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The title compound, [Cd(C9H9O2)2(C12H8N2)]n, was synthesized in a water–methanol solution and its crystal structure was determined by X-ray diffraction analysis. The Cd atoms are octa­hedrally coordinated by two N atoms from phenanthroline and four O atoms from four different 3,5-dimethyl­benzoate ions, completing the octa­hedral geometry. The O atoms of the carboxylate group coordinate to CdII in a bidentate bridging manner. The complex shows a one-dimensional chain structure of Cd atoms bridged by 3,5-dimethyl­benzoate anions.

Supporting information

cif

Crystallographic Information File (CIF) https://doi.org/10.1107/S1600536807009579/br2029sup1.cif
Contains datablocks global, I

hkl

Structure factor file (CIF format) https://doi.org/10.1107/S1600536807009579/br2029Isup2.hkl
Contains datablock I

CCDC reference: 642920

Key indicators

  • Single-crystal X-ray study
  • T = 294 K
  • Mean [sigma](C-C) = 0.006 Å
  • R factor = 0.061
  • wR factor = 0.172
  • Data-to-parameter ratio = 13.4

checkCIF/PLATON results

No syntax errors found



Alert level C PLAT062_ALERT_4_C Rescale T(min) & T(max) by ..................... 0.95 PLAT094_ALERT_2_C Ratio of Maximum / Minimum Residual Density .... 3.68 PLAT154_ALERT_1_C The su's on the Cell Angles are Equal (x 10000) 900 Deg. PLAT220_ALERT_2_C Large Non-Solvent C Ueq(max)/Ueq(min) ... 3.07 Ratio PLAT222_ALERT_3_C Large Non-Solvent H Ueq(max)/Ueq(min) ... 3.03 Ratio PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for O1 PLAT241_ALERT_2_C Check High Ueq as Compared to Neighbors for O3
Alert level G ABSTM02_ALERT_3_G When printed, the submitted absorption T values will be replaced by the scaled T values. Since the ratio of scaled T's is identical to the ratio of reported T values, the scaling does not imply a change to the absorption corrections used in the study. Ratio of Tmax expected/reported 0.947 Tmax scaled 0.868 Tmin scaled 0.841
0 ALERT level A = In general: serious problem 0 ALERT level B = Potentially serious problem 7 ALERT level C = Check and explain 1 ALERT level G = General alerts; check 1 ALERT type 1 CIF construction/syntax error, inconsistent or missing data 4 ALERT type 2 Indicator that the structure model may be wrong or deficient 2 ALERT type 3 Indicator that the structure quality may be low 1 ALERT type 4 Improvement, methodology, query or suggestion 0 ALERT type 5 Informative message, check

Computing details top

Data collection: SMART (Bruker, 2001); cell refinement: SMART; data reduction: SAINT (Bruker, 2003); program(s) used to solve structure: SHELXS97 (Sheldrick, 1997); program(s) used to refine structure: SHELXL97 (Sheldrick, 1997); molecular graphics: SHELXTL (Sheldrick, 2003); software used to prepare material for publication: SHELXTL.

catena-Poly[[1,10-phenanthroline-κ2N,N')cadmium(II)]- µ-3,5-dimethylbenzoato-κ2O:O'] top
Crystal data top
[Cd(C9H9O2)2(C12H8N2)]Z = 2
Mr = 590.94F(000) = 600
Triclinic, P1Dx = 1.518 Mg m3
Hall symbol: -P 1Mo Kα radiation, λ = 0.71073 Å
a = 7.703 (4) ÅCell parameters from 2290 reflections
b = 11.452 (6) Åθ = 2.5–26.0°
c = 15.370 (9) ŵ = 0.88 mm1
α = 78.182 (9)°T = 294 K
β = 77.170 (9)°Block, colorless
γ = 89.784 (9)°0.22 × 0.20 × 0.16 mm
V = 1292.8 (12) Å3
Data collection top
Bruker SMART CCD area-detector
diffractometer
4564 independent reflections
Radiation source: fine-focus sealed tube3155 reflections with I > 2σ(I)
Graphite monochromatorRint = 0.043
φ and ω scansθmax = 25.0°, θmin = 1.4°
Absorption correction: multi-scan
(SADABS; Sheldrick, 2003)
h = 89
Tmin = 0.889, Tmax = 0.917k = 138
6450 measured reflectionsl = 1818
Refinement top
Refinement on F2Primary atom site location: structure-invariant direct methods
Least-squares matrix: fullSecondary atom site location: difference Fourier map
R[F2 > 2σ(F2)] = 0.061Hydrogen site location: inferred from neighbouring sites
wR(F2) = 0.172H-atom parameters constrained
S = 1.02 w = 1/[σ2(Fo2) + (0.1018P)2]
where P = (Fo2 + 2Fc2)/3
4520 reflections(Δ/σ)max = 0.004
338 parametersΔρmax = 2.11 e Å3
0 restraintsΔρmin = 0.57 e Å3
Special details top

Geometry. All e.s.d.'s (except the e.s.d. in the dihedral angle between two l.s. planes) are estimated using the full covariance matrix. The cell e.s.d.'s are taken into account individually in the estimation of e.s.d.'s in distances, angles and torsion angles; correlations between e.s.d.'s in cell parameters are only used when they are defined by crystal symmetry. An approximate (isotropic) treatment of cell e.s.d.'s is used for estimating e.s.d.'s involving l.s. planes.

Refinement. Refinement of F2 against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F2, conventional R-factors R are based on F, with F set to zero for negative F2. The threshold expression of F2 > σ(F2) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F2 are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger.

Fractional atomic coordinates and isotropic or equivalent isotropic displacement parameters (Å2) top
xyzUiso*/Ueq
Cd10.25015 (8)0.11441 (5)0.99996 (4)0.0249 (2)
O10.1183 (4)0.0183 (2)1.10999 (19)0.0422 (7)
O20.0388 (4)0.1583 (2)1.07539 (19)0.0366 (7)
O30.3833 (4)0.0431 (2)0.88954 (19)0.0434 (8)
O40.5405 (4)0.1172 (2)0.92428 (19)0.0368 (7)
N10.1251 (4)0.2569 (3)1.0789 (2)0.0263 (7)
N20.3754 (4)0.2998 (3)0.9209 (2)0.0262 (7)
C10.0345 (5)0.1175 (3)1.1280 (3)0.0255 (8)
C20.0266 (5)0.1926 (3)1.2217 (2)0.0253 (8)
C30.1480 (5)0.1711 (3)1.2718 (3)0.0343 (9)
H30.23260.10851.24760.041*
C40.1457 (6)0.2413 (4)1.3572 (3)0.0432 (11)
C50.0155 (7)0.3306 (4)1.3934 (3)0.0484 (12)
H50.01120.37661.45130.058*
C60.1108 (6)0.3544 (4)1.3456 (3)0.0443 (11)
C70.1019 (5)0.2847 (3)1.2593 (3)0.0345 (9)
H70.18340.29981.22600.041*
C80.2817 (8)0.2175 (6)1.4089 (4)0.0778 (18)
H8A0.24730.26171.47070.117*
H8B0.28880.13371.40850.117*
H8C0.39600.24191.38040.117*
C90.2540 (8)0.4518 (5)1.3881 (4)0.0783 (18)
H9A0.34950.43961.35670.118*
H9B0.29880.44971.45120.118*
H9C0.20490.52801.38340.118*
C100.4661 (5)0.0471 (3)0.8716 (3)0.0260 (8)
C110.4706 (5)0.0730 (3)0.7788 (3)0.0265 (8)
C120.5965 (5)0.1461 (3)0.7415 (3)0.0327 (9)
H120.68130.17790.77330.039*
C130.5980 (6)0.1727 (4)0.6573 (3)0.0407 (10)
C140.4677 (6)0.1258 (4)0.6116 (3)0.0457 (11)
H140.46660.14400.55550.055*
C150.3397 (6)0.0526 (4)0.6476 (3)0.0403 (10)
C160.3455 (5)0.0255 (3)0.7307 (3)0.0324 (9)
H160.26330.02570.75480.039*
C170.7387 (8)0.2529 (5)0.6165 (4)0.0710 (17)
H17A0.78900.29850.66390.106*
H17B0.83110.20440.57140.106*
H17C0.68440.30620.58850.106*
C180.1954 (7)0.0059 (5)0.5992 (3)0.0672 (16)
H18A0.08340.04580.63210.101*
H18B0.22340.02070.53850.101*
H18C0.18730.07840.59630.101*
C190.4968 (5)0.3200 (4)0.8435 (3)0.0361 (10)
H190.53810.25510.81820.043*
C200.5667 (6)0.4347 (4)0.7972 (3)0.0475 (12)
H200.65240.44550.74270.057*
C210.5060 (6)0.5293 (4)0.8341 (3)0.0432 (11)
H210.54970.60610.80430.052*
C220.3793 (5)0.5126 (3)0.9161 (3)0.0323 (9)
C230.3098 (6)0.6067 (4)0.9607 (4)0.0463 (12)
H230.35060.68490.93380.056*
C240.1892 (7)0.5860 (4)1.0391 (4)0.0472 (12)
H240.14850.64971.06600.057*
C250.1206 (5)0.4675 (3)1.0832 (3)0.0336 (10)
C260.0062 (6)0.4396 (4)1.1657 (3)0.0441 (11)
H260.05110.50031.19520.053*
C270.0648 (6)0.3244 (4)1.2033 (3)0.0474 (12)
H270.14860.30531.25840.057*
C280.0046 (5)0.2356 (4)1.1567 (3)0.0369 (10)
H280.03660.15711.18200.044*
C290.1836 (5)0.3720 (3)1.0421 (3)0.0254 (8)
C300.3161 (5)0.3947 (3)0.9579 (3)0.0256 (8)
Atomic displacement parameters (Å2) top
U11U22U33U12U13U23
Cd10.0355 (4)0.0152 (3)0.0259 (3)0.0016 (2)0.0110 (2)0.0039 (2)
O10.066 (2)0.0227 (15)0.0375 (17)0.0094 (14)0.0173 (15)0.0022 (12)
O20.0444 (17)0.0290 (15)0.0398 (17)0.0009 (12)0.0210 (14)0.0022 (12)
O30.063 (2)0.0368 (17)0.0358 (17)0.0162 (15)0.0154 (15)0.0164 (13)
O40.0453 (17)0.0338 (16)0.0377 (16)0.0054 (13)0.0203 (14)0.0103 (13)
N10.0258 (16)0.0209 (16)0.0327 (18)0.0005 (13)0.0087 (14)0.0049 (13)
N20.0277 (17)0.0203 (16)0.0318 (18)0.0015 (13)0.0086 (14)0.0063 (13)
C10.028 (2)0.0190 (19)0.030 (2)0.0071 (15)0.0095 (17)0.0040 (16)
C20.033 (2)0.0182 (18)0.0259 (19)0.0013 (15)0.0064 (17)0.0061 (15)
C30.035 (2)0.032 (2)0.036 (2)0.0003 (17)0.0084 (18)0.0061 (18)
C40.056 (3)0.043 (3)0.033 (2)0.006 (2)0.017 (2)0.006 (2)
C50.071 (3)0.041 (3)0.026 (2)0.002 (2)0.010 (2)0.0061 (19)
C60.054 (3)0.033 (2)0.039 (3)0.006 (2)0.003 (2)0.0010 (19)
C70.039 (2)0.028 (2)0.036 (2)0.0024 (17)0.0107 (19)0.0026 (18)
C80.093 (5)0.092 (5)0.058 (4)0.001 (4)0.047 (3)0.004 (3)
C90.091 (5)0.068 (4)0.060 (4)0.037 (3)0.010 (3)0.015 (3)
C100.029 (2)0.0208 (19)0.031 (2)0.0011 (16)0.0092 (17)0.0088 (16)
C110.032 (2)0.0178 (18)0.028 (2)0.0015 (15)0.0025 (17)0.0057 (15)
C120.036 (2)0.027 (2)0.036 (2)0.0071 (17)0.0090 (18)0.0057 (18)
C130.051 (3)0.036 (2)0.035 (2)0.011 (2)0.004 (2)0.0132 (19)
C140.059 (3)0.052 (3)0.029 (2)0.004 (2)0.006 (2)0.019 (2)
C150.045 (3)0.044 (3)0.032 (2)0.002 (2)0.012 (2)0.004 (2)
C160.033 (2)0.033 (2)0.031 (2)0.0060 (17)0.0057 (18)0.0088 (18)
C170.092 (4)0.072 (4)0.047 (3)0.036 (3)0.000 (3)0.025 (3)
C180.057 (3)0.104 (5)0.047 (3)0.022 (3)0.025 (3)0.017 (3)
C190.033 (2)0.035 (2)0.039 (2)0.0015 (18)0.0038 (19)0.0098 (19)
C200.048 (3)0.047 (3)0.040 (3)0.011 (2)0.004 (2)0.001 (2)
C210.044 (3)0.028 (2)0.054 (3)0.0101 (19)0.017 (2)0.008 (2)
C220.031 (2)0.020 (2)0.049 (3)0.0029 (16)0.022 (2)0.0019 (17)
C230.056 (3)0.025 (2)0.074 (4)0.012 (2)0.045 (3)0.016 (2)
C240.056 (3)0.031 (2)0.074 (4)0.014 (2)0.047 (3)0.019 (2)
C250.034 (2)0.031 (2)0.048 (3)0.0116 (17)0.023 (2)0.0191 (19)
C260.045 (3)0.041 (3)0.058 (3)0.018 (2)0.018 (2)0.029 (2)
C270.047 (3)0.053 (3)0.041 (3)0.012 (2)0.000 (2)0.017 (2)
C280.033 (2)0.035 (2)0.041 (3)0.0045 (18)0.006 (2)0.0085 (19)
C290.0249 (19)0.0190 (19)0.038 (2)0.0068 (15)0.0157 (17)0.0094 (16)
C300.0240 (19)0.0200 (19)0.037 (2)0.0003 (15)0.0165 (17)0.0046 (16)
Geometric parameters (Å, º) top
Cd1—O32.094 (3)C11—C161.386 (5)
Cd1—O12.097 (3)C12—C131.386 (6)
Cd1—O4i2.193 (3)C12—H120.9300
Cd1—O2ii2.200 (3)C13—C141.394 (6)
Cd1—N12.311 (3)C13—C171.530 (6)
Cd1—N22.313 (3)C14—C151.386 (6)
O1—C11.258 (4)C14—H140.9300
O2—C11.245 (4)C15—C161.384 (6)
O2—Cd1ii2.200 (3)C15—C181.508 (6)
O3—C101.259 (4)C16—H160.9300
O4—C101.251 (4)C17—H17A0.9600
O4—Cd1i2.193 (3)C17—H17B0.9600
N1—C281.320 (5)C17—H17C0.9600
N1—C291.359 (5)C18—H18A0.9600
N2—C191.319 (5)C18—H18B0.9600
N2—C301.359 (4)C18—H18C0.9600
C1—C21.508 (5)C19—C201.405 (6)
C2—C31.387 (5)C19—H190.9300
C2—C71.389 (5)C20—C211.359 (6)
C3—C41.389 (6)C20—H200.9300
C3—H30.9300C21—C221.390 (6)
C4—C51.374 (6)C21—H210.9300
C4—C81.505 (6)C22—C301.409 (5)
C5—C61.401 (6)C22—C231.433 (6)
C5—H50.9300C23—C241.326 (7)
C6—C71.388 (6)C23—H230.9300
C6—C91.510 (6)C24—C251.432 (6)
C7—H70.9300C24—H240.9300
C8—H8A0.9600C25—C261.397 (6)
C8—H8B0.9600C25—C291.404 (5)
C8—H8C0.9600C26—C271.362 (6)
C9—H9A0.9600C26—H260.9300
C9—H9B0.9600C27—C281.399 (6)
C9—H9C0.9600C27—H270.9300
C10—C111.508 (5)C28—H280.9300
C11—C121.383 (5)C29—C301.435 (5)
O3—Cd1—O1112.22 (12)C11—C12—C13120.9 (4)
O3—Cd1—O4i101.33 (12)C11—C12—H12119.5
O1—Cd1—O4i86.70 (12)C13—C12—H12119.5
O3—Cd1—O2ii86.75 (12)C12—C13—C14118.5 (4)
O1—Cd1—O2ii100.97 (12)C12—C13—C17120.4 (4)
O4i—Cd1—O2ii165.97 (10)C14—C13—C17121.1 (4)
O3—Cd1—N1158.37 (12)C15—C14—C13121.8 (4)
O1—Cd1—N188.80 (12)C15—C14—H14119.1
O4i—Cd1—N184.29 (10)C13—C14—H14119.1
O2ii—Cd1—N184.14 (11)C16—C15—C14118.0 (4)
O3—Cd1—N288.25 (12)C16—C15—C18120.7 (4)
O1—Cd1—N2158.85 (11)C14—C15—C18121.3 (4)
O4i—Cd1—N283.95 (11)C15—C16—C11121.6 (4)
O2ii—Cd1—N284.87 (11)C15—C16—H16119.2
N1—Cd1—N271.45 (11)C11—C16—H16119.2
C1—O1—Cd1141.8 (3)C13—C17—H17A109.5
C1—O2—Cd1ii139.7 (2)C13—C17—H17B109.5
C10—O3—Cd1141.5 (3)H17A—C17—H17B109.5
C10—O4—Cd1i139.6 (3)C13—C17—H17C109.5
C28—N1—C29117.7 (3)H17A—C17—H17C109.5
C28—N1—Cd1125.6 (3)H17B—C17—H17C109.5
C29—N1—Cd1116.7 (2)C15—C18—H18A109.5
C19—N2—C30118.3 (3)C15—C18—H18B109.5
C19—N2—Cd1125.3 (3)H18A—C18—H18B109.5
C30—N2—Cd1116.4 (2)C15—C18—H18C109.5
O2—C1—O1125.9 (4)H18A—C18—H18C109.5
O2—C1—C2118.3 (3)H18B—C18—H18C109.5
O1—C1—C2115.7 (3)N2—C19—C20123.2 (4)
C3—C2—C7118.9 (4)N2—C19—H19118.4
C3—C2—C1120.5 (3)C20—C19—H19118.4
C7—C2—C1120.6 (3)C21—C20—C19118.3 (4)
C2—C3—C4121.3 (4)C21—C20—H20120.9
C2—C3—H3119.3C19—C20—H20120.9
C4—C3—H3119.3C20—C21—C22120.6 (4)
C5—C4—C3118.6 (4)C20—C21—H21119.7
C5—C4—C8121.3 (4)C22—C21—H21119.7
C3—C4—C8120.1 (4)C21—C22—C30117.4 (4)
C4—C5—C6121.9 (4)C21—C22—C23124.5 (4)
C4—C5—H5119.1C30—C22—C23118.1 (4)
C6—C5—H5119.1C24—C23—C22122.2 (4)
C7—C6—C5118.1 (4)C24—C23—H23118.9
C7—C6—C9121.4 (4)C22—C23—H23118.9
C5—C6—C9120.5 (4)C23—C24—C25121.2 (4)
C6—C7—C2121.1 (4)C23—C24—H24119.4
C6—C7—H7119.4C25—C24—H24119.4
C2—C7—H7119.4C26—C25—C29117.1 (4)
C4—C8—H8A109.5C26—C25—C24124.1 (4)
C4—C8—H8B109.5C29—C25—C24118.9 (4)
H8A—C8—H8B109.5C27—C26—C25120.5 (4)
C4—C8—H8C109.5C27—C26—H26119.7
H8A—C8—H8C109.5C25—C26—H26119.7
H8B—C8—H8C109.5C26—C27—C28118.2 (4)
C6—C9—H9A109.5C26—C27—H27120.9
C6—C9—H9B109.5C28—C27—H27120.9
H9A—C9—H9B109.5N1—C28—C27123.8 (4)
C6—C9—H9C109.5N1—C28—H28118.1
H9A—C9—H9C109.5C27—C28—H28118.1
H9B—C9—H9C109.5N1—C29—C25122.8 (4)
O4—C10—O3125.8 (3)N1—C29—C30117.5 (3)
O4—C10—C11118.0 (3)C25—C29—C30119.7 (3)
O3—C10—C11116.1 (3)N2—C30—C22122.2 (4)
C12—C11—C16119.1 (4)N2—C30—C29117.9 (3)
C12—C11—C10120.8 (3)C22—C30—C29119.9 (3)
C16—C11—C10120.1 (3)
O3—Cd1—O1—C135.1 (5)O4—C10—C11—C1220.2 (5)
O4i—Cd1—O1—C1136.0 (4)O3—C10—C11—C12161.3 (4)
O2ii—Cd1—O1—C155.9 (4)O4—C10—C11—C16158.4 (4)
N1—Cd1—O1—C1139.6 (4)O3—C10—C11—C1620.1 (5)
N2—Cd1—O1—C1160.2 (4)C16—C11—C12—C130.4 (6)
O1—Cd1—O3—C1033.7 (5)C10—C11—C12—C13178.2 (4)
O4i—Cd1—O3—C1057.3 (5)C11—C12—C13—C141.1 (6)
O2ii—Cd1—O3—C10134.3 (5)C11—C12—C13—C17179.5 (4)
N1—Cd1—O3—C10160.6 (4)C12—C13—C14—C150.9 (7)
N2—Cd1—O3—C10140.8 (4)C17—C13—C14—C15179.7 (5)
O3—Cd1—N1—C28160.0 (3)C13—C14—C15—C160.8 (7)
O1—Cd1—N1—C286.7 (3)C13—C14—C15—C18177.7 (5)
O4i—Cd1—N1—C2893.5 (3)C14—C15—C16—C112.3 (6)
O2ii—Cd1—N1—C2894.4 (3)C18—C15—C16—C11176.2 (4)
N2—Cd1—N1—C28179.0 (3)C12—C11—C16—C152.1 (6)
O3—Cd1—N1—C2921.0 (5)C10—C11—C16—C15176.5 (4)
O1—Cd1—N1—C29172.3 (3)C30—N2—C19—C200.4 (6)
O4i—Cd1—N1—C2985.5 (3)Cd1—N2—C19—C20178.9 (3)
O2ii—Cd1—N1—C2986.6 (3)N2—C19—C20—C210.1 (7)
N2—Cd1—N1—C290.0 (2)C19—C20—C21—C220.6 (7)
O3—Cd1—N2—C197.1 (3)C20—C21—C22—C300.7 (6)
O1—Cd1—N2—C19158.7 (3)C20—C21—C22—C23179.0 (4)
O4i—Cd1—N2—C1994.5 (3)C21—C22—C23—C24179.7 (4)
O2ii—Cd1—N2—C1994.0 (3)C30—C22—C23—C240.1 (6)
N1—Cd1—N2—C19179.5 (3)C22—C23—C24—C250.6 (7)
O3—Cd1—N2—C30172.2 (2)C23—C24—C25—C26180.0 (4)
O1—Cd1—N2—C3022.0 (5)C23—C24—C25—C290.2 (6)
O4i—Cd1—N2—C3086.2 (2)C29—C25—C26—C270.2 (6)
O2ii—Cd1—N2—C3085.3 (2)C24—C25—C26—C27180.0 (4)
N1—Cd1—N2—C300.2 (2)C25—C26—C27—C280.5 (7)
Cd1ii—O2—C1—O160.8 (6)C29—N1—C28—C270.5 (6)
Cd1ii—O2—C1—C2120.2 (3)Cd1—N1—C28—C27178.5 (3)
Cd1—O1—C1—O220.7 (7)C26—C27—C28—N10.8 (7)
Cd1—O1—C1—C2158.4 (3)C28—N1—C29—C250.2 (5)
O2—C1—C2—C3159.8 (3)Cd1—N1—C29—C25179.3 (3)
O1—C1—C2—C319.4 (5)C28—N1—C29—C30179.4 (3)
O2—C1—C2—C720.0 (5)Cd1—N1—C29—C300.3 (4)
O1—C1—C2—C7160.8 (4)C26—C25—C29—N10.6 (6)
C7—C2—C3—C41.5 (6)C24—C25—C29—N1179.7 (3)
C1—C2—C3—C4178.3 (4)C26—C25—C29—C30179.0 (3)
C2—C3—C4—C52.5 (6)C24—C25—C29—C300.8 (5)
C2—C3—C4—C8178.6 (4)C19—N2—C30—C220.3 (5)
C3—C4—C5—C61.7 (7)Cd1—N2—C30—C22179.0 (3)
C8—C4—C5—C6179.4 (5)C19—N2—C30—C29179.8 (3)
C4—C5—C6—C70.0 (7)Cd1—N2—C30—C290.5 (4)
C4—C5—C6—C9178.9 (5)C21—C22—C30—N20.2 (5)
C5—C6—C7—C21.0 (6)C23—C22—C30—N2179.5 (3)
C9—C6—C7—C2177.9 (4)C21—C22—C30—C29179.3 (3)
C3—C2—C7—C60.3 (6)C23—C22—C30—C291.0 (5)
C1—C2—C7—C6179.9 (4)N1—C29—C30—N20.5 (5)
Cd1i—O4—C10—O359.2 (6)C25—C29—C30—N2179.1 (3)
Cd1i—O4—C10—C11122.4 (3)N1—C29—C30—C22179.0 (3)
Cd1—O3—C10—O422.5 (7)C25—C29—C30—C221.4 (5)
Cd1—O3—C10—C11155.9 (3)
Symmetry codes: (i) x+1, y, z+2; (ii) x, y, z+2.
 

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