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In the crystals of trans-diaquabis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-O,O')manganese(II) monohydrate, [Mn(C5HF6O2)2(H2O)2].H2O, the Mn atom and all three water molecules lie on a crystallographic mirror plane. Two of the water molecules are coordinated to the Mn atom in a trans geometry and the third links the structure into hydrogen-bonded sheets. The two planar hexafluoroacetylacetonato ligands related by the mirror plane form a dihedral angle of 41.6 (2)° with one another. One CF3 group displayed significant disorder.

Supporting information

cif

Crystallographic Information File (CIF)
Contains datablocks mhd4, global

fcf

Structure factor file (CIF format)
Contains datablock mhd4

CCDC reference: 128574

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