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The synthesis and crystal structure of diaquacobalt tetracyanonickelate tetrahydrate are reported. The structure of Co(H2O)2Ni(CN)4.4H2O is made up of alternating metal cyanide sheets and layers of hydrogen-bonded water molecules. The title compound is isostructural with Cd(H2O)2Ni(CN)4·4H2O.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks coni2, text

fcf

Structure factor file (CIF format)
Contains datablock coni2

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