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The novel monoprotonated decavanadate species [HV
10O
28]
5− has been prepared and characterized. The title compound, tetrapotassium sodium hydrogendecavanadate decahydrate, crystallizes in the monoclinic system in space group
P2/
n, with the polyanion having twofold crystallographic symmetry. The protonated O atom in the polyanion was identified from the elongation of the V—O bond and the shortest O
O inter-polyanion distance. The H atom is disordered around a twofold axis that relates two hydrogen-bonded polyanions.
Supporting information
Key indicators
- Single-crystal X-ray study
- T = 298 K
- Mean (V-O) = 0.003 Å
- H-atom completeness 1%
- R factor = 0.046
- wR factor = 0.128
- Data-to-parameter ratio = 15.5
checkCIF/PLATON results
No syntax errors found
Alert level A
PLAT306_ALERT_2_A Isolated Oxygen Atom (H-atoms Missing ?) ....... OW1
| Author Response: Explained in _publ_section_exptl_refinement
|
PLAT306_ALERT_2_A Isolated Oxygen Atom (H-atoms Missing ?) ....... OW2
| Author Response: Explained in _publ_section_exptl_refinement
|
PLAT306_ALERT_2_A Isolated Oxygen Atom (H-atoms Missing ?) ....... OW3
| Author Response: Explained in _publ_section_exptl_refinement
|
PLAT306_ALERT_2_A Isolated Oxygen Atom (H-atoms Missing ?) ....... OW4
| Author Response: Explained in _publ_section_exptl_refinement
|
PLAT306_ALERT_2_A Isolated Oxygen Atom (H-atoms Missing ?) ....... OW5
| Author Response: Explained in _publ_section_exptl_refinement
|
PLAT306_ALERT_2_A Isolated Oxygen Atom (H-atoms Missing ?) ....... OW6
| Author Response: Explained in _publ_section_exptl_refinement
|
Alert level B
PLAT430_ALERT_2_B Short Inter D...A Contact OC2 .. OW6 = 2.74 Ang.
| Author Response: Those are normal values in the polyoxometalates.
(Strong hydrogen-bonding.)
|
PLAT430_ALERT_2_B Short Inter D...A Contact OB7 .. OW5 = 2.77 Ang.
| Author Response: Those are normal values in the polyoxometalates.
(Strong hydrogen-bonding.)
|
PLAT430_ALERT_2_B Short Inter D...A Contact OB7 .. OW5 = 2.80 Ang.
| Author Response: Those are normal values in the polyoxometalates.
(Strong hydrogen-bonding.)
|
PLAT430_ALERT_2_B Short Inter D...A Contact OB8 .. OW4 = 2.83 Ang.
| Author Response: Those are normal values in the polyoxometalates.
(Strong hydrogen-bonding.)
|
PLAT430_ALERT_2_B Short Inter D...A Contact OW1 .. OW6 = 2.84 Ang.
| Author Response: Those are normal values in the polyoxometalates.
(Strong hydrogen-bonding.)
|
Alert level C
CHEMW03_ALERT_2_C The ratio of given/expected molecular weight as
calculated from the _atom_site* data lies outside
the range 0.99 <> 1.01
From the CIF: _cell_formula_units_Z 2
From the CIF: _chemical_formula_weight 1317.96
TEST: Calculate formula weight from _atom_site_*
atom mass num sum
V 50.94 10.00 509.42
O 16.00 38.00 607.96
H 1.01 0.00 0.00
K 39.10 4.00 156.39
Na 22.99 1.00 22.99
Calculated formula weight 1296.76
PLAT041_ALERT_1_C Calc. and Rep. SumFormula Strings Differ .... ?
| Author Response: Because H atoms of H2O were not included.
|
PLAT042_ALERT_1_C Calc. and Rep. MoietyFormula Strings Differ .... ?
| Author Response: Because H atoms of H2O were not included.
|
PLAT043_ALERT_1_C Check Reported Molecular Weight ................ 1317.96
| Author Response: Because H atoms of H2O were not included.
|
PLAT044_ALERT_1_C Calculated and Reported Dx Differ .............. ?
| Author Response: Because H atoms of H2O were not included.
|
PLAT068_ALERT_1_C Reported F000 Differs from Calcd (or Missing)... ?
| Author Response: Because H atoms of H2O were not included.
|
PLAT128_ALERT_4_C Non-standard setting of Space group P2/c .... P2/n
PLAT430_ALERT_2_C Short Inter D...A Contact OB9 .. OW1 = 2.85 Ang.
| Author Response: Those are normal values in the polyoxometalates.
(Strong hydrogen-bonding.)
|
PLAT430_ALERT_2_C Short Inter D...A Contact OW1 .. OW6 = 2.86 Ang.
| Author Response: Those are normal values in the polyoxometalates.
(Strong hydrogen-bonding.)
|
PLAT720_ALERT_4_C Number of Unusual/Non-Standard Label(s) ........ 20
| Author Response: Explained in the comment.
|
Alert level G
FORMU01_ALERT_2_G There is a discrepancy between the atom counts in the
_chemical_formula_sum and the formula from the _atom_site* data.
Atom count from _chemical_formula_sum:H21 K4 Na1 O38 V10
Atom count from the _atom_site data: K4 Na1 O38 V10
CELLZ01_ALERT_1_G Difference between formula and atom_site contents detected.
CELLZ01_ALERT_1_G WARNING: H atoms missing from atom site list. Is this intentional?
From the CIF: _cell_formula_units_Z 2
From the CIF: _chemical_formula_sum H21 K4 Na O38 V10
TEST: Compare cell contents of formula and atom_site data
atom Z*formula cif sites diff
H 42.00 0.00 42.00
K 8.00 8.00 0.00
Na 2.00 2.00 0.00
O 76.00 76.00 0.00
V 20.00 20.00 0.00
6 ALERT level A = In general: serious problem
5 ALERT level B = Potentially serious problem
10 ALERT level C = Check and explain
3 ALERT level G = General alerts; check
7 ALERT type 1 CIF construction/syntax error, inconsistent or missing data
15 ALERT type 2 Indicator that the structure model may be wrong or deficient
0 ALERT type 3 Indicator that the structure quality may be low
2 ALERT type 4 Improvement, methodology, query or suggestion
Data collection: STADI4 (Stoe, 1996); cell refinement: STADI4; data reduction: X-RED (Stoe, 1996); program(s) used to solve structure: SHELXS97 (Sheldrick, 1990); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: ORTEPIII (Farrugia, 1997) and DIAMOND (Brandenburg, 1998); software used to prepare material for publication: SHELXL97.
tetrapotassium sodium hydrogendecavanadate decahydrate
top
Crystal data top
K4Na[HV10O28]·10H2O | F(000) = 1284 |
Mr = 1317.96 | Dx = 2.684 Mg m−3 |
Monoclinic, P2/n | Mo Kα radiation, λ = 0.71069 Å |
Hall symbol: -P 2yac | Cell parameters from 25 reflections |
a = 10.804 (2) Å | θ = 9.5–10.4° |
b = 11.034 (2) Å | µ = 3.38 mm−1 |
c = 13.748 (3) Å | T = 298 K |
β = 95.78 (2)° | Tetragonal plate, pale brown |
V = 1630.6 (6) Å3 | 0.58 × 0.48 × 0.07 mm |
Z = 2 | |
Data collection top
Stoe STADI4 diffractometer | 2768 reflections with I > 2σ(I) |
Radiation source: fine-focus sealed tube | Rint = 0.000 |
Graphite monochromator | θmax = 27.5°, θmin = 1.9° |
ω/2θ scans | h = −14→13 |
Absorption correction: numerical (X-SHAPE; Stoe & Cie, 1996) | k = 0→14 |
Tmin = 0.162, Tmax = 0.772 | l = 0→17 |
3731 measured reflections | 3 standard reflections every 60 min |
3731 independent reflections | intensity decay: 3.6% |
Refinement top
Refinement on F2 | Primary atom site location: structure-invariant direct methods |
Least-squares matrix: full | Secondary atom site location: difference Fourier map |
R[F2 > 2σ(F2)] = 0.046 | H-atom parameters not refined |
wR(F2) = 0.128 | w = 1/[σ2(Fo2) + (0.0524P)2 + 4.4779P] where P = (Fo2 + 2Fc2)/3 |
S = 1.15 | (Δ/σ)max = 0.001 |
3731 reflections | Δρmax = 0.83 e Å−3 |
241 parameters | Δρmin = −0.76 e Å−3 |
0 restraints | |
Special details top
Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes)
are estimated using the full covariance matrix. The cell e.s.d.'s are taken
into account individually in the estimation of e.s.d.'s in distances, angles
and torsion angles; correlations between e.s.d.'s in cell parameters are only
used when they are defined by crystal symmetry. An approximate (isotropic)
treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s.
planes. |
Refinement. Refinement of F2 against ALL reflections. The weighted R-factor
wR and goodness of fit S are based on F2, conventional
R-factors R are based on F, with F set to zero for
negative F2. The threshold expression of F2 >
σ(F2) is used only for calculating R-factors(gt) etc.
and is not relevant to the choice of reflections for refinement.
R-factors based on F2 are statistically about twice as large
as those based on F, and R- factors based on ALL data will be
even larger. |
Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top | x | y | z | Uiso*/Ueq | |
V1 | 0.59825 (7) | 0.72243 (7) | 0.73747 (5) | 0.01308 (17) | |
V2 | 0.89274 (7) | 0.72146 (8) | 0.53687 (6) | 0.01764 (19) | |
V3 | 0.60767 (7) | 0.72429 (9) | 0.51615 (6) | 0.01894 (19) | |
V4 | 0.75513 (7) | 0.51673 (7) | 0.63997 (6) | 0.01633 (19) | |
V5 | 0.75031 (7) | 0.92626 (7) | 0.63897 (6) | 0.01554 (19) | |
K1 | 0.26547 (11) | 0.77905 (13) | 0.53613 (9) | 0.0323 (3) | |
K2 | 0.46048 (15) | 0.79143 (15) | 0.23514 (10) | 0.0459 (4) | |
Na | 0.7500 | 1.0061 (3) | 0.2500 | 0.0250 (6) | |
Oh1 | 0.7479 (3) | 0.7210 (3) | 0.6528 (2) | 0.0143 (6) | |
Oc2 | 0.6351 (3) | 0.5505 (3) | 0.7404 (2) | 0.0143 (6) | |
Oc3 | 0.6351 (3) | 0.8935 (3) | 0.7408 (2) | 0.0150 (6) | |
Ob4 | 0.5062 (3) | 0.7218 (3) | 0.8299 (2) | 0.0184 (7) | |
Ob5 | 0.7497 (3) | 0.7216 (3) | 0.4538 (2) | 0.0184 (7) | |
Ob6 | 0.5030 (3) | 0.7225 (3) | 0.6326 (2) | 0.0181 (7) | |
Ob7 | 0.8745 (3) | 0.8876 (3) | 0.5635 (2) | 0.0183 (7) | |
Ob8 | 0.6264 (3) | 0.8895 (3) | 0.5446 (2) | 0.0192 (7) | |
Ob9 | 0.8730 (3) | 0.5555 (3) | 0.5628 (2) | 0.0185 (7) | |
Ob10 | 0.6226 (3) | 0.5539 (3) | 0.5421 (2) | 0.0195 (7) | |
Ot11 | 1.0021 (3) | 0.7255 (4) | 0.4659 (3) | 0.0273 (8) | |
Ot12 | 0.4949 (3) | 0.7267 (4) | 0.4309 (2) | 0.0267 (8) | |
Ot13 | 0.7529 (3) | 1.0723 (3) | 0.6388 (3) | 0.0236 (8) | |
Ot14 | 0.7561 (3) | 0.3710 (3) | 0.6408 (3) | 0.0238 (8) | |
OW1 | 0.2145 (4) | 0.5539 (4) | 0.6186 (3) | 0.0388 (10) | |
OW2 | 0.2500 | 0.7773 (5) | 0.7500 | 0.0292 (12) | |
OW3 | 0.7500 | 0.7933 (6) | 0.2500 | 0.0456 (16) | |
OW4 | 0.5906 (4) | 0.9997 (4) | 0.3582 (3) | 0.0423 (11) | |
OW5 | 0.8910 (4) | 1.0145 (5) | 0.3893 (3) | 0.0517 (14) | |
OW6 | 0.5891 (4) | 0.5658 (4) | 0.2630 (3) | 0.0411 (11) | |
Atomic displacement parameters (Å2) top | U11 | U22 | U33 | U12 | U13 | U23 |
V1 | 0.0096 (3) | 0.0130 (4) | 0.0164 (4) | 0.0000 (3) | 0.0002 (3) | 0.0012 (3) |
V2 | 0.0165 (4) | 0.0193 (4) | 0.0175 (4) | −0.0021 (3) | 0.0035 (3) | −0.0007 (3) |
V3 | 0.0149 (4) | 0.0245 (5) | 0.0166 (4) | −0.0032 (4) | −0.0020 (3) | −0.0007 (4) |
V4 | 0.0184 (4) | 0.0120 (4) | 0.0186 (4) | −0.0012 (3) | 0.0020 (3) | −0.0029 (3) |
V5 | 0.0171 (4) | 0.0120 (4) | 0.0174 (4) | −0.0006 (3) | 0.0011 (3) | 0.0019 (3) |
K1 | 0.0300 (6) | 0.0365 (7) | 0.0292 (6) | 0.0023 (6) | −0.0028 (5) | 0.0015 (6) |
K2 | 0.0525 (9) | 0.0518 (10) | 0.0306 (7) | 0.0112 (7) | −0.0096 (6) | 0.0008 (6) |
Na | 0.0230 (14) | 0.0242 (16) | 0.0271 (14) | 0.000 | −0.0006 (12) | 0.000 |
Oh1 | 0.0154 (15) | 0.0111 (15) | 0.0161 (14) | 0.0003 (13) | 0.0004 (12) | 0.0020 (13) |
Oc2 | 0.0141 (15) | 0.0127 (16) | 0.0160 (15) | −0.0006 (13) | 0.0009 (12) | 0.0009 (12) |
Oc3 | 0.0150 (15) | 0.0130 (16) | 0.0168 (15) | 0.0009 (13) | 0.0004 (12) | 0.0012 (13) |
Ob4 | 0.0144 (15) | 0.0199 (17) | 0.0209 (16) | −0.0013 (14) | 0.0019 (12) | −0.0025 (14) |
Ob5 | 0.0196 (16) | 0.0202 (17) | 0.0154 (14) | −0.0036 (15) | 0.0019 (12) | −0.0008 (14) |
Ob6 | 0.0146 (15) | 0.0200 (17) | 0.0190 (15) | 0.0016 (14) | −0.0012 (12) | 0.0033 (14) |
Ob7 | 0.0177 (16) | 0.0173 (17) | 0.0198 (16) | −0.0048 (14) | 0.0024 (13) | 0.0022 (14) |
Ob8 | 0.0172 (16) | 0.0184 (18) | 0.0216 (17) | −0.0011 (14) | −0.0005 (13) | 0.0026 (14) |
Ob9 | 0.0197 (16) | 0.0176 (17) | 0.0186 (16) | −0.0005 (14) | 0.0033 (13) | −0.0045 (13) |
Ob10 | 0.0225 (17) | 0.0173 (17) | 0.0182 (16) | −0.0025 (14) | −0.0008 (13) | −0.0005 (14) |
Ot11 | 0.0246 (18) | 0.033 (2) | 0.0256 (18) | −0.0001 (17) | 0.0097 (15) | 0.0018 (17) |
Ot12 | 0.0190 (17) | 0.039 (2) | 0.0212 (17) | −0.0020 (17) | −0.0044 (14) | 0.0018 (17) |
Ot13 | 0.0284 (19) | 0.0146 (17) | 0.0275 (19) | −0.0025 (15) | 0.0011 (15) | 0.0039 (15) |
Ot14 | 0.0269 (19) | 0.0147 (18) | 0.0290 (19) | −0.0001 (15) | −0.0015 (15) | −0.0051 (15) |
OW1 | 0.049 (3) | 0.034 (2) | 0.033 (2) | −0.003 (2) | 0.0058 (19) | −0.0063 (18) |
OW2 | 0.031 (3) | 0.028 (3) | 0.029 (3) | 0.000 | 0.001 (2) | 0.000 |
OW3 | 0.072 (5) | 0.027 (3) | 0.039 (3) | 0.000 | 0.012 (3) | 0.000 |
OW4 | 0.034 (2) | 0.047 (3) | 0.048 (3) | 0.017 (2) | 0.017 (2) | 0.019 (2) |
OW5 | 0.042 (3) | 0.068 (4) | 0.040 (2) | −0.031 (2) | −0.019 (2) | 0.026 (2) |
OW6 | 0.030 (2) | 0.038 (3) | 0.055 (3) | −0.0114 (19) | 0.006 (2) | −0.008 (2) |
Geometric parameters (Å, º) top
V1—V2i | 3.094 (1) | V5—Ob8 | 1.814 (3) |
V1—V3 | 3.055 (1) | V5—Ot13 | 1.612 (4) |
V1—V4i | 3.156 (1) | K1—Ob6 | 2.838 (3) |
V1—V5 | 3.169 (1) | K1—Ot11ii | 2.970 (4) |
V1—V5i | 3.172 (1) | K1—Ot12 | 3.048 (4) |
V1—V4 | 3.206 (1) | K1—Ot13iii | 2.901 (4) |
V2—V3 | 3.065 (1) | K1—Ot14iv | 2.932 (4) |
V2—V4 | 3.122 (1) | K1—OW1 | 2.808 (5) |
V2—V5 | 3.143 (1) | K1—OW2 | 2.9619 (14) |
V3—V4 | 3.184 (1) | K1—OW4iii | 3.167 (5) |
V3—V5 | 3.110 (1) | K1—OW5iii | 3.073 (6) |
V4—V4i | 3.039 (2) | K2—Ot11v | 2.925 (4) |
V5—V5i | 3.054 (2) | K2—Ot12 | 2.773 (4) |
V1—Oh1 | 2.085 (3) | K2—Ot13iii | 3.374 (4) |
V1—Oh1i | 2.129 (3) | K2—Ot13vi | 2.906 (4) |
V1—Oc2 | 1.939 (3) | K2—Ot14vii | 3.032 (4) |
V1—Oc3 | 1.929 (3) | K2—OW3 | 3.1141 (17) |
V1—Ob4 | 1.691 (3) | K2—OW4 | 3.105 (5) |
V1—Ob6 | 1.684 (3) | K2—OW6 | 2.858 (5) |
V2—Oh1 | 2.343 (3) | Na—OW2iii | 2.390 (6) |
V2—Ob4i | 2.036 (3) | Na—OW3 | 2.348 (7) |
V2—Ob5 | 1.827 (3) | Na—OW4v | 2.387 (4) |
V2—Ob7 | 1.884 (4) | Na—OW4 | 2.387 (4) |
V2—Ob9 | 1.881 (4) | Na—OW5v | 2.325 (4) |
V2—Ot11 | 1.607 (3) | Na—OW5 | 2.325 (4) |
V3—Oh1 | 2.292 (3) | OW1—OW6viii | 2.839 (6) |
V3—Ob5 | 1.832 (3) | OW1—Ob9iv | 2.845 (5) |
V3—Ob6 | 2.051 (3) | OW1—OW6iv | 2.864 (7) |
V3—Ob8 | 1.871 (4) | OW2—Ob4ix | 2.938 (3) |
V3—Ob10 | 1.917 (4) | OW2—OW1ix | 3.057 (6) |
V3—Ot12 | 1.603 (3) | OW3—Ob5 | 2.911 (4) |
V4—Oh1 | 2.263 (3) | OW3—Ob5v | 2.911 (4) |
V4—Oc2 | 2.021 (3) | OW3—OW6 | 3.069 (7) |
V4—Oc2i | 1.964 (3) | OW3—OW6v | 3.069 (7) |
V4—Ob9 | 1.790 (3) | OW4—Oc3iii | 2.919 (5) |
V4—Ob10 | 1.908 (3) | OW4—Ob8 | 2.827 (5) |
V4—Ot14 | 1.608 (4) | OW4—Ob8iii | 3.068 (5) |
V5—Oh1 | 2.273 (3) | OW5—Ob7 | 2.796 (5) |
V5—Oc3 | 1.997 (3) | OW5—Ob7x | 2.771 (5) |
V5—Oc3i | 1.996 (3) | OW6—Oc2iv | 2.738 (5) |
V5—Ob7 | 1.827 (3) | Ob10—Ob10iv | 3.025 (7) |
| | | |
V3—V1—V2i | 176.30 (3) | Ot11—V2—Ob7 | 100.9 (2) |
V3—V1—V4i | 118.12 (3) | Ob5—V2—Ob7 | 91.3 (2) |
V2i—V1—V4i | 59.92 (3) | Ob9—V2—Ob7 | 153.4 (1) |
V3—V1—V5 | 59.92 (3) | Ot11—V2—Ob4i | 100.7 (2) |
V2i—V1—V5 | 117.75 (3) | Ob5—V2—Ob4i | 155.0 (1) |
V4i—V1—V5 | 118.99 (3) | Ob9—V2—Ob4i | 83.8 (2) |
V3—V1—V5i | 117.49 (3) | Ob7—V2—Ob4i | 83.1 (1) |
V2i—V1—V5i | 60.20 (3) | Ot11—V2—Oh1 | 174.4 (2) |
V4i—V1—V5i | 91.14 (3) | Ob5—V2—Oh1 | 81.1 (1) |
V5—V1—V5i | 57.58 (3) | Ob9—V2—Oh1 | 76.9 (1) |
V3—V1—V4 | 61.07 (3) | Ob7—V2—Oh1 | 77.3 (1) |
V2i—V1—V4 | 116.88 (3) | Ob4i—V2—Oh1 | 73.9 (1) |
V4i—V1—V4 | 57.05 (3) | Ot12—V3—Ob5 | 105.6 (2) |
V5—V1—V4 | 90.29 (3) | Ot12—V3—Ob8 | 101.3 (2) |
V5i—V1—V4 | 117.39 (3) | Ob5—V3—Ob8 | 92.0 (2) |
V3—V2—V1i | 91.32 (3) | Ot12—V3—Ob10 | 101.3 (2) |
V3—V2—V4 | 61.93 (3) | Ob5—V3—Ob10 | 90.7 (2) |
V1i—V2—V4 | 61.03 (3) | Ob8—V3—Ob10 | 155.7 (1) |
V3—V2—V5 | 60.10 (3) | Ot12—V3—Ob6 | 97.6 (2) |
V1i—V2—V5 | 61.13 (3) | Ob5—V3—Ob6 | 156.7 (1) |
V4—V2—V5 | 92.32 (3) | Ob8—V3—Ob6 | 84.4 (1) |
V1—V3—V2 | 92.37 (3) | Ob10—V3—Ob6 | 83.6 (1) |
V1—V3—V5 | 61.86 (3) | Ot12—V3—Oh1 | 172.0 (2) |
V2—V3—V5 | 61.20 (3) | Ob5—V3—Oh1 | 82.4 (1) |
V1—V3—V4 | 61.81 (3) | Ob8—V3—Oh1 | 78.2 (1) |
V2—V3—V4 | 59.92 (3) | Ob10—V3—Oh1 | 78.2 (1) |
V5—V3—V4 | 91.79 (3) | Ob6—V3—Oh1 | 74.4 (1) |
V4i—V4—V2 | 121.26 (3) | Ot14—V4—Ob9 | 103.8 (2) |
V4i—V4—V3 | 117.77 (3) | Ot14—V4—Ob10 | 103.0 (2) |
V2—V4—V3 | 58.15 (3) | Ob9—V4—Ob10 | 93.4 (2) |
V4i—V4—V1 | 60.65 (3) | Ot14—V4—Oc2i | 100.4 (2) |
V2—V4—V1 | 88.48 (3) | Ob9—V4—Oc2i | 92.6 (1) |
V3—V4—V1 | 57.12 (3) | Ob10—V4—Oc2i | 153.7 (2) |
V5i—V5—V3 | 119.48 (3) | Ot14—V4—Oc2 | 100.6 (2) |
V5i—V5—V2 | 119.80 (3) | Ob9—V4—Oc2 | 154.8 (2) |
V3—V5—V2 | 58.69 (3) | Ob10—V4—Oc2 | 87.4 (1) |
V5i—V5—V1 | 61.27 (3) | Oc2i—V4—Oc2 | 76.6 (1) |
V3—V5—V1 | 58.22 (3) | Ot14—V4—Oh1 | 174.7 (2) |
V2—V5—V1 | 88.78 (3) | Ob9—V4—Oh1 | 80.8 (1) |
Ob6—V1—Ob4 | 106.8 (2) | Ob10—V4—Oh1 | 79.1 (1) |
Ob6—V1—Oc3 | 97.3 (2) | Oc2i—V4—Oh1 | 76.6 (1) |
Ob4—V1—Oc3 | 97.0 (2) | Oc2—V4—Oh1 | 74.6 (1) |
Ob6—V1—Oc2 | 97.2 (2) | Ot13—V5—Ob8 | 103.5 (2) |
Ob4—V1—Oc2 | 96.6 (2) | Ot13—V5—Ob7 | 102.7 (2) |
Oc3—V1—Oc2 | 156.3 (1) | Ob8—V5—Ob7 | 94.2 (2) |
Ob6—V1—Oh1 | 87.9 (1) | Ot13—V5—Oc3i | 100.0 (2) |
Ob4—V1—Oh1 | 165.3 (1) | Ob8—V5—Oc3i | 154.6 (2) |
Oc3—V1—Oh1 | 81.4 (1) | Ob7—V5—Oc3i | 89.9 (1) |
Oc2—V1—Oh1 | 80.5 (1) | Ot13—V5—Oc3 | 101.2 (2) |
Ob6—V1—Oh1i | 166.5 (1) | Ob8—V5—Oc3 | 89.7 (1) |
Ob4—V1—Oh1i | 86.8 (1) | Ob7—V5—Oc3 | 154.2 (2) |
Oc3—V1—Oh1i | 81.1 (1) | Oc3i—V5—Oc3 | 76.4 (1) |
Oc2—V1—Oh1i | 80.4 (1) | Ot13—V5—Oh1 | 175.3 (2) |
OH1—V1—Oh1i | 78.6 (1) | Ob8—V5—Oh1 | 79.8 (1) |
Ot11—V2—Ob5 | 104.4 (2) | Ob7—V5—Oh1 | 80.2 (1) |
Ot11—V2—Ob9 | 104.3 (2) | Oc3i—V5—Oh1 | 76.2 (1) |
Ob5—V2—Ob9 | 90.8 (2) | Oc3—V5—Oh1 | 75.4 (1) |
Symmetry codes: (i) −x+3/2, y, −z+3/2; (ii) x−1, y, z; (iii) −x+1, −y+2, −z+1; (iv) −x+1, −y+1, −z+1; (v) −x+3/2, y, −z+1/2; (vi) x−1/2, −y+2, z−1/2; (vii) x−1/2, −y+1, z−1/2; (viii) x−1/2, −y+1, z+1/2; (ix) −x+1/2, y, −z+3/2; (x) −x+2, −y+2, −z+1. |
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