—H(19)—C(21) | 98.371 (9) |
C(1)—C(7)—C(4) | 70.789 (13) | C(14)—H(19)—H(21) | 94.205 (6) |
C(1)—C(7)—C(5) | 59.902 (13) | C(18)—H(19)—C(19) | 33.582 (14) |
C(1)—C(7)—C(6) | 39.440 (16) | C(18)—H(19)—C(21) | 160.199 (10) |
C(1)—C(7)—H(3) | 90.554 (14) | C(18)—H(19)—H(21) | 135.276 (8) |
C(1)—C(7)—H(6) | 58.704 (11) | C(19)—H(19)—C(21) | 132.057 (14) |
C(1)—C(7)—H(7B) | 152.08 (3) | C(19)—H(19)—H(21) | 119.155 (14) |
C(1)—C(7)—H(7A) | 93.43 (2) | C(21)—H(19)—H(21) | 27.157 (6) |
C(2)—C(7)—C(3) | 39.355 (17) | C(20)—H(21)—C(21) | 34.883 (14) |
C(2)—C(7)—C(4) | 59.740 (13) | C(20)—H(21)—C(22) | 68.795 (10) |
C(2)—C(7)—C(5) | 70.710 (13) | C(20)—H(21)—H(19) | 74.659 (6) |
C(2)—C(7)—C(6) | 69.614 (18) | C(21)—H(21)—C(22) | 33.913 (15) |
C(2)—C(7)—H(3) | 57.147 (11) | C(21)—H(21)—H(19) | 84.004 (13) |
C(2)—C(7)—H(6) | 91.940 (14) | C(22)—H(21)—H(19) | 94.693 (7) |
C(2)—C(7)—H(7B) | 150.87 (3) | C(21)—H(22)—C(22) | 34.471 (16) |
C(2)—C(7)—H(7A) | 92.90 (2) | C(21)—H(22)—C(23) | 68.390 (10) |
C(3)—C(7)—C(4) | 39.559 (17) | C(22)—H(22)—C(23) | 33.929 (16) |
C(3)—C(7)—C(5) | 70.349 (18) | C(22)—H(23)—C(23) | 34.209 (19) |
C(3)—C(7)—C(6) | 93.82 (2) | C(22)—H(23)—C(24) | 68.210 (10) |
C(3)—C(7)—H(3) | 24.733 (13) | C(23)—H(23)—C(24) | 34.007 (19) |
C(3)—C(7)—H(6) | 119.11 (2) | C(23)—H(24)—C(24) | 34.142 (17) |
C(3)—C(7)—H(7B) | 112.78 (3) | C(23)—H(24)—C(25) | 68.716 (10) |
C(3)—C(7)—H(7A) | 111.74 (3) | C(23)—H(24)—H(17)v | 122.583 (7) |
C(4)—C(7)—C(5) | 34.612 (11) | C(24)—H(24)—C(25) | 34.601 (17) |
C(4)—C(7)—C(6) | 70.335 (17) | C(24)—H(24)—H(17)v | 145.291 (15) |
C(4)—C(7)—H(3) | 58.006 (11) | C(25)—H(24)—H(17)v | 146.610 (7) |
C(4)—C(7)—H(6) | 91.582 (14) | C(20)—H(25)—C(24) | 68.507 (9) |
C(4)—C(7)—H(7B) | 93.36 (2) | C(20)—H(25)—C(25) | 34.502 (14) |
C(4)—C(7)—H(7A) | 150.16 (3) | C(24)—H(25)—C(25) | 34.031 (15) |
Symmetry codes: (i) x−1, y, z; (ii) −x+2, −y+2, −z+1; (iii) x, y, z−1; (iv) x+1, y, z; (v) x, y, z+1. |
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